Cement Admixtures Research Articles

The Toxicity Leaching and the Cement Admixtures Properties with Incineration Fly Ash of Different Furnace Types.

Incineration of fly ash is a hazardous solid waste, and there are two types of furnaces used for production. The impact of furnace types on the properties and toxicity of incineration fly ash was studied. The resource utilization of incineration fly ash has been tested. The results showed that circulated fluidized bed (CFB) ash and grate (GF) ash were alkaline materials, dioxin content ranged between 98 and 359 ng-TEQ/kg, and heavy metals exceeded 7700 ppm. The leaching of Zn in CFB ash was 110.474 ppm, and that in the GF ash was 5.985 ppm. The chlorine content in GF ash was 27.07%, 2.7 times that of CFB ash. When the content was 5%, GF ash promoted cement grinding and improved the 3-day compressive strength of cement, which was 35.55% higher than the control sample. CFB ash generates hydrogen gas during the hydration process, causing volume cracking. When 20% GF ash was added, the hydration heat release peak appeared 10.5 h ahead of time. According to the Chinese standard GB 175-2023, the maximum dosages of CFB ash and GF ash in cement were 0.22 and 0.57%. There was no risk of excessive leaching of heavy metals. During cement production with CFB and GF ash, attention should be paid to the issues of chlorine and dioxins.

An environmental approach to cement admixtures: Utilization of waste olive seed powder as a bio-polymeric admixture.

The integration of organic wastes into cement-based materials shows promise as a solution to mitigate environmental pollutants. It achieves this by minimizing waste sent to landfills and in some conditions decreasing Portland cement use. One of these organic wastes that produces positive effects when used in cement products is olive seed. In this study, the effect of a new generation bio-polymeric admixture on the physical and mechanical properties of cement mortars is examined in detail. The bio-polymeric admixture is prepared by grinding olive seeds in 0/125μm sizes. The olive seeds have been used as bio-polymeric admixture in cement mortars at different rates, i.e., 0, 0.2, 0.35, 0.5, 1 and 1.5% of total weight. The olive seed is characterized by XRD, FT-IR analysis and by determining extracts, pectin, cellulose, hemicellulose and lignin content. The characteristics of hydration products were analyzed by SEM/EDS and XRD investigations. Effect of bio-polymeric admixture addition on the unit weight, flowability, setting time, compressive and flexural strength and capillary water absorption was analyzed. The results suggested that the bio-polymeric admixture hindered the cement hydration at low usage rates but promoted at high usage rates. Accordingly, 28days compressive and flexural strength of test samples decreased. However, 1.5 wt% bio-polymeric admixture was associated with a slight increase of 150-days compressive strength. Bio-polymeric admixture improves the hydrophobicity property of the hardened mortar samples by declining effect on the water absorption. Another important effect of the bio-polymeric admixture contribution was also observed on the flowability property of the cement mortars. As the bio-polymeric admixture increased, the flow diameter values of the mortar were also significantly increased. The research outcomes suggested for the first time the beneficial effect of bio-polymeric admixture as a natural and bio-degradable alternative of chemical admixtures on especially flowability, set retarder and hydrophobicity of cement mortars with comparable mechanical properties.

Investigating the Sway of Marine Brown Seaweed Gel as Natural Polymer in Properties of Concrete

In the present study, the effects of the fresh properties as slump, consistency and setting time and hardened concrete's characteristics such as compressive, split tensile and flexural strength for various ages, the brown seaweed (Sargassum wightii) gel was added to cement throughout differing proportions (1, 2, 3, 4 and 5%) by the mass of concrete. Durability and thermal tests such as water absorption, sorptivity, RCPT, acid attack and thermal conductivity also determined at various ages. Micro structural properties of seaweed gel were found out by SEM, FTIR and XRD analysis. Test results show that seaweed gel act as retarding admixture in cement up to 5% of addition. For instance, 5% alginate collections as a percentage of concrete mass showed a comparable compressive strength of about 42MPa. The use of seaweed gel improved the thermal characteristics of concrete by reducing its thermal conductivity roughly 50% for a 5% addition. The seaweed gels up to 5% addition in concrete will significantly improve the fresh-state properties of concrete without affecting its hardened properties. The future is completely dependent on eco-friendly materials; hence the use of natural organic additives to improve the strength and durability of cement concrete would be the better option for sustainability.

