Altered Basalts Research Articles

Uncovering the oxic-suboxic microenvironment change in seamount flank through authigenic clay minerals in basaltic substrate of ferromanganese crust, Magellan seamount

In low-temperature ocean environments, basalt alteration by seawater precipitates authigenic clay minerals that serve as proxies for reconstructing paleo-ocean conditions because they reflect surrounding oxic-suboxic conditions. In this study, alteration rims on basaltic substrate associated with ferromanganese (Fe-Mn) crust from the Magellan seamount KC-7 were identified by microscopic analyses. Mineralogical and geochemical analyses indicate that the alteration rims contain K-enriched Fe-smectite and glauconite which suggest that seawater-basalt interaction occurred under oxic conditions and in the presence of organic-rich suboxic conditions, respectively. These disparate environmental conditions suggest that the environment changed before and after Fe-Mn crusts formed. During the Cenozoic hyperthermal events, oxygen-rich bottom water was supplied by upwelling driven by the geomorphological influence of the seamounts, which may have led to basalt alteration. The K-enriched Fe-smectites, which indicate oxic condition, formed via seawater-basalt interactions before the Fe-Mn crust incrustation. Later, during the Eocene, the opening of the Drake Passage enhanced the supply of oxygen-rich seawater to the Magellan Seamounts, thereby enabling the formation of hydrogenetic Fe-Mn crust. After the incrustation of seamount flanks with Fe-Mn crusts, the carbonate fluorapatite (CFA), a product of the global phosphatization event, filled the pores in the Fe-Mn crusts during Oi-1 glaciation. As a result, seawater-basalt interactions decreased and led to suboxic conditions, in which glauconite formed as organic matter was remineralized under the organic-rich conditions in the basaltic substrate. This authigenic clay mineral formation sequence suggests that changes in ocean circulation and subsequent changes in the oxic-suboxic conditions in the basaltic substrate occurred on the western Pacific seamount KC-7.

Basalt Alteration in a CO2–SO2 Atmosphere: Implications for Surface Processes on Venus

AbstractVenus' surface and interior dynamics remain largely unconstrained, due in great part to the major obstacles to exploration imposed by its 470°C, 90 bar surface conditions and its thick, opaque atmosphere. Flyby and orbiter‐based thermal emission data provide opportunities to characterize the surface composition of Venus. However, robust interpretations of such data depend on understanding interactions between the planet's surface basaltic rocks and its caustic carbon dioxide (CO2)‐dominant atmosphere, containing trace amounts of sulfur dioxide (SO2). Several studies, using remote sensing, thermodynamic modeling, and laboratory experiments, have placed constraints on basaltic alteration mineralogy and rates. However, constraints on the effects of SO2‐bearing reactions on basalts with diverse compositions remain incomplete. Here, we present new data from a series of gas‐solid reaction experiments, in which samples of two basalt compositions were reacted in an SO2‐bearing CO2 atmosphere, at relevant Venus temperatures, pressure, and oxygen fugacity. Reacted specimens were analyzed by scanning electron microscopy and scanning transmission electron microscopy using sample cross‐sections produced with focused ion beam milling. Surface alteration products were characterized, and their abundances estimated; subsurface cation concentrations were mapped to show the depth of alteration. We demonstrate that the initial development of reaction products progresses rapidly over the course of 30‐day runs. Alkaline basalt samples are coated by Na‐sulfate (likely thenardite, Na2SO4) and amorphous calcium carbonate (CaCO3) alteration products, and tholeiitic basalt samples are primarily covered by anhydrite (CaSO4), Fe‐oxide (FexOy: likely magnetite, Fe3O4), and other minor phases. These mineralogies differ from previous experiments in CO2‐only atmospheres.

