The large N generating functions for the counting of chiral operators in , four-dimensional quiver gauge theories have previously been obtained in terms of the weighted adjacency matrix of the quiver diagram. We introduce the methods of multi-variate asymptotic analysis to study this counting in the limit of large charges. We describe a Hagedorn phase transition associated with the asymptotics, which refines and generalizes known results on the 2-matrix harmonic oscillator. Explicit results are obtained for two infinite classes of quiver theories, namely the generalized clover quivers and affine orbifold quivers.