Agnew-Wiluna Greenstone Belt Research Articles

Sulfur isotopes in Archaean crustal reservoirs constrain the transport and deposition mechanisms of nickel-sulfides in komatiites

Assimilation and prolonged suspension of crust-derived sulfide liquid in komatiites are essential to form Ni-rich mineralisation. Evaluating the spatial relationship between komatiite-hosted Ni mineralisation and crustal S sources may thus provide insights into mechanisms of transport, metal enrichment and deposition of assimilated sulfide liquid. This study applied facies analysis and S isotopes to sulfides in Ni-mineralised komatiites and stratigraphically underlying bimodal volcanic-volcaniclastic and sedimentary rocks, which formed during rifting in the Agnew-Wiluna Greenstone Belt, Western Australia. The results revealed a lateral variation from rift-distal sedimentary sulfides, through sulfidic BIF, to rift-proximal VMS-style sulfides, the latter of which was predominantly assimilated by komatiites. Both crustal and komatiite-hosted sulfides were overprinted by granite-related skarn alteration during later basin inversion. Spatial S isotopes correlation revealed that Ni mineralisation in komatiites predominantly formed < 5 km from their crustal S sources, excluding long lateral transport as the main metal enrichment mechanism. Rather, metal enrichment likely happened through multiple cycles of sulfide entrapment and entrainment in lava flow vortices that formed in the wake of topographic steps represented by syn-rift faults. These faults were the main loci for pre-existing crustal weaknesses, hydrothermal fluid circulation, and VMS-style sulfide deposition, which were subsequently utilised by komatiites for enhanced thermo-mechanical erosion and crustal sulfide assimilation. This study shows that proximity to the syn-rift faults was the dominant control on the formation of komatiite-hosted Ni–sulfide mineralisation, regardless of substrate lithology. The S isotope signatures of crustal sulfides may be used as a proxy to identify syn-rift faults in highly deformed terranes.

Decoupling of Sulfur Isotope Signatures from Platinum Group Elements in Komatiite-Hosted Ore Systems: Evidence from the Mount Keith MKD5 Ni-(Co-Cu) Deposit, Western Australia

Abstract Komatiites require external sulfur from country rocks to generate immiscible sulfide liquid, which concentrates metals to form economic nickel sulfide deposits. Although signatures related to mass-independent fractionation of S isotopes (MIF-S, denoted as Δ33S) may identify external S sources, their values may not be directly indicative of the S reservoirs that were tapped during the ore-forming process, because of dilution by S exchange between assimilated sulfide xenomelt and komatiite silicate melt. To quantify this process and be confident that MIF-S can be effectively used to track S sources in magmatic systems, we investigated the effect of silicate melt-sulfide liquid batch equilibration, using the proxy of silicate/sulfide mass ratio, or R factor, on the resulting MIF-S signatures of pentlandite-rich ore from the Mount Keith MKD5 nickel sulfide deposit, Agnew-Wiluna greenstone belt, Western Australia. We carried out in situ multiple S isotope and platinum group element (PGE) analyses on pentlandite from a well-characterized drill core through the deposit. The variability in Pd tenor and MIF-S signature suggests that these are decoupled during batch equilibration and that the latter is not controlled by metal-derived R factor. Rather, the observed spread of MIF-S signatures implies that the sulfide xenomelt was initially heterogeneous and that chemical equilibration of S isotopes is incomplete as opposed to that of PGEs in a komatiite melt. Consequently, magmatic sulfides, which formed in the hottest, most dynamic, and likely fastest equilibrating magmatic systems on Earth, may still preserve their initial MIF-S isotope compositions, reflecting the range of crustal S reservoirs that were available upon komatiite emplacement.

The komatiite-hosted Perseverance Ni-sulphide deposit, Agnew-Wiluna greenstone belt, Western Australia; new insights into the Perseverance komatiite channel and footwall lithostratigraphy

The paper presents new geological and geochemical data on the Perseverance komatiite complex (PKC) that hosts the Perseverance Ni-sulphide deposit and the volcanic and sedimentary rocks forming the footwall of the PKC. Using the 3D reconstruction of the PKC and its’ footwall volcano-sedimentary succession the heterogeneity of the komatiite channel has been characterised on the basis of spatial distribution of the geochemical petrogenetic indicators.The study shows that the komatiite facies proximal to the mineralised bodies and the main pathway are expressed in the 3Dmodels as the segments with anomalously high MgO concentrations coupled with low contents of Al2O3, TiO2and CaO. The geochemical indicators of komatiite fertility, Ni/Cr and Ni/Ti ratios, commonly are in the range of 1 to 3 for Ni/Cr and 2 to 5 for Ni/Ti within the mainpathway, The Ni/Crexceeds 5and Ni/Ti20 in the mineralised parts of the channel. In the peripheral zone komatiites thesevalues commonly drop to less than 1, corresponding to barren komatiites. Similarly large variations are exhibited by the ratios of mantle normalized Pt and Pd to Al and Ti over short distances from 1 to 25. Closely spaced high and low values of these ratios hinder their use for discriminating fertile from barren komatiites. However, within the komatiite main lava pathway they can be used as geochemical pathfinders for magmatic sulphides.Reconstruction of the structurally complex komatiite sequences can be facilitated by using lithogeochemical correlation of the host volcano-sedimentary successions and particularly tracing geochemically distinctive marker units. For these purposes a special reference in this study was made to the geochemical systematics of rocks that make up footwall succession of the PKC complex. It was shown that amphibolites of the host sequence can be geochemically subdivided into different types, including mafic volcaniclastic rocks (mafic-1) and intrusive mafic rocks, apparently metagabbro sills (mafic-2). The mafic volcaniclastic rocks are strongly enriched in LREE, possibly due to presence of sedimentary epiclastic material or reflecting magma contamination by the crustal material during ascent through the crust. Additionally, they have notably high-Th contents, allowing them to be classified as having high-Th geochemical affinities. The second group (mafic-2), interpreted as coherent in origin, are characterised by flat REE patterns and lower overall abundances of the rare earths and Zr corresponding to a tholeiitic composition. Contents of Th and TiO2of these rocks are clustered in the two narrow intervals of compositions, corresponding to low-Th and intermediate-Th basalts, which form different amphibolite bodies. Mafic volcanics intercalate with the felsic volcanics, and quartz-feldspar-biotite-amphibole (QFBA) schists. It is shown that QFBA schist composition corresponds to metamorphosed clastic sedimentary and volcaniclastic rocks of mixed composition, which contain both clastic materials derived from an Archaean provenance and volcaniclastics material derived from mafic and felsic tuffs. The different geochemical affinities of the mafic rocks distributed in the footwall succession of the PKC apparently suggests different magma sources and, possibly, can also reflect the position of the rocks within the mantle plume structure. In conclusion, abundances, and ratios of the trace elements in composition of the mafic rocks matches that of the different parts of the Agnew Wiluna greenstone belt and can be used for overall stratigraphic correlations.

