Age Of Granite Research Articles

Geochemistry and Zircon U–Pb Chronology of Jinchanshan Gold-Hosted Granitoids, Inner Mongolia: Implications for Petrogenesis and Geodynamic Evolution

Jinchanshan is a medium-sized, granitoid-hosted gold deposit located in the Kalaqin area of Inner Mongolia. Mineralization predominantly occurs in the contact zone between biotite granites and quartz porphyry rocks, associated with the Jinchanshan minor intrusion, suggesting a genetic link to the granitoid-hosted gold deposit. In this study, the petrography, geochemistry, and LA-ICP-MS zircon U–Pb chronology of these two granitoid samples were studied. The results indicate that the zircon U–Pb age of the biotite granites is 127.9 ± 3.0 Ma, while that of the quartz porphyry is 121.4 ± 1.5 Ma, both dating back to the Early Cretaceous. The average SiO2 content of the granites is 66.64%, and the rocks have high total alkali (K2O + Na2O) content, averaging 9.13%. The average K2O content is 4.39%, with a K2O/Na2O ratio of 0.93. The quartz porphyry rocks are enriched in SiO2 (74.41%–76.85%) and have high Na2O + K2O content (8.67%–9.59%), but are low in MgO (0.03%–0.09%), CaO (0.44%–1.02 %), and TiO2 (0.08%–0.12%). Most samples of the biotite granite and the quartz porphyry rocks exhibit high-K peraluminous and medium-K calc-alkaline characteristics, respectively. Both rock types are enriched in Rb, Th, U, K, Zr, Hf, and Gd and relatively depleted in Ba, Sr, P, Ti, Nb, Ta, and Eu, with a pronounced negative Eu anomaly. The biotite granites show high ∑LREE/∑HREE ratios (6.1–6.9), while the quartz porphyry rocks exhibit lower ratios (2.0–4.2). Both granitoid types have elevated FeOT content and FeOT/(FeOT + MgO) ratios, indicating that the Jinchanshan granitoids are A-type granites. The zircon U–Pb ages, combined with the regional tectonic settings, suggest that these granitoids formed during large-scale metallogenic events in the Early Cretaceous, within the Yanshanian post-orogenic extensional tectonic regime. This is consistent with the lithospheric thinning and extensional processes in Eastern China during this period.

Rubidium (Rb) enrichment processes in a highly evolved granitic system: Insights from the petrology and geochemistry of the Guobaoshan Rb deposit in eastern Tianshan, NW China

Highly fractionated granitoids are closely associated with Rb mineralization, yet the mechanisms that control Rb enrichment and details about the enrichment process have not been well constrained. The Guobaoshan Rb deposit in eastern Tianshan, NW China, is one of the largest granite-related Rb deposits; it preserves a series of gradual lithofacies ranging from biotite granite and muscovite granite to Rb-rich amazonite granite and pegmatite, and provides an excellent opportunity to constrain the Rb enrichment processes in granitic systems. The large Guobaoshan Rb deposit hosts 281,000 tons of Rb2O at a grade of 0.12% mainly in its amazonite-bearing granite and amazonite granite lithofacies. In this contribution, we integrate geochronology, bulk-rock geochemistry, and analysis of Nd and zircon Hf isotopes to characterize the evolution of the Guobaoshan granitic pluton and the mechanisms that generated Rb enrichment. The zircon U-Pb age of the biotite granite and columbite U-Pb age of the amazonite granite are 244.8 ± 1.8 Ma (1σ, mean square of weighted deviates [MSWD] = 1.1) and 241.9 ± 2.3 Ma (1σ, MSWD = 1.0), respectively. In situ Rb-Sr analysis of orthoclase, mica, and albite from the amazonite-bearing granite, amazonite granite, and pegmatite yields ages of 249.1 ± 7.3 Ma (2σ, MSWD = 1.6), 245.5 ± 16.8 Ma (2σ, MSWD = 0.63), and 245.8 ± 9.8 Ma (2σ, MSWD = 3.3), respectively. Together, these ages demonstrate that the Guobaoshan granitic pluton formed during the Triassic and underwent a protracted magmatic evolution. The Guobaoshan granitic pluton is characterized by high concentrations of SiO2, alkalis, and Al2O3, and low concentrations of MgO, Fe2O3, CaO, P2O5, and TiO2, with an Al saturation index (A/CNK) of 1.01−1.14. It is enriched in Rb, but depleted in Ba, Sr, P, and Eu, has low total rare earth element (REE) contents (83.1−221 ppm), and is characterized by significantly negative anomalies (Eu/Eu* = 0.01−0.44). The biotite granite is enriched in light rare earth elements (LREEs), whereas the muscovite granite, amazonite-bearing granite, amazonite granite, and pegmatite are depleted in LREEs, and exhibit a marked tetrad effect (TE1.3 = 1.05−1.50). These geochemical characteristics, combined with the non-CHARAC (charge-radius−controlled) ratios of Zr/Hf, Nb/Ta, Y/Ho, and K/Rb, are indicative of melt-fluid interaction during the evolution of the Guobaoshan magma. Given that the biotite granite is the least-evolved rock, its petrological and geochemical characteristics suggest that it is an I-type granite. The slightly variable εHf(t) and consistently negative εNd(t) values indicate that the magma from which the Guobaoshan granitic pluton crystallized was likely sourced from the Mesoproterozoic crust, with limited mantle contributions. The coeval ages and coherent geochemical variations and mineral compositions of these rocks suggest that they formed via fractional crystallization of plagioclase, mica, quartz, and K-feldspar in the same magmatic system. This is supported by fractional crystallization simulations using the rhyolite-MELTS software package. Based on the petrological, mineralogical, and geochemical characteristics of the muscovite granite, amazonite-bearing granite, amazonite granite, and pegmatite, as well as simulations using rhyolite-MELTS, high degrees of fractional crystallization of granitic magma and interaction of this evolving magma with F-rich fluids are suggested to have been the key mechanisms that caused enrichment of Rb, while the melt-fluid interaction was more critical for Rb mineralization.

