Al6Mn Phase Research Articles

Effects of grain size and Al-Mn phase on the corrosion performance of hot-rolled AZ31 magnesium alloy

Effects of grain size and Al-Mn phase on the corrosion performance of hot-rolled AZ31 magnesium alloy

Enhanced Strengthening and Toughening of T6-Treated 7046 Aluminum Alloy through Severe Plastic Deformation

The 7046 aluminum alloy possesses a favorable fatigue property, corrosion resistance and weldability, but its moderate strength and plasticity limit its wider application and development. In the present study, severe plastic deformation (SPD) was applied prior to T6 treatment to significantly enhance the strength and toughness of the 7046 aluminum alloy. The results show that the alloy processed by four passes of equal channel angular pressing (ECAP) at 300 °C prior to T6 treatment exhibits an excellent mechanical performance, achieving an ultimate tensile strength (UTS) and elongation (EL) of 485 MPa and 19%, respectively, which are 18.6% and 375% higher than that of the T6 alloy. The mechanical properties of the alloy are further improved by an additional room temperature (RT) rolling process, resulting in a UTS of 508 MPa and EL of 23.4%, respectively. The increased presence of η′ and Al6Mn phases in the 300°C4P-R80%-T6 and 300°C4P-T6 alloys contributes to a strengthening and toughening enhancement in the SPD-processed T6 alloy. The findings from this work may shed new insights into enhancing the 7046 aluminum alloy.

Study of Intergranular Corrosion Behaviors of Mn-Increased 5083 Al Alloy with Controlled Precipitation States of Al6Mn Formed during Homogenization Annealing

In this study, as a vital part of the production of Mn-increased 5083 Al alloy, i.e., homogenization annealing before hot rolling, the target states of key Al6Mn precipitation, including the dispersed, initial coarsening and intensive coarsening states, were designed, and the corresponding precipitates formed via the control of the temperature and holding time in the annealing process. By means of metallographic corrosion and nitric acid mass loss tests (NAMLT) for assessing the intergranular corrosion (IGC) resistance, temperatures ranging from 175 °C to 225 °C were determined to induce a transition from sensitization to stabilization for this innovative 5083. At a temperature of 175 °C for a duration of up to 24 h (2 h, 4 h, 8 h, 16 h, 24 h), the results show that when the soak time is 24 h, the sample with initially coarsened Al6Mn phases has a lower degree of sensitization (DOS) compared to the samples with Al6Mn phases in both the dispersed and intensive coarsening states, and its NAMLT is reduced by 11% and 15%, respectively. Subsequently, transmission electron microscopy (TEM) analysis has investigated that for the sample with the best IGC resistance, i.e., that with initially coarsened Al6Mn phases, plate-like Al6Mn particles (200~500 nm) can act as heterogenous nucleation sites for β phases, driving their preferential precipitation on Al6Mn particles and resisting their precipitation along grain boundaries, ultimately improving the IGC resistance of 5083 Al alloy after homogenization annealing.

Effect of cryogenic temperature on the strengthening mechanisms of AZ61 Mg alloy extruded at different temperatures

This study investigates the influence of extrusion and deformation temperatures on the mechanical properties of the AZ61 Mg alloy. Increasing the extrusion temperature from 300 to 400 °C led to larger grain size and higher basal texture intensity. At 400 °C, the AZ61 alloy exhibited more Al–Mn phases and fewer Mg17Al12 phases, indicating enhanced dissolution of Mg17Al12 in the α-Mg matrix. Uniaxial tensile tests were conducted at room temperature (RT) and cryogenic temperature (CT, −150 °C). Despite grain growth, a higher yield strength (YS) was achieved at higher extrusion temperatures due to the texture-strengthening mechanism. However, during deformation at CT, the higher YS was primarily attributed to the formation of multiple twinning within individual grains, causing twinning interactions. These twin-interacting boundaries create additional barriers to dislocation movement. Notably, the AZ61 sample extruded at 400 °C demonstrated the formation of stacking faults during deformation at CT, with dislocations accumulating around the faults. This contributed to the best strength without compromising ductility in this sample.

Biocorrosion and Cytotoxicity Studies on Biodegradable Mg-Based Multicomponent Alloys.