Y-Ho fractionation during basalt alteration in hydrothermal system: An implication for superchondritic Y/Ho signature recorded in Precambrian banded iron formations

The concentration of rare earth elements (REE) in Precambrian sedimentary rocks is widely used to estimate their depositional environment. Specifically, superchondritic Y/Ho value is a powerful indicator for determining whether a sedimentary rock was deposited in a marine environment. Currently, superchondritic Y/Ho value in seawater is believed to result from the preferential adsorption of Y onto Fe-Mn oxides. In modern oceans, Fe-Mn oxides are considered the sink for subchondritic Y/Ho value. On the contrary, Precambrian banded iron formations (BIFs) display superchondritic Y/Ho value, suggesting that Precambrian seawater also possessed a superchondritic Y/Ho value. However, Precambrian BIFs cannot account for the sink of subchondritic Y/Ho value. Thus, other processes must have been responsible for maintaining the superchondritic Y/Ho value of Precambrian seawater. A hydrothermal experiment involving mid-ocean ridge basalt (MORB) and a Cl-rich fluid was conducted at 300 °C and 500 bars to assess the role of basalt-hosted hydrothermal systems on the Y/Ho value of seawater. Over time, the fluid's Ca concentration increased while Na decreased, suggesting plagioclase albitization occurred. The REE pattern of the reacted fluids exhibited superchondritic Y/Ho values up to 63.2. Based on the presence of positive Eu anomaly and the degree of light REE depletion, the REE in the hydrothermal fluids was mainly sourced from plagioclase during albitization. The superchondritic Y/Ho values in the fluids can be explained by the preferential leaching of these elements due to differences in chloride complexing strength between REE. Subchondritic Y/Ho values observed in Precambrian hydrothermally altered basalts may be interpreted as remnants generating superchondritic Y/Ho values in coexisting Precambrian hydrothermal fluids. Therefore, we believe that the superchondritic Y/Ho value of Precambrian seawater was maintained by basalt-hosted hydrothermal system.

Geophysical study of the Salto–Arapey Aquifer System in Salto, Uruguay

The Salto–Arapey Aquifer System (SAAS) represents a complex hydrogeological framework composed of a detrital aquifer that lays over a fissured one in the Chaco-Paraná Basin. To enhance our understanding of this underground system, an initiative was undertaken to characterize a specific sector of the SAAS utilizing a geophysical methods known as Audiomagnetotelluric sounding. The primary outcomes of this endeavor include the geoelectrical characterizations of key formations and the development of a 2.5D geological-geophysical model. This endeavor significantly advances our geological and geophysical comprehension of the targeted sector, thereby offering substantial societal and economic benefits. Although the method did not allow differences between sedimentary formations, it did allow the recognition of altered basalts, which would facilitate the identification of areas with considerable potential for the productive development of water wells. Notably, this investigation holds significant local relevance as it presents a replicable methodology to characterize the rest of the system, or even aquifers sharing similar characteristics.

Effects of deep magmatic degassing and shallow seawater circulation on trace element and sulfur cycling in submarine hydrothermal systems: Insights from the Shijuligou analog, North China

Limited access to modern subseafloor sulfides hampers our understanding of the link between magmatic volatile influx and the cycling of trace elements and sulfur, as well as the effect of the subsequent shallow seawater circulation on these processes. Hence, we studied a well-preserved fossil analog of submarine hydrothermal systems – the Shijuligou volcanogenic massive sulfide (VMS) deposit from the North Qilian Mountains in North China to examine variations in elements and isotopes of subseafloor sulfides vertically.The vertical distribution of trace elements in subseafloor sulfides is strongly controlled by temperature gradients and redox states during the interaction between hot fluids and seawater beneath the paleo-seafloor. While the enrichment of elements like As, Sb, and Au (median: 1335, 43.7, and 0.30 ppm, respectively, n = 21) and negative δ34S values (mean: −3.07 ‰, n = 7) of euhedral pyrites in the jasper, along with the precipitation of high sulfidation minerals (e.g., enargite), suggest the input of magmatic volatiles into hydrothermal systems. During the shallow seawater-hydrothermal circulation, pyrites in the veined and stockwork zones exhibit distinctly elevated δ34S values (up to 15.74 ‰), accompanied by increased concentrations of wall-rock-derived elements (e.g., Cu, Ni, Si, and Ti) and low-temperature-responsive elements (e.g., Pb, Zn, and Cd). Sulfur isotopes of sulfides vary significantly from the surface to the deep ore zones, ranging from −3.36 to 19.84 ‰ (mean: 9.25 ‰, n = 37). The negative δ34S values of pyrites at the paleo-seafloor are due to the addition of H2S derived from the disproportionation of magmatic SO2. The increased δ34S values of stockwork and disseminated sulfides at depth are attributed to the progressive reduction of seawater sulfates by ferrous iron released from the alteration of fresh basalts. The trace elemental and isotopic characteristics of sulfides suggest the Shujuligou VMS deposit resembles the fossil analog of immature, subduction-related submarine hydrothermal systems.

