Mechanical Properties Of Alloys Research Articles

Applications of unified phase-field methods to designing microstructures and mechanical properties of alloys

Applications of unified phase-field methods to designing microstructures and mechanical properties of alloys

Effect of Homogenization Process on Microstructure and Mechanical Properties of 4047 Aluminum Alloy

In this study, the homogenization heat‐treatment process and microstructural evolution of 4047 aluminum alloy are investigated. In the results, it is revealed that the homogenization process induces partial dissolution of metastable phases and modification of the fine needle‐shaped eutectic Si. Within the 4047 aluminum alloy, the fine needle‐shaped eutectic Si undergoes granulation, involving two stages: crystal dissolution and granulation of broken crystals. After optimal homogenization heat treatment, the eutectic Si phase transformed from a fine needle‐shaped structure to small, regular spherical structures, reducing stress concentration and improving the interfacial bonding capability and internal structure of the alloy matrix. This significantly reduces the likelihood of microcrack formation within the alloy and effectively hinders crack propagation, enhancing the alloy's mechanical properties.

Microstructures and mechanical properties of Ti-55511 alloy subjected to rolling in the α+β dual-phase region

In this study, dual-phase region rolling was conducted on a Ti-55511 alloy with different initial rolling reductions in the single-phase region. The mechanical properties and microstructural characteristics of the alloy with different deformation conditions were investigated. Microstructure observations show the formation of a heterogeneous structure with a gradient size distribution of the α phase at the recrystallized grain boundaries, induced by the non-uniform stress distribution. The α phase and the β matrix exhibit the Burgers orientation relationship in the recrystallized region with the gradient structure. However, in the unrecrystallized region of the partially recrystallized specimens and in the grain interiors of the fully recrystallized specimens, the α phase and the β phase exhibit Pitsch-Schrader orientation relationship (P–S OR). A large number of the nano-sized α" martensite bands were observed after the dual-phase region rolling. These bands originated from the α/β interfaces and grew towards the interiors of the α phase. As the deformation increased, these nano-bands underwent a transformation into the {10 1‾ 1}α deformation twins, resulting in the fragmentation of the α phase. Mechanical testing results show that the mechanical properties of the alloy can be improved by the dislocation strengthening, the generation of profuse α phase and other microstructures including the heterogeneous distribution of the α phase, the nano-sized α" martensite and the {10 1‾ 1}α deformation twins.

Investigation of Two Laser Heat Treatment Strategies for Local Softening of a Sheet in Age-Hardening Aluminum Alloy by Means of Physical Simulation

AbstractCar manufacturers increasingly aid high-strength aluminum alloys for their advantageous weight-to-strength ratio, but their limited formability poses challenges in plastic deformation processes. Tailored heat-treated blanks (THTBs) are a propitious approach to improve formability. Surface laser treatment is the predominant technology for obtaining THTB. To design this process quickly and accurately, without material waste, the use of physical simulation is increasingly promising. It allows replicating the process on a lab-scale and studying posttreatment mechanical and metallurgical properties. By adopting Gleeble® physical simulator, this study investigates the softening effects of local surface laser heat treatment on a EN AW 6082 T6 aluminum alloy blank. Two laser movement strategies—single linear path and multiple rectangular paths—were investigated at two treatment speeds for each. A finite element (FE) model was developed for simulating the process under all explored conditions. FE-derived thermal cycles were reproduced by means of physical simulation. After physical tests, alloy mechanical properties were evaluated. Results show that these properties depend on both the peak temperature thermal cycle and the interaction time between the laser source and the material surface. The comparison between the two strategies revealed that the multiple rectangular paths strategy allows to achieve a wider softened area at comparable interaction times.

