Alkali Feldspar Granite Research Articles

Water content drives distinct evolution trajectory of Early Cretaceous granitoids in inland and coastal southeast China

Water plays a crucial role in determining the crystallization sequence of magma, which subsequently influences the chemical compositions of magmatic rocks across different tectonic settings. In this study, we compared the evolutionary features of granitic rocks along the coast and inland areas of southeast China, aiming to identify the key factors influencing their evolution. Our work indicates that multiple granitic intrusions formed between 126 and 142 Ma in the coastal region of southeastern China, which is consistent with the formation ages of large-scale granitoids in the inland Gan-Hang Belt. Isotopic characteristics suggest that the granitic rocks in southern Fujian originated from the melting of juvenile crust, while those in northern Fujian and eastern Zhejiang were formed from the partial melting of ancient crustal rocks, incorporating mafic magma evolved from the mantle. Most of the granitoids from the coastal region of southeastern China exhibit low zircon saturation temperatures (680–800 °C) and Zr/Sr ratios (<1), suggesting their origin from a cold, wet magma reservoir. The porphyritic quartz diorite and porphyritic monzogranite represent the residual cumulate rocks of this hydrous magma reservoir, whereas the granitic porphyry and high-silica equigranular alkali feldspar granite evolved from the felsic melts extracted from the same reservoir. In contrast, most of the Early Cretaceous granitoids in the Gan-Hang Belt, located in the inland areas of southeast China, display high zircon saturation temperatures (800–900 °C) and Zr/Sr ratios (>1), indicating their origin from hot, water-poor magma reservoirs. The porphyritic granites in this region represent residual cumulate rocks formed in water-poor magma reservoirs, whereas the high-silica equigranular granites evolved from hot felsic melts extracted from similar magma reservoirs. In the Early Cretaceous, the coastal region of southeastern China was closer to the Late Mesozoic paleo-Pacific subduction zone, where crystal-melt segregation within cold, wet magma reservoirs predominantly influenced magma evolution. Conversely, the granitoids in the Gan-Hang Belt in the inland region, located farther from the Late Mesozoic paleo-Pacific subduction zone, were associated with a rift tectonic setting and formed through crystal-melt segregation within hot, water-poor magma reservoirs. Our study underscores the critical role of water content in magma reservoirs in shaping the chemical composition of granitic rocks through crystal-melt segregation, thereby deepening our understanding of crustal formation processes across diverse tectonic environments.

The geology of the Aracruz pluton (Espírito Santo, Brazil), a Cambrian post-orogenic intrusion in the aftermath of Gondwana amalgamation

ABSTRACT We present the first geological map of the Aracruz pluton (Espírito Santo, Brazil), which belongs to the late Cambrian post-orogenic suite that intruded the Nova Venécia metapelites and Ediacaran syn-orogenic S-type granites of the Araçuaí belt. Our mapping coupled with airbone magnetic and radiometric observations reveals that the pluton is not regularly zoned. It is composed of porphyric alkali feldspar granites, into which charnockite and quartz-diorite bands intruded as several pulses while the granites were a deforming crystal mush, and an undeformed central norite emplaced when most movement of the host magma had ceased. Steep-dipping concentric magmatic foliation, magmatic foliation parallel to tectonic foliation in the country rock, the noritic core, and the irregular charnockite and quartz-diorite band alignment suggest buoyancy-driven diapirism as emplacement mechanism. The Aracruz pluton is a superb example of mantle-derived post-orogenic intrusion attesting for the production of continental crust during the final stages of a Wylson cycle.

Advanced exploration of rare metal mineralization through integrated remote sensing and geophysical analysis of structurally-controlled hydrothermal alterations

Fusing multi-source (remote sensing and geophysical) data and diverse approaches validation in targeting hydrothermal alteration and structural anomalies enhances the potential for accurately detecting and characterizing mineralization zones. Sentinel 2 data and ASTER were processed for lithological and hydrothermal alteration mapping in the rare metal-rich Umm Naggat area (Egypt). Different image processing techniques were implemented, including false color composites, minimum noise fraction, band rationing, band math, mineral indices, relative absorption band depth, and constrained energy minimization. The rare metal-bearing Umm Naggat younger granite (NYG) pluton was lithologically discriminated and intra-differentiated to mafic-rich biotite granites, mafic-poor alkali feldspar granites, and albitized granites. Extensive hydrothermal alterations, such as albitization, ferrugination, propylitization, argillization, and phyllitization, overprint the NYG pluton. Normalized standard deviation, automatic lineament extractions, and trend analysis highlighted the key structural directions (NW, NNW, NNE, and NE) and distinguished the NYG pluton as a moderate to high structural density zone. The high structural density and intensive alteration zones are spatially associated and more localized within the NYG pluton than the surrounding rocks. Spatial overlay analysis confirmed that the hydrothermal alterations and fluid circulation systems are structurally-controlled. Furthermore, the hydrothermal alteration mapping and structural analysis outcomes were verified by combining fieldwork, slab polishing, petrographic investigations, and mineral chemistry through semi-quantitative scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and quantitative electron probe microanalysis (EPMA) analysis. As a result, the hydrothermal genesis of rare metal-bearing minerals (Nb-rutile, Nb-ilmenite, and columbite) close to or incorporated within alteration minerals (chlorite, muscovite, and hematite) is confirmed from the alteration zones (propylitic, phyllic, and ferruginated). In addition, biotite muscovitization and chloritization significantly contribute to the secondary rare metal enrichment. The current study emphasizes the extensive distribution of secondary rare metal-bearing minerals within the entire NYG pluton (not only limited to the northern albitized granite as depicted by previous studies), which might shed light on these hydrothermally-altered younger granites as a new potential source for Nb and Ta in Egypt.