Elucidating the Genetic Mechanism and the Ore-Forming Materials of the Kaladawan Iron Deposit in the North Altyn Tagn, Western China

The Kaladawan iron deposit is located in the North Altyn Tagh and exhibits occurrences of iron ore bodies at the contact zone between Ordovician magmatic rocks (basalts, rhyolite, and granodiorite) and marble. However, controversy persists regarding the genetic classification and metallogenic mechanism of this deposit. Through a field investigation, single mineral in situ geochemical analysis, whole-rock geochemical analysis, and Fe isotope determination, the following conclusions are made: (1) Ti-(Ni/Cr) and (V/Ti)-Fe diagrams indicate that the magnetite from all studied rocks underwent hydrothermal metasomatism, while (Ni/(Cr + Mn))-(Ti + V) and (Ca + Al + Mn)-(Ti + V) diagrams suggest a skarn origin for these magnetites. Therefore, it can be inferred that the Kaladawan iron deposit is skarn-type. (2) The iron ore exhibits similar rare-earth-element characteristics to the altered basalt. Additionally, the altered basalts (δ56Fe = 0.024~0.100‰) are more enriched in light Fe isotopes than the unaltered basalts (δ56Fe = 0.129~0.197‰) at the same location, indicating that the ore-forming materials of the Kaladawan iron ore are mainly derived from basaltic rocks. (3) According to the law of mass conservation and the intermediate Fe isotopic composition of the iron ore between the granodiorite and basalt, the hydrothermal fluid for the formation of iron ores was inferred to be derived from the late intrusive granodiorite.

Numerical simulation of CO2 storage by basalts in Xingouzui formation, Jianghan Basin, China

Sedimentary basins often develop large amounts of basalts, but there are few studies. The diagenetic history of basalts in sedimentary basins is different from that of continental flood basalts and deep-sea basalts. A large amount of basalt is developed in the Jianghan Basin. Minerals undergo varying degrees of alteration, such as the alteration of olivine into serpentine. Numerical simulations were used to study the interaction between basalt-CO2-formation water in the Xingouzui Formation. The effects of basalt alteration and CO2 injection mode (supercritical CO2, saturated CO2 water, co-injection of CO2 and water) on CO2 storage were investigated. The results show that the reactivity between unaltered basalt and CO2 is strong, and the maximum CO2 mineral trapping reaches 22–49 kg/m3 after CO2 injection for one month. However, the reactivity between the altered basalt and CO2 is obviously decreased. Compared with the unaltered basalt, the maximum CO2 mineral trapping for the altered basalt decreased by at least 15.4 % after CO2 injection for one year. For severely altered basalt with high serpentine content, the maximum CO2 mineral trapping even drops by more than 90 %. CO2 mineral trapping will be overestimated when the feedback of reservoir porosity and permeability changes on flow is not considered. The co-injection of CO2 and water can make full use of the advantages that water injection can promote CO2 dissolution and the resulting acidic environment is beneficial to mineral dissolution. This method could be an option after careful assessment of CO2 leakage risks and technical feasibility.

