Atmospheric aerosols play a pivotal role in shaping our environment, impacting climate, human health, and ecosystems. Characterizing the influence of aerosols on ecosystems, especially in mountain environments, is a challenging task due to their complex-orography and scarcity of aerosol ground stations. Satellite-based aerosol data can improve our knowledge over such complex-orography areas. Thus, we have analyzed the Aerosol Optical Depth (AOD) product from the MODerate resolution Imaging Spectrometer (MODIS) sensor produced by the inversion algorithm MultiAngle Implementation of Atmospheric Correction (MAIAC) over the last two decades for the period 2001–2022 with a spatial resolution of 1 × 1 km. Our study focuses on the Sierra Nevada Mountain region and National Park in Southeastern Spain. As a first step, we have validated the AOD from MODIS+MAIAC against three AERONET stations at different altitudes (680 m, 1800 m, and 2500 m above sea level (a.s.l.)). MODIS+MAIAC AOD showed good agreement with the ground-based AOD observations, with R values ranging from 0.75 to 0.82, RMSE values ranging from 0.047 to 0.066 and having 80% of the samples within the expected error (EE) of the product. The MODIS+MAIAC AOD product is able to characterize the fine-scale features of such complex-orography area and hence evaluate the spatio-temporal distribution of the AOD over the mountainous region. We have generated the most extended AOD dataset for a mountainous region, spanning the past two decades. We have deepened into the spatial and seasonal AOD patterns from 2001 to 2022, unveiling elevated AOD values near valleys and urban areas. In general, the AOD values decrease with increasing altitude with the exception of snow-covered areas at high altitudes (>2800 m a.s.l.), which might affect aerosol retrieval and provide bias due to higher-reflecting surfaces and pixel removal. For the first time, the relationship of aerosol loading with ecosystem type has been assessed in the protected environment of Sierra Nevada Natural Park. Monthly AOD trends across different ecosystem types and altitudinal ranges are analyzed in detail over the last two decades. In addition, Generalized Linear Models (GLM) are applied to reveal significant correlations between ecosystems and AOD, irrespective of altitude, latitude or longitude. Based on the interannual variation of AOD over the last two decades, we have analyzed the relationship of AOD with the different ecosystems of Sierra Nevada at 500 m elevation ranges. The patterns of the ecosystem's types are maintained over the elevation ranges 1200–1700 m and 1700–2200 m a.s.l., which demonstrates that land-type has an impact on the AOD product. Furthermore, it is observed that forest-like ecosystems tend to present lower AOD compared with bare-soil or low-growth vegetation ecosystems. In addition, the areas of the mountain closer to Granada city present generalized higher AOD values on the western part of the mountain, regardless of the ecosystem, showing the significant influence of the proximity of urban sites over the ecosystems and the potential impact on the environment.
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