The dielectric breakdown strength of an arcing contact gap after current zero was compared when using alumina, polyamide 6/6 (PA 6/6), and polyoxymethylene (POM) arc chamber wall materials. Plasma characteristics were obtained for each material by applying a reverse recovery voltage across the open contacts at a predetermined delay time after current zero. Ablation from each type of chamber wall material produced different plasma compositions each with different recovery voltage, arc voltage, and pressure characteristics. Tests were performed for an arcing current of 12 kA/sub p/, for one half-cycle using symmetric AgW contacts. A thermal breakdown model along with an exponential curve fit to the measured results were used to obtain the initial holdoff voltage and plasma time constant for each material. PA 6/6 and POM had similar time constants with PA 6/6 having slightly better performance. Two types of breakdown mechanisms were identified-thermal and dielectric.