Pernambuco-Alagoas, Riacho do Pontal, and Sergipano domains of the Borborema Province, Northeastern Brazil: a geological and geochronological synthesis

Abstract In recent years, the number of works seeking to advance the geological and geotectonic knowledge of the Borborema Province has been increasing. However, in the context of the Southern Borborema Province there are few studies aimed at understanding its tectonic evolution in an integrated way. This work presents a review of the lithostratigraphic and geochronological data available for the Pernambuco-Alagoas, Riacho do Pontal and Faixa Sergipana Domains, located in the southern portion of the Borborema Province (Northeast Brazil), in addition to a discussion on the tectonic evolution model. The Southern Borborema Province fully encompasses the state of Alagoas and partially the states of Pernambuco, Sergipe, Bahia and Piauí, and is delimited to the north by the Pernambuco Lineament and to the south by the São Francisco Craton. The methodology involved bibliographical survey, geological cartography, geochronological compilation, creation of detrital zircon histograms for metasedimentary rocks (with unconformity below 10%) and magmatic “barcodes” for ortho-derived rocks and preparation of regional geological profiles. The tectonic evolution of the Southern Borborema Province began with the breakup of the Rodínia Supercontinent (1000 Ma) during the Cariris Velhos Cycle. The processes involved in the interaction of fragments descending from Rodinia are diachronic, in a broad scenario of accretions and collisions that resulted in the merger of Gondwana. The Pernambuco-Alagoas Block is considered a complex tectonic domain, which was affected by the Cariris Velhos (1000 – 950 Ma) and Brasiliana (740 - 570 Ma) orogenies (Caxito & Alkmim 2023), preserving remnants of Archean rocks (Riacho Seco Fragment) and proterozoic. The Riacho do Pontal Domain and the Faixa Sergipana Domain are part of a large folding system formed from the collision of the Pernambuco-Alagoas Domain with the São Francisco Craton, in a tangential deformation, vergent towards the craton, during the Brasiliana Orogeny. From the ages of the syncollisional granites we can infer that the orogenic event that gave rise to the aforementioned folded bands occurred at very close time intervals, presenting a slight diachronism. The article presents an integrated approach to tectonic evolution, however, the need for new studies is quite evident, with an emphasis on isotopic geology, geochronology, geochemistry and geological mapping that can contribute to the understanding of the processes involved in the formation of tectonic domains, their space-time relationships and their implications for the evolution of the Gondwana Continent.

A new type of clay-Li deposit: Fault-controlled hydrothermal alteration in southern Hubei Province, China

Clay-Li deposits are among the major Li deposits in the world and occur mainly in sedimentary and/or volcanic-sedimentary strata. The Li orebodies are generally stratiform and stratibound, and Li is mainly hosted in various clay minerals. Here, we report a new type of clay-Li deposit that occurs along fault zones developed in metasedimentary rocks with significant alteration, and Li is also hosted in clay minerals in the Jinyinshan area in Xianning, southern Hubei Province, China. The study area has no granitic rock outcrops, but approximately 15 km south is the Mufushan granite batholith, where large-scale rare metal mineralization, such as Li, Be, Nb and Ta granitic pegmatites, developed in the internal and outer contact zones of the granite batholith. In this study, high-Li clay minerals, including chlorite, kaolinite and smectite, were identified. The enrichment of Li is closely related to hydrothermal activity along the F9 fault in the region. Hydrothermal apatite coexisting with Li-clay in the orebody along the fault zone yielded an in situ U–Pb age of 135.2 ± 13.9 Ma, which is in good agreement with the ages of granites and Li-pegmatites around the Mufushan batholith. Petrographic, geochemical, and chronological evidence suggests that the ore-forming fluids and Li were likely sourced from the Mufushan granite batholith or a similar blind granite at the depth of the study area; that is, the granite-derived ore-forming fluids can travel long distances along fault zones, and during this pathway, Li from the metasedimentary rocks (i.e., the Lengjiaxi Group) may also have been leached by the fluids and contributed to the Li mineralization in the Jinyinshan clay-Li deposit. The close spatial relationships among different clay minerals indicate that fluid physical–chemical conditions (changes in temperature) may play a crucial role in controlling the formation of Li-rich clay minerals. Our study indicates that the Mufushan area has great potential for hydrothermal clay-Li mineralization occurring in the Lengjiaxi Group metasedimentary rocks around the Mufushan batholith.