Lithium isotopic composition of low-temperature altered oceanic crust and its implications for Li cycling

To investigate the Li fluxes and its isotopic fractionation during low-temperature seafloor alteration, we present the Li isotope compositions of fifty fresh and altered basalts drilled from the Integrated Ocean Drilling Program (IODP) 329 Expedition Sites U1365 and U1368, which show different low-temperature (<150 °C) alteration styles and intensities (i.e., total volume of secondary minerals and degrees of elemental enrichment) with meager sedimentation rates (0.71 and 1.1 m/Myr, respectively). The fresh basalts (δ7Li vary from +2.7 to +6.4) show Li isotope compositions consistent with the published N-MORB (+3.5 ± 1.0‰), whereas the altered basalts exhibit considerably higher δ7Li values (+1.7‰ to +11.6‰). Furthermore, their δ7Li values show positive correlations with alkali elements and loss on ignition and follow a mixing trend between a MORB-like endmember and a Li-rich seawater-derived endmember (+9.2 ± 0.2‰), which indicates the effects of low-temperature seafloor alteration on Li isotopic compositions. Based on previously reconstructed paleo-seawater Li isotope compositions, the Li isotopic fractionation scale between seawater and altered basalts is estimated (+12.6‰ and +18.0‰ for Sites U1365 and U1368, respectively), which further supports previous conclusions that the scale of Li isotope fractionation changes over time. A mass calculation suggests the upper limits of the Li-uptake fluxes during low-temperature seafloor alteration are 14.9 ± 2.2 × 109 mol/year and 3.6 ± 1.3 × 109 mol/year for Sites U1365 and U1368, respectively. In addition, our estimation shows the Li-uptake flux during low-temperature seafloor alteration in the Cretaceous is comparable to the total Li-input flux, whereas, in the Neogene, the Li-uptake flux during low-temperature seafloor alteration is much lower than that of the Li-input flux, which suggests a large diagenetic Li sink may be necessary to maintain the seawater Li budget balance if we assume the seawater Li concentration is roughly constant.

Lithogeochemistry of the Nesjavellir geothermal field, SW Iceland—Implications for elemental mass movement in active geothermal systems

The lithogeochemistry of altered basalts was investigated to assess elemental mass changes in the active meteoric water dominated geothermal system at Nesjavellir, SW Iceland. The study revealed that elemental mass changes upon hydrothermal alteration is rather limited and the extent of metasomatism is controlled by the type of alteration minerals. Large mass movement was detected in volatiles (C and S), likely derived from magma degassing. The geothermal system at Nesjavellir may thus provide an ideal locality to investigate the natural sequestration of deep-sourced volatiles and deliver insights in quantifying the input of mantle degassing on the budget of geothermal systems.

Large-scale groundwater flow and sedimentary diagenesis in continental shelves influence marine chemical budgets

The major ion chemistry of the ocean has been assumed to be controlled by river input, hydrothermal circulation at mid-ocean ridges, carbonate production, and low-temperature alteration of seafloor basalt, but marine chemical budgets remain difficult to balance. Here we propose that large-scale groundwater flow and diagenetic reactions in continental shelf sediments have been overlooked as an important contributor to major ion budgets in the ocean. Based on data synthesized from 17 passive margin basins, continental shelves contribute fluid exchanges comparable to hydrothermal circulation at mid-ocean ridges. Chemical exchange is similarly significant, indicating removal of Mg2+ from the oceans at rates similar to mid-ocean ridge convection. Continental shelves likely contribute Ca2+ and K+ to the oceans at rates that, in combination with low-temperature basalt alteration, can close current budget deficits. Flow and reaction in continental shelf sediments should be included in a new generation of studies addressing marine isotope budgets.

Nanoparticulate apatite and greenalite in oldest, well-preserved hydrothermal vent precipitates.

Paleoarchean jaspilites are used to track ancient ocean chemistry and photoautotrophy because they contain hematite interpreted to have formed following biological oxidation of vent-derived Fe(II) and seawater P-scavenging. However, recent studies have triggered debate about ancient seawater Fe and P deposition. Here, we report greenalite and fluorapatite (FAP) nanoparticles in the oldest, well-preserved jaspilites from the ~3.5-billion-year Dresser Formation, Pilbara Craton, Australia. We argue that both phases are vent plume particles, whereas coexisting hematite is linked to secondary oxidation. Geochemical modeling predicts that hydrothermal alteration of seafloor basalts by anoxic, sulfate-free seawater releases Fe(II) and P that simultaneously precipitate as greenalite and FAP upon venting. The formation, transport, and preservation of FAP nanoparticles indicate that seawater P concentrations were ≥1 to 2 orders of magnitude higher than in modern deepwater. We speculate that Archean seafloor vents were nanoparticle "factories" that, on prebiotic Earth, produced countless Fe(II)- and P-rich templates available for catalysis and biosynthesis.

