Aluminum Base Research Articles

Detecting bubbles in world aluminum prices: Evidence from GSADF test

The aim of this research is to assess the existence of multiple bubbles in the global aluminum market by employing the Generalized Supremum Augmented Dickey-Fuller (GSADF) methodology. This method offers practical time series analysis tools for identifying periods of rapid price escalation, followed by subsequent collapses. Findings indicate the identification of six explosive bubbles occurring between January 1980 and March 2023, during which the aluminum price strayed from its underlying fundamental value. Additionally, this finding is consistent with the asset pricing model, which generally considers both fundamental and bubble components. Based on the empirical results, the aluminum price bubbles are positively influenced by the copper price, GDP, the U. S dollar index, industrialization of China, China’s urbanization rate, whereas the global aluminum production, oil price, and base metal price index have a negative explanatory effect on the aluminum price bubbles. To effectively stabilize the international aluminum price, policymakers are suggested to be vigilant in identifying bubble episodes and monitoring their progression. Additionally, regulatory authorities should implement measures to curb excessive speculative activity during periods of extreme market volatility, thereby mitigating excessive price fluctuations and the formation of aluminum bubbles.

Versatile hybrid magnetic core silver-shell (Fe3O4@PEI@Ag) microspheres based SERS substrates for detection of organic dyes pollutant

In recent years, the development of highly sensitive and versatile substrates for Surface-Enhanced Raman Scattering (SERS) has become pivotal in environmental monitoring. This study introduces a hybrid SERS substrate designed to enhance the detection and discrimination of organic dyes in aqueous environments. In this report, we present silver shell magnetic core (Fe3O4@PEI@Ag) microspheres as a versatile SERS substrate for the detection and differentiation of organic dyes, specifically malachite green (MG), crystal violet (CV), Rhodamine 6G (R6G), and Safranin O (S.O), which are often overlooked water pollutants. The core-shell structure of Fe3O4@PEI@Ag microspheres have been synthesized via seed-mediated growth method. The microspheres, integrates a magnetic core of iron oxide (Fe3O4) through a polymeric layer of polyethyleneimine (PEI) with silver shell (Ag), are optimized to act as magnetic separator and show SERS activity. The SEM measurements confirm the spherical shape of grown nano-particles whereas magnetization experiments confirm the presence of magnetic cores as well non-magnetic layers coating in the end products. These microspheres with aluminium (Al) base combination demonstrate high SERS sensitivity with enhancement factor of 1 × 105, 5.6 × 106, 6.4 × 106, and 4.2 × 105 for MG, CV, R6G, and S.O respectively. The detection limits have been found in the range between 10–8–10–10 for all four dyes. A linear relationship between Raman intensity and concentrations of dyes make it suitable for quantitative analysis of unknown concentration. Principal component analysis (PCA), a multivariate analysis has been adopted to discrimination of dyes. These dyes have been effectively detected quantitative in tap water to express substrate's suitability in real-world application. Their dual functionality, as SERS-active substrate and as magnetic separator, enhances their utility in real-world applications such as organic contaminants in aquatic environments.

Characterization of the Aluminium-Based Metal Foam Properties for Automotive Applications

AbstractMetal foams are solids where the gas is filled inside uniformly in the metal matrix. Blowing agent supplies air inside the parent metal, and metal foam has emerged to be a promising material because of its low density, high absorption capacity, low thermal conductivity and high strength which finds its huge applications in automobile components. The present work deals with the application of the aluminium metal foam with different densities 200 and 400 kg/m3 in automobiles. Various tests such as toughness, hardness, bending and compression are carried out for four chosen densities, and the values are compared with the aluminium base metal. The result showed that the hardness value increased significantly by 24.48% with the rise in the density from 200 to 400 kg/m3. Maximum modulus of resilience for the low-density specimen is found to be 2.21 MJ/m3. Surface topography showed irregular pore shapes with discontinuity, resulting in a loss of cell integrity with the neighbouring cell walls. This affected the performance of the foam significantly. Thermal experiments were carried out to determine the thermal conductivity where thermal conductivity increased by 122% with the rise in the density from 200 to 400 kg/m3. Based on the results, it is concluded that aluminium foam with density 400 kg/m3 can be recommended for use in automobile applications due to its lightweight properties, which contribute to improving fuel efficiency, impact absorption capacity and the vehicle’s speed. Additionally, the air trapped within the foam cells serves as a sound barrier and insulator in cars.

