Entrapped Air Bubbles Research Articles

Transcrystalline Mechanism of Banded Spherulites Development in Melt-Crystallized Semicrystalline Polymers.

The decades-long paradigm of continuous and perpetual lamellar twisting constituting banded spherulites has been found to be inconsistent with several recent studies showing discontinuity regions between consecutive bands, for which, however, no explanation has been found. The present research demonstrates, in three different semicrystalline polymers (HDPE, PEG10000 and Pluronic F-127), that sequential transcrystallinity is the predominant mechanism of banded spherulite formation, heterogeneously nucleated on intermittent self-shear-oriented amorphous layers excluded during the crystals' growth. It is hereby demonstrated that a transcrystalline layer can be nucleated on amorphous self-shear-oriented polymer chains in the melt, by a local melt flow in the bulk or in contact with any interface-even in contact with the interface with air, e.g., in contact with an entrapped air bubble or at the edges of the sample-or nucleated following the multiple directions and orientations induced by a turbulent flow. The bilateral excessive local exclusion of amorphous non-crystallizable material, following a short period of initial non-banded growth, is found to be the source of dislocations leading to spirally banded spherulites, through the transcrystalline layers' nucleation thereon. The present research reveals and demonstrates the sequential transcrystalline morphology of banded spherulites and the mechanism of its formation, which may lead to new insights in the understanding and design of polymer processing for specific applications.

Revealing the mechanisms of water permeability enhancement of urban loess subgrades due to vibration application

Urban loess subgrades are affected by considerable vibrations from traffic, especially when the underground pipelines leak, and seepage under vibrations often causes road damage. However, the influence of vibrations on the water permeability of loess subgrades remains elusive. Here we address this issue by performing vibration-assisted permeability tests and scanning electron microscopy, mercury intrusion porosimetry, and suction–nuclear magnetic resonance measurements. This allowed the evolution of the saturated hydraulic conductivity (Ks), water-air migration, soil microstructure, and pore water forms to be evaluated. The water permeability of the loess subgrade is promoted by vibrations due to the increase in Ks, the acceleration of wet front migration, and the escape of entrapped air. Moreover, the value of Ks under vibration is 3–14 times greater than that without vibration, and the maximum increase occurs at a vibration frequency near the natural frequency of the loess. Furthermore, a theoretical framework of loess vibration permeability is proposed, and the mechanisms by which vibration accelerates the permeability behavior of the loess subgrade are revealed. Vibration promotes the expansion of soil pores, a decrease in the binding capacity of pore water, the mobilization of fine particles, and the formation of local low-permeability layer. Moreover, it accelerates the opening of entrapped air bubbles and the displacement of water-air, the reduction in seepage resistance. Thus, seepage water flows rapidly along infiltration channels. These findings are highly important for the road safety performance and the sustainable development of the traffic environment in loess regions.

Insect-inspired breathing interfaces: investigating robustness of coating-free gas entrapping microtextured surfaces under pressure cycles

Numerous natural and engineering scenarios necessitate the entrapment of air pockets or bubbles on submerged surfaces. Current technologies for bubble entrapment rely on perfluorocarbon coatings, limiting their sustainability. Herein, we investigated the efficacy of doubly reentrant cavity architecture towards realizing gas-entrapping microtextured surfaces under static and dynamic pressure cycling. The effects of positive (>1 atm), negative (<1 atm), and positive–negative cycles on the stability the gas entrapment inside individual doubly reentrant cavities were studied across a range of pressures, ramp rates, intercycle intervals, and water-column heights. Remarkably, the fate of the trapped air under pressure cycling fell into either of the following regimes: the bubble (i) monotonically depleted (unstable), (ii) remained indefinitely stable (stable), or (iii) started growing (bubble growth). This hitherto unrealized richness of underwater bubble dynamics should guide the development of coating-free technologies and help us understand the curious lives of air-breathing aquatic and marine insects.