Geochronological, geochemical and isotopic characterisation of the Early Cretaceous Andean margin within Ecuador: The Alao Arc

Tectonic models of the Early Cretaceous Andean margin in Ecuador are hindered by a paucity of accurate crystallisation ages of igneous rocks. The Alao Arc, situated on the western flank of the Cordillera Real in Ecuador, is mainly composed of submarine altered basalts to andesites, and the most deformed areas are frequently modified by greenschist metamorphism. To improve our knowledge of the evolution of the northern Andes prior to the accretion of the Caribbean Large Igneous Province we attempt to constrain the tectonic origin and crystallisation age of the arc's volcanic rocks, using whole-rock geochemistry and isotopic tracing, combined with 40Ar/39Ar geochronology. Major oxides and trace element abundances and Sr-Nd-Pb compositions show that the Alao Arc comprises two separate assemblages, namely, typical arc-like volcanic rocks and E-MORB-like basalts. These have been interpreted to have formed in a continental arc above thinned continental crust in an extensional setting, and the E-MORB-type basalts are considered to have formed in an intra-arc rift. As the Alao Arc's volcanic rocks are devoid of zircon and baddeleyite we attempted to date the time of their crystallisation using 40Ar/39Ar analyses of whole-rock groundmass and plagioclase. However, as the igneous rocks are modified by varying degrees of alteration with the formation of secondary K- and Ca-bearing phases, none of the ∼75 Ma to ∼16 Ma 40Ar/39Ar dates record the age of their crystallisation. The plateau and weighted mean 40Ar/39Ar date populations define peaks at ∼75–60 Ma and ∼ 45–30 Ma that coincide with previously recognised tectonic events that drove fluid circulation, modifying the Ar isotopic compositions. Based on the maximum depositional ages of intercalated sedimentary rocks, the degree of deformation, geochemical and isotopic trends of the Jurassic arc in Ecuador, and correlations with the Early Cretaceous Quebradagrande Arc of Colombia, we propose that the Alao Arc formed during ∼140–110 Ma.

Submarine basalt xenoliths confirm the occurrence of post-rift volcanism in the Southern Santos Basin, SW Atlantic

We report here the finding and analysis of xenoliths of altered basalt clasts dredged from the top of two exhumed diapirs in the southern Santos Basin (SW Atlantic). The diapirs crossed the stratigraphic column from the Aptian and outcropped on the seafloor. Complemented by seismic data, these findings provide the first direct evidence of an Early Campanian post-rift magmatic event in the southern Santos Basin (SW Atlantic). One 82 Ma Ar–Ar age of these xenoliths indicates that the volcanism developed coeval with the intrusion of the Serra do Mar Alkaline Province rocks on land. The tholeiitic composition of the xenoliths excludes a genetic correlation with the alkaline province. Seismic reflection data indicate the possible source of the xenoliths from a 40-km-wide cluster of volcanic centers and sills located above the Aptian salt deposits (∼115 Ma), between the top-Turonian (90 Ma) and top-Campanian (72 Ma) interval. We suggest that salt diapirism peented the overlaying volcanic units and carried fragments upwards through the entire stratigraphic column to the ocean floor. Our findings stress that salt diapirism is an important mechanism for conveying unreachable subsurface fragments to the surface, particularly the ocean floor. With the expanding knowledge of the seascape worldwide, enhanced exploration of salt diapirism and its xenolith products has the potential of opening new windows to unknown parts of geologic history.