Stratigraphy of the Agnew-Wiluna Greenstone Belt: review, synopsis and implications for the late Mesoarchean to Neoarchean geological evolution of the Yilgarn Craton

Our ability to understand the geological evolution of Archean cratons is fundamentally dependent on stratigraphic reconstructions across greenstone belts. Here, we integrate published stratigraphic, geochemical and geochronological data to produce a revised stratigraphic model for the Agnew-Wiluna Greenstone Belt of the Yilgarn Craton. The Agnew-Wiluna Greenstone Belt records ca 130 m.y. of magmatism that occurred between ca 2820 and 2690 Ma and can be divided into three cycles. Cycle 1 is marked by ca 2820–2740 Ma mafic–ultramafic volcanic rock successions. Cycle 2 is associated with ca 2740–2720 Ma felsic volcanic rocks, associated fragmental deposits and contemporaneous mafic–ultramafic intrusions. Cycle 3 consists of ca 2720–2690 Ma mafic–ultramafic volcanic rock successions and co-magmatic intrusions. Exhumation and reworking of these continental rift basin successions after ca 2690 Ma resulted in two younger, additional, depositional cycles in the Agnew-Wiluna Greenstone Belt. Cycle 4 is associated with intermediate to felsic volcanoclastic rocks and epiclastic rocks erupted/deposited between ca 2690 and 2665 Ma. Cycle 5 is associated with the deposition of polymict conglomerates and sandstones in localised depocentres between ca 2665 and 2655 Ma. The stratigraphic scheme identified at the scale of the Agnew-Wiluna Greenstone Belt is the local expression of craton-wide tectono-thermal events. Our revised stratigraphic model for the Agnew-Wiluna Greenstone Belt and proposed correlations at the craton scale support a para-autochthonous model whereby crust from a proto-Yilgarn continental mass was extended/thinned, favouring the activation of translithospheric pathways associated with the ca 2720–2690 Ma Kalgoorlie Large Igneous Province. Inversion of this intra-cratonic rift basin after ca 2680 Ma led to the protracted activation of shear zones and multiple shifts in sedimentary depocentres. The widespread occurrence of previously unidentified fragments of ca 2820–2720 Ma substrate within the Kalgoorlie-Kurnalpi Rift has significant implications for craton-scale stratigraphic reconstructions and challenges existing terrane and domain boundaries. KEY POINTS We propose a revised, coherent and testable stratigraphic model for the Agnew-Wiluna Greenstone Belt of the Kalgoorlie Terrane. We compare our revised stratigraphic model for the Agnew-Wiluna Greenstone Belt with that of the Murchison and Southern Cross domains of the Youanmi Terrane in order to build a new space–time–integrated stratigraphic cross-section across the western half of the Yilgarn Craton. We demonstrate for the first time the existence of a magmatic continuum (i.e. no significant magmatic hiatus) between ca 2820 and 2690 Ma, providing the missing link between the geological record of the Youanmi Terrane and that of the Eastern Goldfields Superterrane.

A revised stratigraphic model for the 2.7 Ga Agnew-Wiluna greenstone belt, Yilgarn Craton, Western Australia

Abstract The lower stratigraphy of Agnew-Wiluna greenstone belt is composed of two main elements; a mafic/komatiite domain and a felsic/komatiite/basalt domain. Previous stratigraphic models show the mafic domain overlying the felsic domain. Komatiites in the latter host the vast majority of the nickel sulphide endowment of the belt (>20 significant deposits) whereas those in the mafic domain contain 3 and 4 relatively small deposits. Recently published geochemical data from well-preserved mafic domain rocks exposed in the Agnew area opens up the possibility to match these units with mafic rocks within the more structurally disrupted felsic domain. Analytical data from basalts at the Cliffs and Mount Keith Ni deposits and from the Wiluna Au mine sequence show that these can be matched to the basalt sequence stratigraphically below the Agnew Komatiite at Agnew and also show that basalts previously thought to occupy different stratigraphic positions (Centenary Bore and MacFarlanes Basalts) are laterally equivalent but structurally displaced. The revised stratigraphic model together with available age dates show that komatiites in both domains, Mount Keith and Cliffs/Agnew Komatiites, are laterally equivalent and part of the 2705 Ma Kalgoorlie-Kurnalpi komatiite LIP. This greatly enhances the Ni prospectivity of komatiites within the mafic domain which, previously being thought younger, were historically considered less prospective. The footwall to the komatiite is composed of basalt (Never Can Tell Basalt, in the mafic domain) and felsic sequences (Mount Keith Dacite in the felsic domain) that are laterally separated but occupy the same stratigraphic position and together with the komatiite correlate with the Kambalda Sequence in the south of the Kalgoorlie Terrane. The oldest crystallisation ages from the Mount Keith Dacite are 2719–2725 Ma but whether these rocks belong to the Kalgoorlie or Youanmi Terrane is currently unknown. The Kalgoorlie-aged sequence has an unconformable contact with underlying Youanmi-aged sequence (the latter including dates of 2724–2729, 2734, 2749 Ma) composed of basalt, komatiitic basalt, komatiite and minor felsic volcanic (in decreasing stratigraphic order; felsic volcanics, Songvang Basalt, Hickies Bore Basalt, Donegal Komatiite, Butchers Well Basalt). The Youanmi sequence is exposed throughout the AWB, is present in the Leonora area to the immediate south and extends eastward to other areas within the northern part of the Kalgoorlie-Kurnalpi Terranes.

