Alkaline Rocks Research Articles

Multiscale characterisation on the adhesion and selective adsorption at bitumen–mineral interface

The adhesion between bitumen and minerals is essential for the durability of asphalt mixtures, influenced by bitumen composition and mineral structure. The chemical action theory suggests that polar components in bitumen are adsorbed onto the mineral surface, facilitating adhesion. In this study, environmental scanning electron microscopy with energy-dispersive X-ray (ESEM-EDS) is used to analyse bitumen–mineral interfaces at a microscopic level. Elemental analysis reveals selective adsorption of polar substances from bitumen onto the surfaces of four types of minerals. Results show that alkaline rocks (limestone and albite) have a higher adsorption capacity than acidic rocks (granite and quartz). Additionally, treating mineral surfaces with alkaline solutions enhances adsorption. The adhesion properties of bitumen to various minerals are evaluated using the pull-off test. The correlation between ESEM-EDS and pull-off tests demonstrates that the macroscopic adhesion of bitumen to minerals is linked to the microscopic selective adsorption of polar substances.

On the coexistence of rift-related silica-undersaturated and silica-saturated alkaline rocks – The cretaceous Messum alkaline complex (Namibia) revisited

The ~132 Ma-old Messum igneous complex, a circular structure of ~18 km diameter, belongs to the Damaraland intrusive complexes that intruded into the Pan-African Damara basement of Namibia. The plutonic rocks of the core of the complex comprise olivine-gabbro, biotite-gabbro, nepheline-syenite and quartz-syenite as well as minor alkali gabbro and coexist with the Etendeka volcanic sequences of the Goboboseb Mountains, comprising basalts (Tafelkop and Tafelberg types) that are overlain by deposits of several quartz latite eruptions. New major and trace element and Sr, Nd and Pb isotope data are reported for nepheline-syenite and quartz-syenite. Major and trace element data are consistent with the development of nepheline-syenites through fractional crystallization processes. The nepheline-syenite samples have initial 87Sr/86Sr of 0.7046–0.7049 and initial εNd ranging from +0.53 to +1.47, indicating a mantle source with time-integrated lithophile element depletion. Initial Pb isotopes are rather uniform (206Pb/204Pb:17.89–18.14, 207Pb/204Pb: 15.56–15.58, 208Pb/204Pb: 37.78–38.00). Uniform initial Sr and Pb isotope ratios for nepheline-syenites suggest that the syenite magmas evolved through fractional crystallization from an inferred mafic alkaline magma without crustal contamination. However, the range in Nd isotope composition is too large to be related to crystal fractionation alone and imply a heterogeneous source with respect to the Nd isotope composition. The quartz-syenites show a large range in initial εNd (+1.0 to −4.4) and initial 87Sr/86Sr (0.7047–0.7115). Initial Pb isotope ratios are also heterogeneous (206Pb/204Pb: 18.29–18.74, 207Pb/204Pb: 15.60–15.65, 208Pb/204Pb: 37.43–38.49). These data, together with major and trace element constraints and results from AFC modeling substantiate the production of the quartz-syenites by fractional crystallization of clinopyroxene, amphibole and K-feldspar accompanied by assimilation of up to about 30 % pre-Pan African lower crust. Isotope and chemical data do not support derivation from a single batch of magma undergoing contamination, but suggest that a large magma body at depth evolved largely by fractionation with batches of melt extracted from this chamber being variably contaminated at lower crustal levels.