Investigation of mechanical and thermal performances and masonry quality for new raw soil-based insulating hollow bricks

ABSTRACT The development of raw soil-based insulating hollow bricks (RSIHB) provides a promising way for improving the efficiency of building energy conversation and resource utilization of construction waste soil. In this paper, the response surface method (RSM) was adopted to study the effect of multifactor on mechanical and thermal performances of modified raw soil-based samples. The results indicate that the thermal conductivity is significantly affected by the interactions between molding pressure and mixture moisture content, as well as between mixture moisture content and cement admixture. Thus, the optimal mix ratio was determined by the RSM-based regression model. The assessment based on numerical simulation demonstrates that the middle wall ribs immensely improve the stress concentration. The porous structure elongates the path of heat flow conduction, effectively enhancing the thermal resistance of the brick. In addition, bonding strength tests manifest that the mortar consistency should be within 60–80 mm for construction and plastering of the new raw soil-based insulating hollow brick. The research results have strong theoretical significance and practical value for recycling of construction waste and provide a reference for actual production and construction.

Effect of plantain peel ash as an admixture on concrete properties

This study investigates the effect of plantain peel ash as an admixture on concrete properties, which is a sustainable alternative to conventional concrete production. The aim is to optimize the mix design of concrete required for improved performance, investigate the effect of the plantain peel ash on the compressive strength of the concrete, and examine the effects of plantain peel ash as a supplementary material on the durability and service life of concrete. The use of plantain peel ash as an admixture for cement in concrete has gained increasing popularity due to its ability to reduce the environmental impact of concrete production. This study contributes to the understanding of the durability and performance of plantain peel ash in concrete which is crucial for sustainable construction practices. The methodology involves mix design according to IS 10262:2009 for M15 grade of concrete with 5%, 10%, 15% and 20% plantain peel ash replacement, testing of compressive strength and durability of the concrete samples and also the optimal dosage required, in comparison with conventional concrete. The result of this study shows that the addition of 5% plantain peel ash increases the compressive strength of the concrete with obtained value of 27.30 N/mm2 and also has the standard workability for a normal concrete at 45 mm for the control and 60 mm for 5% PPA. The 10%, 15% and 20% shows a decrease in their compressive strength compared to the control mix (0%) with a value of 18.42 N/mm2 for 28 days curing. Overall, it can be said that 5% plantain peel ash has provided a strong basis for the use of plantain peel ash in concrete mixtures. The 5% is equivalent to 0.72 kg PPA.

Ex Situ Stabilization/Solidification Approaches of Marine Sediments Using Green Cement Admixtures.

The routine dredging of waterways produces huge volumes of sediments. Handling contaminated dredged sediments poses significant and diverse challenges around the world. In recent years, novel and sustainable ex situ remediation technologies for contaminated sediments have been developed and applied. This review article focuses on cement-based binders in stabilizing contaminants through the stabilization/solidification (S/S) technique and the utilization of contaminated sediments as a resource. Through S/S techniques, heavy metals can be solidified and stabilized in dense and durable solid matrices, reducing their permeability and restricting their release into the environment. Industrial by-products like red mud (RM), soda residue (SR), pulverized fly ash (PFA), and alkaline granulated blast furnace slag (GGBS) can immobilize heavy metal ions such as lead, zinc, cadmium, copper, and chromium by precipitation. However, in a strong alkali environment, certain heavy metal ions might dissolve again. To address this, immobilization in low pH media can be achieved using materials like GGBS, metakaolin (MK), and incinerated sewage sludge ash (ISSA). Additionally, heavy metals can be also immobilized through the formation of silicate gels and ettringites during pozzolanic reactions by mechanisms such as adsorption, ion exchanges, and encapsulation. It is foreseeable that, in the future, the scientific community will increasingly turn towards multidisciplinary studies on novel materials, also after an evaluation of the effects on long-term heavy metal stabilization.