The Cosmos greenstone succession, Agnew-Wiluna greenstone belt, Yilgarn Craton, Western Australia: Geochemistry of an enriched Neoarchaean volcanic arc succession

Abstract The geodynamic setting of the Neoarchaean Eastern Goldfields Superterrane (EGS) of the Yilgarn Craton is the subject of debate. Some authors propose plume models, while others advocate variants on a subduction accretion model for the origin of mineralised greenstone belt sequences. Felsic volcanism in the Kalgoorlie Terrane, the westernmost terrane of the EGS, is considered to have a tonalite-trondhjemite-granodiorite/dacite (TTG/D) geochemical affinity. The Cosmos greenstone succession, which lies in the Agnew-Wiluna greenstone belt (AWB) of the Kalgoorlie Terrane, contains several komatiite-hosted nickel sulphide deposits, the volcanic footwall to which consists of an intercalated succession of fragmental and coherent rocks ranging in composition from basaltic andesite to rhyolite. Light rare earth elements (LREEs) and large ion-lithophile elements (LILEs) are strongly enriched relative to high field strength elements (HFSEs) across all volcanic units, and the rocks display strong positive Pb and negative Nb anomalies. These geochemical characteristics resemble closely those of modern high-K calc-alkaline to shoshonite continental arc successions. Contrasting REE, LILE and HFSE concentrations, coupled with assimilation-fractional crystallisation (AFC) modelling, shows that the intercalated dacitic and andesitic volcanic rocks within the footwall succession are not co-genetic. Xenocrystic zircons within the felsic volcanic lithologies indicate that some assimilation of older continental crust contributed to the generation of the footwall volcanic sequence. The geochemical characteristics of the Cosmos volcanic succession indicate that parental melts were derived via partial melting of enriched peridotite that had been contaminated by subducted crustal material within the mantle wedge of a subduction zone. In contrast, two younger felsic porphyry intrusions, which cross-cut the volcanic succession, have a distinct TTG/D affinity. Therefore, these intrusions are considered to be generated via partial melting of a subducting slab and are related to local high-Ca granitoid intrusions. The Cosmos volcanic succession represents the first extrusive high-K calc-alkaline to shoshonitic volcanic arc sequence described in the Kalgoorlie Terrane and, coupled with age dating of the stratigraphy, is indicative of formation in a long-lived volcanic arc setting active from 2736 Ma to later than 2724 Ma. The composition and geochemical affinity of the volcanic footwall succession to the Cosmos komatiite-hosted nickel-sulphide deposits contrasts with the majority of felsic volcanic rocks within the AWB and also the wider Kalgoorlie Terrane, suggesting that the overall architecture of this region is more complex than is currently thought. Our conclusions not only have consequences for recent models of the tectonic evolution of the EGS but also contribute to the debate on the operation of plate tectonics during the late Archaean in general. The arc affinity of the Cosmos volcanic succession, containing abundant high-K calc-alkaline andesite lavas, provides further support for the operation of plate tectonics in the Neoarchaean.

Leaching of S, Cu, and Fe from disseminated Ni-(Fe)-(Cu) sulphide ore during serpentinization of dunite host rocks at Mount Keith, Agnew-Wiluna belt, Western Australia

Komatiite-hosted disseminated Ni sulphide deposits in the Agnew-Wiluna greenstone belt occur both above and below the olivine isograd that was imposed on the greenstone sequence during the M2 metamorphic/deformation event. Deposits in the northern and central part of the belt and that are located below the isograd (Mount Keith, Honeymoon Well and West Jordan) have complex sulphide mineralogy and strongly zoned sulphide assemblages. These range from least-altered assemblages of pentlandite-pyrrhotite-chalcopyrite±pyrite to altered assemblages of pentlandite±chalcopyrite, pentlandite-heazlewoodite (or millerite), heazlewoodite (or millerite), and rarely to heazlewoodite-native Ni. Deposits to the south and that are above of the olivine isograd (Six Mile, Goliath North) are dominated by less complex magmatic assemblages with a lower proportion of weakly altered pentlandite±chalcopyrite assemblages. More altered assemblages are uncommon in these deposits and occur as isolated patches around the periphery of the deposits. The sulphide zonation is reflected by whole-rock reductions in S, Cu, Fe and Zn, whereas Ni, Pt and Pd and, with some exceptions, Co are conservative. The leaching of S, Cu, Fe and Zn from sulphide assemblages and the whole rock was initiated by highly reduced conditions that were produced during low fluid/rock ratio serpentinization. Consumption of H2O resulted in Cl, a component of the fluid, being concentrated sufficiently to stabilise iowaite as part of lizardite-rich assemblages. Once the rate of olivine hydration reactions declined and during and after expansion and associated fracturing of the ultramafic sequence allowed higher fluid access, a more fluid-dominated environment formed and new carbonate-bearing fluid gained access to varying extents to the ultramafic rock sequence. This drove Cl from iowaite (to form pyroaurite) and caused the sulphide assemblages to be altered from the original magmatic assemblages and compositions to those stable at the prevailing fO2 and fS2 conditions. Mass transfer was made possible via metal chloride complexes and H2S with fluids driven by deformation associated with the M2 metamorphism. Disseminated deposits in higher metamorphic grade terrains where olivine was stable during peak metamorphism did not undergo the metasomatism seen in the deposits in areas of lower metamorphic grade. Some minor leaching of S, Fe and Cu occurred around the periphery of the deposits during early, pre-M2 peak metamorphism, but once olivine stability was reached the driving force for the series of leaching reactions was exhausted. The effect of this process on the original magmatic sulphides is to induce significant variability in texture, mineralogy and bulk composition and to markedly reduce the Fe and S contents of the sulphide fraction (in extreme cases to zero for both elements), and to reduce the volume of the sulphide fraction per unit of Ni. These changes impact unfavourably on Ni sulphide recoveries and metallurgical characteristics of these Ni ores.