Tunable amorphous carbon films formed on ultralow wear, Pt–Au alloys

The mechanocatalytic formation of carbonaceous films at the interface between sliding metallic contacts is simultaneously advantageous for reducing friction and adhesion in several tribological applications and detrimental for electrical contacts as they can induce device failure by increasing the contact resistance. Yet, remarkably little is still known about the chemistry, structural and mechanical properties, and tunability of these interfacial layers. In this study, we performed contact pressure-dependent tribological experiments in dry nitrogen containing trace organics on four, nanocrystalline Pt–Au alloys ([Au] from 0 at.% to 10 at.%) – a promising class of alloys for ultralow wear and electrical contact applications. The ex-situ, multi-technique characterization results did not only provide insights into the chemical nature and mechanical behavior of the mechanocatalytic, carbon-rich films formed on Pt–Au surfaces, but also revealed the interplay between catalytic and mechanochemical tribofilm formation controlled by the composition-dependent electronic structure of the Pt–Au substrate and the applied contact pressure. The results of this work provide guidelines for tailoring nanocrystalline alloys to control their mechanocatalytic activity on the basis of variations of the alloy mechanical properties and element's electronic structure with the alloy stoichiometry.

Microstructural evolution and dynamic recrystallization in Fe50Mn30Co10Cr10 medium entropy alloy under hot compression

This comprehensive study investigates the recrystallization behavior and deformation mechanisms of the Fe50Mn30Co10Cr10 alloy during hot compression conditions. The alloy undergoes discontinuous dynamic recrystallization, evidenced by necklace-like structures at grain boundaries, competing with the initial hexagonal close-packed (HCP) phase and γ→ε reversion. Early deformation is dominated by strain-induced martensite transformation, twinning, with slip with strain partitioning at the end of deformation. The developed Zener-Hollomon equation, validated experimentally, shows a constant activation energy of 126.96 kJ/mol. Stress-strain curves indicate that recrystallization only partially compensates for hardening effects, with no significant peaks observed. The work hardening curve exhibits significant oscillations due to encounters with pre-existing thermal HCP layers, influencing the work hardening rate. Energy efficiency maps based on temperature and strain rate identify optimal deformation conditions at temperatures ranges of 710–750 °C and strain rates of 0.0025–0.0035 s⁻1. This study provides a deeper understanding of the alloy's behavior, offering insights into the interplay between recrystallization, HCP phase formation, and twin generation. These findings contribute to the optimization of the alloy's mechanical properties for industrial applications.

Anisotropic behavior and temperature-dependent mechanical properties of AA1060 aluminum alloy: A comprehensive microstructural study

This study rigorously examines the AA1060 aluminum alloy's mechanical properties across different thermal conditions (298K–77K) and orientations (RD-ND and TD-ND). Through annealing at 350 °C for 50 min followed by extensive mechanical testing at ambient and cryogenic temperatures, the study delves into the microstructural evolution and deformation mechanisms utilizing Electron Backscatter Diffraction (EBSD) and Transmission Electron Microscopy (TEM). Findings indicate a pronounced increase in yield strength, tensile strength, and ductility with decreasing temperature. Notably, RD-ND oriented samples demonstrated enhanced mechanical strength over TD-ND oriented samples under both temperature regimes, underscoring the alloy's pronounced anisotropy. This comprehensive study illuminates the AA1060 alloy's temperature-dependent mechanical enhancements and anisotropic behavior, emphasizing the significant impact of microstructural orientation on its mechanical properties. The insights gained illuminate the AA1060 alloy's temperature-dependent and anisotropic behaviors, highlighting microstructural orientation's important role in its mechanical properties, with profound implications for aluminum alloy application across varying temperature and stress conditions.

Accurate prediction of aging effects on microstructure evolution and related mechanical strength of Mg-Zn alloys via multiscale simulations