Patterns distribution, concentrations and sources of radioactive elements from black sand in the Red Sea coast, Egypt

In Egypt, the distribution of black sand in various coastal regions has been readily apparent by thorough research. Unfortunately, these investigations did not measure radioactivity in black sand, particularly in the vicinity of the Red Sea. Gamma-ray spectroscopy was used to detect the naturally occurring radioactivity from 238U, 232Th, 40K, and 226Ra in black sand samples from eight locations along the Red Sea coast: Ras Elbehar, Gemsa, Hurghada Elahiaa, Hurghada Titanic, Safaga, Qusier Elsharm Alqbly, Gabal Alrosass, and Marsa Alam. The resultant data were interpolated to represent the spatial distribution. Additionally, the potential rocks sources of radionuclides were geologically mapped to elucidate the relationship between rock components and radioactivity. The results showed that 226Ra, 232Th and238U were higher at samples collected from Ras Elbehar, Hurghada Elahiaa and Hurghada Titanic compared to the other sites. On the other hand, 40K showed the lowest mean value (75.3 ± 3.8 Bq/kg) in Hurghada Titanic samples, while it peaked (563 ± 28 Bq/kg) in Qusier Elsharm Alqbly samples. The interpolated results show notable differences in radioactive amounts between the north and south, which are indicative of several environmental conditions and human activities. Alkaline syenite, syenogranite, older granites (tonalite and granodiorite), and minor acidic volcanic/metavolcanic rocks make up the upstream area of the basin area draining into, for example, the Ras Elbehar locality (highest activity concentrations for 238U (1596 ± 80 Bq/kg) and 226Ra (886 ± 44 Bq/kg)), while alkali-feldspar granite, schist, and shale rocks make up the mid-stream area. The findings provide a basis for scientific forecasting on the impact of synthetic or naturally occurring radioactive isotopes introduced into aquatic environments.

Geochronological Assessment of the Arabian-Nubian Shield plutonic intrusions in the arc assemblages along the Qift-Quseir transect, Central Eastern Desert of Egypt

The ophiolitic mélange and granitic intrusions along the Qift‒Quseir transect in the Central Eastern Desert (CED) of Egypt are parts of the Egyptian Nubian Shield (ENS), which is the northern segment of the East African Orogeny (EAO). The Arabian-Nubian Shield (ANS) is the longest Neoproterozoic belt on Earth, and it was formed during the East and West Gondwanaland collisions within the framework of the EAO. The ANS basement rocks were developed during three distinct phases of magmatic activity: the island arc and syn-collisional phases, identifying a compressional tectonic regime, and a post-collisional phase that identifies changing the tectonic regime into an extensional type. The geochronological assessment of these magmatic activities is essential for understanding the regional geology and tectonic development of the ANS. In our study, we dated different rock units along the Qift‒Quseir transect and revealed ages ranging from the Late Tonian (820 ± 8 Ma) to the Late Ediacaran (563 ± 4 Ma). These ages were associated with three different magmatic pulses: (1) a seafloor spreading and island arc phase (ophiolite and related rocks), represented by sample QQ05, which was dated from 820 ± 8 Ma; (2) a syn-collisional phase, represented by samples QQ08 and QQ10, dated from 733 ± 10 Ma and 729 ± 10 Ma, respectively; and (3) a post-collisional phase, represented by all the other samples, dated from the Ediacaran at 603 ± 9 Ma to 563 ± 5 Ma. These results showed that the post-collisional phase was dominant, especially in terms of the alkali-feldspar granites, relative to ophiolitic rocks, and the syn-collisional granites in the CED. Initiation of the Dokhan Volcanic eruptions at 639 ± 2 Ma gave us the date of the compressional-to-extensional tectonic transition setting, and the post-collisional tensional regime was activated at 603 ± 9 Ma. Additionally, we identified evidence of local magmatic sources by dating 11 grains of Paleo- to Meso-Proterozoic xenocrysts with ages ranging from 1876 ± 18 to 1070 ± 13 Ma (i.e., components of the pre-Arabian-Nubian Shield).

New insights on the petrogenesis of the Koktokay No.3 pegmatitic dyke: Petrological and zirconological evidence from the Aral granitic complex (Xinjiang, China)