U–Pb dating constraints on the felsic and intermediate volcanic sequence of the nickel-sulphide bearing Cosmos succession, Agnew-Wiluna greenstone belt, Yilgarn Craton, Western Australia

The Cosmos succession, within the Agnew-Wiluna greenstone belt of the Yilgarn Craton, consists of ultramafic, intermediate and felsic volcanic lithologies, and contains several komatiite-hosted nickel sulphide ore bodies. The volcanic succession that forms the stratigraphic footwall to the mineralised komatiite lavas consists of an intercalated sequence of fragmental and coherent extrusive lithologies, ranging from basaltic-andesites through to rhyolites. It also contains cross cutting felsic intrusions. The stratigraphic hangingwall consists largely of reworked volcanic-derived sedimentary rocks that include polymictic conglomerates containing granitic clasts. SIMS U–Pb dating was undertaken on zircons from nine felsic lithologies spanning the established stratigraphy. The footwall succession gives emplacement ages ranging from 2736±4 to 2724±3Ma. The overlying Cosmos Ultramafic sequence consists of two units; the basal ultramafic UMu1 package and the upper ultramafic UMu2 package, which are separated by a discontinuous felsic volcanic horizon that sits approximately 30–60m above the basal contact of the Cosmos Ultramafic sequence. This discontinuous felsic horizon is dated at 2685±8Ma and represents a break in accumulation of komatiite lavas and may be associated with a major hiatus. The succession also features two felsic intrusions emplaced at 2653±7Ma and 2670±6Ma, where the latter cross-cuts the upper contact of the UMu2 package. These results bracket the age of UMu1 package between 2724±3Ma and 2685±8Ma and that of UMu2 package between 2685±8Ma and 2670±6Ma. This stratigraphic division of the Cosmos ultramafic is further strengthened by the contrasting styles of mineralisation above and below the discontinuous felsic horizon and associated unconformity; UMu1 hosts several massive nickel sulphide deposits situated at the contact with the footwall volcanic succession, while UMu2 is typified by high-tenor disseminated nickel sulphide deposits situated just above the discontinuous felsic horizon. Our data indicates that the Cosmos volcanic succession was accumulated via punctuated volcanism spanning ∼50Ma that was followed by intrusive activity lasting for at least a further 32Ma. The results also imply that construction of this relatively small, mineralised greenstone succession lasted longer than anticipated on stratigraphic considerations alone, an outcome that may have implications for the timing of emplacement of other bi-modal volcanic successions in similar greenstone terranes.

The West Jordan deposit, a newly-discovered type 2 dunite-hosted nickel sulphide system in the northern Agnew–Wiluna belt, Western Australia

The West Jordan nickel deposit, in the northern Agnew–Wiluna greenstone belt of Western Australia, is a newly-discovered Type 2 dunite-hosted, low-grade, large tonnage, disseminated sulphide system. Located in the core of a large dunite body, mineralisation is dominated by intercumulus sulphide blebs (20μm to 6mm across) in assemblages containing pentlandite, pyrrhotite, heazlewoodite and locally, native nickel, sphalerite and chalcocite. Mineralisation grades between 0.2 and 2wt.% Ni, with the majority of samples in the 0.35–0.7% Ni range, were consistent with most komatiitic Type 2 systems. Hypogene alteration of the ultramafic host rock is interpreted to have been effected by retrograde metamorphic fluids, and has resulted in extensive serpentinisation and localised, structurally-controlled, talc-magnesite alteration. This gangue alteration has resulted in modification of original magmatic sulphide assemblages, and localised remobilisation of the minor Cu and Zn components of the magmatic sulphides. The deposit is deeply weathered, and all samples utilised in this study were obtained from a series of 12 diamond drill holes which were comprehensively assayed. An igneous stratigraphy is presented which is interpreted to be west-younging, consistent with along-strike deposits to the south, such as the Mount Keith and Yakabindie Type 2 nickel deposits.

District to Camp Controls on the Genesis of Komatiite-Hosted Nickel Sulfide Deposits, Agnew-Wiluna Greenstone Belt, Western Australia: Insights from the Multiple Sulfur Isotopes

The Agnew-Wiluna greenstone belt of Western Australia is the largest komatiite-hosted nickel sulfide belt in the world and contains two world-class Ni-Cu-(PGE) deposits and a host of smaller deposits. This study focuses on the broader scale geology of this greenstone belt in order to understand the key controls on the genesis of the komatiite-hosted Ni-Cu-(PGE) deposits, with specific focus on camp to district controls. We apply multiple sulfur isotopes to this geologic framework and conclude not only that the addition of crustal sulfur is a prerequisite for ore genesis in komatiite systems, but above all that the sulfur required to generate world-class deposits is most likely derived from barren volcanic massive sulfide lenses, which are spatially and genetically associated with felsic volcanic and volcaniclastic sequences that were emplaced coevally with large komatiitic sills and channelized lava flows. Multiple sulfur isotope data can be utilized in exploration at the deposit to district scales. At the deposit scale, the spatial pattern of mass-independent S isotope values (Δ 33 S) provides crucial insight into the identification of proximal high-grade and high-tenor ores in mineralized systems. In fact, sulfur data reflect the assimilation process that occurred upon komatiite emplacement, whereby hot turbulent magma thermomechanically eroded and assimilated exhalative sulfides spatially located close to vent with negative to near zero Δ 33 S values, whereas less turbulent flows interacted with distal sulfidic shales having Δ 33 S values above 0 per mil. Accordingly, the spatial variation of multiple sulfur isotope values in magmatic sulfides and associated host rocks may be utilized as a vector towards high-grade ores of poorly known systems. At the district scale, rather than ascertaining what controls the distribution of komatiite-hosted Ni-Cu-(PGE) deposits, the appropriate question to ask is what controls the distribution of country rock sulfides, considering that exhalative sulfides may be crucial to ore genesis in komatiite systems. We propose that felsic lava domes unambiguously mark their vents and can be directly mapped or inferred from gravity data. This work provides the first step in identifying district-scale control on komatiite-hosted Ni-Cu-(PGE) deposits. This is the scale that has high impact on exploration for new komatiite-hosted nickel sulfide belts globally.