Experimental and numerical study of a linear Fresnel solar collector attached with dual axis tracking system

The demand for an alternative to fossil fuel energy is increasing as environmental and economic challenges rise. The linear Fresnel solar collector is considered a promising option for obtaining thermal energy at medium and high temperatures. A linear Fresnel solar collector consists of a number of mirror strips that are used to focus solar beam radiation toward a line receiver. This study aims to obtain a clear evaluation of the thermal performance of a linear Fresnel solar collector through design, manufacture, and experimental testing under different outdoor conditions in Baghdad over various periods. There have been tests on April 1 and 22, as well as May 8 and 27, using water as the working fluid. The solar collector used is an aluminum base measuring 200 cm in length and 150 cm in width on which 14 mirror strips from each side are fixed. The receiver (absorber copper tube) has a length of 200 cm and a height of 60 cm from the base. The solar collector is provided with a dual-axis tracking system (North-South and East-West) for ensuring that the solar concentrator faces the sun at normal incidence during all daytime hours. The best thermal performance of the solar collector was observed on May 27, where the average useful energy, thermal and exergy efficiency reached 1042.61 W, 39.15 %, and 1.31 %, respectively. The present study also included a numerical analysis done using computational fluid dynamics (CFD) to verify the experimental results. The numerical results confirmed the validity of the experimental results.

An Experimental Investigation Of Local Thermo-Fluidic Heat Transfer In A U-Shaped Mini-Channel Sink

This study investigates experimentally a heated U-shaped mini-channel heat sink using Infrared Thermography and Particle Image Velocimetry for a water coolant flow of Reynolds numbers of 280, 650, and 1350 (based on the hydraulic channel diameter). The choice of this cell geometry is based on its role as a simplified unit of a serpentine heat exchanger, which is proved to be one of the most promising for cooling processes. The use of the infrared camera allows the detection of temperature fields on top of the external surface of the cell. Therefore, aiming to derive the temperature distribution on the channel roof, a dedicated transfer function is implemented. Moreover, we employed the lumped capacitance model for thermal analysis on both infrared measurements and thermocouple data. The latter are recorded to capture the cooling process of the aluminium base and water temperature at the end of the outlet tube. As a result, thermal transient rate, cooling magnitude and equilibrium temperature are obtained. These parameters indicate that higher Reynolds numbers correspond to increased thermal transient rates, enhanced cooling effects, and lower equilibrium temperatures. A non-uniform distribution of heat transfer along the channel is reported, with the most efficient cooling area localized close to the first 90-degree corner. These findings are consistent with numerical simulations and previous experimental observations. PIV results reveal the presence of two fluid acceleration zones following both 90-degree corners, which contribute to improve the water cooling ability in their respective regions. Additionally, the formation of two recirculating bubbles is reported at the inner wall from corners vertices, whose intensity is dependent on Reynolds number, pushing the main flow towards the outer channel wall and reducing the local heat transfer. Turbulent kinetic energy distributions are also investigated, pointing out the presence of intense areas that better match with regions of minimum equilibrium temperature than maximum velocity zones. This suggests the presence of local turbulent unsteadiness and three-dimensional phenomena, which contributes significantly to cooling enhancement.

Development of Aluminium Base Anode for Cathodic Protection of Steel

Development of Aluminium Base Anode for Cathodic Protection of Steel

Ballistic resistance of 7XXX laminate aluminum alloy plates and base alloys subjected to different projectiles

The ballistic impact of two 7XXX aluminum alloys, 7A52-T6 and 7A62-T6, as well as their combination in a 7B52 laminate plate, was simulated and experimentally tested. Three types of projectiles were utilized hard ogival nosed, hard blunt nosed, and 304 steel core projectiles to investigate the ballistic resistance and failure mechanisms of the aluminum alloy targets. Additionally, an existing modified Gurson-Tvergaard-Needleman (GTN) model incorporating shear, void growth, and spalling failure mechanisms, was employed to simulate the ballistic impact process, utilized to analyze energy dissipation during impact. The results reveal that the 7A52 alloy only experiences ductile hole expansion failure, whereas the 7A62 high-strength aluminum alloy undergoes spalling and fragmentation subsequent to penetration, leading to potential impact hazards. Due to its backing layer being the highly ductile 7A52 alloy, the laminate plate will not produce fragments after penetration. The improved GTN model provided better predictions of the impact failure modes of the aluminum alloys. Concerning impact performance, when subjected to hard ogival projectiles, the laminate alloy did not enhance material impact resistance. However, when impacted by blunt-nosed projectiles, the laminate alloy exhibited a 27 % improvement over the 7A52 plate and an 11.9 % increase over the 7A62 plate. Furthermore, when impacted by 304 steel core ogival projectiles, the laminate alloy demonstrated over a 41.3 % improvement compared to the 7A52 plate and over a 15.5 % increase compared to the 7A62 plate. The laminate plate's high ballistic performance was attributed to the increased plastic deformation energy after spalling failure, while ensuring high energy absorption during ductile hole expansion penetration.