Experimental determination of the reactivity of basalts as a function of their degree of alteration

The element release rates from naturally altered basalts were measured in batch experiments at 27 °C, and in mixed-flow experiments at 25 °C in reactive fluids initially consisting of pH 3 or 4 aqueous solutions. The basalts reacted in this study consist of 1) surface weathered basalts ranging in age up to 13 million years, and 2) hydrothermally altered basalts from zeolite to actinolite alteration zones (temperatures of ∼50 to 300 °C). The in situ pH in the batch experiments increased over time with the final pH of the fluids ranging from to 4 to 8. Most experiments exhibited a preferential release of Ca and Mg compared to Si from the dissolving basalts, both initially and over the long-term. This behavior is attributed to the combination of an initial rapid cation-proton exchange reaction and the relatively fast dissolution rates of Ca-bearing minerals. The BET surface area normalized Si release rates for all of the altered basalts are within one order of magnitude of each other, and from one to two orders of magnitude lower than corresponding rates from fresh basaltic glass and fresh crystalline basalts. This is interpreted to stem from 1) the fast removal of reactive basaltic glass and olivine from fresh basalts during the natural alteration of the rocks, 2) the similarity of the dissolution rates of the remaining albitic plagioclase, pyroxenes, epidote, and zeolites, and 3) the high surface areas of some less reactive secondary minerals such as clays. Overall, the results suggest that altered basalts will be effective in consuming CO2 during both natural and engineered processes, though at a somewhat slower rate than unaltered basalts.

A practical approach for discriminating tectonic settings of basaltic rocks using machine learning

Elucidating the tectonic setting of unknown rock samples has long attracted the interest of not only igneous petrologists but also a wide range of geoscientists. Recently, attempts have been made to use machine learning to discriminate the tectonic setting of igneous rocks. However, few studies have designed methods that are applicable to altered rocks. This study proposes a novel approach that utilizes the ratio of elements less susceptible to weathering, alteration, and metamorphism as feature values for analyzing altered basalts. The method was evaluated using six well-established machine learning algorithms: K-Nearest Neighbor (KNN), Support Vector Machine (SVM), Random Forest (RF), Light Gradient Boosting Machine (LightGBM), eXtreme Gradient Boosting (XGBoost), and Multi-Layer Perceptron (MLP). The results show that KNN achieved the highest classification score of 83.9% in the balanced accuracy of classifying the eight tectonic settings, closely followed by SVM with a score of 83.7%. In addition, oceanic and arc/continental basalts could also be discriminated against with an accuracy of more than ∼90% for KNN. This study suggested that the machine learning method can discriminate tectonic settings more accurately and reliably than previously used discrimination diagrams by designing appropriate feature values.

Integrated geophysics for investigation of landslide-affected site located near to Alemketema town, Central Ethiopia

The Central Ethiopian highlands are known for recurrent landslides that pose major challenges to development of infrastructure. In 2021 a landslide was occurred about 4 km northwest of Alemketema town following the construction of the Alemketema-Wereilu highway. Therefore, to map the landslide area, elucidate the causes and triggering factors, and thereby propose plausible mitigation measures, geophysical studies were carried out applying electrical resistivity and seismic refraction methods. Data interpretation revealed three contrasting lithologies, namely the upper colluvium-eluvium deposit (with 10–101 Ω-m and < 526 m/s), in the middle a highly altered (decomposed) basalt containing considerable moisture, and a relatively resistive (>180 Ω-m) and dense (1280-1580 m/s) weathered and fractured basalt at the bottom. These results are compared with geological log data obtained from nearby borehole and found to be in good correlation. In addition, the main slip surfaces and weak tectonic features are indicated which directly and indirectly destabilize the slopes and affect the road's foundation. The presence of physically weak lithologies covering steep terrain, poor agricultural and earth work practices are the main factors exposing the area for sever landslide that usually triggered by intense rainfall, Therefore, the development of alternative road design should properly considers these subsurface characteristics, and incorporate surface and shallow groundwater management, slope area stabilization measures, and improve earthwork practices to reduce their impacts.