Structural evolution of the Agnew–Wiluna greenstone belt, Eastern Yilgarn Craton and implications for komatiite-hosted Ni sulfide exploration

The Agnew–Wiluna greenstone belt in the Yilgarn Craton of Western Australia is a narrow package of complexly deformed Archean supracrustal rocks that hosts two of the world's largest komatiite-hosted nickel sulfide deposits, the Mt Keith and Perseverance deposits. These deposits and several others in the belt are centred on thick lenses of adcumulate-textured komatiite interpreted to represent areas of channelised magma flow. The large nickel sulfide deposits are located in parts of the belt associated with ca 2720 to 2700 Ma felsic volcanism (e.g. the Leinster and Mt Keith nickel camps). In these areas, felsic to intermediate volcanic rocks are intercalated with syn-volcanic massive sulfides of inferred exhalative origin. While these primary magmatic features are clearly first-order controls on the distribution of Ni sulfide deposits in the belt, several regional-scale deformation events have significantly complicated the interpretation of primary stratigraphic relationships. The earliest recorded deformation events (D1,2,3) resulted in an east–west trending greenstone belt with recumbent isoclinal folds and ductile shear zones. Subsequent west-southwest–east-southeast shortening during the D4 event at ca 2666 Ma involved the refolding of the tectono-stratigraphy to produce belt-scale, north- to north-northwest-trending upright folds, a pervasive axial planar schistosity in all rocks, and the present-day steeply dipping, overturned supracrustal sequences, and emplacement of granitoids in major antiformal fold hinges. Polyphase folding of supracrustal rocks produced Type 2 fold interference patterns with multiple facing reversals at various scales across the belt. West-southwest–east-southeast extension during the D5 event at ca 2665 Ma triggered the development of terrestrial basins (i.e. Scotty Creek and Jones Creek) in areas flanking major antiforms, resulting in the deposition of the Jones Creek Conglomerate. Subsequent west-southwest–east-southeast shortening during the D6 event resulted in the folding of the Jones Creek Conglomerate and formation of gold-bearing veins in the Agnew gold camp. Belt-wide relaxation in east–west shortening during the D7 event caused open, recumbent F7 folding of the steeply dipping stratigraphy. Broadly east–west shortening during the D8 to D10 events resulted in the tightening of existing fold hinges, the dismemberment and displacement of panels of supracrustal rocks by sinistral (e.g. Perseverance shear zone) and then dextral (Waroonga) shear zones. The Agnew–Wiluna belt displays (para)autochthonous associations within the belt, with district-scale heterogeneities caused by primary volcano-sedimentary facies changes combined with polyphase deformation. Importantly, nickel sulfide-bearing sequences identified in nickel camps can potentially be traced to different parts of the belt by unravelling the effects of polyphase deformation.

Evidence of water degassing during emplacement and crystallization of 2.7 Ga komatiites from the Agnew-Wiluna greenstone belt, Western Australia

Komatiites are ancient volcanic rocks, mostly over 2.7 billion years old, which formed through >30% partial melting of the mantle. This study addresses the crucial relationship between volcanology and physical manifestation of primary magmatic water content in komatiites of the Agnew-Wiluna greenstone belt, Western Australia, and documents the degassing processes that occurred during the emplacement and crystallization of these magmas. The Agnew-Wiluna greenstone belt of Western Australia contains three co-genetic komatiite units that (1) display laterally variable volcanological features, including thick cumulates and spinifex-textured units, and (2) were emplaced as both lava flows and intrusions at various locations. Komatiite sills up to 500 m thick contain widespread occurrence of hydromagmatic amphibole in orthocumulate- and mesocumulate-textured rocks, which contain ca. 40–50 wt% MgO and <3 wt% TiO2. Conversely, komatiite flows do not contain any volatile-bearing mineral phases: ~150-m-thick flows only contain vesicles, amygdales and segregation structures, whereas <5–10-m-thick flows lack any textural and petrographic evidence of primary volatile contents. The main results of this study demonstrate that komatiites from the Agnew-Wiluna greenstone belt, irrespective of their initial water content, have degassed upon emplacement, flow and crystallization. More importantly, data show that komatiite flows most likely degassed more water than komatiite intrusions. Komatiite degassing may have indirectly influenced numerous physical and chemical parameters of the water from the primordial oceans and hence indirectly contributed to the creation of a complex zonation at the interface between water and seafloor.