AGE AND GEODYNAMIC SETTINGS FOR FORMATION OF CARBONATITE COMPLEXES AND ASSOCIATED RARE METAL DEPOSITS OF THE SOUTH URAL

The Ilmen-Vishnevogorsky and Buldym carbonatite complexes occurring in the Southern Urals represent linear deformed carbonatite complexes. Their origin, as well as the age and geodynamic conditions remain the subject of debate. The isochron methods (Rb-Sr, Sm-Nd, TIMS) and local U-Pb-dating of zircons (SHRIMP II and LA-ICP MS) of these carbonatite complexes were employed to determine the age and duration of the stages of alkali-carbonatite magmatism and associated rare-metal ore formation. The Silurian-Devonian U-Pb zircon ages of the early phases of Ilmen-Vishnevogorsky miaskites and carbonatites were determined as 420.7±11 Ma (S2) and 417±2.8 Ma (D1), respectively. In the later phases of miaskites and carbonatites, early zircons are resorbed, they have broken isotope systems, and later zircon generations form a cluster of 386±7.6 Ma (D2). The Lower Permian U-Pb age of zircon 280±8 Ma (P1) was determined in the miaskite-pegmatite and late carbonatite. The isochron dating of late ore-bearing varieties of carbonatites provided the ages from the Lower Permian to the Early Triassic (P1–T1): 254±18 Ma, Sm-Nd and 247±4 Ma, Rb-Sr, IVC; 280±53 Ma, Sm-Nd, Buldym complex. Thus, the generation and intrusion of alkaline magmas in the Urals occurred ~420 Ma (S2–D1), synchronously with the formation of island-arc complexes. They are related to rifting on the emerging continental margins. The tectonic activity and formation of alkaline rocks and carbonatites proceeded in the Middle Devonian (~380 Ma, D2); it correlates with the accretion-collision stage of the Urals development. At the stage of "hard" collision (~280 Ma, P1), the Ilmen-Vishnevogorsky and Buldym complexes were plastically deformed, underwent melting and emplaced conformably with collision-slip tectonic structures. Recrystallization of rocks and minerals, plastic and brittle deformations, processes of pegmatitic, carbonatitic and rare-metal ore formation are associated with palingenic-metasomatic transformation of rifting alkaline complexes of Silurian-Devonian age at the collision and post-collision (~250 Ma, P3–T1) stages of the Urals emplacement.

The role of magma recharge and mixing in producing compositional modality in post-collisional volcanic rocks, Konya Volcanic Field, Central Anatolia (Türkiye)

The Neogene Erenlerdağ-Alacadağ (ErAVC) and Sulutas (SVC) volcanic complexes in the Konya Volcanic Field, Türkiye have distinctly different unimodal and bimodal compositional variations, respectively. They occurred in graben-like extensional basins behind the retreating Cyprus subduction zone between the African and Eurasian plates. We here investigate their compositional modality by using new and published whole-rock major and trace element and Sr-Nd-Pb isotope data.Both complexes are characterized by basaltic to rhyodacitic high-K calc-alkaline rocks with the geochemical signatures of orogenic volcanism, except for minor alkaline rocks in the SVC. Mass-balance models suggest that major element variations can be largely explained by the fractional crystallization of amphibole, plagioclase, and Fe-Ti oxides. However, Sr-Nd-Pb isotopes show correlations with SiO2 indicating that open-system processes played a role in their differentiation. Modeling of AFC (Assimilation and Fractional Crystallization) involving a recharge situation shows that low degrees of crustal assimilation (rate of assimilation/rate of fractional crystallization, r < 0.2 and crust/magma ratio, ρ: 15–16 %) of lower and upper crust-like rocks was involved in the differentiation of the ErAVC and SVC, respectively. However, the modeling suggests that magma recharge (β: rate of magma recharge/rate of assimilation) was more efficient in the ErAVC (β: 3.45, % ∼52.5 rate of recharge) relative to that of the SVC (β: 2.15, % ∼36.55 rate of recharge). We conclude that for the ErAVC and SVC, different parental magmas derived from the subduction-modified mantle source followed distinct differentiation paths in the crust, and their compositional modality was mainly controlled by the magma recharge and mixing process.

Composite Granitic Plutonism in the Southern Part of the Wadi Hodein Shear Zone, South Eastern Desert, Egypt: Implications for Neoproterozoic Dioritic and Highly Evolved Magma Mingling during Volcanic Arc Assembly

The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. Field observations, supported by remote sensing and geochemical data, reveal a composite granitic intrusion that is differentiated into two magmatic phases. The early granitic phase comprises weakly deformed subduction-related calc–alkaline rocks ranging from diorite to tonalite, while the later encloses undeformed granodiorite and granite. Landsat-8 (OLI) remote sensing data have shown to be highly effective in discriminating among the different varieties of granites present in the area. Furthermore, the data have provided important insights into the structural characteristics of the AFG region. Specifically, the data indicate the presence of major tectonic trends with ENE–WSW and NW–SE directions transecting the AFG area. Geochemically, the AFG generally has a calc–alkaline metaluminous affinity with relatively high values of Cs, Rb, K, Sr, Nd, and Hf but low contents of Nb, Ta, P, and Y. The early magmatic phase has lower alkalis and REEs, while the later phases have higher alkalis and REEs with distinctly negative Eu anomalies. The AFG is structurally controlled, forming a N–S arch, which may be due to the influence of the wadi Hodein major shear zone. The diorite and tonalite are believed to have been originally derived from subduction-related magmatism during regional compression. This began with the dehydration of the descending oceanic crust with differential melting of the metasomatized mantle wedge. Magma ascent was long enough to react with the thickened crust and therefore suffered fractional crystallization and assimilation (AFC) to produce the calc–alkaline diorite–tonalite association. The granodiorite and granites were produced due to partial melting, assimilation, and fractionation of lower crustal rocks (mainly diorite–tonalite of the early stage) after subduction and arc volcanism during a late orogenic relaxation–rebound event associated with uplift transitioning to extension.