Textural and chemical variations in cassiterite from the Yuanlinzi Sn-Cu deposit, NE China: Insights into ore-forming processes

Microtextural, U–Pb isotopic, and trace element analyses were conducted on magmatic and hydrothermal cassiterites from the Yuanlinzi Sn–Cu deposit (NE China) to determine the timing of mineralization and investigate the ore-forming process. Magmatic cassiterites are disseminated in pegmatite, while hydrothermal cassiterites can be classified into three types: cassiterite-bearing stockworks in pegmatite, disseminated cassiterite in wall rock, and cassiterite-quartz-feldspar veins. U–Pb dating of the four types of cassiterite yields a similar age of ∼ 139 Ma, which is consistent with the ages of regional tin mineralization and granites within the mining district. These results suggest a strong association between Early Cretaceous magmatism and tin mineralization. The four types of cassiterite exhibit comparable textural features, characterized by alternating oscillatory CL zonation and dark homogeneous bands, with the latter commonly enriched in W, Nb, Ta, and U. The direct substitution of tetravalent ions, including Zr, Hf, Ti, and V, with Sn4+ and the coupled substitutions of Fe3+ + OH– = Sn4+ + O2– or Fe3+ + H+ = Sn4+, 2Sb3+ + U6+ = 3Sn4+ and Sc3+ + V5+ = 2Sn4+ are responsible for the incorporation of these elements in cassiterite. The enrichment of W, Nb, Ta, and U in the dark domains of cassiterite is related to the coupled substitution of W + U and Nb + Ta, while the excess of Nb and Ta in the oscillatory-zoned domains may be attributed to the substitution of 4(Nb, Ta)5+ + □ = 5Sn4+. The trace element variations observed in the four types of cassiterite, particularly Al, Sc, Ti, V, and Fe, reflect the ongoing enhancement of the water–rock reaction during the mineralization process. The examination of redox-sensitive elements such as Fe, U, and V suggested that tin mineralization in the Yuanlinzi deposit occurred in an oxidizing environment where oxygen fugacity gradually increased. Additionally, we proposed that the Sc/V ratio of cassiterite could serve as an indicator of the redox state of the associated melt/fluid.

Abnormal enrichment of Th and U in melanosome of migmatite in Jivumdnubanda, Eastern Dharwar Craton, India: A unique occurrence in the world

The Neoarchaean (∼2.7Ga) migmatite melanosome of Jivumdnubanda area comprises anomalous radioactive elemental concentration. Significant amount of Th (68.54–290.85 ppm) and U (29.68–114.47 ppm) is observed within biotite-rich melanosome as inclusions. Radioelements are concentrated in certain accessory minerals e.g., allanite, apatite, xenotime and zircon. Leucosomal counterparts are devoid of such higher radioactive elemental concentration, which makes the study significant because the incompatible elements as well as the accessory minerals tend to go into the melt phases more preferentially. Each component of migmatite e.g., melanosome, leucosome and the diatexites are studied in detail from outcrops, under an optical microscope and by geochemical analysis. Structural deformation aspects are also taken care along with granite age determination to link the diatexite with anatexis timing. It is found that the migmatites formed around a pressure of ∼600 MPa correspond to a ∼20–22 km crustal depth when the hydrous mineral breakdown led to ∼50 % melting of evolved TTG protolith. Radiation-induced damage of the accessory minerals due to alpha decays destroyed the internal crystal structures at places. This metamictization and associated radiation damage of more or less refractory minerals along with deformation associated grain-scale fractures make easier to release mobile uranium during hydration and associated alteration at later stage. The presently observed radioactive elemental concentrations are the remnants left behind in the melanosome after leaching out of significant uranium.

THE REFERENCE GAREVKA GRANITE (YENISEI RIDGE, WESTERN MARGIN OF THE SIBERIAN CRATON): THE FINAL ATTEMPT TO VERIFY PALEOPROTEROZOIC Pb/U ISOTOPIC AGE BY M.I. VOLOBUEV

The article unravels a confusing history of ideas about the age of the Garevka granite pluton, which is considered as a reference object for the Precambrian of the Yenisei ridge. Initially, the Paleoproterozoic (1750 Ma) age of granite was determined by M.I. Volobuev and co-authors half a century ago using Pb/U isotope analyses of zircons and orthites. This dating is widely used up to recent to substantiate the Early Precambrian age of the metamorphic rocks of the Trans-Angara region. In 2003, V.A. Vernikovsky and his colleagues published data on the Neoproterozoic (752±3 Ma) age of the massif, obtained with modern technique of isotopic analysis. However, some of experts on the geology of the Yenisei ridge considered both isotopic ages correct, believing that the eastern part of the massif comprises Paleoproterozoic gneissic granite. Our investigation revealed the following: V.A. Vernikovsky and M.I. Volobuev indeed have collected their granite samples at the western and at the eastern parts of the pluton correspondingly. Krasnoyarsk geologists map the Garevka pluton as part of the Neoproterozoic Glushikha granite suite, but use to apply its Paleoproterozoic dating to substantiate the early Precambrian age of the host rocks. M.I. Volobuev obtained ten mainly discordant Pb/U analyses of the Garevka granites, and six of them form an explicable combination consistent with the age of 1750 Ma. The only concordant analysis with a known sampling point is decisive for the entire system. Thus, to fix the problem, it was necessary to reproduce this analysis using modern isotope techniques. We have dated (SHRIMP) a granite sample collected at the same point. In addition, three more samples from different parts of the massif were analysed to exclude the possible presence of ancient domains in it. The isotope ratios of all analysed zircons form a concordant cluster with an age of 762±7 Ma. The Garevka pluton comprises a separate mappable body composed of biotite leucogranites with fluorite. Granites do not replace some older rocks, but crystallized from the melt, ascended from deep crust. The question about possible Paleoproterozoic age of the Garevka granite pluton or any part of it is closed. Ideas about the wide distribution of Archean and Paleoproterozoic gneisses in the Trans-Angara region require additional geochronological verification. To date, the presence of such rocks has been reliably established here only at two local points.