Contrasting komatiite belts, associated Ni–Cu–(PGE) deposit styles and assimilation histories

The Agnew–Wiluna greenstone belt in the Yilgarn Craton of Western Australia is the most nickel-sulfide-endowed komatiite belt in the world. The Agnew–Wiluna greenstone belt contains two mineralised units/horizons that display very different volcanological and geochemical features. The Mt Keith unit comprises >500 m-thick spinifex-free adcumulate-textured lenses, which are flanked by laterally extensive orthocumulate-textured units. Spinifex texture is absent from this unit. Disseminated nickel sulfides, interstitial to former olivine crystals, are concentrated in the lensoidal areas. Massive sulfides are locally present along the base or margins of the lenses or channels. The Cliffs unit is locally >150 m thick and comprises a sequence of differentiated spinifex-textured flow units. The basal unit is the thickest, and contains basal massive nickel-sulfide mineralisation. The Mt Keith and Cliffs units display important common features: (i) MgO contents of 25–30% in inferred parental magmas; and (ii) Al/Ti ratios of ∼20 (Munro-type). However, the Mt Keith unit is highly crustally contaminated (e.g. LREE-enriched, high HFSEs), whereas the Cliffs unit does not display evidence of significant crustal assimilation. We argue that the distinct trace-element concentrations and profiles of the two komatiite units reflect their different emplacement style and country rocks: the Mt Keith unit is interpreted to have been emplaced as an intrusive sill into dacitic volcanic units whereas the Cliffs unit was extruded as lava flow onto tholeiitic basalts in a subaqueous environment. The mode of emplacement and nature of country rock is the single biggest factor in controlling mineralisation styles in komatiites. On the other hand, evidence of crustal contamination does not necessarily provide information of the prospectivity of komatiites to host Ni–Cu–(PGE) mineralisation, despite being a good proxy for the style of komatiite emplacement and the nature of country rocks.

Towards a volcanic–structural balance: relative importance of volcanism, folding, and remobilisation of nickel sulphides at the Perseverance Ni–Cu–(PGE) deposit, Western Australia

Perseverance is a world-class, komatiite-hosted nickel sulphide deposit situated in the well-endowed Leinster nickel camp of the Agnew–Wiluna greenstone belt, Western Australia. The mine stratigraphy at Perseverance trends north-northwest (NNW), dips steeply to the west, and is overturned. Stratigraphic footwall units lie along the western margin of the Perseverance Ultramafic Complex (PUC). The PUC comprises a basal nickel sulphide-bearing orthocumulate- to mesocumulate-textured komatiite that is overlain by a thicker, nickel sulphide-poor, dunite lens. Hanging wall rocks include rhyodacite that is texturally and compositionally similar to footwall volcanic rocks. These rocks separate the PUC from a second sequence of nickeliferous, E-facing, spinifex-textured komatiite units (i.e. the East Perseverance komatiite). Past workers argue for a conformable stratigraphic contact between the PUC and the East Perseverance komatiite and conclude that the PUC is extrusive. This study, however, clearly demonstrates that these komatiite sequences are discordant, implying that the PUC may have intruded rhyodacite country rock as a sill with subsequent structural juxtaposition against the East Perseverance komatiite. Early N–S shortening associated with the regional DI deformation event (corresponding to the local DP1 to DP3 events at Perseverance) resulted in the heterogeneous partitioning of strain along the margins of the competent dunite. A mylonite developed in the more ductile footwall rocks along the footwall margin of the PUC, while isoclinal F3 folds, such as the Hanging wall limb and Felsic Nose folds, formed in low-mean stress domains along the fringes of the elongated dunite lens. Strata-bound massive and disseminated nickel sulphides were passively fold thickened in hinge areas of isoclinal folds, whereas basal massive sulphides lubricated fold limbs and promoted thrust movement along shallowly dipping lithological contacts. Massive sulphides were physically remobilised up to 20 m from their primary footwall position into deposit-scale fold hinges to form the 1A and Felsic Nose orebodies. First-order controls on the geometry of the Perseverance deposit include the thermomechanical erosion of footwall rocks and the channelling of the mineralised komatiitic magma. Second- or third-order controls are several postvolcanic deformation events, which resulted in the progressive folding and shearing of the footwall contact, as well as the passive fold thickening of massive and disseminated sulphide orebodies. Massive sulphides were physically remobilised into multiple generations of fold hinges and shear zones. Important implications for near-mine exploration in the Leinster camp include identifying nickeliferous komatiite units, defining their three-dimensional geometry, and targeting fold hinge areas. Fold plunge directions and stretching lineations are indicators of potential plunge directions of massive sulphide orebodies.

Mass and magnetic properties for 3D geological and geophysical modelling of the southern Agnew–Wiluna Greenstone Belt and Leinster nickel deposits, Western Australia

Physical property measurements provide a critical link between geological observations and geophysical measurements and modelling. To enhance the reliability of gravity and magnetic modelling in the Yilgarn Craton's Agnew–Wiluna Greenstone Belt, mass and magnetic properties were analysed on 157 new rock samples and combined with an existing corporate database of field measurements. The new samples include sulfide ore, serpentinised and olivine-bearing ultramafic host-rocks, granitoid, and felsic and mafic volcanic and volcaniclastic country rock. Synthesis of the data provides a useful resource for future geophysical modelling in the region. Several rock types in the region have sufficiently distinct physical properties that a discriminant diagram is proposed to facilitate a basic classification of rock types based on physical properties. However, the accumulation of emplacement, metamorphic, hydrothermal and structural processes has complicated the physical properties of the rocks by imposing duplicate and sometimes opposing physical property trends. The data confirm that massive sulfide and ultramafic rocks have the most distinctive mass and magnetic properties but with variability imposed by their complex history. Sulfide content imposes the strongest control on densities, but can only be identified when comprising >10 vol% of the rock. The pyrrhotite-rich Ni-sulfide assemblages generally have similar magnetic properties to the host ultramafic rocks, but can have much lower susceptibilities where the thermal history of the rocks has favoured development of hexagonal pyrrhotite over monoclinic pyrrhotite. In ultramafic rocks that contain <10 vol% sulfides, density and susceptibility are primarily controlled by serpentinisation, with olivine breaking down to serpentine and magnetite in the presence of water. Serpentinisation dramatically lowered densities and increased susceptibilities, but had limited influence on the intensity of remanent magnetisation. All ultramafic rocks contain multidomain magnetite, and most contain low coercivity grains prone to overprinting by in situ viscous remanent magnetisation or drilling-induced isothermal remanent magnetisation during extraction. Despite the low coercivities, Koenigsberger ratios of 1–20 are observed indicating that viscous remanent magnetisation aligned parallel to the present Earth field must be considered in any magnetic modelling. It is also noted that coarser-grained intrusive varieties of all rock types (e.g. granite, gabbro) show remanent magnetisation intensities 1–2 orders of magnitude greater than their extrusive equivalents (felsic and basaltic volcanics).