Platinum-rhenium-osmium isotope systematics of chromitite and native osmium from the Guli Massif (Maimecha-Kotui Province, Russia)

To gain insight into the source of ore material, this study presents the first Re-Os and Pt-Os isotopic and highly siderophile element (HSE) abundance data for chromitite and osmium minerals from the Guli massif of ultramafic, alkaline rocks and carbonatites located in the Maimecha-Kotui province, Polar Siberia. The study utilized a number of analytical techniques, including electron microprobe analysis, negative thermal ionization mass spectrometry (N-TIMS) and high pressure asher digestion and an isotope dilution-inductively coupled plasma-mass spectrometry. The HSE concentrations in chromitite samples range from 191 to 866 ppb with a predominance of Ir-group platinum-group elements (PGE) (Os, Ir and Ru) over Pt-group PGE (Rh, Pt and Pd) and Re, which is consistent with their platinum-group mineral control (i. e., Os-Ir alloys and laurite, RuS2) within the chromitite. The Re-Os and Pt-Os isotope data indicate that the HSE budget of the chromitite and osmium minerals from the Guli massif was largely controlled by that of the mantle source, which evolved with long-term near-chondritic Re/Os and Pt/Os ratios; this source is within the range of those for the majority of komatiite and abyssal peridotite sources.

Carbonatites and related mineralization: an overview

Despite of their scarcity, carbonatites are documented from diverse geological settings, including cratons, continental rifts, orogenic belts and large igneous provinces, which range in age from the Archean to Recent. This study provides a concise overview of the evolution of igneous carbonatites, compiling data on their diverse characteristics and classifying them into mantle- and crustal-derived subtypes. Mantle-derived carbonatites, typically associated with alkaline rocks, are enriched in rare earth elements (REEs) and display geochemical affinities to the mantle. By contrast, crustal-derived carbonatites usually show much lower REE contents and crustal-affinity geochemical features similar to sedimentary carbonaceous rocks. Our study documents the significant economic potential of carbonatites that can host world-class deposits of REE, rare metals, alkaline earth metals and non-metallic resources. Typically, the key processes controlling REE mineralization include the low-degree melting of refertilized mantle, liquid immiscibility, fractional crystallization and hydrothermal fluids. Thus, carbonatites are of significant economic value due to the rapidly increasing global demand for REEs, mainly driven by the ‘green energy transition’.

Barium-bearing micas of the muscovite-ganterite series from alkaline rocks of the Sredneziminsky ijolite-syenite-carbonaite massif (Eastern Siberia, Russia)

Barium-bearing micas (BaO content from 1.2 to 18.7 wt %) were found in hydrothermally altered ijolites and alkaline syenite of the Sredneziminsky ijolite-syenite-carbonatite massif (Eastern Siberia, Russia). It occurs in the products of low-temperature replacement of cancrinite, in association with natrolite, analcime, calcite, diaspore/boehmite, celsian, and strontianite. Ba-bearing micas are represented by grains up to 1 mm, heterogeneous in chemical composition. The amount of Ba increases in the marginal parts of grains; enrichment of some layers in mica grains with barium is also observed. The main isomorphic substitution in muscovite corresponds to the scheme K++Si4+↔Ba2++IVAl3+. The empirical formula of barium-richest areas in one of the mica grains is (Ba0.54–0.56Sr0–0.09K0.46)∑1.02–1.06Al1.98–2.01(Si2.37–2.40All.60–1.63)∑4.00 O10(OH1.70–2.00F0–0.30)∑2.00, which corresponds to ganterite. The maximum content of BaO in the majority of muscovite grains of the Sredneziminsky massif is 14.0–14.9 wt % that is equal to 0.41‒0.44 apfu Ba. It is assumed that the source of barium in the hydrothermal solution was orthoclase containing 0.5–0.9 wt % BaO which underwent albitization at the post-magmatic stage. The widespread occurrence of sulfides in the rocks indicates low oxygen fugacity, which prevents the formation of barite and is favorable to the formation of Ba-bearing muscovite and celsian.