Multiple isotopic dating constraints on diverse W metallogeny in the Baiyunxian ore field, South China

The Baiyunxian ore field, a large tungsten ore filed in the Nanling Metallogenic Belt of South China, hosts a variety of tungsten deposits such as the Dapu (quartz wolframite vein type), Chashanjiao (skarn type), Toutianmen (greisen type), and Dashan (quartz scheelite vein type). However, precise mineralization ages of these deposits remain poorly constrained and this has long vexed a better understanding of genetic relationships between diverse W mineralization types and the spatially associated Jiufeng granitic complexes. Here, we report firsthand zircon U–Pb, monazite U–Pb, garnet U–Pb, cassiterite U–Pb, and molybdenite Re–Os ages of different granites and ores from the Baiyunxian ore field. The Jiufeng granitic complexes consists of phase Ⅰ biotite granite (P1), phase Ⅱ two-mica granite (P2), and phase Ⅲ granitic dikes (P3, including greisen W ore). Zircons from P1 granite define a concordant U–Pb age of 166.0 ± 0.9 Ma (MSWD = 1.1). Monazites from P2 granite yielded a Tera–Wasserburg lower intercept age of 159.2 ± 0.7 Ma (MSWD = 0.45). In addition, zircons and monazites from P3 granite in the Toutianmen deposit yield a concordant U–Pb age of 154.7 ± 1.3 Ma (MSWD = 1.3) and a Tera–Wasserburg lower intercept age of 156.6 ± 1.9 Ma (MSWD = 0.14), respectively, suggestive of multi-stage emplacement processes of the Jiufeng complexes. Ten molybdenite samples from the Dapu deposit generate an isochron age of 156.0 ± 3.0 Ma (MSWD = 0.93). In situ garnet and cassiterite LA-ICP-MS U–Pb dating results of the Chashanjiao skarn deposit yield lower Tera–Wasserburg intercept ages of 155.3 ± 1.2 Ma (MSWD = 1.6) and 153.4 ± 3.7 Ma (MSWD = 1.3), respectively. These dating results indicate that different W mineralization events in the Baiyunxian ore field intensively occurred in the Late Jurassic (∼159–153 Ma). Despite a close spatial relationship between various W orebodies and P1 granite, the geochronological results demonstrate that extensive W metallogeny in the Baiyunxian ore filed likely occurred later than P1 granite and contemporaneous with P2–3 granites. In addition, scheelites from the four deposits have similar REE patterns that are characterized by weak MREE enrichment, despite few exceptions being found in scheelites from the Dashan and Chashanjiao deposits. This suggests that the diverse W metallogeny in the Baiyunxian ore field were derived from the same magmatic hydrothermal system and changed as the ore-forming fluid evolved. Multidisciplinary evidence indicates that the Late Jurassic highly evolved P2–3 granites of the Jiufeng complexes were crucial to W mineralization in the Baiyunxian ore field and the lithology of wall rocks exerted first-order control of W mineralization types.

Late Tonian (ca. 780–750 Ma) bimodal magmatism in the Ogcheon Metamorphic Belt, Korea, at the eastern margin of North China Craton

Neoproterozoic rift-related rocks of the North China Craton (NCC), including the Korean Peninsula, provide crucial information for global supercontinent reconstruction during the Rodinia breakup and Gondwana assembly. Here, we report not only zircon and baddeleyite U-Pb ages but also zircon Hf isotopic and bulk rock compositions of amphibolites in the Ogcheon Metamorphic Belt (OMB), Korea. Zircon occurs as either primary phase or secondary one replacing igneous baddeleyite. Primary zircons analyzed from three amphibolites yielded the weighted mean 206Pb/238U ages of 755 ± 5 Ma (n = 19), 772 ± 3 Ma (n = 9), and 779 ± 13 Ma (n = 12), respectively; this result is corroborated by the baddeleyite age of ∼760–745 Ma. Secondary zircons define discordia lines with lower intercepts corresponding to the Jurassic or Cretaceous age of granites emplaced adjacent to the amphibolite. In conjunction with the occurrence of coeval (ca. 762–745 Ma) metatrachytes, our result suggests that late Tonian bimodal magmatism has lasted for ∼30 m.yr. in the OMB. Moreover, positive εHf(t) values (4.9–21.4) of zircon in amphibolites indicate a depleted mantle source of mafic magma, whereas trace element compositions attest to an intraplate setting for the crystallization. A compilation of Nb-Th and Zr–Zr/Y data suggests that the intraplate setting is also pertinent to ca. 950–750 Ma mafic rocks from the Gyeonggi Marginal Belt, Korea, as well as the NCC. Such a tectonomagmatic correlation is corroborated by detrital zircon age spectra of metasedimentary rocks in the OMB equivalent to those of early Tonian rocks in the NCC. In marked contrast to tectonic scenarios conjecturing a linkage between the OMB and the Nanhua rift, South China Craton (SCC), we conclude that the Ogcheon Belt provides rare geologic-geochronologic evidence for late Tonian breakup of the Rodinia supercontinent at the eastern NCC margin.