The Koktokay No.3 pegmatite dyke (KPD), containing numerous Li–Be–Nb–Ta–Cs mineral resources, is among the world’s most famous rare-metal deposits, and attracted much attention. Up to now, over thirty geochronological data have been reported ranging from 332 Ma to 120 Ma for the KPD, which causes uncertainty about the origin and petrogenesis of the pegmatite. In this contribution, whole-rock geochemistry and zircon geochronology have been conducted on the Aral biotite monzogranite (BMG), the Koktokay muscovite alkali-feldspar granite (MAG), and the KPD. Petrological and whole-rock geochemistry results reveal that the BMG is normal granite with medium SiO2 (mean of 67.23 %), enriched in compatible trace elements such as Ba, Sr and Zr, and slight negative Eu anomalies, while the MAG belongs to highly-fractionated granite with high SiO2 (mean of 73.92 %) and extensive negative Eu anomalies, and enriched in incompatible trace elements such as Rb, Ta, and U. Zircon morphology and LA–ICPMS analysis reveal that magmatic zircons from the BMG, hydrothermal zircons from the MAG and KPD yield lower intercept ages at 217.3 ± 2.4 Ma, 197.8 ± 4.7 Ma, and 195.4 ± 2.0 Ma, respectively. Combining with tectonic information and geochronological data of granitic activity and its mineralization in the Altay, this study explains the petrogenetic mechanism of the KPD after Wang et al. (2021)‘s metallogenic model: (1) In late stage of Middle Triassic, the collision between the Siberian plate and the Kazakhstan–Junggar plate caused a large number of thrust nappe faults and crust thickening in the Altay orogenic belt; At ∼217 Ma, the compression reached its peak, the crustal anatexis produced syn-collisional BMG (i.e., the Aral BMG); After the compressive peak, huge amount of granitic magma in deep-seated magma chamber underwent over 20 Myr of fractional crystallization, and the residual magma enriched in ore-forming materials (rare metal elements, volatile components, and aqueous fluids) occurred at the top of the magma chamber; (2) When the regional stress converted from compression to extension, the highly-fractionated residual magma ascended rapidly from the long-lived magma chamber along extensional faults at ∼195 Ma; The huge amount of melt-bearing fluids were exsolved from the residual magma in the course of its emplacement due to sharply decreasing pressure, and intruded into a large cavity generated by extensional fault; Along with slowly decreasing temperature, the melt-enriched fluids crystallized outside-in as (quasi-) concentric pegmatitic zones (i.e., KPD); (3) The residual magma which lost huge amount of fluid filled the lower space of the extensional system, and crystallized as post-collisional MAG (i.e., the Koktokay MAG). Based on the genetic relationship among tectonics, petrogenesis, and metallogeny, the proposed model shows material and energetic conversion processes from syn-collisional granites to post-collisional granites with granitic–pegmatitic deposits

Enhanced geological and radioactive mapping of Gabal Abu Ashayir-Gabal El Bakriyah area, central Eastern Desert, Egypt, using remotely sensing data

AbstractThe primary goal of this work is to integrate airborne gamma-ray spectrometry with multispectral data from ASTER and Landsat-8 for mapping of the geology, radiometric data, and types of alterations of Gabal Abu Ashayir-Gabal El Bakriyah area, central Eastern Desert, Egypt. Utilizing various image processing techniques like color band composites (CBC), principal component analysis (PCA), band ratios (BR), and minimum noise fraction (MNF), it is possible to map the hydrothermal alterations zones and identify the lithological units under investigation. By identifying the various lithological units and alteration types, these results are validated and verified in the field. These methods’ outputs are combined to create an accurate geological map of the research region and tracing the propylitic, phyllic and iron oxy-hydroxides alterations. These rock units are ophiolitic mélange (oldest), arc metavolcanics, arc granitoids, younger gabbro, late-collision granites (monzogranites, syenogranites and alkali feldspar granites) and Nubian Sandstone (Taref formation and Quseir Formation) youngest, Furthermore, the radioactive anomalies are primarily associated with ferrugination zones (iron oxy-hydroxides alteration) at Gabal El Bakriyah monzogranite and alkali feldspar granite. The radioactive minerals are uranothorite, thorite and fergusonite. The opaque minerals that encountered at the rock units of Gabal Abu Ashayir-Gabal El Bakriyah are chromite, ilmenite, magnetite, chalcopyrite and chalcocite, whereas the non-opaque minerals comprises titanite, rutile, fluorite, garnet, zircon, apatite and barite.

Age and petrogenesis of the Madi intrusion in the Huashi area, northern margin of the North China Craton: Implications for magma evolution and Nb–Ta mineralization

Although the mineralization of rare earth elements (REEs) and rare metals is intimately associated with the extreme fractionation of granitic magmas, the metallogenic intrusions of many granite-hosted Nb–Ta deposits have undergone fluid–melt interaction. Nevertheless, the precise mechanisms by which fluid–melt interaction influences mineralization remain poorly understood. The present investigation examines the issues of the fluid–melt interaction in highly fractionated granites with Nb–Ta mineralization, utilizing data from the newfound Huashi deposit in the northern margin of the North China Craton (NNCC). The Huashi Nb–Ta–Rb–Li deposit hosted in the Madi intrusion consists of two lithologies that have evolved continuously, namely medium–fine grained granite (MGG) in the lower section and alkali-feldspar granite (AG) at the top. The ages of the MGG and AG were determined using LA–ICP–MS columbite U–Pb dating, yielding values of 182.9 ± 1.7 Ma and 184.7 ± 1.3 Ma, respectively. The Madi intrusion has high SiO2, Al2O3, and total alkali contents, along with low CaO, MgO, MnO, and TFe2O3 contents and high Al2O3 / (CaO + Na2O + K2O) (A/CNK) values, classifying it as highly peraluminous granite with a high-K calc-alkaline affinity. Additionally, the intrusion also exhibits enrichment in Rb, U, Th, and Nb alongside significant depletion in Sr, Ba, Ti, Eu, and P, with a noticeable tetrad effect of REEs. The investigation of mica and feldspar minerals in the Madi intrusion using electron probe microanalysis (EPMA) indicates that the mica is mainly zinnwaldite, while the plagioclase belongs to albite. In summary, the Madi intrusion exhibits a highly I-type fractionated granite affinity. The extreme fractionation, intense fluid–melt interaction, and hydrothermal alteration of the intrusion contribute to the formation of the Huashi deposit.