Numerical simulation of droplet impact onto heated surfaces below the boiling point

Droplet impact onto heated surfaces is a widespread process in industrial applications, particularly in the context of spray cooling techniques. Therefore, it is essential to study the complex phenomenon of droplet spreading, heat removal and flow distributions during this process. The primary focus of this research centers on the wetting dynamics at a surface temperature below the saturation temperature of the liquid. This study employs a Computational fluid dynamics (CFD) framework to simulate the impact dynamics of a water droplet onto a heated surface. The impact dynamics, spreading, air entrapment and heat transfer in the process are discussed using simulation results. The Direct Numerical Simulation (DNS) tool Free Surface 3D (FS3D), an in-house code at the Institute of Aerospace Thermodynamics, University of Stuttgart, is utilized. The Finite-Volume method is used to solve the incompressible Navier-Stokes equations, and the interface is defined by the Volume of fluid (VOF) method. In this study, the temperature change above the entrapped air bubble formed due to droplet inertia is shown, which can influence the heat removal rate in the process. Therefore, conducting a comprehensive study on the temperature shift caused by the air bubble is crucial.

Thermocapillary central lamella recess during droplet impacts onto a heated wall

We experimentally observe a new phenomenon, the formation of a toroidal region of lower film thickness in the center of the lamella formed during high Weber number water droplet impacts onto smooth heated walls. This region forms around the air bubble, which is entrapped during the initial impact phase at the impact center. Our study encompasses a variation of the droplet size, impact velocity, surface wettability and temperature. We show how this phenomenon can be explained considering a two-step process involving thermocapillary convection in two separate regions: The temperature gradient along the surface of the entrapped air bubble caused by heat conduction induces flow that pumps warmer liquid to the lamella-ambient interface due to the Marangoni effect. The non-uniform temperature distribution along it then causes fluid acceleration in the radial direction, depleting the fluid volume around the bubble in a self-amplifying manner. We use direct numerical simulations of a stagnant liquid film with an enclosed bubble at the wall to confirm this theory.

A dilute nematic gel produced by intramicellar segregation of two polyoxyethylene alkyl ether carboxylic acids

MotivationSurfactants like C8E8CH2COOH have such bulky headgroups that they cannot show the common sphere-to-cylinder transition, while surfactants like C18:1E2CH2COOH are mimicking lipids and form only bilayers. Mixing these two types of surfactants allows one to investigate the competition between intramicellar segregation leading to disc-like bicelles and the temperature dependent curvature constraints imposed by the mismatch between heads and tails. ExperimentsWe establish phase diagrams as a function of temperature, surfactant mole ratio, and active matter content. We locate the isotropic liquid-isotropic liquid phase separation common to all nonionic surfactant systems, as well as nematic and lamellar phases. The stability and rheology of the nematic phase is investigated. Texture determination by polarizing microscopy allows us to distinguish between the different phases. Finally, SANS and SAXS give intermicellar distances as well as micellar sizes and shapes present for different compositions in the phase diagrams. FindingsIn a defined mole ratio between the two components, intramicellar segregation wins and a viscoelastic discotic nematic phase is present at low temperature. Partial intramicellar mixing upon heating leads to disc growth and eventually to a pseudo-lamellar phase. Further heating leads to complete random mixing and an isotropic phase, showing the common liquid–liquid miscibility gap. This uncommon phase sequence, bicelles, lamellar phase, micelles, and water-poor packed micelles, is due to temperature induced mixing combined with dehydration of the headgroups. This general molecular mechanism explains also why a metastable water-poor lamellar phase quenched by cooling can be easily and reproducibly transformed into a nematic phase by gentle hand shaking at room temperature, as well as the entrapment of air bubbles of any size without encapsulation by bilayers or polymers.

