Aggregation Of Nanoparticles In Solution Research Articles

Development of sustainable and reusable silver nanoparticle-coated glass for the treatment of contaminated water.

Water contaminants like pathogenic microbes and organic pollutants pose a serious threat to human and aquatic life forms; thus, there is an urgent need to develop a sustainable and affordable water treatment technology. Nanomaterials especially metal nanoparticles have extensive applications in wastewater treatment, but the recovery and aggregation of nanoparticles in solution is a major limitation. In the present work, green synthesized silver nanoparticles were covalently immobilized on a glass surface to prevent aggregation of nanoparticles and to enhance their applicability. Fourier transform infrared (FTIR) of silver nanoparticle (AgNP)-coated glass shows peaks of Si-O-Si, Si-O-C, and Ag-O at 1075 cm-1, 780 cm-1, and 608 cm-1 respectively which confirms the immobilization/conjugation of nanomaterial on glass surface. The surface morphology of immobilized AgNP was studied using scanning electron microscopy (SEM) which reveals nanoparticles are spherical and uniformly distributed on glass surface. The AgNP-coated glass was used for the removal of textile dyes in solution; the result indicates approximately 95% of textile dyes were removed after 5 h of treatment. Removal of microbial contaminants from Yamuna River was studied by optical density analysis and confirmed by fluorescence dye staining. The AgNP-coated glass was also studied for their reusability and the data indicates 50% removal of microbes up to the 5th cycle. To further enhance the applicability, the inhibition of bacterial biofilms were analyzed by dark-field illumination with a fluorescence microscope. Thus AgNP-coated glass can be used in the development of food/water storage containers and in textile industries.

Integral Estimation of Effects of Aggregation of Nanoparticles in Solutions from Autocorrelation Functions of Intensity of Scattered Radiation

A method of investigation of processes that arise in aggregation of nanoparticles in colloidal solutions based on estimation of variations in the coefficients of rotational diffusion of nanoparticles is proposed. It is shown that rotational diffusion is more sensitive to variations in the dimensions of the particles than is translational diffusion. A comparative estimation of these types of variations is presented and the relative index of aggregation is calculated from the integral values of the autocorrelation function of depolarized dynamic light scattering. Results of numerical simulation of the proposed method and its experimental certification are compared.

Combined Effect of Ultrasound Stimulations and Autoclaving on the Enhancement of Antibacterial Activity of ZnO and SiO₂/ZnO Nanoparticles.

This study investigates the antibacterial activity (ABA) of suspensions of pure ZnO nanoparticles (ZnO-NPs) and mesoporous silica doped with ZnO (ZnO-UVM7), as well as electrospun nanofibers containing those nanoparticles. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of these two materials were also determined under the same conditions. The results showed a concentration-dependent effect of antibacterial nanoparticles on the viability of Escherichia coli (E. coli). Moreover, the combination of the stimulations and sterilization considerably enhanced the antimicrobial activity (AMA) of the ZnO suspensions. Poly (lactic acid) (PLA) solutions in 2,2,2-trifluoroethanol (TFE) were mixed with different contents of nanoparticles and spun into nonwoven mats by the electrospinning process. The morphology of the mats was analyzed by scanning electron microscopy (SEM). The amount of nanoparticles contained in the mats was determined by thermogravimetric analysis (TGA). The obtained PLA-based mats showed a fibrous morphology, with an average diameter ranging from 350 to 450 nm, a porosity above 85%, but with the nanoparticles agglomeration on their surface. TGA analysis showed that the loss of ZnO-NPs increased with the increase of ZnO-NPs content in the PLA solutions and reached 79% for 1 wt % of ZnO-NPs, which was mainly due to the aggregation of nanoparticles in solution. The ABA of the obtained PLA mats was evaluated by the dynamic method according to the ASTM standard E2149. The results showed that, above an optimal concentration, the nanoparticle agglomeration reduced the antimicrobial efficiency of PLA mats. These mats have potential features for use as antimicrobial food packaging material.

Green synthesis of curcumin conjugated nanosilver for the applications in nucleic acid sensing and anti-bacterial activity

Silver nanoparticles (Ag NPs) are often synthesized by chemical and physical methods. Natural and non-toxic molecules are recently being replaced for nanoparticles preparation. In this paper we have used curcumin, which interacts with Ag+ and subsequently synthesizes silver nanoparticles. Further continuation of the reaction often makes aggregation and forms dark brown/black silver oxide. Presence of glycerol in the reaction mixture gives mono-disperse curcumin conjugated Ag NPs, which can be made stable by capping with polyvinylpyrolidone (PVP). XRD data confirm that curcumin conjugated Ag NPs are crystalline in nature with a mean crystalline size of 13.27nm. The Ag NPs are spherical and in the range of 10–50nm though their hydrodynamic radius is found to be higher, ∼294nm, due to polyvinylpyrolidone capping and aggregation of nanoparticles in solution. The production of curcumin conjugated Ag NPs follows first order kinetics and the effect of curcumin concentration during formation of Ag NPs indicates a linear enhancement in the production of Ag NPs with an increase in concentration of curcumin. These curcumin conjugated silver nanoparticles show anti-bacterial activity and can successfully determine nucleic acid (DNA and RNA) in the concentration range 100–1000ng/mL with a linear regression coefficient >0.997 using Resonance Rayleigh Scattering spectra.

Extracellular synthesis of zinc oxide nanoparticle using seaweeds of gulf of Mannar, India.

BackgroundThe biosynthesis of metal nanoparticles by marine resources is thought to be clean, nontoxic, and environmentally acceptable “green procedures”. Marine ecosystems are very important for the overall health of both marine and terrestrial environments. The use of natural sources like Marine biological resources essential for nanotechnology. Seaweeds constitute one of the commercially important marine living renewable resources. Seaweeds such as green Caulerpa peltata, red Hypnea Valencia and brown Sargassum myriocystum were used for synthesis of Zinc oxide nanoparticles.ResultThe preliminary screening of physico-chemical parameters such as concentration of metals, concentration of seaweed extract, temperature, pH and reaction time revealed that one seaweed S. myriocystum were able to synthesize zinc oxide nanoparticles. It was confirmed through the, initial colour change of the reaction mixture and UV visible spectrophotometer. The extracellular biosynthesized clear zinc oxide nanoparticles size 36 nm through characterization technique such as DLS, AFM, SEM –EDX, TEM, XRD and FTIR. The biosynthesized ZnO nanoparticles are effective antibacterial agents against Gram-positive than the Gram-negative bacteria.ConclusionBased on the FTIR results, fucoidan water soluble pigments present in S. myriocystum leaf extract is responsible for reduction and stabilization of zinc oxide nanoparticles. by this approach are quite stable and no visible changes were observed even after 6 months. These soluble elements could have acted as both reduction and stabilizing agents preventing the aggregation of nanoparticles in solution, extracellular biological synthesis of zinc oxide nanoparticles of size 36 nm.