Decoding Apatite in Volcanic Carbonatitic breccia from Mongra, Northwest of Amba Dongar Carbonatite Complex, Gujarat, India: Insights to Genesis &amp; Rare Earth Element Budgets

Chemical variations in apatite in context to carbonatites and trace element partitioning between apatites and carbonatite-rich liquids are important in assessing the petrogenesis and evolution of the carbonatites as well as the associated carbonatitic breccia due to apatite's sensitivity to surrounding magma composition. Volcanic carbonatitic breccia is one of the constituent rock types found outside the ring structure of the Amba Dongar Carbonatite Complex (ADC) situated in western India. In the present work, we report the mineral chemistry of apatites from the carbonatitic breccias of the Mongra region (ADC outer core) and compare them to apatites from ADC carbonatites. Apatite chemistry from Mongra displays a larger concentration of rare earth elements, manganese, and chlorine when compared to those of ADC carbonatites. Morphology and distinct zoning of these apatites represent late-stage magmatic processes with high heavy rare earth element concentrations (high Lutetium), followed by interaction of fluids from the surrounding alkaline rocks. Variation in sulphur concentration in the apatites of this study indicates crystallisation under mildly reducing conditions. Integrated field observations, petrography, and apatite mineral chemistry from the Mongra region allow for an understanding of the genesis of apatites in the ADC outer core, with possible implications for late-stage mineral-melt interactions.

Subsurface interconnection beneath the Mio-Plio-Quaternary volcanoes of the Ain Leuh causse (Middle Atlas, Morocco): Structural framework and emplacement mechanisms

In the Ain Leuh causse, located southwest of the Middle Atlas Volcanic Province (MAVP), a combined study using aeromagnetic data, fieldwork, and remote sensing is carried out to improve our understanding of the subsurface structure and its correlation with surface structural and volcanic features. The tectonically controlled emplacement mechanisms of the MAVP, which continue to hold undisclosed aspects, were investigated as well. Numerous techniques and mathematical filters for edge detection and 2D modelling were used. The main observations show that the positive magnetic anomalies in the study area are mainly related to the magmatic activity, which was organized into two main episodes: i) Triassic, with a tholeiitic affinity, well recorded along the NE-SW inherited Variscan faults; and ii) Mio-Plio-Quaternary, with an alkaline affinity, forming scoria cones, maars, and lava flows. They are also expressed as hidden domes, laccoliths, and interconnected magma bodies revealed by 2D modelling of the aeromagnetic data. Uncommon coarse-grained undersaturated alkaline rocks crop out in Talzast dome (Talzastite, Fasinites, and Ankaratrite). They are unique in the MAVP and restricted to this part of the Middle Atlas. 2D aeromagnetic modelling has revealed the presence of shallow magmatic rocks bodies beneath Talzast dome. The extracted structural lineaments using aeromagnetic data and remote sensing reveal that the structural framework of the study area is controlled by NE-trending faults reaching depths of up to 3000 m, which is the depth of the magnetic signature of the faults. Additionally, NNE, NNW and N-trending short-length lineaments are defined and rooted at depths up to 3000 m. The predominant NE-SW structural trend may be linked to the reactivation of Hercynian faults during Alpine tectonics. These faults likely controlled the emplacement of the Mio-Plio-Quaternary volcanism in the area. The magma reservoirs that would have fed the various volcanic edifices are located at a shallow depth of less than 500–2000 m.

Trace element geochemistry of carbonatites and associated alkaline rocks of Mundwara Igneous complex, Sirohi district, Rajasthan, India

Carbonatites are widely recognized for their potential to host significant deposits of rare earth elements (REEs) and other rare metals. These igneous rocks, characterized by their high carbonate mineral content, are often rich in REEs, niobium, tantalum, and other valuable elements. This makes carbonatites key targets for mining and exploration. Carbonatites are believed to form from either primary carbonate magma derived directly from the mantle or from secondary melts. These secondary melts can originate from carbonated silicate magmas through liquid immiscibility or from the residual melts resulting from the fractional crystallization of silicate magmas. The coexistence of carbonatites and alkaline silicate rocks in most complexes, their coeval emplacement in many, and overlapping initial 87Sr/86Sr ratios supports the theory of their cogenesis. In this study, we aim to investigate the trace element geochemistry of carbonatites and coeval alkaline silicate rocks from the Mundwara Igneous Complex, Sirohi district, Rajasthan in India. Our trace element data indicate that the carbonatites and alkaline silicate rocks in this complex are products of fractional crystallization from two separate parental melts, formed through liquid immiscibility of a carbonated alkaline silicate magma.