Preparation of biomimetic reinforced modified carbon fiber composites and study of their friction properties

Because aluminum-based parts cannot be used for long-term applications in large load-wear environments, nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composites were successfully prepared in this study for that purpose. By adjusting the plating solution ratio, nickel–tungsten was used as a carrier to introduce molybdenum disulfide nanoparticles, forming a nickel–tungsten/molybdenum disulfide composite coating on the surface of carbon fibers. To enhance the interfacial bonding strength between the carbon fiber and aluminum matrix, a laser was employed to induce the formation of a honeycomb-like structure on the surface of the aluminum base. This increased the contact area between the carbon fiber, aluminum matrix, and epoxy resin adhesives, forming a nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composite material. The performance of this composite material was tested and analyzed. The results demonstrated that compared with the carbon fiber/aluminum composite material, the shear strength of the nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composite material was increased by 129.7 %, and the friction coefficient and wear rate were reduced by 54.8 % and 83 %, respectively. Next, investigation of the mechanism underlying the honeycomb structure's contribution to the adhesive strength of the composites and their resistance to shear load revealed that the wear-resistant mechanism of molybdenum disulfide nanoparticles reinforced the nickel–tungsten composite coatings. The preparation and study of nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composites provide a reference for expanding the applications of aluminum-based composite materials to meet the service requirements of complex environments.

Improving bonding strength of medium-thick Al-Cu dissimilar joint by a novel splat cooling assisted double side friction stir welding

To obtain a high-strength medium-thick Al-Cu dissimilar joint, a novel splat cooling assisted double side friction stir welding (SDS-FSW) is proposed. The microstructure and tensile properties of conventional double-side friction stir welding (DS-FSW) and the novel SDS-FSW joints under optimal welding parameters are systematically compared, it shows that the utilization of in-process splat cooling significantly reduces the welding peak temperature and the high-temperature dwell time. The in-process splat cooling causes significant grain refinement in the welding nugget zone (WNZ) of the Al-Cu dissimilar SDS-FSWed joint, it exists the lower recrystallization fraction and the higher KAM value. Although both DS-FSW and SDS-FSW joints fracture at the Al-Cu interface, the DS-FSW joint represents a brittle fracture characteristic, while the SDS-FSW joint represents a mixed ductile-brittle fracture mode. Under the drive of the mechanical stirring of the tool and the welding thermal cycle, the aluminium atoms and copper atoms diffuse to the copper base material and aluminium base material, respectively. Since copper diffuses in aluminium at a higher diffusion rate than aluminium diffuses in copper, and the solubility of copper in aluminium is much smaller than that of aluminium in copper, thus the Al2Cu becomes the first phase with the nucleation and growth. As the welding temperature and time continue to increase, Al2Cu reaches the supersaturation state, and the Al4Cu9 phase is produced between the Cu (Al) and the Al2Cu phase. In the end, the interface forms the stable double-layer IMCs structure (Al2Cu/Al4Cu9). The optimal tensile strength of the SDS-FSWed joint is 159 MPa, which is increased by 42% compared to the DS-FSWed joint at the same welding parameter. This was mainly because in-process splat cooling contributed to forming a thinner IMCs layer at the A-Al-Cu interface. It reveals that the application of in-process splat cooling is a versatile method to thin the IMCs layer at the Al-Cu medium-thick DS-FSW process.