In-vitro and In-vivo Evaluation of Cevimeline HCl Fast Dissolving Films

The primary aim and objective of the present work was to formulate the cevimeline HCl fast-dissolving films and assess the films, a pharmaceutical compound utilized for the management of xerostomia symptoms linked to Sjogren’s disease. Fast-dissolving films of cevimeline HCl were formulated by utilizing the solvent casting technique and the sodium carboxy methyl cellulose, HPMC E5, polyvinyl alcohol, and polyvinyl pyrrolidone were used as film-forming agents. Additionally, polyethylene glycol 600 and sodium starch glycolate were used as a super disintegrant and plasticizers. The formulation contains citric acid and stevia powder, which serve the purpose of stimulating saliva and providing sweetness, respectively. This study focused mainly on the development and assessment of cevimeline HCl fast-dissolving films, specifically examining parameters such as film thickness, folding resistance, drug content, air bubble entrapment, and film curling. The obtained results were found to be consistent with the preset ranges established for these parameters. The drug release from the fast-dissolving films formulated with PVP K30 was 99.91% released within 5 minutes timeframe. The results indicates that the films prepared with PVP K30 show enhanced solubility, rate of dissolution, flexibility, and tensile strength in comparison to the films formulated with sodium carboxy methyl cellulose, HPMC E5 and Polyvinyl alcohol. Fourier transform infrared (FTIR) and differential scanning calorimetry (DSC) studies were done to characterize the pure drug, polymers and to C11 the optimized formulation. These findings indicated, no observed incompatibilities among the drug and polymers utilized in this study. Moreover, in-vivo investigations were conducted on optimized formulation C11, which demonstrated its notable stability.

What Controls the Hole Formation of Nanodroplets: Hydrodynamic or Thermodynamic Instability?

Using molecular dynamics simulations, we investigate the air hole formation of water nanodroplets impacting hydrophilic to hydrophobic surfaces in the range of static contact angles from 30° to 140° with different initial surface temperatures ranging from 300 to 1000 K. We show that the hole dynamics of nanodroplets are different from those observed in millimeter-sized droplets. The hole formation can be observed on smooth surfaces for nanodroplets; however, it only occurs on nonsmooth surfaces for millimeter-sized droplets. We clarify that the hole formation of nanodroplets is triggered by a nucleated vapor bubble due to thermodynamic instability, whereas it is initiated by air bubble entrapment during impact due to hydrodynamic instability for millimeter-sized droplets. The hole formation of nanodroplets relies heavily on the surface temperature and surface wettability, because the nucleated vapor bubble more easily occurs and grows on the surface with high initial temperatures and hydrophobic surfaces. Based on the thermal stability analysis, a criterion is developed to predict the hole formation of nanodroplets, which verifies the dependence of hole formation on the surface temperature and wettability. Furthermore, we show that the ring-bouncing of nanodroplets is triggered by the nucleated vapor bubble. We clarify the reasons for the reduced contact time of nanodroplets caused by the ring-bouncing.

Regulating air cushioning and bubble entrapment in charged droplet impact via external electric fields

Air cushioning and bubble entrapment are common phenomena observed during low-velocity droplet impact on solid or fluid surfaces, whereby a thin layer of air mediates the lubrication pressure. Previously, it is found that both charging droplets and the application of external electric fields can eliminate air cushioning and bubble entrapment. In this study, we numerically investigate the air cushioning and bubble entrapment in the charged droplet impacting onto a solid surface under external electric fields. It is found that the presence of net charge has a field enhancement effect on polarized charges on the same side while weakening the electric field of polarized charges on the opposite side, which can be linearly superimposed in the atmospheric environment. Based on the mirror charge model, the scaling law of the electric field threshold required for the impact of charged droplets without air cushioning or bubble entrapment is given. A fitting function based on the scaling law shows a good agreement with the phase diagram of a charged droplet impact modes under electric fields. These findings offer valuable insight for applications that rely on charged droplets' impact under electric fields, such as electrohydrodynamic printing and spray coating, to mitigate the negative impact of air cushioning or bubble entrapment.

Efficacy of cyanoacrylate adhesive as a mounting medium for soft tissue sections as an alternative to Kirkpatrick and Lendrum's DPX

Introduction: Mounting is the final stage in histologically preparing a slide and creates a permanent the bond between the coverslip and the slide, preventing breakage, air drying artefacts, and stain fading. Materials &amp; methods: In this study, fifty slides were prepared, twenty-five of which were mounted using DPX and twenty five using cyanoacrylate adhesive. The slides were assessed for clarity of nuclear and cytoplasmic details, adhesion between coverslip and slide, and the presence of air bubbles by two blinded observers. Results: The results showed that adhesion between coverslip and slide was better when mounted with cyanoacrylate adhesive, but better clarity of nuclear and cytoplasmic details and minimal air bubble entrapment was seen when tissue sections were mounted using DPX. Conclusion: Therefore, the use of cyanoacrylate adhesive cannot be an alternative to DPX for mounting soft tissue sections.