Age strengthening is a common method to achieve superior mechanical properties employed in magnesium (Mg) alloys. However, the experimental approaches to examine the aging effects on mechanical properties are primarily based on trial and error, posing challenges for the design and development of high-strength Mg alloys. A promising solution to address this challenge is to establish an accurate prediction model for the aging effects on Mg alloys, covering the evolution of microstructure and corresponding mechanical properties. This paper introduces a multiscale simulation approach to accurately predict the aging effects on the Mg-2.3Zn (at.%) alloy. To begin, we establish a phase field model to simulate the microstructure evolution at 150 ℃, demonstrating precipitate growth during aging in alignment with experimental observations. Secondly, based on the microstructures obtained from phase field simulations, the corresponding yield strength is determined through finite element method simulations. The simulation successfully captures the peak-aged behavior of yield strength during aging, resulting in a yield strength of 167 MPa at the peak-aged state, with a deviation of less than 5 % from experimental results. In-depth analysis indicates that the peak value of total yield strength arises from the interplay between solid solution strengthening and precipitate strengthening. Furthermore, precipitate strengthening reaches a peak value at a specific aging time, deviating from the total yield strength. This deviation is primarily attributed to the effect of precipitate size on shear strengthening during aging. This study presents a general method for predicting the microstructure evolution and corresponding mechanical properties of alloys through multiscale simulations, offering valuable insights for designing and predicting the performance of metallic alloys.

Machine Learning-Based Prediction of Elastic Properties Using Reduced Datasets of Accurate Calculations Results

In this paper, the applicability of machine learning for predicting the elastic properties of binary and ternary bcc Ti and Zr disordered alloys with 34 different doping elements is explored. The original dataset contained 3 independent elastic constants, bulk moduli, shear moduli, and Young’s moduli of 1642 compositions calculated using the EMTO-CPA method and PAW-SQS calculation results for 62 compositions. The architecture of the system is made as a pipeline of a pair of predicting blocks. The first one took as the input a set of descriptors of the qualitative and quantitative compositions of alloys and approximated the EMTO-CPA data, and the second one took predictions of the first model and trained on the results of the PAW-SQS calculations. The main idea of such architecture is to achieve prediction accuracy at the PAW-SQS level, while reducing the resource intensity for obtaining the training set by a multiple of the ratio of the training subsets sizes corresponding to the two used calculation methods (EMTO-CPA/PAW-SQS). As a result, model building and testing methods accounting for the lack of accurate training data on the mechanical properties of alloys (PAW-SQS), balanced out by using predictions of inaccurate resource-effective first-principle calculations (EMTO-CPA), are demonstrated.

Competitive segregation to grain boundaries between Cr and Co in FeNiCrCo alloy

Alloying elements segregating to grain boundaries (GBs) is vital in determining structural stability and mechanical properties of alloys, especially in high‐entropy alloys (HEAs) that consist of multiple elements. However, some details remain unclear, such as the process of varied atoms (Cr and Co) cosegregation to GBs in FeNiCrCo alloy. Therefore, the competition and cooperation between Fe, Ni, Cr, and Co atoms segregating to GBs of FeNiCrCo alloy were investigated via molecular dynamic (MD) simulation. Five [110] symmetric tilt GBs of FeNiCrCo were applied to study the relation between the tendency of atomic segregation especially Cr and Co and GB characters including GB energy and GB excess free volume (GB excess volume). A competitive segregation phenomenon between Cr and Co atoms was discovered, which could be dominated by GB excess volume and different atomic radii among components.

Effect of Multi-Path Asynchronous Rolling Process on Microstructure and Mechanical Properties of ZK60 Magnesium Alloy.

At the initial rolling temperature of 400 °C, ZK60 magnesium alloy was hot rolled by three different rolling paths with different roll speed ratios (RSR) of 1:1.15, 1:1.2, and 1:1.5, respectively. The effects of different rolling processes on the microstructure and mechanical properties of the alloy were studied. The microstructure, plasticity, strength, hardness, and texture intensity of rolled samples were analyzed in this work. The results show that the microstructure uniformity of the alloy under multi-path asynchronous rolling (MAR) is significantly improved, which improves the mechanical properties of the material to a certain extent, and effectively weakens the texture intensity of the basal plane and reduces the anisotropy. The amount of randomly oriented grains of ZK60 magnesium alloy rolled by the C-1.5 (path C combined with the RSR of 1:1.5) process are significantly increased, which significantly weakens the basal texture and improves the ductility of the alloy, greatly enhancing the processing and formability of ZK60 magnesium alloy.