Evaluating the potential of high free-CaO fluidized bed boiler ash as a cement admixture

This study investigates the feasibility of utilizing ash from circulating fluidized bed combustion (CFBC) boilers as a cement admixture. Two types of CFBC ash, distinguished by their free-CaO contents, are examined to evaluate their impact on the hydration reactions and mechanical properties of cement. The incorporation of CFBC ash with elevated free-CaO content into cement facilitates a hydration reaction, which results in accelerated setting and reduced compressive strength. To effectively utilize CFBC ash as a cement admixture, it is necessary to reduce the free-CaO content to an appropriate level, and carbonation curing is found to be an efficient method. It is confirmed that even CFBC ash with a high free-CaO content can effectively be utilized as a cement admixture through pretreatment with carbonation curing. This study may have valuable implications for the ability of CFBC ash to reduce carbon dioxide via mineral carbonation and its potential use as a cement admixture.

Experimental Performance of Filling Material with Modified Red Mud for Roadbed

Cement-modified red mud as roadbed filler was investigated through tests, including compaction, California Bearing Ratio (CBR), modulus of resilience (E0), unconfined compressive strength (UCS), and scanning electron microscopy. Optimum moisture content (ω0), maximum dry density(), CBR, modulus of resilience, UCS, and microscopic characteristics of red mud were analyzed in different modified states. An optimal cement admixture for red mud modification was proposed. Results showed that (1) adding cement significantly improved CBR and modulus of resilience, (2) cement-modified red mud exhibited faster initial strength formation, with 7-day UCS over 65% of 28-day UCS, (3) water stability and frost resistance improved significantly with 4% and 6% cement dosing, (4) recommended cement admixture was 1.1% without adverse conditions, but not less than 6% with water immersion. Modified red mud is unsuitable for seasonal frozen regions. The recommended blending and leaching concentration met regulatory requirements, meeting technical, environmental, and economic goals for roadbed filler in highway construction.

Research on Temperature Field of Cement-Mixing Pile-Reinforced Soft Soil Foundation

To investigate the mechanism of reinforcing soft soil with cement-mixing pile, based on ABAQUS secondary development, a numerical simulation study of the hydration reaction of cement-mixing piles was conducted. In this study, the influence of ground temperature variations on the distribution patterns of the temperature field in and around the pile was also considered. The temperature field of the pile–soil model can be primarily divided into two stages: the temperature rise stage (0~5 d) and the temperature decrease stage (5~90 d). The following observations were made: (1) The temperature of the pile body rapidly increased within the first 5 days, dissipating heat to the surrounding soil, leading to an elevation of the temperature in the soil around the pile and a decrease in soil moisture content. Around the 5th day, the temperature reached its maximum value, and the heat release rate of the pile body was higher than that of the surrounding soil. (2) With a 15% cement admixture, under the influence of 425# cement hydration, the temperature inside the pile increased by 5 °C, and the temperature in the soil around the pile increased by 4.2 °C. After considering the ground temperature, the temperature in the soil around the pile increased by 4.6 °C. (3) The maximum temperature generated during the hydration of 425# Portland cement is higher than that of 525#; the temperature of the soil around piles made with 425# cement is consistently higher than that made with 525#. (4) The hydration temperature of piles with a 10% cement admixture increased by 4.4 °C; for piles with a 15% cement admixture, the hydration temperature increased by 6.6 °C; and for piles with a 20% cement admixture, the hydration temperature increased by 9.1 °C. The temperature field of this structure gradually stabilizes after 7 days with increasing time and cement admixture. The results indicate that the hydration of cement-mixing piles raises the temperature of the soil around the piles. Additionally, the temperature resulting from the hydration of cement-mixing pile increases with the addition of cement.