Influence of Tool Pin Profiles on Aluminium Alloy A356 and Ceramic-Based Nanocomposites for Light Weight Structures by Friction Stir Processing

In this research, the main aim is to focus the enhancement of aluminium-based metal matrix composites for improving the attributes of light weight metals, aerospace structures and other tailor blank material properties. By this way, the friction stir processing (FSP) was the suited alternate technique to enhancing the mechanical attributes and superior microstructural amendment in the processed MMCs. Therefore, this study investigates the dispersion of ceramic-based strengthening particles of chromium oxide (Cr2O3) in the aluminium base matrix of A356 alloy. During the processing, the different tool pin sizes having the conical threaded tool pin profiles. Similarly, the tool spinning speed and tool travel speed also varied while in FSP. Before the processing, the A356 alloy was prepared by the grooved surfaces for packing the chromium oxide particles to compose the aluminium metal matrix composites. The tensile strength and hardness was employed to carry out from the friction stir processed A356 alloy with influencing of Cr2O3. The maximum occurred tensile processing parameters are 1500 rpm of spinning speed, 6 mm of tool pin sizes and 90 mm/min of tool travel speed. Similarly, the maximum obtained hardness processing parameter are 2000 rpm of spinning speed, 5 mm of tool pin sizes and 90 mm/min of tool travel speed. A scanning electron microscope was utilized to investigate the dispersed Cr2O3 in the A356 alloy for confirming the refinement grains in the nugget zones of FSPed A356 alloy. The increased grain boundary by the influence of different tool pin sizes was the major reason to produces the better mechanical properties in the processed A356/Cr2O3.

Effect of hydrogen embrittlement on the tribo-mechanical properties of TiN coated aluminium alloys

ABSTRACT In this research, the effects on tribological properties of titanium nitride (TiN) coating by hydrogen embrittlement were investigated. TiN was deposited to about 2.5 μm on aluminium alloy by arc ion plating (AIP). Hydrogen embrittlement was conducted for 3 and 6 h to investigate the dependence of wear properties of the TiN coating on hydrogen embrittlement time. As the hydrogen embrittlement time increased, the surface hardness and the adhesive force with the substrate decreased due to the peeling of the coating. In a ball on disk wear experiment, the hydrogen embrittlement specimens showed an increase in coefficient of friction due to the debris generated by the peeling of the TiN coating. In the 3 h hydrogen embrittlement specimen, the wear track was locally damaged. However, the 6 h hydrogen embrittlement specimen showed that the aluminium base material was exposed while the wear track was damaged as a whole.

Influence of nano-BN inclusion and mechanism involved on aluminium-copper alloy.

Taking advantage of the high specific surface area of the nanoparticles, boron nitride (BN) nanoparticles were incorporated into the semi-solidified aluminium-copper alloy Al-5Cu-Mn (ZL201) system during the casting process, and its properties and enhancement mechanism were studied. The results shown that the BN in the new composite material is more uniformly distributed in the second phase (Al2Cu), which can promote grain refinement and enhance the bonding with the aluminium-based interface, and the formation of stable phases such as AlB2, AlN, CuN, etc. makes the tensile strength and hardness of the material to be significantly improved (8.5%, 10.2%, respectively). The mechanism of the action of BN in Al2Cu was analyzed by establishing an atomic model and after calculation: BN can undergo strong adsorption on the surface of Al2Cu (0 0 1), and the adsorption energy is lower at the bridge sites on the two cut-off surfaces, which makes the binding of BN to the aluminum base more stable. The charge transfer between B, N and each atom of the matrix can promote the formation of strong covalent bonds Al-N, Cu-N and Al-B bonds, which can increase the dislocation density and hinder the grain boundary slip within the alloy.

Effect of Mn and Mg reinforcing particles on physico-mechanical behavior of close-cell Al metal foam for energy absorption material

A solid substance encircled by a three-dimensional network of voids not interconnected with each other is referred to as close-cell metal foam. The work is based on enhancing mechanical properties of aluminum base close-cell metal foam through the addition of reinforcing particles in varying percentages. Closed-cell aluminum foams with the addition of Mn (0.5 wt.%) and Mg (0, 1, 1.5, 2) were successfully prepared by the melt route method. Al-based metal foam’s morphology and mechanical behavior were examined in order to understand the impact of reinforcing elements. From the current work, it is inferred that the addition of reinforcing elements initially helped to increase the compressive strength as found in Foam-1, but further addition of Mg did not have any beneficial effects. It was found that the value of compression strength depends on foam density. The addition of reinforcing elements increases the length of the plateau which in turn increases the value of energy absorption. It is found that proper bonding of reinforcing particles helps in improving energy absorption. From the evaluation, it was found that besides the increase in density and variations in pores uniformity, Al + Mn (0.5wt. %) + Mg (1.5wt. %) Foam (Foam-1) was found to be superior among all other foams. It can also be concluded that by fixing the percentage of Mn by 1 wt%, the best results can be obtained by addition of 1.5 wt. % Mg in the melt. Further addition of Mg shows a detrimental effect on mechanical and physical properties.