Hydrothermal alteration of basalts in the ultramafic-associated Tianxiu Vent Field, Carlsberg Ridge

The Tianxiu vent field (TVF) is the first active ultramafic-associated hydrothermal field to be discovered at the termination of a detachment fault on the slow-spreading Carlsberg Ridge. Most hydrothermal chimneys in the TVF are developed on the basaltic apron. This paper presents mineralogical, petrological, and geochemical data for altered basalts in and surrounding the TVF. The basalt samples can be classified into seafloor-weathered and hydrothermally altered (i.e., slightly saponite-altered, highly saponite-altered, and silicified) types. At the periphery of the TVF, the basalts have experienced seafloor weathering, which has resulted in slight mineralogical and geochemical changes. In the TVF, most basalts have interacted with diffuse low-temperature hydrothermal fluids, leading to variable degrees of saponite alteration. As the distance from the vents decreases, basaltic glass, olivine, and pyroxene are progressively replaced by saponite; Zn, Cu, Co, and U are enriched; and Ca and Mn are depleted. Magnesium, Fe, and Li have been lost due to olivine replacement by saponite, and have been gained due to pyroxene replacement by saponite. In the fluid flow conduits, the basalts have interacted with focused medium- to high-temperature fluids, which has led to the replacement of saponite by opal; depletion in Mg, Fe, Li, and rare earth elements; and enrichment in Zn, Cu, Co, and U. We propose a new hydrothermal alteration model for basalts in an ultramafic-associated vent field. Based on a comparison with mafic-hosted vent fields along mid-ocean ridges, we propose that: (1) the permeable host rocks promote lateral fluid flow, widespread mixing with cold seawater, and pervasive low-temperature hydrothermal alteration; and (2) H2S-poor reducing fluids reduce the solubility of U and inhibit the precipitation of Fe, leading to high Cu/Fe and Zn/Fe ratios, and high U concentrations. The hydrothermal alteration model for the TVF is applicable to similar vent fields and can guide exploration for seafloor massive sulfide deposits along slow-spreading ridges.

Molybdenum in basalt-hosted seafloor hydrothermal systems: Experimental, theoretical, and field sampling approaches

Seafloor hydrothermal vents represent potential sources of Mo and other biologically relevant transition metals to the global ocean, complementing continental runoff. Here, we use a combination of experimental, theoretical, and field-sampling approaches to investigate the behavior of Mo in basalt-hosted seafloor hydrothermal systems to provide insight into the processes controlling Mo concentrations in hydrothermal fluids and to derive estimates of vent fluid Mo concentrations and fluxes. Results of this study demonstrate that reaction fluids generated from 350 °C, 500 bar hydrothermal basalt alteration experiments contain 775–801 nmol/kg Mo and are thus comparable to a recently collected time series of natural seafloor vent fluids that contained 200–220 nmol/kg Mo at 302 °C and 29–30 nmol/kg at 281–282 °C (Evans et al., 2023). Synchrotron-based analyses of experimentally altered basalt produced in this study and additional natural samples of altered oceanic crust originally collected from Pito Deep Rift reveal the presence of Mo-rich particles consistent with trace molybdenite. Comparisons of Mo:Cu ratios in natural vent fluids and near-vent sediment trap samples from Main Endeavour Field indicate that vent fluid Mo is readily incorporated into buoyant plume particles and advected out of the near-vent field, analogous to previous mass balance studies of Cu in this region.Thermodynamic calculations of molybdenite solubility in the context of mineral-buffered hydrothermal fluids and comparisons with natural and experimental hydrothermal fluids suggest that high-temperature vent fluids contain 30–1500 nmol/kg Mo. While a minor component of the modern Mo budget, hydrothermal Mo fluxes are estimated to have constituted 0.3–200× the contemporaneous continental weathering fluxes prior to the ∼2.4 Ga ago “Great Oxidation Event” and widespread oxidative continental weathering. Overall, identification of hydrothermal vents as a source of Mo-rich plume particles with potential for dispersal into the wider marine environment has significant implications for hypotheses regarding the co-evolution of Life and Earth’s environments, specifically the form and availability of Mo in anoxic Archean-Eon oceans, where Mo-dependent enzymatic pathways are thought to have emerged and subsequently evolved.