Geochronology and Geochemical Characteristics of Granitoids in the Lesser Xing’an–Zhangguangcai Range: Petrogenesis and Implications for the Early Jurassic Tectonic Evolution of the Mudanjiang Ocean

This article focuses on zircon U-Pb isotope dating and a whole-rock elemental analysis of granodiorites, monzonitic granites, granodioritic porphyries, and alkali feldspar granites in the Yangmugang area of the Lesser Xing’an–Zhangguangcai Range. The zircon U-Pb isotope-dating results revealed that these granitic rocks formed during the late Early Jurassic period (182.9–177.2 Ma). Their geochemical characteristics and zircon saturation temperatures suggest that the granodiorites are moderately differentiated I-type granites and the monzonitic granite, granodioritic porphyries, and alkali feldspar granites are highly differentiated I-type granites. The degree of magma differentiation progressively increased from granodiorites to alkali feldspar granites. By combining the regional Nd and Hf isotope compositions, it was inferred that the magma source involved the melting of lower crustal material from the Mesoproterozoic to the Neoproterozoic eras. By integrating these findings with contemporaneous intrusive rock spatial variations, it was indicated that the late Early Jurassic granitoids in the Lesser Xing’an–Zhangguangcai Range formed within an extensional tectonic setting after the collision and closure of the Songnen–Zhangguangcai Range and Jiamusi blocks. Additionally, this study constrains the closure of the Mudanjiang Ocean to the late Early Jurassic period (177.2 Ma).

Integrative mapping of radioactive and alteration zones in Um Had plutons, Egypt: Using Landsat 9, ASTER imagery, and airborne geophysical data

The study aims to assess the effectiveness of using ASTER, Landsat 9, and airborne geophysical data to generate maps depicting hydrothermally altered regions and their correlation with radioactive-mineralized zones in Egypt's Um Had area. Various image processing methods were applied, including color composite images, band ratios, selective principal component analyses, and lineament extraction with enhancement procedures. The ASTER ratios identified the three types of hydrothermal alterations; phyllic, argillic, and propylitic, with other significant alteration zones related to mineralization. Airborne gamma-ray spectrometry contour maps displayed marked varied levels of total count (T.C), eU, eTh, and K, ranging from 1.2 to 21.2 Ur, 0.5–12.34 ppm, 1.45–28 ppm, and 0.13–3.65 %, respectively. The highest anomalies of these radioelements concentration have coincided with the alkali feldspar granite and along their intrusive contact zone with the Hammamat Group sedimentary rocks. Higher anomalies are well recorded in the center and eastern regions of Um Had's, according to the radioelements composite image. The lowest concentrations of these radioelements are associated with gneiss, ophiolitic mélange, metavolcanic, Hammamat Group sedimentary rocks, Taref Formation, and Wadi sediments. To mitigate local magnetic effects, the total aeromagnetic data was reduced to the north magnetic pole (RTP). Power spectrum analysis of the RTP data identified distinct magnetic wavelengths for regional-residual components. In order to identify near-surface magnetic lineaments, such as contacts, shear zones, faults, and dykes, advanced algorithms were applied to the RTP data. The lineaments derived from ASTER and airborne magnetic data revealed dominant fault systems characterized by E–W, NE, NNW, NW and N–S trends, governing the structural framework of the study area. Depth levels of geological contacts and faults that represented pathways for altered and mineralized zones reached more than 1200 m (Euler deconvolution). These findings highlight the consistent results obtained when combining ASTER data with airborne survey data, allowing for the identification of hydrothermally altered zones and primary conductive zones.

Studies of radioactive minerals and geochemistry of uranium at the granitic rocks of Wadi Um Shillman Area, South Eastern Desert, Egypt

The northwestern part of Gabal Um Ara granitic pluton is represents a good example for uranium occurrence in the southeastern desert of Egypt. Among the different lithologies in the study area, the granitic rocks attract attention for more detailed geological, geochemical and radiometrical studies. Um Ara granitic masses cover an oval outline area of about 300 km2, which is characterised by moderate topography. The granitic rocks are classified as monzogranite and alkali feldspar granite. Both of them belong to the post-orogenic younger granite magmatic activity that intruded the Egyptian shield between 620 and 530 Ma. The intrusion of Um Ara monzogranite and alkali feldspar granite appears to have been controlled by deep-seated tectonic zones and block faulting. The studied area lies at southeast of Aswan City between 22ͦ 38′ 12˝–22ͦ 38′ 34˝ N and 33ͦ 47′ 27˝–33ͦ 48′ 14˝ E. Geochemically, the average concentration of the elements in North Um Ara granite shows that the relative abundance decreases gradually with decreasing incompatibility from Rb to Y. The common features are enrichment in more mobile elements Rb, Th and U. The monzogranite shows the lowest U and Th content, whereas the alkali-feldspar shows an enhanced contents of both elements, with average Th/U ratio = 3.0. the alkali-feldspar exhibits an expanded enrichment of Th relative to U. The U of the alkali-feldspar may be included within the structure of the refractory accessory minerals. The northern part of the Um Ara granitoids has subjected to different types of alterations. The radiometric survey of the northwestern part of Gabal Um area granitic pluton revealed the presence of several radioactive anomalies near the contact with the Dokhan volcanic and metavolcanic rocks in the north. Some visible uranium mineralisation of uranium minerals occur mainly along the NW, NE, E-W and N-S joints, of a highly sheared alkali feldspar-granite. Uranophane is visible secondary uranium mineral, characterised by bright yellow lemon colours and occurs mainly as filling fractures and joints associated with violet fluorite, iron and manganese oxides. The radioactive and accessory minerals studying and X-ray diffraction analysis that of the mineralised alkali feldspar-granite granite in the northwestern part of Gabal Um Ara granitic pluton revealed include the presence of fluorite, zircon, columbite, spessartine garnet whereas, the secondary uranium minerals are represented by uranophane, β-uranophane and kasolite. The hydrothermal origin was proposed as two possible alternatives for this uranium mineralisation.

