The air jet nozzle structure has a significant impact on the heat transfer uniformity and cooling rate of glass during the glass tempering process, and there is a lack of research on the discrepancy of different jet structures. The effects of double air knife, single air knife structures, and air hole structures on the cooling performance of glass in air-cooled tempering were investigated using numerical simulation and simplified analytical models. The calculated results are in agreement with the experimental results. The results show that the DK structure has a significant effect on improving the overall heat exchange performance of the glass, with lower surface temperatures for the same quenching time. The temperature inhomogeneities of DK, SK, and AH structures in the glass axial direction were 2.09%, 2.53%, and 3.33%, respectively, and the heat transfer uniformity of the DK structure was significantly better than the latter two. In comparison to the AH structure, the average heat transfer coefficients of the DK and SK structures increased by approximately 17.82% and 8.13%, respectively, while the heat transfer rates increased by approximately 7.05% and 4.51%. The study further improves the insufficiency of glass tempering research and provides theoretical guidance for the actual production of tempered glass.