Aqueous Bubbles Stabilized with Millimeter-Sized Polymer Plates.

(Sub)millimeter-sized hexagonal polymer plates that were monodisperse in shape and size were utilized as stabilizers for aqueous bubbles, and the effects of the hydrophilic-hydrophobic property, size, and solid concentration of the plates on the formability, stability, and shape and structure of aqueous bubbles were investigated. The formability and stability of the bubbles were improved by increasing the hydrophobicity of the plate surface, decreasing the plate size, and increasing the solid concentration of the plates. For plates with suitable water wettability, three-dimensional bubbles with nearly spherical and polyhedral shapes were formed by the adsorption of plates to the bare air bubbles introduced into the continuous water phase by air-water mixing. On the contrary, two-dimensional bubbles with accordion-type structures consisting of alternating layers of plates and entrapped air bubbles were formed by the transfer of multiple plates with poor wettability from the air phase to the water phase by air-water mixing. Furthermore, a correlation was found between the bubble/stabilizer size ratio and bubble shape for plates with the suitable wettability: bubbles with nearly spherical shapes were formed when the bubble/plate size ratios were >2, bubbles with hexahedral, pentahedral, and tetrahedral shapes were formed when the size ratios were approximately 1, and bubbles with triangular and sandwich shapes were formed when the size ratios were <0.8. Additionally, bubbles with similar shapes were formed when the bubble/plate size ratios were close, even when the sizes of the plates and bubbles were different.

Impact of Submerged Entry Nozzle (SEN) Immersion Depth on Meniscus Flow in Continuous Casting Mold under Electromagnetic Brake (EMBr)

Complex multi-phase phenomena, including turbulent flow, solidification, and magnetohydrodynamics (MHD) forces, occur during the continuous casting (CC) under the applied electromagnetic brake (EMBr). The results of the small-scale experiment of the liquid metal model for continuous casting (mini-LIMMCAST) at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), investigating MHD flow with a deep immersion depth of 100 mm, are supplemented by newly presented numerical studies with the shallow position of the submerged entry nozzle (SEN) at 50 mm below the meniscus. Herein, the focus is on the MHD effects at the meniscus level considering (i) a fully insulating domain boundary, (ii) a perfectly conductive mold, or (iii) the presence of the solid shell. The volume-of-fluid (VOF) approach is utilized to model a Galinstan flow, including free surface behavior. A multiphase solver is developed using conservative MHD formulations in the framework of the open-source computational fluid dynamics (CFD) package OpenFOAM®. The wall-adapting local eddy-viscosity (WALE) subgrid-scale (SGS) model is employed to model the turbulent effects on the free surface flow. We found that, for the deep immersion depth, the meniscus remains calm under the EMBr for the conductive and semi-conductive domain. For the insulated mold disregarding the SEN position, the self-inducing MHD vortices, aligned with the magnetic field, cause strong waving of the meniscus and air bubble entrapment for shallow immersion depth. Secondary MHD structures can form close to the meniscus under specific conditions. The influence of the EMBr and immersion depth on the flow energy characteristics is analyzed using power spectral density (PSD).

A high-adaptability nozzle-array printing system based on a set covering printing planning model for printed display manufacturing

Inkjet printing technology is expected to enhance printed display mass production technology in the future. Nozzle-array printheads form the basis for printed display mass production applications. However, jet instability caused by air bubble entrapment and nozzle wettability changes during the printing process is a major challenge in the application of this technology. To adapt to possible nozzle abnormalities, a high-adaptability nozzle-array printing system based on a set covering printing planning (SCPP) model for printed display manufacturing is designed in this study. The study consists of two parts. First, a printing system based on multistep visual inspection and closed-loop feedback is proposed to accurately detect and screen abnormal nozzle positions. Notably, the inkjet printing system can identify nozzles with abnormal ejection characteristics and ensure that the remaining nozzles work accurately and stably. Then, an SCPP model is established for display pixel printing planning by using the remaining normal nozzles on the nozzle-array printhead. This model can output the most efficient printing path and nozzle printing action and can adapt to any pixel pattern, nozzle type, and abnormal nozzle distribution. The system and technology are highly adaptable and scalable for fabricating large-area printed display devices.