Thermodynamic stability analysis of AlxCrMn5MoTi high-entropy alloys for high-temperature applications: A CALPHAD-assisted approach

In lightweight high-entropy alloy development, a titanium- aluminium (TiAl) base matrix is favored for its low density, high strength- to-weight ratio, and excellent corrosion resistance. Multi-component alloys using TiAl have shown stability under high temperatures. This study aimed to develop a high-entropy alloy by adding chromium (Cr), manganese (Mn), and molybdenum (Mo) to the TiAl base matrix, forming an AlxCrMn5MoTi alloy. CALPHAD models were employed to establish phase stability and phase formation rules were used to assess thermodynamic stability. The resulting AlxCrMn5MoTi alloy features a body-centered cubic solid-solution phase, a solidus temperature exceeding 1600°C, a density under 6.2 g/cm³, and a Young's modulus of over 190 GPa. The thermodynamic properties measured include mixing entropy (10.9 to 11.9 J/K), mixing enthalpy (-11.5 to -18.1 kJ/mol), an Omega parameter (Ω) of at least 1.1, an atomic size difference (δ) no greater than 6.6%, and a valence electron concentration (VEC) ranging from 4.89 to 4.83. The AlxCrMn5MoTi alloy shows significant promise for transportation, energy, and industrial applications, meeting the demands for lightweight, high-temperature, and corrosion- resistant materials.

A COMPREHENSIVE REVIEW ON THE NON-DESTRUCTIVE TEST FOR POLYMER MATRIX COMPOSITE

Polymer matrix composite (PMC) is widely applied in structural engineering mainly due to its high strength-to-weight ratio. Of many benefits, the transportation industry uses this type of material mainly due to its high strength-to-weight ratio. In many cases, this strength-to-weight ratio is higher than aluminum or steel base materials. Its manufacturing and fabrication, however, are challenging. For this reason, destructive and non-destructive tests to control product quality during the manufacturing process are worked out. The non-destructive test delivers many benefits since the finished product does not. This paper discusses the benefits of polymer matrix composite application in the structural engineering. In addition, this work also outlined the key parameters and comparison of various non-destructive tests applied for the PMC.

Microstructure and Mechanical Properties of Friction Stir Lap Welding Joint of Al/CU Dissimilar Metals

In this paper, 5083 aluminum alloy and T2 copper were selected for the friction stir lap welding test. The effect of intermetallic compounds on the microstructure and properties of Al/Cu dissimilar metal lap joints was studied. The results showed that the circulating Al/Cu composite structure was formed on the advancing side of the lap joint, and the Al/Cu staggered hook-like structure and copper-rich region were generated on the retreating side. There was no typical ‘onion ring’ structure in the joint. Element diffusion occurred at the interface of the joint, forming a thin and uniform interfacial layer of Al/Cu intermetallic compounds, thus achieving a well-metallurgical bond at the Al/Cu interface. There were the intermetallic compounds Al2Cu and Al4Cu9, without AlCu, in the lap joint. In addition, dynamic recrystallization occurred in the nugget zone, and higher dislocation density and dislocation entanglement were generated, which enhanced the deformation resistance in the nugget zone and increased the joint strength. The tensile test showed that the ductile–brittle mixed fracture occurred in the heat-affected zone on the advancing side of the aluminum plate, and the fracture had necking. The failure load of the lap joint was 4350 ± 30 N, about 80% of the aluminum base metal. The elongation of the Al/Cu dissimilar lap joint tensile specimen was 2.5%.