Heating aluminum dross: Harmless process and utilization as cement admixture

Phosphogypsum (PG) and aluminum dross (AD) with harmful impurities seriously hinder its large-scale engineering utilization. In this paper, the properties of AD and PG as cement admixture were investigated with the aim of reducing the environmental pollution and landfill stockpiling pressure. The migration and transformation rules under crucial factors were analyzed by different characterization methods while AD was heated at different temperature. Then, the compressive strength, soluble phosphorus and fluorine concentration, hydration heat and expansion rate of specimens prepared with AD, PG, and Portland cement (PC) were evaluated to illustrate the hydration mechanism. Compared to the other experiment sets, the results indicated that AD treated at 900°C not only had a higher nitrogen removal rate, but also maintained hydration activity at a relatively high level. Moreover, Heating AD at 900℃ effectively accelerated the dissolution of gypsum and calcium silicate, resulting in increased formation of ettringite (AFt), calcium silicate hydrates (C-S-H) and calcium aluminium hydrates (C-A-H). When the binder consisted of 14% heated aluminium dross (HAD), 6% PG, and 80% PC, the specimen reached the highest compressive strength value at 25.87 MPa. This work provided a new strategy for synergistic utilization of PG and AD, promoting the development of environment-friendly industrial wastes-based cementitious materials effectively.

Thermal activation and mechanical properties of high alumina coal gangue as auxiliary cementitious admixture

In order to use high alumina coal gangue as auxiliary cementitious admixture via a simple and convenient thermal activation technique, the thermal transformation, mineral phase transformation and structure changes of coal gangue at calcining temperatures of 500–1000 °C were analyzed using x-ray diffraction (XRD), differential thermal Analysis (DTA), thermogravimetry (TG), infrared analysis (IR) and scanning electron microscope (SEM). The mechanical properties of cement mortar with 30% coal gangue auxiliary cementitious admixture were also measured to determine the optimal calcining temperature. As calcining temperature was increased, the coal gangue experienced the following transformations: carbon combustion, dehydroxylation, metakaolin transformation and mullite transformation. The cement mortar with coal gangue auxiliary cementitious admixture calcined at 700 °C presented the highest 28-d flexural and compressive strength, increasing by 8.27% and 11.85% respectively as compared with the benchmark cement mortar. The maximum dosage of coal gangue auxiliary cementitious admixture in cement mortar was further identified to be less than 30% by mechanical properties testing. The activity of high alumina coal gangues at different calcining temperatures was explained from the view points of hydration degree and products. The present investigation can provide a useful reference to utilize high alumina coal gangue as auxiliary cementitious admixture by means of a simple thermal activation at 700 °C.

Thermal Activation of High-Alumina Coal Gangue Auxiliary Cementitious Admixture: Thermal Transformation, Calcining Product Formation and Mechanical Properties.

In this paper, a new preparation technology is developed to make high-alumina coal gangue (HACG) auxiliary cementitious admixture by calcining HACG-Ca(OH)2 (CH) mixture. HACG powders mixed with 20 wt.% CH were calcined within a temperature range of 600-900 °C, and the thermal transformation and mineral phase formation were analyzed. The hydration reaction between activated HACG-CH mixture and cement was also investigated. The results showed that HACG experienced a conventional transformation from kaolinite to metakaolin at 600 °C and finally to mullite at 900 °C, whereas CH underwent an unexpected transformation process from CH to CaO, then to CaCO3, and finally to CaO again. These substances' states were associated with the dehydroxylation of CH, the chemical reaction between CaO and CO2 generating from the combustion of carbon in HACG, and the decomposition of CaCO3, respectively. It is the formation of a large amount of CaO above 800 °C that favors the formation of hydratable products containing Al2O3 in the calcining process and C-A-H gel in the hydration process. The mechanical properties of HACG-cement mortar specimens were measured, from which the optimal calcination temperature of 850 °C was determined. As compared with pure cement mortar specimens, the maximum 28-d flexural and compressive strengths of HACG-cement mortar specimens increased by 5.4% and 38.2%, respectively.