Unveiling the correlation between anomalous hardening and grain boundary diffusional transformation in ω single-phase nano-grained Ti-Fe alloy

A metastable ω single-phase nanograined (NG) Ti-Fe alloy was synthesized using laser inert-gas condensation (IGC). Upon being annealed at 360 °C, the NG Ti-Fe alloy exhibited a remarkable ultra-hardening, increasing the hardness from 4.7 to 8.6 GPa. Subsequent findings revealed an unexpected hardness enhancement, rising from 6.6 GPa at 420 °C to 7.6 GPa at 460 °C, despite the occurrence of grain growth. In-depth investigations into the strengthening mechanisms of the NG Ti-Fe alloy were conducted using in-situ synchrotron high-energy X-ray diffraction (XRD) and transmission electron microscopy (TEM). The comprehensive analysis unveiled that the diffusion-controlled structure evolution during annealing played a pivotal role in enhancing the alloy’s mechanical properties. This study not only presents the synthesis of a novel metastable alloy but also provides valuable insights into the intricate relationship between diffusion-controlled structure evolution and the resulting superior mechanical properties.

CHANGES IN THE STRUCTURE AND PROPERTIES OF ALUMINIUM ALLOYS WHEN MODIFIED WITH POWDER COMPOSITIONS

Purpose. To determine the effect of modification with powder compositions on the structure and mechanical properties of cast and deformed aluminium alloys. Research methods. Metallographic analysis, stereometric metallography, testing of strength and plastic properties of cast alloys AL4, AL4C of the Al-Si system and deformed alloys 1545 of the Al-Mg-Sc system, 2219 of the Al-Cu-Mn system in their original and modified state. Results. Meltings of AL4, AL4C, 1545, 2219 alloys were carried out in the initial state and with melt treatment with a complex nano-disperse modifier of magnesium silicide Mg2Si and silicon carbide SiC with a particle size of 50...100 nm. The optimal content of Mg2Si+SiC (0.10%) for increasing σ0.2 of aluminium alloys was determined. A 1.6-fold reduction in the grain structure of cast alloys was achieved. The dependence of the particle size and the amount of the modifier on the mechanical properties of the alloys was established. In industrial experiments, the most effective particle size of Mg2Si+SiC was established for increasing σ0.2 of AL4, AL4C alloy from 115 to 260 MPa in the as-cast state. The increase in the strength properties of the modified alloys is 44 % compared to the original state. Scientific novelty. Further development, insight into the influence of melt modification on the parameters of the structure and properties of aluminium alloys was obtained. The use of nanodispersed complex modifier Mg2Si+SiС with a particle size of 50...100 nm is proposed. It has been confirmed that the use of complex nanodisperse modifiers allows you to actively influence the structure and mechanical properties of aluminium alloys. Practical value. It has been experimentally proven that the rational amount of the introduced complex modifier is 0.10% of the mass of the melt. A significant grinding of the grain structure and an increase in the strength properties of cast and deformed aluminium alloys were achieved as a result of the modification.

Magnesium and magnesium alloy dissolution by high intensity focused ultrasound: erosion/cavitation vs. Wave propagation

The dissolution of metals, influenced by mechanical and chemical factors, plays a crucial role in various applications. Ultrasonic irradiation has been explored for its ability to enhance dissolution rates and modify surface characteristics. In this study, we investigate the dissolution of magnesium (Mg) and magnesium alloys under high-intensity focused ultrasound (HIFU) conditions with frequency sweeping (wobbling). Our findings reveal distinct effects of cavitation and acoustic streaming on the dissolution process. For pure magnesium, ultrasonic treatment significantly increases dissolution rates compared to silent conditions. Negative frequency sweeps result in the highest dissolution rates, linked to increased cavitation activity, while positive sweeps reduce dissolution rates but maintain acoustic streaming effects. The removal of surface oxides is accelerated in all sonication conditions. Macro- and micro-roughness patterns on the surface correspond to the wobbling frequency range, with wavelengths matching the average ultrasonic frequency. However, dissolution is not uniform across the sample, and preferential attack occurs at the focal point during negative frequency sweeps. In contrast, magnesium alloys exhibit lower dissolution rates than pure Mg. The alloy's mechanical properties make it less susceptible to cavitation erosion but more sensitive to acoustic streaming-induced dissolution. Grain boundaries are preferentially attacked, revealing differences between ductile pure Mg and the harder, more cavitation-resistant, alloy. This study highlights the complex interplay between cavitation and acoustic streaming in the dissolution of magnesium and its alloys under HIFU conditions, shedding light on the limits and potential applications of this technique, particularly in microstructure analysis.