Microtexture, geochemistry and geochronology of monazite and zircon from the Jialu deposit in the Lesser Qinling: Implications for multi-stage magmatic and metamorphic events in the southern margin of the North China Craton

The Lesser Qinling area is the largest outcrop of the Precambrian basement in the southern margin of the North China Craton (S-NCC). Notably, many carbonatite-related polymetallic deposits are distributed in this area, including the Jialu deposit with light and heavy REE mineralization. Carbonatite and granite from the Jialu deposit contain diverse monazite and zircon grains, and deciphering the age distributions and chemical compositions of these monazites and zircons is crucial for comprehending the multi-stage magmatic and metamorphic events in the S-NCC. Type I monazite from banded REE ore veins yields a U-Pb age of 217.0 ± 5.0 Ma, representing the formation age of carbonatite. Type II monazite from granite yields consistent U-Pb and Sm-Nd ages of ∼1.95 Ga, representing the emplacement age of granite. Type III monazite is hydrothermal in origin, and yields two dominant age peaks at ∼550 Ma and ∼525 Ma. Types I, II and III zircons are xenocrysts from the Taihua Group and yield two main age peaks at ∼2.35 and ∼2.17 Ga. Of note, type III zircon also records an early Paleozoic tectonothermal event by a lower intercept age of 532 ± 59 Ma, which overlaps the ages recorded by hydrothermal monazite. The early Paleozoic tectonothermal events discovered may be a manifestation of the global Pan-African Orogeny in the S-NCC. This new finding further implies that the S-NCC was significantly affected by the assembly of the Gondwana supercontinent during the early Paleozoic.

Late Magmatic Activity in the Tarim Large Igneous Province: Evidence from the Puchang Granites.

The magmatic evolution sequence and tectonic activity background of the Permian Tarim large igneous province were discussed based on the research of petrogeochemistry, chronology, and zircon Lu-Hf isotope of two types of granite distributed in the Puchang V-Ti-magnetite deposit in the northwestern margin of Tarim. The results show that the two types are characterized by high silica, alkali, and potassium content. Both types of granites are enriched with light rare earth elements, including porphyritic granites with a negative anomaly of Eu and biotite monzogranites with a weak positive anomaly of Eu. The trace elements generally show that the large-ion lithophile elements are enriched relative to the high-field-strength elements, P and Ti are obviously depleted, and Rb, U, and K are relatively enriched. The zircon U-Pb age of porphyritic granites is 275.7 ± 1.0 Ma, the εHf(t) value ranges from -6.6 to -3.3, and the tDM2 ranges from 1469 to 1684 Ma. The zircon U-Pb age of biotite monzogranites is 268.9 ± 1.4 Ma. The εHf(t) value ranges from -1.2 to 0.5, and the tDM2 ranges from 1232 to 1340 Ma. The two types of granite were formed in a postcollisional extensional environment at the end of the early Permian, which is related to the Permian Tarim mantle activity and asthenosphere upwelling. The porphyritic granite was derived from an enriched lithospheric mantle; the biotite monzogranite was formed by the melting of mantle with crust contamination; and basalt and intrusive complexes in the research area were formed in an extensional intraplate rift environment.

Indosinian W–Sn mineralization in the Dupangling area, Western Nanling: Cassiterite U–Pb dating and trace element data for the Maoershi Sn polymetallic deposit

Nanling is located in central South China and contains the most important area of W–Sn polymetallic deposits worldwide. However, a lack of geochronological data hinders our understanding of the timing and mechanisms of W–Sn mineralization in the Dupangling area of western Nanling. The Maoershi Sn polymetallic deposit is located in the western body of Dupangling complex pluton, and is a significant hydrothermal vein deposit. Cassiterite U–Pb dating shows that the Maoershi Sn mineralization occurred during the Late Triassic (206.2 ± 2.6 Ma). This age is different from the age of granite in the western Dupangling pluton and similar to the age of the eastern Dupangling pluton. The cassiterite is enriched in Sc (4.5105–18.4049 ppm), V (37.2267–88.9671 ppm), Nb (62.0104–194.1846 ppm), Ta (11.1965–85.6881 ppm), Hf (22.0511–30.7650 ppm), U (2.8870–17.9187 ppm), Th (0.0005–0.0908 ppm), Ti (3873–6170 ppm), and other high-field-strength elements. Based on Nb/Ta and Y/Ho ratios, and the W–Fe discriminant diagram, Sn and the other mineralizing materials were mainly derived from hidden Indosinian granitic rocks. Tungsten–Sn mineralization in the Dupangling pluton exhibits a clear spatial–temporal relationship with Indosinian granitic magmatism, and occurred in an extensional setting after the continent–continent collision that marked the late Indosinian Orogeny.

THE ZABAIKALIAN PARAMETRIC BOREHOLE: A FIRST EVIDENCE ABOUT DEEP STRUCTURE OF THE BORSHCHOVOCHNY METAMORPHIC CORE COMPLEX

The Zabaikalian parametric borehole drilled out a metamorphic core complex on the reference geological and geophysical profile within the Central Asian fold belt, south of the Mongol-Okhotsk suture zone. In the section of the borehole drilled to a depth of 2600 m, a set of geophysical, geological and laboratory-analytical studies identified three main structural elements of metamorphic core complexes: the upper plate, detachment, and the lower plate. The upper plate (weakly metamorphosed rocks) is represented by serpentinite melange, which is separated from the underlying rocks of the lower plate by a zone of chlorite breccias (detachment). The lower plate, which is part of the crystalline basement complex, includes rocks of granite-schist and granite-plagiogneiss subcomplexes. The granite-schist subcomplex is composed of mafic and intermediate schist with amphibolites and quartzites. Biotite granite is widespread in the section; it forms layered veins with signs of synkinematic formations. According to preliminary estimates, the age of biotite granite is about 130 Ma. The schist is characterized by mylonite structure at intervals of interbedding with biotite granite veins. In accordance with data of geophysical surveys in the borehole and the petrophysical characteristics of cored rocks, the mylonite zone is the provenance of a series of inclined reflectors on the seismic reflection-CDP section, which can be traced to a depth of at least 10 km. The granite-plagiogneiss subcomplex is represented by plagiogneiss, leucogranites, and gneissic granites. In the Zabaikalian parametric borehole, a detailed section of the orshchovochny metamorphic core complex, fully characterized by core samples, of the was obtained, which should be considered as a reference for studying these structures. The investigation of this section will answer later many questions about the formation and evolution of the Central Asian fold belt.