Alkaline Devonian magmatism of the Menorca Island: Tracking the mantle isotopic sources in the realm of the western Paleo-Tethys Ocean

Several locations with alkaline magmatism are recognised in Silurian-Devonian basins along the southern variscan autochthon units (e.g. Central Iberian Zone) of the northern Gondwana margin. The origin of the Devonian basins and their magmatism has not been studied in the context of the passive margin of Gondwana. The basement of Menorca, Balearic Islands, consists of a deep Devonian-Carboniferous basin with mafic igneous rocks, the Tramuntana Gabbros. In this study, we trace the geodynamic setting and isotopic sources of the Tramuntana Gabbros through elemental geochemistry, isotopic geochemistry (SrNd) and UPb geochronology in zircons. These gabbros are the product of an intraplate alkaline magmatism with immobile trace element and REE contents similar to those of Ocean Island Basalts. Average 87Sr/86Sr(370) of 0.708456 and εNd(370) of +4.0 indicate a source similar to a Type-2 enriched mantle with average TDM of 665 Ma, suggesting a relatively old metasomatized mantle. Concordant UPb ages of c. 597 Ma (Ediacaran, radiometric age) from a single population of 31 zircons separated from the Tramuntana Gabbros (Devonian, biostratigraphic age) reinforce the presence of older units in the corresponding lithospheric mantle. The Tramuntana Gabbros and the Devonian-Carboniferous sequences of Menorca limit the westward extension of the Paleo-Tethys Ocean, whose development never reached these westernmost regions. Assuming a common sublithospheric mantle source for the peri-Gondwanic Devonian alkaline rocks and considering the previous Cadomian (Neoproterozoic) subduction to be the most favourable origin of the separated zircons, the bulk rock TDM and zircon UPb data obtained from the Tramuntana Gabbros track the mixing, recycling, and mantle accretion in this peri-Gondwanic section from Precambrian to Devonian times.

Geochemistry of Cenozoic mafic potassic and sodic volcanic rocks in southwestern Madagascar: Long-lived lithospheric mantle heterogeneities in an extensional tectonic setting

Cenozoic (≥ 43 Ma) silica undersaturated (potassic) trachybasalts and trachyandesites in southwestern Madagascar (Tsianihy-Manja, southern Morondava Basin) form a small monogenetic volcanic field emplaced above Paleogene detritic sedimentary rocks, along a NE-SW-trending fault system. These olivine-chromite±clinopyroxene-phyric primitive lavas (Mg# = 69; MgO = 10–11 wt%; Cr = 450 ppm, Ni = 200 ppm; K2O = 3–4 wt%) have highly peculiar trace element and isotopic composition (e.g., Ba/Nb = 18.4; 87Sr/86Sri = 0.70529–0.70555, 143Nd/144Ndi = 0.51262–0.51263, 206Pb/204Pbm = 18.415–18.424, 207Pb/204Pbm = 15.576–15.579, 208Pb/204Pbm = 38.799–38.813). A hitherto undescribed plug of primitive (sodic) basanite of the 11–12 Ma-old Ankililoaka district south of Tsianihy-Manja (hosting spinel lherzolite mantle xenoliths) has noticeable different geochemistry (Ba/Nb = 8–9.2; 87Sr/86Sri = 0.70346–0.7036, 143Nd/144Ndi = 0.51281–0.51282, 206Pb/204Pbm = 19.079–19.374, 207Pb/204Pbm = 15.621–15.645, 208Pb/204Pbm = 39.115–39.424).The relatively low CaO, Sc, V, Fe2O3t, MnO at high MgO, Cr and Ni, and the potassic affinity of the Tsianihy-Manja trachybasalts, all indicate that the mantle source is relatively clinopyroxene-poor (i.e., depleted by previous melt extractions), in the same way as the source of lamproitic (or boninitic) magmas, but the primitive nature, the concentration of high field strength elements, the incompatible element patterns and their isotopic ratios indicate their unequivocal within-plate setting and indicate a derivation by low-degree partial melting of an incompatible element-enriched mantle and insignificant role for crustal contamination. In terms of incompatible element concentrations, and thus also Sr-Nd-Pb-isotopic composition, we find no evidence in favour of a mid-ocean ridge basalt (MORB)-mantle component, or for a MORB-mantle strongly enriched by ocean island basalt-like components, to form the mantle source regions of the Tsianihy-Manja and Ankililoaka mafic alkaline rocks. The significant isotopic change from the northernmost Cenozoic volcanic rocks of Madagascar and those in the central and southern part of the island (which range in composition from sodic to potassic, and from tholeiitic basalt to olivine melilitite) implicates a distinct source heterogeneity, and ultimately assess the role of the old continental lithospheric mantle as source region.