Mineral Recource Prospecting and Evaluation of Dry Stream Sediments of Wadi Umm Gheig – Umm Naggat Area, Eastern Desert, Egypt

The area of Wadi Umm Gheig-Umm Naggat is located at the central part of the Eastern desert, Egypt, 50km south to El-Quseir city at the Red Sea coast. The area is dominated by metavolcanics, Older Granites, Dokhan Volcanics, intrusive cumulate gabbro and Younger Granites. This works focuses on heavy minerals distributed in dry stream sediments of Wadi Umm Gheig and Gabal Umm Nagat. The study has followed up the traditional methods for sample collection from the stream sediments and the plane study for investigation and prospecting, as well as evaluation of heavy mineral deposits. The studied bed rocks are represented mainly by monzogranite, alkali feldspar granite, syenogranite and alkali granite. The investigated heavy minerals dominating the stream sediments are given by magnetite, ilmenite, rutile, leucoxene, zircon, fluorite and apatite which are arranged in decreasing order as percentages of abundances. Few trace minerals are detected in some samples like thorite and monazite, and xenotime as well. The evaluation of heavy minerals concentration reveals higher concentration of magnetite, ilmenite and zircon at the western sector, while fluorite show random distributions within the stream sediments area.

A-type tonian granite in the northwest of the gavião block: Record of within-plate magmatism precursor to the continental rifting of the São Francisco paleoplate?

The Early Tonian period in the São Francisco Craton represents the development of an intracontinental rift across the northern and central Espinhaço regions, playing a crucial role in understanding the tectonic evolution of the Neoproterozoic Period within this craton and its adjacent orogens. This rift is associated with the breakup of the São Francisco paleoplate, marked by the formation of several rifts, some of which were aborted (e.g. Santo Onofre Rift), and magmatism associated. Field investigations, coupled with petrographic, lithogeochemical, and U–Pb geochronological data of the Serra do Meio Suite, elucidate key characteristics and offer significant insights into the Tonian tectonic evolution of the São Francisco Craton and its relationship with Santo Onofre Rift. The suite comprises metagranitoids exhibiting a mineralogical composition spanning from alkali-feldspar granites to granites and its petrogenesis and tectonic characteristics reveal an alkaline to calc-alkalic signature, exhibiting extreme ferroan geochemistry and indications of moderate to high oxygen fugacity. Pressure estimations suggest low-pressure conditions during magma crystallization, implying shallow crustal emplacement. The suite's evolution involves complex petrogenetic processes, likely influenced by fractional crystallization and contamination by country rocks from a quartz-feldspathic crustal source, as well as a possible contribution from juvenile tholeiitic mantle sources associated with rift environments, showcasing a signature typical of A1-type granite. The U–Pb SHRIMP age, determined as 930 ± 2 Ma (MSWD = 0.34), is interpreted as the crystallization age of the rock and allows us to connect it to the opening of the Santo Onofre-Macaúbas Rift in the São Francisco Craton.

Genesis of Rare Metal Granites in the Nubian Shield: Tectonic Control and Magmatic and Metasomatic Processes

The Igla Ahmr region in the Central Eastern Desert (CED) of Egypt comprises mainly syenogranites and alkali feldspar granites, with a few tonalite xenoliths. The mineral potential maps were presented in order to convert the concentrations of total rare earth elements (REEs) and associated elements such as Zr, Nb, Ga, Y, Sc, Ta, Mo, U, and Th into mappable exploration criteria based on the line density, five alteration indices, random forest (RF) machine learning, and the weighted sum model (WSM). According to petrography and geochemical analysis, random forest (RF) gives the best result and represents new locations for rare metal mineralization compared with the WSM. The studied tonalites resemble I-type granites and were crystallized from mantle-derived magmas that were contaminated by crustal materials via assimilation, while the alkali feldspar granites and syenogranites are peraluminous A-type granites. The tonalites are the old phase and are considered a transitional stage from I-type to A-type, whereas the A-type granites have evolved from the I-type ones. Their calculated zircon saturation temperature TZr ranges from 717 °C to 820 °C at pressure &lt; 4 kbar and depth &lt; 14 km in relatively oxidized conditions. The A-type granites have high SiO2 (71.46–77.22 wt.%), high total alkali (up to 9 wt.%), Zr (up to 482 ppm), FeOt/(FeOt + MgO) ratios &gt; 0.86, A/CNK ratios &gt; 1, Al2O3 + CaO &lt; 15 wt.%, and high ΣREEs (230 ppm), but low CaO and MgO and negative Eu anomalies (Eu/Eu* = 0.24–0.43). These chemical features resemble those of post-collisional rare metal A-type granites in the Arabian-Nubian Shield (ANS). The parent magma of these A-type granites was possibly derived from the partial melting of the I-type tonalitic protolith during lithospheric delamination, followed by severe fractional crystallization in the upper crust in the post-collisional setting. Their rare metal-bearing minerals, including zircon, apatite, titanite, and rutile, are of magmatic origin, while allanite, xenotime, parisite, and betafite are hydrothermal in origin. The rare metal mineralization in the Igla Ahmr granites is possibly attributed to: (1) essential components of both parental peraluminous melts and magmatic-emanated fluids that have caused metasomatism, leading to rare metal enrichment in the Igla Ahmr granites during the interaction between rocks and fluids, and (2) structural control of rare metals by the major NW–SE structures (Najd trend) and conjugate N–S and NE–SW faults, which all are channels for hydrothermal fluids that in turn have led to hydrothermal alteration. This explains why rare metal mineralization in granites is affected by hydrothermal alteration, including silicification, phyllic alteration, sericitization, kaolinitization, and chloritization.