Influence of the smectites in the microstructure and the mechanical properties of an altered basalt

Here, the microstructure and mechanical properties of a basalt with three alteration degrees (low, medium, and high) are studied, and these properties are compared to the alteration degree of the basalt. The representative samples of each alteration degree have been studied both in raw state as after a short ageing treatment with ethylene glycol. The properties studied are density, P-wave velocity (VP) and uniaxial compression strength (UCS). The microstructure has been studied via optical and scanning electron microscopy and X-ray computed microtomography (microCT), which also provides quantitative data on connected and non-connected porosity. The representative samples of the three alteration degrees show clear differences and Vp and UCS values are progressively lower as higher the alteration. The loss of the good properties of low altered basalt was due to smectites filling a dense network of micro- and nano-fractures that crossed the full rock. Smectites as alteration products of the basalt explained the behaviour of these rocks. With only three swelling–shrinking cycles of smectites, the porosity grew ∼500% in the most altered sample, which explains the cohesion loss of the rock and its lower UCS. Statistical analysis showed the negative correlation among the connected porosity and the mechanical properties of these basalts.

Hydrothermal vent fluid-seawater mixing and the origins of Archean iron formation

Precambrian iron formation provides valuable windows onto ancient marine environments, but exactly how these Fe- and Si-rich chemical sedimentary rocks formed have remained a matter of debate. Traditional models envisage Fe(III)-oxide formation through chemical and/or biological oxidation of soluble Fe2+, but sedimentological and textural data show that, throughout much of Archean stratigraphy, the finest-grained Fe(III)-oxides, previously interpreted to reflect primary components, were largely derived through the oxidation of the Fe(II)-silicate mineral greenalite. These observations have formed the basis for an alternative model where Fe2+ and SiO2(aq) combined to precipitate greenalite upon the mixing of hydrothermal fluids with ambient seawater. All models for iron formation genesis invoke hydrothermal alteration of seafloor basalt as the principal source of soluble Fe2+, and its subsequent transport in an anoxic deep ocean. However, the processes and products associated with the venting of near-axis hydrothermal fluids into Precambrian seawater, and implications for Archean iron formation, have not been investigated.In order to test models for Archean iron formation genesis, we used reaction path models to investigate the interactions between ancient hydrothermal vent fluids and anoxic seawater. We assembled available thermodynamic data and executed reaction path models to examine: (1) the equilibration between anoxic SO4-free seawater and basalt/gabbro at subseafloor hydrothermal conditions (400oC and 400-500 bar), (2) the cooling and decompression of these fluids during their ascent through the oceanic crust, and (3) their subsequent mixing with anoxic SO4-free seawater. Our results confirm previous suggestions that the effective lack of SO4 in Archean seawater would have allowed fayalite-magnetite-pyrrhotite-quartz equilibria to buffer fluid chemistry, in turn leading to reaction zone fluids characterised by high Fe/H2S ratios. Cooling and decompression of these reducing fluids upon ascent, and further reaction with mafic wall rock, leads to significant Fe-chlorite and quartz precipitation with little to no sulfide precipitation. As these vent fluids mix with cold seawater directly, or with conductively-heated seawater, mineral assemblages are dominated by pyrite, greenalite, and/or siderite. These results were obtained with no constraints imposed by Archean iron formation, aside from the exclusion of minnesotaite, a demonstrably secondary mineral.The quantity of hydrothermally-derived Fe2+ partitioned into Fe(II)-bearing minerals upon mixing (96-99% of total aqueous Fe), the relative proportion of greenalite precipitated, and its further concentration via plume-driven transport (by virtue of its low density), together imply that the mixing between hydrothermal vent fluids and anoxic seawater may have served as a principal mechanism for generating a large proportion of the mineral mass now preserved as Archean iron formation. These results reconcile long-standing sedimentological and geochemical observations indicating that Archean banded iron formations record a strong hydrothermal influence, and suggest that these unique deposits have the potential to constrain the nature of seafloor-hosted hydrothermal systems on the ancient Earth, and their chemical interactions with seawater.