Magnesium-based multicomponent alloys with different compositions, namely Mg60Al20Zn5Cu10Mn5 (Mg60 alloy), Mg70Al15Zn5Cu5Mn5 (Mg70 alloy), and Mg80Al5Cu5Mn5Zn5 (Mg 80) alloys, were prepared using the disintegrated melt deposition technique. The DMD technique is a distinctive method that merges the benefits from gravity die casting and spray forming. This approach facilitates high solidification rates, process yields, and reduced metal wastage, resulting in materials with a fine microstructure and minimal porosity. Their potential as biodegradable materials was assessed through corrosion in different simulated body fluids (SBFs), microstructure, and cytotoxicity tests. It was observed that the Mg60 alloy exhibited low corrosion rates (~× 10-5 mm/year) in all SBF solutions, with a minor amount of corrosive products, and cracks were observed. This can be attributed to the formation of the Mg32(AlZn)49 phase and to its stability due to Mg(OH)2 film, leading to excellent corrosion resistance when compared to the Mg70 and M80 alloys. Conversely, the Mg80 alloy exhibited high corrosion rates, along with more surface degradation and cracks, due to active intermetallic phases, such as Al6Mn, Al2CuMg, and Al2Cu phases. The order of corrosion resistance for the Mg alloy was found to be ASS > HBSS > ABP > PBS. Further, in vitro cytotoxicity studies were carried out using MDA-MB-231 tumor cells. By comparing all three alloys, in terms of proliferation and vitality, the Mg80 alloy emerged as a promising material for implants, with potential antitumor activity.

Microstructure Evolution and Mechanical Properties of 7A52 Aluminum Alloy Thin Sheet Repaired with Friction Stir Surfacing.

A solid-state repair technique based on surface friction welding is investigated in depth to achieve excellent mechanical properties of damaged 7A52 aluminum alloy. The results show that the yield strength and tensile strength along the repair direction are 436 MPa and 502 MPa, respectively, at a rotational speed of 1400 rpm and a travel speed of 300 mm/min, which are about 157.9% and 129.7% of those before the defects were repaired, respectively, while the elongation is 17.2% compared to the base material. Perpendicular to the repair direction, the yield strength and tensile strength are 254 MPa and 432 MPa, which are 111.4% and 129.7% of those before the defects were repaired, respectively, while the elongation is 11.8% compared to the base material. The mechanical properties of the repaired areas are still improved compared to those of the defect-free sheets. On the one hand, this is attributed to the dynamic recrystallization of the nugget zone due to the thermo-mechanical coupling, resulting in the formation of a fine, equiaxed grain structure; on the other hand, the precipitated Mg2Si phase, which is incoherent within the base material, transforms into the Al12(Fe, Mn)3Si phase, as well as the precipitation of the Al6Mn phase and η' phase, resulting in the enhancement of the properties. The material fracture at the junction of the nugget zone and the heat-affected zone occurs after repair, which is attributed to the significant difference in the texture of the nugget zone and the heat-affected zone, as well as to the stress concentration at the junction.

Effect of Alloying Elements in Steels on the Interfacial Structure and Mechanical Properties of Mg to Steel by Laser-GTAW Hybrid Direct Lap Welding.

Mg alloy AZ31B was directly bonded to SK7 with a low alloy content, DP980 with a high Mn content, 316L with a high Cr and high Ni content by laser-gas tungsten arc welding (GTAW) and hybrid direct lap welding. The results showed that the tensile loads of AZ31B/SK7 and AZ31B/DP980 joints were 283 N/mm and 285 N/mm respectively, while the tensile load of AZ31B/316L joint was only 115 N/mm. The fracture and interface microstructures were observed using scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and identified through X-ray diffractometry (XRD). For AZ31B/SK7 and AZ31B/DP980, the interface of the front reaction area and the keyhole reaction area was mainly composed of an Fe-Al phase and an Al-Mn phase. However, for AZ31B/316L, the interface of the keyhole reaction area was mainly composed of an Fe-Al phase and an Al-Mn phase, but a multi-layer composite structure consisting of the Mg17Al12 compound layer and eutectic layer was formed in the front reaction area, which led to a deterioration in the joint property. The influencing mechanism of Mn, Cr and Ni elements in steel on the properties and interface structure of the laser-GTAW lap joint between the Mg alloy and the steel was systematically analyzed.