Geochemical and petrological diversity of a transcrustal magmatic system driven by mushy magma mixing: Insights from the Triassic dike swarms in East Kunlun orogen, northern Tibetan Plateau

Geochemical and petrological diversity within transcrustal magmatic systems usually reflects the magma properties and magmatic processes and thus is critical to understanding the origin of magmatic complexes and the evolution of continental crust. Herein, we present an integrated study on the petrology, mineralogy, geochronology, geochemistry, and Sr-Nd-Hf isotopes of Triassic mafic-felsic dikes in the East Kunlun orogenic belt, northern Tibetan Plateau, to elucidate the nature and evolution of the transcrustal magmatic system. The studied dikes intruding into the granodiorite pluton (ca. 235−233 Ma) comprise coeval ca. 220−218 Ma gabbroic diorite porphyry, diorite porphyry, granodiorite porphyry, and alkali-feldspar granite, resembling composite dike swarms. The macrocrysts in these dikes show various zoning patterns, indicating episodic magma recharge and crystal resorption. The compositional gap between the intermediate-mafic dikes (SiO2 = 52.9−67.8 wt%) and the granitic dikes (SiO2 &amp;gt;75 wt%), as well as their homogeneous whole-rock Sr-Nd isotopes, with (87Sr/86Sr)i = 0.708387−0.710995 and εNd(t) = −5.83 to −4.34, but variable zircon Lu-Hf isotopes, i.e., εHf(t) = −7.67 to −0.36, demonstrates that magma mixing rather than cogenetic fractional crystallization accounts for their origin. In combination with thermobarometric insights, these results suggest that the mafic and felsic parental magmas originating from an enriched lithospheric mantle and ancient continental crust, respectively, were ultimately emplaced and stagnated at varying crustal depths (∼22−30 km and 8−17 km). Subsequently, the felsic magma mush was replenished and rejuvenated by the underplated mafic magma, leading to varying degrees of crystal-melt and/or melt-melt mixing. This mush-facilitated crust-mantle magma mixing is an important mechanism accounting for the compositional diversity of the transcrustal magmatic system.

Space/ground-borne techniques and petrographic microscopic dissection for geologic mapping in Gabal Ras Abda area, Northeastern Desert, Egypt

BackgroundGabal Ras Abda area as a part of the Red Sea Mountain range, is characterized by inaccessible and rugged terrains. The exposed rock units are hardly followed in the field because of the rigid topography. Thus, the present work proposes and develops an integrated approach to map the exposed rock units and extract the geologic structures using satellite imagery data followed by both field and petrographic verification, saving time, efforts and cost.ResultsTo achieve the target, both the measured spectral signature curves with Landsat-8 and Sentinel-2A data were used to develop and create the most enhanced Band Ratios and Principal Components for lithological discrimination and mapping which were (((Band7 + Band 4)/(Band 7), (Band 2)/(Band 2 + Band 5) and (Band 5) in RGB) and ((Band 9 + Band 11 + Band 12)/(Band 1), (Band 4 − Band 2) and (Band 11/Band 6) + (Band 6) in RGB)) with Principal Component Bands ((PC1, PC2 and PC3 in RGB) and (PC3, PC2 and PC1 in RGB)), respectively. Also, georeferenced Google Earth Pro, panchromatic band of Landsat-8 and ALOS PALSAR Digital Elevation Model images were used to extract the structural lineaments. Geologic, petrographic and field structural studies were emphasized the remote sensing results, indicating that the main rock types cropped out in Ras Abda area from the oldest to the youngest are older granitoids (quartz-diorites, tonalites and granodiorites), Dokhan volcanics (andesites, rhyodacites, rhyolites and their related tuffs), younger gabbros, younger granites (monzogranites, syenogranites and alkali-feldspar granites), post-granite dykes and offshoots (acidic, microgranitic and basic types) and Phanerozoic sedimentary rocks. Also, the study emphasized that the E-W trend is the main structural trend controlling the investigated area followed by WNW-ESE and NE-SW directions.ConclusionsThe results of remote sensing achieved compliance with the geologic, petrographic and structural investigation through distinctly differentiating the different rocks and extracting the lineaments, indicating the accuracy of the remote sensing results and emphasizing their importance and effective role in producing a precise and highly accurate geologic map.Graphical abstract