Magma-related origin for Pb–Zn–Ag vein formation at the Aerhada deposit, Inner Mongolia, NE China: Constraints from fluid inclusion, C–H–O–S–Pb isotopic compositions, and geochronological studies

The Aerhada Pb–Zn–Ag deposit is on the western margin of the Great Xing’an Range in NE China. Prior studies on this deposit lack information regarding precise mineralization age and convincing genetic interpretation, which limits both the prospecting at Aerhada and the reconstruction of the regional metallogenic evolution. Based on a detailed field investigation and microscopic observation, in this study, our aim was to determine the origin and evolution of the hydrothermal system and the timing of magmatism and mineralization, as well as to develop a possible metallogenic model, by revealing information regarding the mineralization paragenetic relationship, fluid inclusions, H–O–C–S–Pb isotopes, and sphalerite Rb–Sr and zircon U–Pb ages. Three successive mineralization stages were recognized: stage I quartz-arsenopyrite-pyrite, stage II quartz-sphalerite-galena, and stage III fluorite-calcite-pyrite. Four types of fluid inclusions were also identified in host minerals: CH4-rich two-phase, halite-bearing, vapor-rich two-phase, and liquid-rich two-phase. Fluid inclusion and microthermometric results showed that the homogenization temperatures were 287–341 °C for stage I, 237–291 °C for stage II, and 162–230 °C for stage III, with respective salinities of 1.7–40.2 wt%, 6.7–10.9 wt%, and 4.2–8.8 wt% NaCl equivalent. The δ18Ofluid and δDfluid values of quartz in stage I (δ18Ofluid = 8.6–10.3 ‰, δDfluid = -126.6 to −124.3 ‰) indicated that initial magmatic water interacted with organic strata, while decreasing the values of quartz in stage II (δ18Ofluid = 3.9–6.8 ‰, δDfluid = -129.1 to −127.6 ‰) and calcite in stage III (δ18Ofluid = -3.5 to −1.0 ‰, δDfluid = -115.5 to −113.4 ‰), showing a trend of dilution and cooling by meteoric water. The negative δCfluid values (δCfluid = -15.9 to −12.6 ‰) of quartz fluid inclusions from stages I and II emphasize that organic carbon was added to the hydrothermal system through water–rock interactions. The δ34S values (δ34Ssulfides = 1.2–7.5 ‰) and lead isotope data of sulfides (206Pb/204Pb = 18.153–18.684, 207Pb/204Pb = 15.370–15.750, 208Pb/204Pb = 37.653–39.301), coupled with those of the hidden biotite granite and Devonian strata, indicate that the ore-forming material was primarily derived from magma and wall rocks. The sphalerite samples produced a Rb–Sr isochron age of 154.1 ± 3.5 Ma (2σ, MSWD = 0.82, n = 8), which was like the zircon U–Pb age of biotite granite (156.3 ± 1.4 Ma, 2σ, MSWD = 0.89, n = 14). Combining the alteration pattern, fluid inclusions, and isotopic and geochronological studies, it was concluded that Aerhada is a magma-related hydrothermal Pb–Zn deposit formed under the post-collision extension setting following the Mongol–Okhotsk Ocean closure during the Late Jurassic period. The proposed metallogenic model is expected to assist in the exploration and development of polymetallic mineralization in the Great Xing’an Range.

Geochemistry Signature and K-Ar Age of the I-type Granite at East Coast of Bangka Island

This work presents microscopic-, whole-rock geochemical- , and K-Ar age data for Tanjung Berikat Granitoid at the easternmost part of Bangka Island. Some selected samples are in the range of monzogranite and granodiorite based on microscopic analysis. The rocks are characterized by a wide range in SiO2 (62.75 - 70.17 wt %), high-K calcalkaline to shoshonitic affinity, and ferroan signature. Very good correlation values of bivariate SiO2 plotted against other major oxides, similar spider diagrams normalized to the composition of the N-MORB and chondrite-normalized REE diagrams demonstrate the same origin and crystallization mechanism of the granitoid. The I-type nature of the studied granite is based on the hornblende existence, metaluminous character, negative SiO2 to P2O5 correlation, and volcanic arc characteristics of the rock. Tanjung Berikat Granitoid was crystallized in the mid ̶ late Early Cretaceous at 125.5 ± 2.8 Ma and 109.4 ± 2.5 Ma based on the K-Ar dating method. Keywords: granitoid, geochemistry, I-type, Bangka Island

Two-stage crust-mantle interactions from oceanic subduction to post-collisional extension in the northern margin of the North China Craton: Insights from Paleozoic to Mesozoic magmatism