Influence of minor cerium addition on microstructure and fluidity of as-cast Al-Cu-Mn-Mg alloy

Al-Cu-Mn alloys are widely used to produce automobile components like cylinder heads and engine blocks because of their capability to retain excellent thermal and mechanical characteristics at high temperatures. However, the Al-Cu-Mn-based alloys demonstrate restricted fluidity, leading to casting defects such as shrinkage and incomplete filling. This research investigated the microstructure and fluidity of Al-4.7Cu-1.0Mn-0.5Mg (wt%) alloy with minor cerium (Ce) addition. The as-cast alloys predominantly comprise α-Al matrix, accompanied by the presence of Al2Cu, Al6Mn, and Al8Cu4Ce phases. The influence of adding Ce on the fluidity of the Al-4.7Cu-1.0Mn-0.5Mg alloy was investigated using a tri-spiral fluidity test mold in this research. The findings suggest that the addition of Ce within the range of 0.1 wt% to 0.5 wt% in the Al-4.7Cu-1.0Mn-0.5Mg alloy results in an enhancement in fluidity. Specifically, the alloy containing 0.4 wt% Ce exhibits a significant increase in fluidity distance, from 349.7 to 485.7 mm. This improvement can be attributed to the reduction in viscosity, the refinement of secondary dendrite arm spacing, and the modification of secondary phase particles. However, a higher concentration of Ce leads to a decrease in fluidity length, potentially due to the formation of Al8Cu4Ce.

Tuning the mechanical and corrosion properties of Al-Mg-Sc-Zr alloy processed by laser powder bed fusion through heat treatment

The current interest in Al-Mg-Sc-Zr alloy fabricated by powder bed fusion-laser beam (PBF-LB) is centered around excellent mechanical property without taking into account its corrosion behavior. In this work, gas-atomized Al-Mg-Sc-Zr alloy powder was manufactured by PBF-LB. The influence of heat treatment on microstructure, phase evolution, mechanical properties, and electrochemical corrosion behaviors were investigated and microstructure–property relationship was established to obtain high-performance alloy. The result suggests that the sample heat treated at 350°C for 4 h possesses highest mechanical properties, but is more susceptible to corrosion. When heat treatment temperature reaches 400°C, the loss of coherency for Al3(Sc, Zr) precipitates decreased the strength, but the Al6Mn phase is corroded as cathode instead of the α-Al matrix, thereby inhibiting the occurrence of pitting corrosion. The specimen heat treated at 300°C for 4 h exhibited high strength and high elongation as well as superior corrosion resistance.

Corrosion resistance of in situ steam LDH coating on AZ31 and AM30 Alloys: Influence of NaOH and Al–Mn phase

In situ formation mechanism of steam Mg–Al layered double hydroxide (Mg–Al–CO3-LDH) coatings on AZ31 and AM30 alloys was compared in presence of NaOH aqueous solution. The microstructure and elemental composition of the obtained coatings were analyzed using SEM, EDS, XRD and FTIR. The corrosion resistance of the coated samples was evaluated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and salt spray test. The results indicated that the addition of NaOH significantly influenced the morphology as well as the thickness of the prepared LDH coating. The effect of different Al–Mn phase contents of AZ31 and AM30 alloy on the growth mechanism of the LDH coatings was discussed. The addition of 0.01 M NaOH promoted the growth of the LDH coating on AZ31 and AM30 alloys. The AM30-NaOH-0.01 sample possessed the most compact and uniform surfaces as well as the maximum thickness. The corrosion current density of the samples was reduced by three orders of magnitude compared to their substrates. It was revealed that the addition of a moderate amount of NaOH in the steam would raise the pH level, which would benefit the dissolution of the aluminum phase and promote the growth of LDH coating.