Multi-stage magmatism and Sn-polymetallic mineralization in the Shuicheng Region, SW China

The economically important tin‑tungsten mineralization in southwestern China has attracted much interest in recent years, yet its age, tectonic setting, and genetic relationship to the host granites remain uncertain in most regions. Our focus in this study is the Shuicheng tin-polymetallic deposit, situated in the western sector of the Diantan Batholith, within the northern Tengchong Block. The granites in this area consist of two intrusive units, i.e., 1) biotite monzogranite (T1), with LA-ICP-MS zircon UPb ages ranging from 76.88 ± 0.43 Ma to 74.69 ± 0.57 Ma, whole-rock εNd(t) values ranging from −9.75 to −8.11, and zircon εHf(t) values from −12.19 to −8.85; and 2) alkali-feldspar granite (T2), with an LA-ICP-MS zircon UPb age of 52.16 ± 0.23 Ma, whole-rock εNd(t) values of −10.15 to −8.25, and zircon εHf(t) values of −9.64 to −8.06. These two intrusive events have been linked to prolonged low-angle subduction and retreat of the subducting Neo-Tethys Ocean Plate, respectively. The Shuicheng granites exhibit high concentrations of SiO2 and Al2O3, contrasted with low levels of FeOT, CaO, MgO, TiO2, and P2O5, suggesting that they are highly fractionated S-type granites. High abundances of Rb, K, U, and Hf, along with low contents of Ba, Sr, and Ti, further indicate significant fractionation and crystallization processes during magma evolution. Importantly, a transition from purely magmatic conditions to a magmatic-hydrothermal state occurred during the latter stages of magmatic evolution. This transition, associated with an amplified potential for tin mineralization, provides fresh insight into the role of magmatic processes in ore genesis, enriching our understanding of the tin‑tungsten mineralization history of the Tengchong region.

Magmatic–Hydrothermal Evolution at the Barren Wushan Pluton, Southeast China: Insight into Controls on Mineralization Potential

Abstract A-type granites typically exhibit enrichment and mineralization of critical metals such as molybdenum and tin, essential for emerging technologies. However, the key factors influencing their mineralization potential remain elusive. The scarcity of studies on barren systems impedes the understanding of this question. Here, a detailed melt and fluid inclusion study was conducted on the barren Wushan pluton to reconstruct its magmatic evolution and magmatic–hydrothermal transition and explore the factors controlling the metallogenic potential of Mo and Sn in A-type granites. The Wushan pluton displays apparent lithological zoning consisting of two major phases, i.e., medium-grained seriate to porphyritic alkali feldspar granite and fine-grained porphyritic granite. Miarolitic cavities are widely developed in each lithofacies. The silicate melt inclusions from two granitic phases are rhyolitic, with moderate F contents (0.06–0.53 wt %) and depleted H2O contents (2.0–3.5 wt %). Melt inclusions show a wide range of incompatible element contents, such as Cs (9–1977 μg/g) and Rb (268–2601 μg/g), suggesting that Wushan has undergone a high degree of magma evolution. Mo behaves incompatibly in the magmatic evolution, and its content is enriched with the increasing degree of fractional crystallization, but remains constant after the Cs content exceeds 50 μg/g. Rayleigh fractionation model suggests that a large amount of Mo is extracted from fluid exsolution, which restrains Mo from further enrichment. In contrast, Sn behaves as a mildly incompatible element during the entire magmatic evolution history. The contents of Sn increase slowly compared to the trend of Mo, and the maximum contents reach ~30 μg/g in the highly evolved melts. The separation and crystallization of Sn-bearing minerals such as biotite, magnetite, and titanite inhibit the enrichment of Sn. Intermediate-density (ID-type) fluid inclusions hosted in the miarolitic quartz, representing the initial fluid exsolving from magma, display high Mo but low Sn concentrations. Constrained from two assemblages of coexisting ID-type fluid and melt inclusions, the fluid/melt partition coefficients of metals are obtained, with DMo, fluid/melt at 16–19, while DSn, fluid/melt is only about 1. The comparison between Mo-mineralized and barren intrusions worldwide shows that the metal contents in melts and fluids are not fundamentally different. The mineralized intrusions are characterized by the lower melt viscosity and the development of apophyses, both of which facilitate the extraction of metals and fluids from large magma chambers, followed by their concentration into a small rock volume. Consequently, it appears that physical and structural conditions rather than chemical compositions play a crucial role in the Mo mineralization process. Enrichment of Sn in melts is necessary but not decisive for Sn mineralization, whereas Sn enrichment in the initial exsolving fluid determines the Sn mineralization potential of a given granitic system. Compared to Sn enrichment in source melting and fractional crystallization which commonly enhance final Sn fertility in the highly evolved melts, the efficiency of Sn partitioning between melt and fluid plays a fundamental role in converting melt fertility into Sn-enriched fluids and thereby high mineralization potential of the magmatic–hydrothermal system. Our findings suggest a prospect for Mo exploration in the coastal A-type granite belt in South China, while the potential for Sn mineralization is expected to be limited.