Deformation Behavior and Microstructure of 6061 Aluminum Alloy Processed by Severe Plastic Deformation Using Biaxial Alternate Forging.

The deformation behavior and microstructure of 6061 aluminum alloy processed by severe plastic deformation (SPD) using biaxial alternate forging that can evaluate the forming limit and mechanical properties of alloys, simultaneously, were investigated in this study. A finite element (FE) analysis on the biaxial alternating forging process, considering the strain-hardening coefficient and forging pass of the material, was conducted. When the strain-hardening coefficient is 0, an average effective strain of 440% was found within a diameter of 4 mm in the core of the workpiece after eight passes, while it was 300% at the same pass number when the strain-hardening coefficient was 0.2. The average effective strain estimated from the FE analysis was about 264% after eight passes of forging, which is considered to be a level of SPD that significantly exceeds the elongation of the raw material. As a result of the tensile test according to the forging pass, after two passes, the strength of the material could be gradually improved without significant degradation of elongation. Even though a large strain of 264% was found after eight passes were applied, deformed grains and twins with no recrystallized structure in optical microstructures with different forging passes were found.

Microstructure and mechanical properties of multi-principal component CoCrNiMo medium entropy alloys

In traditional high entropy alloy (HEA) systems, achieving a synergistic enhancement of alloy strength and ductility remains a challenge. However, dual-phase high entropy alloys, with their simultaneous high strength and high ductility, have shown potential for industrial applications. In this study, three multi-principal element CoCrNiMo alloys were synthesized by adding varying amounts of Mo to the base medium entropy Co45Cr27Ni28 alloy, which possesses a single face-centered cubic (FCC) phase. The impact of variations in Mo content on the alloy's microstructure and mechanical properties was investigated. Experimental data revealed that all three alloys formed dual-phase (FCC + μ) precipitation-strengthened medium entropy alloys (MEAs), where the μ phase is enriched with Mo, and its quantity increases with the increase in Mo content. With the rise in Mo content, the alloy's hardness increased from 240 ± 20 HV to 668 ± 35 HV, and tensile strength also increased, albeit at the cost of reduced plasticity. The single-phase medium entropy Co45Cr27Ni28 alloy exhibited a tensile strength and elongation rate of 591 ± 15 MPa and 44 ± 3%, respectively. The tensile strength of the dual-phase CoCrNiMo HEAs could be elevated to 857 ± 16 MPa and 1045 ± 25 MPa, while maintaining considerable elongation rates of 16 ± 2% and 5 ± 1%, respectively. This work provides a pathway for strengthening CoCrNi alloys and contributes positively to the development of high-performance HEAs.

Effect of High-Frequency Electric Pulse on the Solidification Microstructure and Properties of Hypoeutectic Al-Si Alloy.