Additive manufacturing of a lightweight Al-Ca alloy by direct energy deposition and laser powder bed fusion

Abstract High strength and low density materials are needed to achieve lightweight design of components. Aluminum base metals alloyed with calcium are of potential interest because of the low density of calcium and its abundance. The additive manufacturing of dense and crack free samples out of an Al-10 wt.% Ca (Al-10Ca) alloy is presented. Both laser-based direct energy deposition (DED-LB) and laser powder bed fusion (LPBF) processes were applied to manufacture sample material. Preheating of the substrate plate is needed in LPBF to receive crack free samples. An analysis of the microstructure shows an Al-Al4Ca lamellar eutectic.

Evaluation of Laser Lap Weldability between the Titanium Alloy Ti-6Al-4V and Aluminum Alloy 6060-T6

This work investigates laser weldability between non-ferrous dissimilar metallic materials, specifically the aluminum 6060-T6 alloy and titanium Ti-6Al-4V. These materials are used in several engineering applications, including aerospace. In a simple lap joint configuration, these were welded with a pulsed Nd:YAG laser, with direct incidence on the titanium piece. Preheating and post-weld heating were introduced to mitigate cracking issues. Based on the primary experiments, the main variables were the peak laser power, which varied between 60 and 70%, and the number of beads (a single bead and double beads). The quality of the welds was assessed via uniaxial tensile tests, subjecting the joint to shear loading. Additionally, SEM micrographs were obtained to analyze the quality of the fusion between the dissimilar alloys. The higher strength of the welded samples achieved was 90 MPa, which is close to the reported value for the aluminum base material. A fracture occurred near the weld bead in the heat-affected zone (HAZ). The observed microporosities and cracks explain the lower value as compared to the base material. Although these were mitigated through the thermal cycle strategy employed and the shielding gas, they were not entirely avoided.

Static and Fatigue Characterization of Adhesive T-Joints Involving Different Adherends

It is very important to understand the damage mechanisms as well as the mechanical response of T-joints involving different materials on the base plate. For this purpose, two configurations were studied. In one, the joint is composed of a base plate and a T-element, both in Al 6063-T5, while in the other one, the aluminum base plate was replaced by a glass fiber composite. Finally, each configuration was divided into two batches, where in one, the elements were bonded with a stiff adhesive (Araldite® AV 4076-1/HY 4076) while in the other, a more ductile adhesive (Araldite® AW 106/HV 953 U) was used. The static and fatigue strength of all configurations was evaluated in bending. In all cases, the damage occurred at the end of the T-element, where a crack appeared and propagated toward the interior of the T-joint. The bending strength is highest for joints involving aluminum and the ductile adhesive, which is 2.8 times higher than the same configuration involving composite base plates and 1.7 times higher than that using the stiff adhesive. Finally, the highest fatigue lives were obtained for T-joints involving Al 6063-T5 base plates, and regardless of the base plate material, the ductile adhesive promoted the highest fatigue strength.

Simultaneous immobilizations of soluble phosphorus and fluorine in phosphogypsum by milling with calcareous and aluminiferous samples: Reaction products and immobilization performances

Phosphogypsum (PG) is a by-product of phosphorus chemical industry, which contains a large amount of soluble phosphorus and fluorine impurities to pose a great ecological risk to the environment and human health. In this study, we proposed one-step mechanical ball milling as a cleaner operation for simultaneous immobilization of phosphorus and fluorine in PG waste with different calcareous and aluminiferous immobilization reagents. The results show that, the remaining soluble PO43− and F− concentrations could reduce to 0.056 and 0.99 mg/L in PG-Ca(OH)2–Al(OH)3 system, respectively, when the total mass ratio at 5% of Ca(OH)2 and Al(OH)3 was added to PG. Furthermore, mineralogical and chemical evidence indicated that, the main immobilization mechanisms of soluble phosphorus and fluorine in PG are as follows: a) the transformation of co-crystal phosphorus (Ca((SO4)x,(HPO)4)1-x), CSHP) into insoluble phosphorus during milling process, b) the exchange of F− by OH− in Katoite formed by Ca(OH)2 and Al(OH)3, c) the formation of calcium aluminum fluorosilicate and hydroxyapatite due to the increased activity of silicate. Additionally, when using kaolinite and calcium carbonate slag as calcareous and aluminiferous alternative reagents, the concentrations of PO43− and F− were 0.056 and 7.42 mg/L in leaching solution, within the permitted level for the GB8978-1996 (0.5 mg/L for PO43−, 10.0 mg/L for F−). The application of calcium base, aluminum base solid wastes could provide a potential solution for large-capacity disposal of industrial waste and sustainable utilization of PG.