The northern margin of the North China Craton experienced prolonged tectono-magmatic evolution during the late Paleozoic−early Mesozoic in response to the southward subduction and closure of the Paleo-Asian Ocean. However, details about the subduction process and the timing of the tectonic transition from subduction to post-collision are still poorly constrained. Here, we identify two-stage crust-mantle interactions in the Wulashan area and report new geochronology, geochemistry, and Sr-Nd-Pb-Hf isotopic data for magmatic rocks that record such processes following the subduction and closure of the Paleo-Asian Ocean. The early Carboniferous Xiguanjing pluton features a bimodal suite of gabbro (ca. 333 Ma) and syenogranite (ca. 331 Ma). The gabbros have arc-like geochemical affinities, with low Nb/La (0.31−0.40) and La/Ba (0.04−0.09) ratios, and variable Rb/Y (1.22−2.94) ratios, as well as enriched, mantle-like Sr-Nd-Pb (87Sr/86Sri = 0.7046−0.7047; εNd(t) = −3.8 to −3.5; 206Pb/204Pbi = 17.078−17.141) and enriched to depleted Hf (εHf(t) = −4.5 to +6.2) isotopic values. Such geochemical signatures indicate that they were derived from partial melting of the subcontinental lithospheric mantle that was metasomatized by slab-derived fluids, with minor involvement of asthenospheric components. In contrast, the contemporaneous syenogranites are characterized by lower negative εNd(t) (−13.5 to −12.1) and εHf(t) values (−16.3 to −8.2), which suggests that they were formed by partial melting of the lower crust. Late Triassic Shadegai and Xishadegai plutons are mainly composed of enclave-bearing syenogranite, and both mafic microgranular enclaves and syenogranites crystallized at ca. 233−231 Ma. The mafic microgranular enclaves have geochemical features similar to those of the early Carboniferous gabbros, and also have moderately enriched isotopic compositions (εNd(t) = −9.7 to −8.4; εHf(t) = −9.2 to −0.3), which suggests that they originated from interaction between mantle-derived magma and overlying crust-derived magma, with minor additions of asthenospheric melts in their sources. Field and petrological observations, coupled with the similar ages of the host granites and mafic microgranular enclaves, suggest a magmatic mingling process. Isotopic mixing models suggest that minor amounts (∼10%−20%) of lower crustal materials were mixed during the formation of the mafic microgranular enclaves. The host syenogranites display calc-alkaline to alkalic and metaluminous to weakly peraluminous compositions, and negative εNd(t) (−15.0 to −12.1) and εHf(t) values (−16.4 to −9.8), which indicates that they were mainly derived from partial melting of the lower crust and experienced the injection of deep mantle-derived magmas. Our new data, along with previously published data for magmatic rocks in the northern margin of the North China Craton, suggest that the early Carboniferous bimodal intrusive rocks formed in a localized back-arc extensional regime that was probably triggered by slab rollback of the Paleo-Asian Ocean. However, the Late Triassic plutons formed in a post-collisional extensional regime in response to slab breakoff or lithospheric delamination. Temporal variations of Nd-Hf isotopes for the magmatism in the northern margin of the North China Craton suggest that tectonic switching from advancing to retreating subduction to post-collisional extension occurred during the late Paleozoic to early Mesozoic. We propose that a tectonic transition from subduction to post-collisional extension may have occurred during the Early−Middle Triassic, marking the final closure of the Paleo-Asian Ocean, which most likely took place at ca. 250−235 Ma.

Age and petrogenetic constraints of the post-collisional Parati Granite, southeast Brazil

The Ribeira orogen is one of the orogens formed in the Pan-African-Brasiliano collisional event. Post-collisional Cambrian-Ordovician magmatism occurred after the main agglutination event of this orogen, being recorded in its central segment by a series of granitic bodies exhibiting few or no deformation, which have been divided into three suites, Suruí, Nova Friburgo and Sana. This work brings a contribution to the understanding of the generation of these bodies through the geochemical - petrological study of the Parati Granite. In addition, unpublished data about crystallization temperature and pressure conditions during the emplacement, as well as a proposition on source and generation model for this granite is also presented. The Parati Granite has a batholithic size showing a predominant inequigranular porphyritic facies with feldspar phenocrysts, besides another inequigranular to equigranular facies also composed of feldspar, quartz, biotite, hornblende and titanite. Geochemically, it is a high potassium, Hi-BaSr metaluminous, magnesian to slightly ferroan calc alkaline granitoid. REE and multielemental diagrams along with biotite composition suggest that Parati Granite was generated from crustal melting with involvement of an enriched mantle, which is corroborated by isotopes of Sr, Nd and Hf. Geothermobarometry results point to crystallization temperature ranging from 760° to 810 °C and pressures varying from 3 to 5 kbars. Geochronological data indicate crystallization age interval between ca. 520 to 505 Ma. Due to the similarities of geochemical patterns and isotopic data, it is believed that the source of this granite could be rocks of the Rio Negro Arc. As a geodynamic model, slab breakoff followed by uplift can be considered as a mechanism responsible for the formation of Parati Granite, as it explains its mantle and crustal signatures.

