The escalating global water crisis necessitates innovative approaches to developing sustainable water resources. Fog water collectors with variable surface wettability offer controlled fog harvesting in water-scarce regions. This study develops thermoresponsive fog collecting materials by electrospinning poly(N-isopropylacrylamide)-polyvinylidene fluoride (PNIPAm-PVDF) into yarns that are transformed into harp-like structures for enhanced water harvesting rate. Both meshes and harps using electrospun membranes exhibit the remarkable ability to transition between hydrophilic and hydrophobic wetting states at temperatures below the lower critical solution temperature (LCST). Hydrophilic and hydrophobic surfaces play distinct roles in fog water collection. Hydrophilic surfaces have a high affinity for water and enables droplet capture. Hydrophobic surfaces help the removal of aggregated water droplet and fog water collection. The highest water collection rate obtained with the electrospun PNIPAm-PVDF harp was 1415 ± 7.0 mg·cm−2 h−1. The water harvesting system based on the electrospun PNIPAm-PVDF harps exhibits a 485 % increase in water collection compared to the standard meshes made from the same material, emphasizing their potential for significantly improving the overall rate in fog water harvesting applications.