Metasomatic interaction between disseminated nickel sulphides and reduced metamorphic fluids, Honeymoon Well komatiite complex, Western Australia

Within the Honeymoon Well komatiite complex located within the Archaean Agnew-Wiluna greenstone belt, Western Australia, disseminated Ni sulphide deposits are hosted by completely serpentinised olivine-rich cumulates. These are unusual deposits as they contain large tonnages of mineralisation that are devoid of Cu despite containing up to >2%Ni and having magmatic Co and PGE values. About 55% of the 43 Mt Hannibals deposit consists of this style of mineralisation. The Cu distribution is spatially and geochemically related to bulk-rock changes in S and Fe with the Cu-absent parts of the deposit being variably depleted in these elements. Mimicking these changes in bulk composition is a zonation in sulphide–oxide assemblages of Ni-poor pentlandite-magnetite±pyrrhotite±chalcopyrite, pentlandite-magnetite±chalcopyrite, Ni-rich pentlandite-heazlewoodite±magnetite, and heazlewoodite-only with the latter occurring in zones showing the strongest S and Fe depletion. The sulphide mineral assemblages and bulk compositions correspond to variations in the non-sulphide mineralogy with much of the heazlewoodite mineralisation hosted by lizardite-iowaite±brucite-(magnetite absent) assemblages. Formation of highly reduced fluids during serpentinisation of olivine adcumulate and mesocumulate host sequences resulted in dissolution of sulphides in parts of the disseminated deposits. Copper, Co and Fe, soluble as chloride species, and S in the form of H2S were variably leached and removed from parts of the deposits. Passage of these reduced fluids through barren ultramafic rocks caused partial leaching of Fe and resulted in the formation of lizardite-rich alteration assemblages devoid of magnetite. Metamorphic Fe-Cu±Zn±Ni±Co bearing sulphides are common in pyroaurite-brucite magnetite veins and in former pyroxene-rich lithologies indicating the presence and mobility of these elements in some of the metamorphic fluids at Honeymoon Well. The location of the sulphide deposits immediately adjacent to major shear zones that bound the ultramafic complex allowed the infiltration and passage of large volumes of metamorphic fluids. During the lowermost greenschist facies metamorphism this caused semi-regional scale metasomatism of the ultramafic complex.

Controls on the genesis and emplacement of komatiite-hosted Ni–Cu–PGE-sulphides at Albion Downs (Agnew-Wiluna Belt, Western Australia): a case study on the development of PGE lithogeochemical vectors to Ni–Cu–PGE-sulphide deposits

Albion Downs is a structural domain within the Agnew-Wiluna Greenstone Belt of Western Australia, which contains one of the most highly Ni-endowed komatiite sequences in the world. Albion Downs comprises adcumulate-textured pods and lenses, which are flanked by thinner meso- and orthocumulate-textured units. Basal massive nickel-sulphide mineralisation (e.g. Jericho) generally occurs in the thinner meso- and orthocumulate-textured units, whereas stratabound disseminated nickel-sulphide mineralisation (e.g. Jordan) is hosted in the largest adcumulate-textured pod. After reaching sulphide-saturation, basal massive sulphides formed in settings where magma flow was less fast and turbulent than in channels. Conversely, in channellike settings sulphide blebs were entrained in the flow, thus forming disseminated sulphides. Platinum-group element lithogeochemistry indicates that the signature associated with the oreforming process is only recorded <100 m-away from nickel-sulphide mineralisation, where samples display a positive relationship between Pd+Pt and MgO and Pd+Pt and S. Conversely, the PGE signature of samples collected farther away is not directly controlled by sulphide segregation. Understanding the scale at which ore-formation processes operate is crucial to the development of any lithogeochemical exploration vector that is dependent on PGE variation.

Reconstruction of an extensive Archaean dacitic submarine volcanic complex associated with the komatiite-hosted Mt Keith nickel deposit, Agnew-Wiluna Greenstone Belt, Yilgarn Craton, Western Australia

Felsic volcanic rock units characterise a large portion of the 2.7 Ga. Agnew-Wiluna Greenstone Belt (Western Australia) stratigraphy and form the hangingwall and footwall sequences to several komatiite-hosted nickel sulphide deposits in the region. The Mt Keith region of the Agnew-Wiluna Greenstone Belt (AWB) comprises a sequence of felsic, mafic and ultramafic extrusive and intrusive units. The felsic volcanic dominated footwall and hangingwall sequences to the Mt Keith nickel deposit comprise cyclical packages of coherent dacite lavas, with associated monomictic in situ to resedimented breccias. Clasts in the monomictic breccia facies are identical to the coherent dacite and the two facies are often in gradational contact. The dacites are interpreted as submarine lavas and the breccias as associated autoclastic facies (hyaloclastite, autobreccia). These dacite lavas are inferred to have been emplaced into a deep water environment which retarded volatile exsolution suppressing explosive fragmentation and increasing lava mobility, resulting in large tabular flow units. The AWB sequence has undergone multiple periods of deformation and metamorphism subsequent to emplacement resulting in strain and alteration in large sections of the coherent lava facies. A notable textural variant within the lavas is a set of pseudo-textures/structures resembling tuffaceous and brecciated dacitic units. The process of pseudo-clastic texture/structure generation is related to a combination of polyphase alteration, brecciation and development of a secondary structural/metamorphic layering. Understanding the origin of these pseudo-clastic textures/structures has allowed recognition of the lateral and vertical facies variation of the felsic sequence and reconstruction of the original volcanic architecture.