The Trans-Baikal Parametric Borehole: First Evidence of the Deep Structure of the Borshchovochnyi Metamorphic Core Complex

The Trans-Baikal parametric borehole drilled out a metamorphic core complex in the reference geological and geophysical profile within the Central Asian fold belt, south of the Mongol–Okhotsk suture zone. In the section of the borehole drilled to a depth of 2600 m, a set of geophysical, geological, and laboratory–analytical studies made it possible to identify three main structural elements of metamorphic core complexes: the upper plate, detachment, and the lower plate. The upper plate (slightly metamorphosed rocks) is represented by a serpentinite mélange separated from the underlying rocks of the lower plate by a zone of chlorite breccias (detachment). The lower plate as a part of the crystalline basement complex comprises rocks of granite–schist and granite–plagiogneiss subcomplexes. The granite–schist subcomplex is composed of mafic and intermediate schist with amphibolites and quartzites. Biotite granite is widespread in the section as layered veins with synkinematic signs. According to the preliminary estimates, the age of biotite granite is about 130 Ma. Schist is characterized by a mylonite structure at intervals of interbedding with biotite granite veins. In accordance with the geophysical survey data on the borehole and the petrophysical characteristics of cored rocks, the mylonite zone is the provenance of a series of inclined reflectors in the seismic RSS–CDP section, which can be traced to a depth of at least 10 km. The granite–plagiogneiss subcomplex is represented by plagiogneiss, leucogranite, and gneissic granite. In the Trans-Baikal parametric borehole, a detailed section of the Borshchovochnyi metamorphic core complex, fully characterized by core samples, was obtained. It should be considered as a reference for studying these structures. The investigation of this section will make it possible later to answer many questions about the formation and evolution of the Central Asian fold belt.

Sources, evolution and ages of A-type granites from the post-orogenic Itu batholith, SE Brazil: Inferences from zircon U–Pb dating, Lu–Hf isotope ratios and trace-element geochemistry

A combination of U–Pb dating by SHRIMP and Lu–Hf isotope and trace-element analyses by LA-ICPMS in zircon crystals from representative samples of the Itu Granitic Batholith, allowed to determine timing, sources and intensive parameters of crystallization (T, fO2) of the plutons that generated this large (>300 km2) occurrence of A-type granites that locally marks the end of the Neoproterozoic orogeny in SE Brazil. The main episode of batholith construction is dated at 578 ± 4 Ma, with possible minor manifestations as young as ∼560 Ma. Negative zircon εHf(t) as low as −19 to −17 in the Indaiatuba pluton requires a significant crustal input, but a component from enriched mantle (which has εHf(t) as low as −10, reflecting contamination from previous subduction) is evident in all plutons by the presence of small mafic bodies and frequent mafic microgranular enclaves showing evidence of mixing with the host granites. Distinct sources are implied by large contrasts in redox state, estimated qualitatively from negative Eu anomalies and quantitatively from Ce anomalies in zircon, with samples from the Itupeva and Salto plutons showing fO2 ∼FMQ+2 and a sample from the Cabreúva pluton closer to FMQ. Significant intra-sample variations of εHf(t) and trace-elements (e.g., Th, U) in zircon are also indicative that multiple sources have contributed to individual magma batches and were probably preserved by fast crystallization related to magma mixing processes.

Petrogenesis of early Cretaceous granites in Mufushan complex, northeastern Hunan Province: Insights on middle-late Mesozoic tectonic evolution of eastern South China

We present new field observations, whole-rock major and trace elements, Sr-Nd-Pb-Hf isotopes and zircon UPb ages for the Mesozoic granites in the Mufushan complex, eastern South China. The age determinations by LA-ICP-MS UPb dating of zircons indicate that the porphyritic biotite granites and two-mica monzogranites have ages of ∼136 Ma and ∼ 130 Ma, respectively. These granites display highly evolved S-type granite geochemical characteristics, with high SiO2 (70–74 wt%) contents, high 10000*Ga/Al ratios (2.3–3.2, average of 2.8) and weakly peraluminous (A/CNK > 1.1). Both types of granites are enriched in large ion lithophile elements (LILEs, e.g., Rb, K, Ba, Sr) and depleted in high field strength elements (HFSEs, e.g., Nb, Ta, Ti), with negative anomalies of Eu and positive anomalies of Pb, which are akin to continental arc rocks. The two-mica monzogranites have high 87Sr/86Sr(i) (0.71355–0.71535), 206Pb/204Pb(i) (18.105–18.157), low εNd(t) (−9.1 to −9.6) and εHf(t) (−4.1 to −10.4), similar to those of the porphyritic biotite granites which are characterized by high 87Sr/86Sr(i) (0.717337–0.71692), 206Pb/204Pb(i) (18.134–18.580), low εNd(t) (−9.1 to −9.7) and zircon εHf(t) (−6.8 to −3.3). The similar emplacement ages and mineral assemblages as well as Sr-Nd-Hf isotopic signatures indicate their derivations were likely derived from a common magma source. These early Cretaceous granites yield two-stage Nd model ages of 1.6–1.7 Ga, similar to the two-stage Hf model ages of 1.3–1.8 Ga. The presence of Neoproterozoic and subordinate Mesoproterozoic zircons within the granitic rocks suggest a significant contribution of ancient crustal materials involved in the genesis of the magmas. In combination with comprehensive studies on the magmatic rocks, the early Cretaceous Mufushan granitic rocks may have experienced an extensive enrichment process, contemporaneously with partial melting of the Neoproterozoic volcanic-sedimentary sequences that produced the arc-like rocks. Almost simultaneously, an extensional event caused by the subduction and slab roll-back of the Paleo-Pacific plate (Izanagi plate) dominates the middle-late Mesozoic tectonics in eastern South China. This extensional regime was accompanied by the underplating of mantle-derived magma and crustal melting, producing the widespread early Cretaceous granites in adjacent regions. The development of coeval basin-and-range structures with the production of contemporaneous magmatic rocks and related polymetallic deposits in eastern South China are all related to slab roll-back tectonics.