Large-scale paleo water-table rise in a deep desert aquifer recorded by dissolved noble gases

• Very high amounts of dissolved noble gases were identified in a deep desert aquifer. • Large water table fluctuations during past pluvial periods are reconstructed. • Hydrogeological settings highly affect the air entrapment and dissolution process. • Similar excess air dissolution patterns are identified in distinct desert aquifers. Illuminating past hydrological and climatological conditions in arid regions may provide insights into future trends in groundwater availability. The main objective of this study is to explore paleorecharge processes in the deep regional Nubian Sandstone Aquifer (NSA), which stretches below the hyperarid deserts of the Sinai Peninsula (Egypt) and the Negev (Israel), using dissolved noble gas data. Extremely high amounts of dissolved excess air (Ne concentrations up to 4 × solubility equilibrium) were observed in the ancient ( 81 Kr-depleted) groundwater that was recharged during past pluvial epochs in the basin. The observed unique excess air signal and the clear spatiotemporal structure of the noble gas compositions in the aquifer are hypothesized to reflect two major characteristics of the groundwater system: (a) large-scale, long-term rises in the water table that facilitate the entrapment and dissolution of air bubbles under increased hydrostatic pressure, and (b) the geological settings in the southern recharge area in Sinai, including an almost horizontal position of the layers and intercalation of low-permeability rock formations within the aquifer, which inefficiently reject air bubbles from groundwater, thereby allowing for substantial entrapment of bubbles that dissolve as the water table rises. Enhanced dissolution of entrapped air was also observed in other paleo-groundwater-containing regional sandstone aquifers across North Africa, which, together with the recent findings from the NSA, suggest that large-scale water table fluctuations have likely extensively occurred during past pluvial periods over these (and possibly other) arid regions. A preliminary assessment of noble gas recharge temperatures (NGTs) indicates an apparent decoupling of surface and water table temperatures in the case of deep aquifers with a thick (hundreds of m) unsaturated zone. This observed decoupling calls for a re-evaluation of previously obtained NGT records and a need for future work to consider the modification of NGTs due to soil air fractionation and geothermal heating of the underlying deep unsaturated zones.

Air entrapment of a neutral drop impacting onto a flat solid surface in electric fields

When a charge neutral drop impacts on a flat solid substrate, a small air bubble is always trapped underneath due to the lubrication pressure coming from the viscous stress in the squeezed air film. Herein we find experimentally and numerically that the process of the air entrapment and the initial contact state of the drop with the substrate can be profoundly altered via an external electric field. In an electric field, the induced electric stresses at the bottom of the drop increase drastically right before the drop contacts the substrate, which acts against the lubrication pressure, resulting in reduced initial contact radius and air bubble size. When the external electric field reaches a critical value, the electrical stress accelerates the flow near the bottom of the drop and generates a conical tip quickly instead of a dimple, resulting in a centre contact and eliminating the air bubble entrapment. Based on the dipole mirror charge model, we find the dimensionless strength of critical electric field scales with the square root of capillary number based on the air viscosity. This scaling law of the critical electric field for eliminating the air bubble entrapment is verified experimentally and numerically. This work may offer a new way to mitigate defects caused by air bubble entrapment for inkjet printing and droplet-based additive manufacturing.

3D Printed Acoustically Programmable Soft Microactuators.