EVOLUTION OF THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AL-B COMPOSITE WITH THE ULTRAFINE-GRAINED ALUMINUM MATRIX

The paper examines the microstructural evolution of alloy 1565ch of the Al-Mg-Mn-Zn-Zr system during thermomechanical treatment, including severe plastic deformation by high-pressure torsion or equal channel angular pressing according to the conform scheme and subsequent isothermal rolling at 200°C. Formation of the nanostructured and ultrafine-grained states in alloy 1565ch with the controlled distribution of Al3Mg2, Al6Mn and Al3Zr phases both inside grains and at their boundaries allows for the superplastic effect at the temperatures 250 and 300°C and strain rates 5 × 10-2, 10-2, and 5 × 10-3 s-1. Microstructural analysis by transmission electron microscopy shows that superplastic deformation at the temperatures 250 and 300°C allows a homogeneous ultrafine-grained state to be preserved. The studied ultrafine-grained aluminum alloy 1565ch has a high strength and the ability to relieve stresses, and therefore it can be favorably used as the matrix material in composites reinforced with continuous boron fibers. In the paper, we use this alloy to study special features of production of a multilayer metal matrix composite according to the foil-fiber-foil scheme by isothermal pressing in the low-temperature superplastic mode. This method has a positive effect on the mechanical properties of the composite, such as ultimate strength at 200°C, impact strength at room temperature, and fracture toughness at room temperature.

Effect of Mechanical Alloying on the Dissolution of the Elemental Mn and Al-Mn Compound in Aluminum

The grain boundary, solid solution, and precipitation strengthening mechanisms are important for controlling the mechanical properties of Al-based alloys. Due to severe plastic deformation, mechanical alloying refines grain structure to a nanoscale level which leads to a strong increase in solute content and the related strengthening effect of solute atoms and secondary-phase precipitates. This study analyzed the elemental Mn and Al6Mn phase dissolution in Al during high-energy ball milling. For this purpose, XRD data, microstructure, and hardness evolutions were compared for two Al—5.2 at% Mn alloys prepared by mechanical alloying using elemental Al and Mn powders and a pre-melted master alloy. In the two-phase master alloy, containing the Al solid solution and the Al6Mn phase, the strain accumulation, grain refinement, solid solution supersaturation, and milling-induced hardening effects were facilitated. Both elemental Mn and intermetallic compound were dissolved during mechanical alloying, and the maximum solute content was near 3.1 at% Mn. A fine crystalline size of ~25 nm and the maximum Mn solute content were observed after milling of elemental powders and the master alloy for 60 h and 20 h, respectively. The microhardness of ~3 GPa corresponded to a ~3.1% solute Mn content, and the microhardness increased to ~5 GPa after long–term milling due to precipitation strengthening effect of the secondary Al6Mn phase in the master alloy.

Development of low-carbon energy storage material: Electrochemical behavior and discharge properties of iron-bearing Al–Li-based alloys as Al–air battery anodes

With inevitable introduction of Fe in aluminum processing, a method for achieving high-value utilization of iron-bearing aluminum-based alloys is essential. Aluminum–air batteries are among the most promising power sources and have attracted the attention of researchers. In this study, the electrochemical behavior and discharge properties of Al–0.5Fe and Al–0.5Mn–0.5Fe–0.1Sn–xLi (x = 0, 1, 2, and 3 wt %) alloys as Al–air battery anodes are investigated in 4 M NaOH. Using x-ray diffraction (XRD) and scanning electron microscopy (SEM), the constituents and distributions of the main phases are discussed. Alloying improves electrochemical behavior and discharge properties of Al–0.5Fe. The static and dynamic electrochemical experiments indicate that Al–0.5Mn–0.5Fe–0.1Sn–2Li exhibits the best corrosion resistance. The discharge performances of the five alloys show that the average voltages decrease with increasing current density and Li content. Based on the electrochemical and discharge results, Al–0.5Mn–0.5Fe–0.1Sn–2Li is an excellent candidate for use in Al–air battery anodes, reaching a peak anodic efficiency of 77.86% at a relatively high current density of 80 mA cm−2, with a power density and specific energy of 83.60 mW cm−2 and 1618.06 mW h g−1, respectively. The optimal discharge performance is attributed to dispersed AlLi particles and the fragmentation effect of AlLi on the long strip-like Al6Mn(Fe) phase.