The Role of Continental Alkaline Magmatism in Mantle Carbon Outflux Constrained by a Machine Learning Analysis of Zircon

AbstractContinental alkaline magmatism has been suggested to play a significant role in releasing deep mantle carbon into the atmosphere, which can greatly impact the global climate. However, the temporal variations of alkaline magmatism and their potential to modulate climate over geologic time remain poorly constrained. The detrital zircon record is a frequently used proxy for tracking secular variations in particular magmatism. Here, we use a novel machine‐learning technique to discriminate zircon from carbonatites, kimberlites, and other alkaline rocks. A global compilation of detrital zircon yields continental alkaline magmatic flare‐ups between 1,050−850, 650−500, 250−200, and 50−0 Ma. Our estimates indicate relatively elevated contributions of total magmatic carbon outgassing from alkaline magmatism during the aforementioned magmatic flare‐ups. We infer that anomalous alkaline magmatism may influence global warming during specific intervals of geologic time, but when they are not that voluminous or persistent extensive arc magmatism may drive warming conditions.

PETROLOGICAL AND GEOCHEMICAL PECULIARITIES OF ALKALINE ROCKS IN THE NORTH-WESTERN REGION OF THE UKRAINIAN SHIELD

The data of chemical composition and content of trace elements in alkaline-ultrabasic rocks of the northwestern region of the Ukrainian Shield are summarized. The occurrences of alkaline rocks of this composition were discovered as results of drilling in four areas (Horodnytska, Hlumchanska, Bolyarkivska, and Hubkivska). They are presented by small hypabyssal intrusions, stem- and dike-like bodies. The rocks are represented by the jacupirangite-melteigite series, which belong to high-Mg (Mg# 0.7–0.8) varieties. Less common are alkaline and subalkaline gabbroids found in thin apophyses and veins near alkaline-ultrabasic bodies. It is assumed that these gabbroids were formed as a result of crust material contamination of the primary alkaline-ultrabasic melts. The alkaline-ultrabasic rocks of all occurrences have high Cr (233–2737 ppm) and Ni (95–1022 ppm), but are unusually depleted in incompatible elements (Nb, Ta, Zr, Hf, REE, Y), with moderate Ba and Sr. Their geochemical features sharply differ from similar rocks, carbonatite and alkaline complexes known as in the Ukrainian Shield and other regions of the world. Despite the primitive composition of alkaline-ultrabasic rocks and anomalous REE depletion, their chondrite-normalized patterns have negative slopes and are similar to differentiated rocks with a prevailing of LREE (La/Yb = 6–16). The petrogenesis of such primitive and trace-element depleted alkaline-ultrabasic rocks is enigmatic. We suppose that these unusual geochemical features are the result of primary melt(s) generation from mantle source and their evolution by a similar way. For the alkaline rocks of the Horodnytska and Hlumchanska intrusions, and possibly the Hubkivska occurrence, the primary melts arose through partial melting of garnet (with amphibole?) peridotites. At the same time, the primary melt for the Bolyarkivska intrusion was generated by partial melting of spinel peridotite, probably in a shallower environment. The anomalous depletion at HFSE and REE can be considered as the result of specific conditions of partial melting of depleted mantle source at low temperature and pressure, when refractory minerals concentrating these elements (rutile, amphibole) remained in the restite, or due to early crystallization and fractionation of concentrating minerals (perovskite, apatite).