The effects of different pulse frequencies on the microstructure grain size and solid solubility of Al-9Si alloy were systematically investigated using OM, SEM, and EDS. The impact on the mechanical properties of the alloy was analyzed using a micro-Vickers hardness tester and multifunctional friction tester. During solidification, the Al-9Si alloy is exposed to high-frequency electric current pulses with a current density of 300 A/cm2 and frequencies of 0 Hz, 500 Hz, 1000 Hz, and 2000 Hz. The experimental results show that the Lorentz force also increases as the high-frequency pulse frequency increases. Intense electromagnetic stirring leads to grain refinement. However, as the pulse frequency continues to grow, the combined effect of Joule heating and Lorentz force results in an enlargement of the melt zone and an increase in grain size. At a pulse frequency of 1000 Hz, the eutectic structure size of the Al-9Si alloy is optimal, with the average size being reduced to 13.87 μm and a dense distribution, effectively eliminating primary Si. The EDS results revealed that the high-frequency pulse led to a more uniform distribution of Si elements within the matrix, and the solid solubility of Si in the α-Al matrix increased to a maximum value of 1.99%, representing a 39.2% increase. At a pulse frequency of 1000 Hz, the sample demonstrates the most favorable mechanical properties, with the friction coefficient reaching a minimum value of 0.302, representing a 37.7% decrease in the average friction coefficient. The results demonstrate that high-frequency pulsing is an effective method for enhancing the mechanical properties of Al-9Si alloy.

Mechanical properties of hypoeutectic, eutectic, and hypereutectic Al-Si automotive alloys under ageing treatment

The role of different levels of silicon on mechanical properties has been investigated through tensile and impact tests along with fractography of Al-Si automotive alloys. Cast alloys are given precipitation strengthening through T6 heat treatment. It has been experimentally determined that ageing these alloys leads to the enhancement of tensile properties, which is mainly caused by the precipitation of the intermetallics such as Al2Cu, Mg2Si, and Al2CuMg within the Al-matrix. The ductility of these alloys primarily exhibit a diminishing trend as the ageing temperature increased. This diminishing trend can be attributed to the formation of fine precipitates like GP zones and metastable phases. However, after reaching a certain temperature, the ductility started to increase again. This is caused by the coarsening of the precipitates. At higher strain rates, the tensile strength is found to be identical for higher Si-added alloys due to their brittleness. The microstructures of the alloys reveal that as Si content increases, eutectic phases become more apparent. Fractography of the base alloy exhibits a small dimple structure, and higher Si-added alloys initiate the crack propagation. Beyond eutectic composition, the mechanical properties of the alloys became distorted due to block-like primary Si into the Al-matrix.

Study on the effect of the ECAP deformation on the organization and properties of the extruded Mg-Sn-Al alloys

In order to refine the grain and the second phase size of the Mg-Sn-Al alloys further, as well as enhance the alloy's strength-ductility performance match, the alloy was deformed by equal-channel angular pressing (ECAP) technique after conventional extrusion. After ECAP (180℃), the microstructures and mechanical properties of the alloy were observed. The results show that the average grain size of the alloy reduced from 23.3 μm to 1.25 μm, and the percentage of the high-angle grain boundaries rise to 71 %. The texture of the ECAPed alloy on TD direction shows a typical fiber (10 1¯ 0) < 11 2¯ 0>, with an intensity of 12.016. The mechanical properties of the ECAPed alloy were tested after aging at 240℃ for 192 h, and the results show that the ultimate tensile strength of the aging alloy was 415 MPa, the yield strength was 324 MPa and the elongation was 10.5 %.

Effect of multistage lamellar microstructure on mechanical properties of Tc18 alloy

In this study, a three-step heat treatment approach, which included annealing, solution treatment at 740–820 °C, and aging at 450–550 °C, was employed to control the precipitation behavior of the α phase in TC18(Ti-5Al-5Mo-5 V-1Cr-1Fe) alloy. The multistage microstructure resulting was found to contain both the primary lamellar structure (α) and the secondary lamellar structure (αs), and the relationship between the spacing of multi-level lamellar microstructure and the mechanical properties of the alloy was effeciently determined. The study demonstrates that lowering the solid solution temperature reduces the interlayer spacing of the primary α phase, and increasing the aging temperature enlarges the interlayer spacing of the secondary αs phase, thereby enhancing the material's mechanical performance. Nevertheless, a substantial discrepancy in yield strength exists between these two interlayer spacings, which impacts the stress-strain coordination and reduces the plastic zone at the crack tip, and also increases the likelihood of formation of microvoids and microcracks at grain boundaries.