Evolution mechanism of intermetallic compounds and the mechanical properties of dissimilar friction stir welded QP980 steel and 6061 aluminum alloy

Intermetallic compounds (IMCs) play an important role in the welding quality of steel and aluminum (Al) alloys by friction stir welding (FSW). However, the evolution mechanism of IMCs and their effects on the mechanical properties of FSW joints are still unclear and need to be further elucidated. In this work, QP980 steel and 6061 Al alloy are successfully welded by FSW. The microstructure and mechanical properties of joints are characterized. The results show that an IMC layer composed of Al3Fe, Al5Fe2, Al2Fe, and Al6Mn phases is generated at the weld interface. The joint efficiency is about 70.1%. The formation sequence of IMCs in the same binary system is affected by the effective enthalpy of formation, while it is related to the element concentration in different binary systems. Furthermore, the formation sequence is Al3Fe, Al5Fe2, Al2Fe, and Al6Mn phases. The interfacial bonding strength is enhanced by the low lattice mismatch between IMCs and matrix. The interfacial bonding strength of IMCs with Fe and Al matrices in the joint is in ascending order: Al2Fe and Fe, Al2Fe and Al, Al5Fe2 and Fe, Al5Fe2 and Al, Al6Mn and Fe, Al3Fe and Fe, Al6Mn and Al, as well as Al3Fe and Al. It is noted that the bonding strength between the Al2Fe and Fe is lowest, indicating that Al2Fe phase is responsible for the joint fracture during tensile test.

Deformation behavior and microstructure evolution induced by nano-sized Al6Mn phase particles in a homogenized Al–6Mg–0.8Mn alloy during hot compression

In the present work, hot compression deformation behavior and microstructure evolution in a homogenized Al–6Mg–0.8Mn alloy with nano-sized Al6Mn phase particles were investigated at the temperature ranging from 300 to 500 °C with tha strain rate of 0.001–1 s−1. The constitutive equation of the Al–6Mg–0.8Mn alloy was established and the average deformation activation energy was calculated to be 167.07 kJ/mol. The flow stress of the alloy decreased with increasing the compression temperature and raised with increasing the strain rate, which was closely associated with the competitive relationship between work hardening and dynamic recovery (DRV). The low compression temperature accelerated the formation of shear bands in the alloy. The low strain rate was beneficial for the generation of low-angle grain boundaries (LAGBs), and the high compression temperature and strain rate promoted dynamic recrystallization (DRX). The interaction between the nano-sized Al6Mn phase particles participating near the initial grain boundaries and mobile dislocations facilitated the generation of LAGBs. Discontinuous DRX through grain boundary bulging mechanisms and continuous DRX with the LAGBs transforming to HAGBs led to the preferred formation of recrystallized grains along the initial large-sized grains. Furthermore, this interaction also resulted in the dissolution of Al6Mn phase particles.

Influence of Al Addition on the Microstructure and Mechanical Properties of Mg-Zn-Sn-Mn-Ca Alloys.

The effects of Al addition on the microstructure and mechanical properties of Mg-Zn-Sn-Mn-Ca alloys are studied in this paper. It was found that the Mg-6Sn-4Zn-1Mn-0.2Ca-xAl (ZTM641-0.2Ca-xAl, x = 0, 0.5, 1, 2 wt.%; hereafter, all compositions are in weight percent unless stated otherwise) alloys have α-Mg, Mg2Sn, Mg7Zn3, MgZn, α-Mn, CaMgSn, AlMn, Mg32(Al,Zn)49 phases. The grain is also refined when the Al element is added, and the angular-block AlMn phases are formed in the alloys. For the ZTM641-0.2Ca-xAl alloy, the higher Al content is beneficial to elongation, and the double-aged ZTM641-0.2Ca-2Al alloy has the highest elongation, which is 13.2%. The higher Al content enhances the high-temperature strength for the as-extruded ZTM641-0.2Ca alloy; overall, the as-extruded ZTM641-0.2Ca-2Al alloy has the best performance; that is, the tensile strength and yield strength of the ZTM641-0.2Ca-2Al alloy are 159 MPa and 132 MPa at 150 °C, and 103 MPa and 90 MPa at 200 °C, respectively.