Evolution of Silurian to Devonian magmatism associated with the Acadian orogenic cycle in eastern and southern Newfoundland Appalachians: Evidence for a three-stage evolution characterized by episodic hinterland- and foreland-directed migration of granitoid magmatism

The migration and character of magmatism over time can provide important insights into the tectonic evolution of an orogen. We present evidence for three separate stages of compositionally distinct granitoid magmatism associated with the Acadian orogenic cycle in the eastern and southern Newfoundland Appalachians. The interpretations are based on new zircon U-Pb ages, geochemical data, and Sr-Nd-Hf-O isotopic data for 18 samples from 15 Silurian and Devonian granitoid plutons, combined with previously published data. The three stages outline hinterland- and foreland-directed migration trends and represent subduction (435−420 Ma), syncollision (415−405 Ma), and postcollision (395−370 Ma) settings in the Acadian orogenic cycle. The Silurian plutons (435−420 Ma) of the first stage consist mainly of quartz diorite, tonalite, granodiorite, monzogranite, and syenogranite, with high-K calc-alkaline and enriched Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −5 to −2; εHf[t] = −3 to −1; δ18O = +6‰ to +8‰). They are interpreted to record the subduction of oceanic lithosphere of the Acadian seaway that separated the leading edge of composite Laurentia, represented by the Gander margin, and Avalonia. Early Devonian plutons (415−405 Ma) of the second stage contain more voluminous monzogranite and syenogranite; they have calc-alkaline to high-K calc-alkaline features, adakite-like compositions, and more depleted Sr-Nd-Hf-O isotopic compositions (e.g., εNd[t] = −6 to 0; εHf[t] = +1 to +3; δ18O = +5‰ to +6‰). Plutons of this stage occur mostly to the northwest of the Silurian granitoids, indicating a regional-scale northwestward (hinterland-directed) migration of magmatism with a rate of &amp;gt;9 km/m.y. The migration is interpreted to have been related to the progressive shallow underthrusting of Avalonia beneath the Gander margin (composite Laurentia) at least as far as 90 km inboard. The Middle to Late Devonian plutons of the third stage (395−370 Ma) consist mainly of monzogranite, syenogranite, and alkali-feldspar granite, which are silica- and alkali-rich granites with large negative Eu anomalies. These rocks are concentrated along both sides of the Dover−Hermitage Bay fault zone, which represents the boundary between Avalonia and composite Laurentia, to the southeast of the Silurian and Early Devonian igneous rocks. This stage of magmatism represents a foreland-directed (retreating) migration. The Early Devonian and Middle to Late Devonian episodes of magmatism were separated by a gap between 405 Ma and 395 Ma and recorded an evolution from (high-K) calc-alkaline to alkaline compositions, ascribed to partial delamination of Avalonian lithospheric mantle in a postcollisional setting.

Geochronology and geochemistry of zircon and columbite–tantalite group minerals from the Weilasituo Sn–polymetallic deposit, northeastern China: Implications for the relationship between mineralization and the magmatic–hydrothermal transition

The Weilasituo Sn–polymetallic deposit, located in the southern portion of the Great Xing'an Range of Inner Mongolia, China, is a super-large Sn deposit associated with abundant Li, Rb, Nb, Ta, Zn, and Cu resources. Despite that previous studies have characterized the age, hydrothermal evolution, and genetic relationship between the alkali feldspar granite porphyry and associated Sn–polymetallic mineralization, the magmatic–hydrothermal evolution and ore–forming processes remain ambiguous. To address these ambiguities and bridge this knowledge gap, this contribution characterizes the texture, geochemistry, and U–Pb isotope composition of zircon and columbite–tantalite group minerals (CGMs) from amazonitized alkali feldspar granite (AMG) and albitized alkali feldspar granite (ABG) in the Weilasituo deposit. Type-I zircon (Zr1) is inclusion-poor, translucent, and is characterized by low light rare earth element (LREE) contents, high (Sm/La)N ratios (mean = 655.7), and low Th/U (mean = 0.21 < 0.3), Zr/Hf (mean = 5.46), and Y/Ho ratios (mean = 4.42), indicating that it formed during the magmatic–hydrothermal transition. Type-II zircon (Zr2) is inclusion-rich, porous, has a low CL response, and is characterized by low Th/U ratios (0.08–0.32, mean = 0.17), high LREE contents, weakly positive Ce anomalies, and low (Sm/La)N ratios (mean = 20.7), indicating that it formed via hydrothermal alteration of Zr1 (i.e., magmatic–hydrothermal zircon). Type-I CGM (CGM1) generally lacks oscillatory zoning, and has similar and positively correlated Ta/(Nb + Ta) and Mn/(Mn + Fe) values (AMG: R2 = 0.93; ABG: R2 = 0.75), indicative of a magmatic origin. Type-II CGMs (CGM2) occur as rims on CGM1 and are characterized by higher Ta/(Nb + Ta) and lower Nb/Ta ratios than CGM1, indicative of precipitation from a hydrosilicate liquid during the magmatic–hydrothermal transition. Based on the characteristics of CGMs, two stages are evident in the evolution of the Weilasituo granite porphyry: an earlier magmatic differentiation stage and a later magmatic–hydrothermal transition stage. Furthermore, the magmatic–hydrothermal transition stage can be subdivided into the AMG and ABG substages within the porphyry system based on petrological and mineralogical characteristics. The U–Pb ages for zircons and CGMs from the alkali feldspar granite porphyry range from 137.2 ± 2.0 Ma to 129.8 ± 1.4 Ma, without a notable age gap. The similarity in U–Pb ages between CGM1–CGM2 and Zr1–Zr2 indicates that the magmatic stage and the magmatic–hydrothermal transition at Weilasituo were continuous processes that occurred during the Early Cretaceous.