Exploring the influence of wood ash, maize cob ash, and tequesquite (alkaline rock) on nixtamalization of maize

Nixtamalization, an ancient process vital for maize processing, enhances maize's nutritional value, texture, flavor, and shelf life while reducing mycotoxin contamination, making it a cornerstone technique in maize processing with both nutritional and food safety implications. Initially performed with ashes, modern nixtamalization relies on food-grade calcium hydroxide or calcium oxide (lime). However, regions lacking lime deposits or processing technology necessitate alternative nixtamalization options for sustainable maize processing. This study aimed to assess the mineral composition of alkaline rocks (tequesquite) and two types of ash (wood and maize cob) and determine the optimal cooking conditions to achieve tortillas comparable to those made from lime-nixtamalized maize. Different ash and tequesquite concentrations (5%, 10%, and 15%) were tested with nixtamalization durations of 40, 50, and 60 min. Quality parameters of nixtamal and tortillas were evaluated. Data were analyzed using a completely randomized design with Tukey's comparison of means (p ≤ 0.05) and principal components analysis. Results revealed potassium as the predominant element in the ash, while sodium prevailed in tequesquite. Although significant differences were observed in nixtamalization variables, tortillas made with 5% maize cob ash or tequesquite closely resembled those treated with lime in terms of quality parameters.

Carbonatite research: The African Legacy

Almost all igneous rocks are composed of silicate minerals; carbonatites are the main exception to this rule. They form only a minor proportion of the continental crust but are of fundamental scientific and economic importance. These rocks, originally described as a limestone (Kaiserstuhl, Germany) or magmatic limestone (Alnö, Sweden), were recognized in 1921 by W. C. Brøgger as a distinct magmatic rock type under the name “Karbonatite” in the Fen complex (Norway). Extensive field mapping in Africa, and particularly studies within the Chilwa Alkaline Province (Malawi), have led to the discovery of diverse intrusive and extrusive carbonatites. The latter, including the Fort Portal volcanic field in Uganda, Rufunsa Province in Zambia, and Oldoinyo Lengai volcano in Tanzania (the only volcano ever to have been seen to erupt carbonatites), have been exceptionally important in the recognition of carbonatites as truly magmatic rocks. The possibility of the existence of carbonate melts has been confirmed and shown by experimental studies of diverse carbonate systems with added volatile components (H2O, F) and alkali elements (Na, K). The study of the Oldoinyo Lengai gregoryite-nyerereite carbonatites, which are mineralogically and compositionally different from all known carbonatites worldwide, has led to long-lasting discussions about the origin of carbonatites. This includes composition of primary/parental carbonate melt, derivation of carbonatites by either liquid immiscibility or fractional crystallization, carbonatite evolution, and especially, the possible genetic relationships between alkali-rich and alkali-poor carbonatites. The rapid alteration of Oldoinyo Lengai carbonatites and their transformation to calcite carbonatite-like rocks has been proposed as the explanation for the absence of alkali-rich carbonatites in the geological past. Detailed mineralogical studies have shown that the occurrence of nyerereite is not restricted to Oldoinyo Lengai and that this mineral is now known to occur in other carbonatites (e.g., Guly, Kovdor, Oka, Kerimasi), alkaline rocks, and kimberlites (and even in diamond). This would suggest compositionally different mantle-derived melts enriched in alkali elements. In addition, carbonatite tephra has an important role in the preservation of some key paleontologic and anthropologic localities in East Africa. Despite these important discoveries, several problems related to carbonatite petrogenesis are not yet resolved. Future work is required, and carbonatites within Africa, with its key localities, may help to solve these problems.

Mineral Textures and Chemistry Trace the Origin and Transcrustal Evolution of the Sanyuangou Syenite in Southern North China Craton