Influence of Pre-Milling on the Mn Solid Solubility in the Al-Mn-Cu Alloy during Mechanical Alloying

Increasing the strength of Al-based alloys is an important issue of physical metallurgy and industrial processing. Severe plastic deformation and related extension of solid solubility during mechanical alloying provide an opportunity for significant strengthening due to grain refinement, solid solution, and precipitation strengthening mechanisms. During mechanical alloying, an anomalous increase in the solid-state solubility of alloying elements occurs. The present study focuses on the investigation of the pre-milling treatment to the microstructure, phase composition, and solubility in Al-7.7 Mn-3.5 Cu (wt%) alloy processed by a high-energy ball milling of Al-14.3 Mn-6.5 Cu (wt%) master alloy diluted with Al powder. During milling, the mean granular size decreased to ~5 µm, and a strong grain refinement occurred. According to our TEM and XRD data, ball milling provided a mean grain size of 13–14 nm and a microhardness of 490–540 HV. The lattice parameter of the Al-based solid solution decreased with an increase in the milling time to 7.5–10 h, which suggested the dissolution of the alloying elements, and the lattice parameter increased at a higher milling time of 12.5–40 h, which suggested the decomposition of the solid solution. The XRD data revealed the dissolution of the Al6Mn and Al20Cu2Mn3 solidification-originated phases with a further precipitation of the Al6Mn dispersoids. Pre-milling of the master alloy entailed a significant decrease in the minimal lattice parameter value from 0.4029 nm to 0.4023 nm due to an increase in the Mn solute content from 6.2 wt% (3.3 at%) to 7.5 wt % (4.0 at%) in the studied alloy during high-energy ball milling.

Effect of P-MIG and CMT on microstructure and properties of 6082-T6 joints

This paper focuses on pulse metal inert gas welding (P-MIG) and cold metal transfer (CMT) of 6082-T6 aluminium alloy. The microstructure and properties of joints were analysed and the phase transformation of the welding zones (WZ) was calculated using JMatPro. The results showed that CMT joints are better than P-MIG joints in tensile strength and hardness. The main reason is that the average grain size and the second phase size of CMT joints are smaller than those of P-MIG joints. Moreover, the larger number of large-angle grain boundaries (LAGB), diffusely distributed Al3Mg2 and Al6Mn phases in CMT WZ, as well as a small amount of distributed Al3Zr, are beneficial to the joints properties too.

Precipitation Behavior of the Metastable Quasicrystalline I-Phase and θ′-Phase in Al-Cu-Mn Alloy

The precipitation behavior and mechanical properties for conventionally solidified Al-2.0wt.%Cu-2.0wt.%Mn alloy were studied. The supersaturated aluminum-based solid solution, CuAl2, Al6Mn and Al20Cu2Mn3 phases of solidification origin were identified after casting. The high temperature ageing of as-cast samples (T5 treatment) in a temperature range of 300–350 °C led to the formation of the metastable θ′ phase and equiaxed precipitates of the quasicrystalline-structured I-phase. The θ′ phase demonstrated a high size stability in a studied temperature range with a mean length of ~300 nm and a mean thickness of ~24 nm. A mean size of the I-phase precipitates varied in a range of ~30–50 nm depending on the treatment regimes. The rod-shaped T-phase precipitates were formed with an increase in ageing temperature to 400 °C. Mechanical properties were analyzed at room temperature in a solid solution-treated state. The increased yield strength at room temperature and 200–300 °C were observed after ageing at 300 °C for 148 h.

Microstructure and Salt Fog Corrosion of Wrought Mg-Al-Zn and Mg-RE Alloys.

Wrought magnesium alloys have received attention due to their potential application as lightweight materials. However, their use is limited by their poor corrosion resistance. Rare earth additions have the potential to enhance corrosion resistance. The present work included a microstructural investigation and corrosion testing of the alloy WE-43, containing Nd and Y, which was compared against the more conventional compositions of AZ31 and AZ61 alloys. All three alloys exhibited a recrystallized equiaxed structure after hot rolling with the presence of second phases-precipitates. The WE-43 alloy exhibited a better corrosion resistance than AZ31 and AZ61 under salt fog testing, indicated by the lower depth of attack and lower weight loss. The second phases in the microstructure of AZ31 and AZ61 alloys determined their corrosion resistance. The second phases in the AZ31 and AZ61 alloys (based on Al-Mg and Al-Mn phases) were nobler than the Mg matrix and catholically acted, thus sacrificing the Mg matrix. The superior corrosion resistance of WE43 was due to the incorporation of Y in the oxide/hydroxide film. In addition, the second phases in the WE43 consisted of Nd and Y and were less noble than the Mg-matrix. Thus, they acted as anodic sites protecting the Mg-matrix. The above results show the beneficial effect of rare earth additions to wrought Mg alloys towards increased corrosion resistance.