Controls on the emplacement and genesis of the MKD5 and Sarah’s Find Ni–Cu–PGE deposits, Mount Keith, Agnew–Wiluna Greenstone Belt, Western Australia

The Mount Keith (MKD5) nickel sulfide deposit is one of the largest komatiite-hosted nickel sulfide deposits in the world; it is hosted by a distinctive spinifex-free, cumulate-rich, ultramafic horizon/unit termed the Mount Keith Ultramafic (MKU). The Mount Keith Ultramafic shows significant variation along its lateral extent. The internal architecture is made up of adcumulate-textured pods and lenses, which are flanked by thinner meso- and orthocumulate-textured units, overlain by pyroxenitic and gabbroic horizons. The lateral and vertical changes in the geometry and internal architecture reflect variations in the lithological association and emplacement conditions along the strike extent of the belt. The chilled margins of the Mount Keith Ultramafic unit contain ∼1,200 ppm Ni. Olivine cumulates average ∼2,500–3,500 ppm Ni, with few exceptions (Ni > 4,500 ppm) reflecting occurrence of minor nickel sulfides, whereas pyroxenites and gabbros generally contain, respectively, ∼1,500–2,000 and ∼100–1,000 ppm Ni. Olivine cumulates generally contain low Cr concentrations ( 5,000 ppm Cr). The internal stratigraphy of the Mount Keith Ultramafic unit may be subdivided into two groups based on rare earth element distribution. The chilled margins and the internal units of the Main Adcumulate domain display LREE-enriched patterns [(La/Sm)n > 1–3] and negative Eu, Hf, Zr, Nb, and Ti anomalies. The internal units in the Western Mineralized Zone generally display flat chondrite-normalized REE patterns and only minor negative Nb anomalies. The pattern of platinum-group element (PGE) distribution varies greatly along the strike extent of the Mount Keith Ultramafic unit. The chilled margins display relatively low absolute concentrations [PGE (excl. Os) ∼16 ppb] and relatively fractionated patterns, with subchondritic Pt/Pd ratios (∼1.5), and superchondritic Pd/Ir ratios (∼3). The PGE trends in the thick adcumulate-textured pods containing widespread nickel sulfide mineralization display positive correlation with sulfide abundance, whereas fractionated pyroxenites and gabbros in the thinner domains display highly depleted PGE concentrations and generally show compatible PGE trends. The nickel sulfide ore typology and style vary greatly along the strike extension of the Mount Keith Ultramafic unit. Basal massive nickel sulfide mineralization (e.g., Sarah’s Find) occurs in the thinner meso- and orthocumulate-textured units, whereas stratabound disseminated nickel sulfide mineralization (e.g., MKD5 Ni Deposit) is hosted in the adcumulate-textured pods. We hypothesize that the very low PGE content of the initial liquid of the Mount Keith Ultramafic unit indicates that the initial magma pulse that penetrated through the dacite host-rock had already equilibrated with sulfides at depth and/or carried entrained immiscible sulfide blebs. We argue that upon emplacement, the intruding magma experienced a significant thermal shock at the contact with water-saturated volcaniclastic breccias. The sudden chilling would have increased the viscosity of the magma, possibly to the point where it was no longer able to sustain the suspension of the immiscible sulfide liquid. As a result, the sulfide blebs coalesced and formed the basal massive sulfide nickel sulfide mineralization at the base of the sill (i.e., Sarah’s Find). Prolonged focused high volume magma flow within the sill resulted in the emplacement of a thick, lens-shaped accumulation of olivine adcumulate. Local variations in intensive parameters other than crustal assimilation (e.g., T, fO2, fS2) may be principally responsible for sulfide supersaturation and controlled the local distribution of stratabound disseminated nickel sulfide mineralization (e.g., MKD5 Ni Deposit), generally localized within the core of the thicker dunite lenses.

Internal stratigraphic architecture of the komatiitic dunite-hosted MKD5 disseminated nickel sulfide deposit, Mount Keith Domain, Agnew-Wiluna Greenstone Belt, Western Australia

The MKD5 nickel deposit is hosted by the Mount Keith Ultramafic Complex (MKUC), a dunite body of komatiitic affinity located in the Agnew-Wiluna Greenstone Belt, Western Australia. The internal architecture of the MKUC comprises seven distinct internal units that range from extreme adcumulate dunite to relatively fractionated pyroxenitic and gabbroic horizons. The MKUC is divided into three packages of units. The main adcumulate domain (MAD), which is situated in the lower portion of the complex, contains the bulk of disseminated nickel sulfide and is dominated by coarse adcumulate olivine textures. Overlying the MAD is an upper fractionated zone, which is dominated by mesocumulate-to-orthocumulate peridotite with domains containing oikocrystic pyroxenite and gabbroic lenses. An aerially restricted unit comprising texturally and chemically distinct olivine cumulate rocks is known as the western mineralized zone (WMZ). The fractionation trend between the MAD and UPZ indicates a westerly facing for the MKUC, conformable with the bounding stratigraphy. In the MKUC, truncation of some of the uppermost internal stratigraphic units by the hangingwall contact indicates that the unit has undergone structural modification since its emplacement and suggests that a proportion of the upper section has been removed by faulting. Furthermore, vertical and lateral textural transitions within the internal stratigraphy suggest that the MKUC (excluding the WMZ) was emplaced from an essentially continuous magma flow, with the MAD representing the period of highest magma flux and the major constructional period of emplacement. Conversely, the WMZ is interpreted to represent a later pulse of ultramafic magma, emplaced stratigraphically above the main MKUC. Comparison of the MKUC with other komatiitic dunites from both within the Agnew-Wiluna Greenstone Belt and worldwide indicates that despite apparent geometrical differences between lens and sheet komatiitic dunites, a broad facies architecture can be defined. We suggest that the differences in geometry are related to differing degrees of flow localization within dunitic units and are a function of both differences in the thermal characteristics and the degree of litho-facies heterogeneity of the enclosing lithologies.