Abstract Alkaline rocks are widely distributed in various geological environments and are important carriers for exploring the formation and compositional diversity of continental crust. Extensive studies have investigated the processes of mantle melting and crustal differentiation that produced such rocks. However, the potential interaction processes between mantle-derived magma and crust during their formation are poorly constrained. In this study, we focus on a Paleoproterozoic garnet-bearing syenite in the Xiong'er large igneous province (LIP) on the southern margin of the North China Craton through detailed whole-rock and mineral analyses. The high K2O (7.4–8.8 wt %) syenite emplaced at ~1772 Ma with ancient inherited zircon (1800–2800 Ma). The dominant mineral assemblage is composed of clinopyroxene, garnet, and K-feldspar with a small amount of titanite. Complex compositional oscillatory zoning of clinopyroxene and garnet indicates that magma mixing played a significant role in the formation of the syenite. We estimated the major elements composition for melts in equilibrium with clinopyroxene and calculated the clinopyroxene/melt partition coefficients by crystal lattice strain model, thus calculating the trace elements of the equilibrated melts. The equilibrium melts of high Mg# (&amp;gt;85) clinopyroxene have high CaO/Al2O3 (&amp;gt;0.6) and low Hf/Sm (&amp;lt;0.4), which suggests a role for carbonatitic metasomatism of the mantle. The variables La/Yb (24.4–56.1), Dy/Yb (0.8–5.9), and Yb (0.6–10.3 μg/g) indicate that the initial melts were formed by 1% to 2% partial melting of spinel-garnet phlogopite lherzolite. An REE-based model for melts in equilibrium with low Mg# (&amp;lt;85) clinopyroxene indicates that 10% to 30% felsic magma from ancient crust participated in hybridization. In addition to well-documented magma mixing, the oscillatory zoning of garnet is also related to competition with titanite. The initial alkaline magmas have a high water content (~4 wt %), which delays the crystallization of K-feldspar, leading to the enrichment of K2O, until the K-feldspar accumulates in the shallow crust to form the syenite. Magma mixing under an open system further leads to alkalinity enrichment. Magma source and crustal evolution jointly determine the potassium-rich characteristics of syenite. Multiple episodes of magma mixing and fractional crystallization occur in the crust (700–300 MPa), suggesting complex and vertically extensive magma chambers. This study represents the first identification of carbonatitic metasomatism as a mantle source in the Xiong'er LIP. Furthermore, it offers a new perspective on magma mixing between the mantle and crust in transcrustal magmatic systems, contributing to the formation of alkaline rocks.

Classification of rare earths mineral resources using the Jequié/BA complex rock weathering chemical index

The most common economic mineral deposits of Rare Earths are associated to magmatic calc-alkaline to alkaline rocks and their products. This work presents data from drilling carried out in rocks of the Jequié/BA Complex, mineralized in rare earths, which were subjected to an intense weathering process, similar to what occurred in the Ion Adsorption Clays deposits in southern China. The interpretation of the survey data allowed the classification of rare earths mineral resources with similar, sometimes higher, levels than those of Chinese deposits, contained in the lateritic regolithic profile studied. The chemical index of rock alteration (CIA) was adopted as a classification tool, horizontally separating the mineralized weather profile into six zones. The data indicate that there was supergenic enrichment REO in the lower portions of the profile and sometimes in the upper zones. The average levels ranged between 0.09% and 0.22% REO, with maximum values of 1.6%. A model section representing the deposit of rare earths minerals of supergenic origin in rocks of the Jequié/BA Complex was developed.

Geochemistry, geochronology, and radiogenic isotopes of the Balmer and Confederation assemblages of the Laird Lake Area, Red Lake greenstone belt, Canada: implications for Archean tectonic evolution

The Laird Lake property, southwest Red Lake greenstone belt, straddles the contact between the Balmer (2.99–2.96 Ga) and the Confederation (2.74–2.73 Ga) assemblages. The property is 10 km along strike from the Madsen and Starrat–Olsen Au mines that are hosted near the contact. The Balmer assemblage consists of fine-grained, aphyric, locally pillowed mafic volcanic rocks, ultramafic intrusive and volcanic rocks with flow breccia textures hosting local spinifex-bearing clasts, and banded-iron formations. In contrast, the Confederation assemblage comprises porphyritic mafic volcanic rocks intercalated with intermediate to felsic volcanic rocks that include crystal lapilli tuffs, crystal tuffs, and tuffs. The Balmer assemblage is composed of tholeiitic mafic volcanic rocks with minor Al-undepleted komatiites, whereas the Confederation assemblage is calc–alkalic. Neodymium isotopes, in conjunction with trace element geochemistry, suggests that parts of the Balmer assemblage were weakly contaminated by an older intermediate basement. Both arc and back-arc volcanism occurs in the Confederation assemblage, with the arc rocks showing a stronger crustal component than the back-arc rocks. A maximum U–Pb age of 2741 ± 19 Ma for a crystal tuff and an age of 2737.68 ± 0.79 Ma for a diorite are consistent with a Confederation assemblage affinity for the intermediate calc–alkaline rocks south of the Au-bearing horizon. The Balmer assemblage represents an oceanic plateau formed by plume magmatism on the margins of the North Caribou Terrane, whereas the Confederation assemblage at Laird Lake formed in an oceanic arc setting where both arc and back-arc volcanism occurred simultaneously.