The concept of creating all-mechanical soft microrobotic systems has great potential to address outstanding challenges in biomedical applications, and introduce more sustainable and multifunctional products. To this end, magnetic fields and light have been extensively studied as potential energy sources. On the other hand, coupling the response of materials to pressure waves has been overlooked despite the abundant use of acoustics in nature and engineering solutions. In this study, we show that programmed commands can be contained on 3D nanoprinted polymer systems with the introduction of selectively excited air bubbles and rationally designed compliant mechanisms. A repertoire of micromechanical systems is engineered using experimentally validated computational models that consider the effects of primary and secondary pressure fields on entrapped air bubbles and the surrounding fluid. Coupling the dynamics of bubble oscillators reveals rich acoustofluidic interactions that can be programmed in space and time. We prescribe kinematics by harnessing the forces generated through these interactions to deform structural elements, which can be remotely reconfigured on demand with the incorporation of mechanical switches. These basic actuation and analog control modules will serve as the building blocks for the development of a novel class of micromechanical systems powered and programmed by acoustic signals.

CT investigation of 3D liquid pathways in the anatomical structure of Norway spruce wood during imbibition

Abstract Wood permeability is a macroscopic property resulting from complex pathways at the cellular level. In this study, high-resolution X-ray CT scans were performed during longitudinal imbibition in Norway spruce to investigate the role of wood rays and tracheids network in liquid migration. A customized setup was designed to maintain the bottom face of a wooden cylinder in contact with water, without vibration, despite the sample rotation required during each scan. The results highlighted a contrasted role of latewood and earlywood in water migration. Liquid imbibition was fast in latewood, because the bordered pits are less prone to aspiration than in earlywood, due to their smaller diameter and larger cell wall thickness. In earlywood, the migration pattern was complex due to pit aspiration that isolate tracheids clusters. Indeed, the images revealed a significant contribution of wood rays in the migration pathways. Consequently, tracheids were not progressively filled in the longitudinal direction from one tracheid to the next, but they were filled laterally with water coming from wood rays at different heights of the cells. This explained entrapped air bubbles in the lumens and led to a 3D heterogeneous liquid distribution.

Air bubble entrapment during drop impact on solid and liquid surfaces

The phase-field modeling (PFM) of water drop impact onto a dielectric hydrophobic parafilm surface is performed to explore air entrapment and its influence on deposition and rebound phenomena. Local and global characteristics of the drop impact are taken into account by using the combined Cahn-Hilliard and Navier-Stokes equations. The modeling results of water drop impact are directly compared with our experimental measurements in terms of maximum spreading distance, and air bubble size. The simulation results reveal that air can be trapped under the liquid drop during the initial impact as well as during the retraction phase at the center of the drop due to the closure of the liquid layer above a cavity. It is found that the drop diameter and the impact velocity play significant roles in the air entrapment phenomena. The probability of air bubble formation is higher at lower impact velocity and for larger drop size. The model is also capable of simulating the case of drop impact onto a water surface, and the results are validated using prior literature data. In addition, the influence of the phase-field variables and the mesh adaptation scheme on the PFM is studied and discussed. Thus, our findings provide new qualitative and quantitative insights into the influence of air entrapment on drop deposition onto hydrophobic and liquid surfaces.

Experimental validation of a compression flow model of Non-Newtonian adhesives

ABSTRACT Currently, adhesive bonding processes are developed and optimised in a time-consuming trial and error procedure, which rarely leads to an optimal solution due to the high complexity of the adhesive flow behaviour during application. The ideal adhesive layer has precise geometric specifications; entrapped air bubbles or overfilling of the bond should be avoided. Numerical methods, such as Computational Fluid Dynamics (CFD), are only capable of calculating squeeze-flow processes to a limited extent. Apart from high computing times, mesh and convergence problems often occur due to the small ratio of adhesive layer thickness to adhesive layer length and width. The Generalised Partially Filled Gap (GPFG) model, published in a companion paper uses fundamental characteristics of every bonding process to derive clever assumptions, and thus provide an efficient simulation tool for adhesive squeeze-flow. The GPFG model simplifies the squeeze-flow to a two-dimensional problem, as the flow in thickness direction can be neglected for most bonding processes – without significant loss of accuracy compared to analytical or CFD solutions. The experimental validation of the model is presented in this study. Both stresses and flow geometry were evaluated, and a very good agreement between experiments and model was proven.

Entrapment and cross-flow transport of air bubbles by a hydrophobic strip in a turbulent channel flow

Entrapment and cross-flow transport of air bubbles by a hydrophobic strip in a turbulent channel flow