Compaction, strength, and volume change characteristics of excavated clayey soil stabilized with composite admixture of cement and autoclaved aerated concrete powder

Low-strength and highly compressible excavated clayey soils are common in geotechnical engineering, which cannot serve as a bearing stratum and typically end up being disposed of in landfills. Autoclaved aerated concrete powder (AACP) is a lightweight and porous waste material, with its stockpiles rapidly accumulating worldwide. To promote sustainable development in geotechnical engineering, a type of composite admixture consisting of cement and AACP was developed to modify clayey soils in this study. The physical and mechanical properties of untreated and the composite admixture-treated soil samples were investigated via Atterberg limits, compaction, bender element, constraint compression, free swell, and unconfined compressive strength (UCS) tests. The physicochemical and microstructural observations, including soil pH, scanning electron microscopy, and mercury intrusion porosimetry analyses, were conducted to interpret the macroscopic mechanical behaviors. Test results showed that the incorporation of AACP improved the workability of clayey soils, while cement further enhanced their mechanical properties. Hydration compounds primarily filled the voids with a diameter ranging from 0.1 to 1 µm. From the perspective of volume change behavior, 8% cement content was recommended. Shear wave velocity showed a strong correlation with the UCS, demonstrating that the bender element technique was an effective non-destructive tool for assessing the strength of compacted samples.

ВЛИЯНИЕ ИЗВЕСТНЯКА В ЦЕМЕНТЕ НА СТРУКТУРУ И МОДУЛЬ УПРУГОСТИ ТЯЖЁЛОГО БЕТОНА

The beginning of the 21st century in Russia was marked by the intensification of activities aimed at adapting Russian construction standards to European ones. In this connection, they cancelled the decision taken in the Soviet Union not to introduce limestone additives into binders in the new GOST 31108 “Cements for general construction. Technical conditions”. Moreover, in 2003 the Russian GOST allowed the production of CEM II/A-I with limestone content from 6 to 20%, and in 2016 – introduced also CEM II/B-I with limestone content from 21 to 35%. However, earlier, the studies of V.V. Timashev’s school proved that the use of limestone additive in the dosage up to 5% positively affects the phase composition of cement stone and makes only a stabilizing effect when it is increased to 10%.The introduction of limestone admixture in cement above 10% starts to significantly affect the phase composition of hydrates, elastic modulus and Poisson's ratio of concrete, therefore it should be used in cement composition above 5% only after additional tests of concrete composition intended for operation in strictly specified conditions.

High-value utilization of modified magnesium slag solid waste and its application as a low-carbon cement admixture

A large amount of magnesium slag solid waste, insufficient comprehensive disposal capacity, high disposal costs, and uncertain environmental stability hinder the low-carbon, green, and sustainable development of magnesium and magnesium alloy smelting. Therefore, this study proposed a high-quality, large-scale, and industrialized disposal method for modified magnesium slag (MMS). Through relevant experimental tests and microscopic characterization methods (physical and chemical performance, hydration heat, resistivity, and microstructure tests), the physical and chemical properties, curing mechanism, and social benefits of MMS low-grade magnesium slag were investigated. The physical and chemical properties, curing mechanism, and social benefits of modified magnesium slag low-carbon Portland cement (MMSPC) produced by MMS as a cement admixture were elucidated. The results showed that (1) the physical and chemical properties of MMSPC met the requirements of the GB 175–2007 “General Portland Cement” standard. (2) A significant difference was observed in the early hydration heat release of fresh MMSPC slurry, confirming a hydration composite effect between MMS and clinker, which was also the key reaction mechanism of MMS replacing clinker to produce MMSPC. (3) The resistivity of MMSPC increased, decreased, and then increased with time, which was mainly controlled by the settling of the aggregate, the dissolution of the binder, and the hydration reaction of the system. However, the variation in resistivity with time and value was influenced by the mixing ratio of the system. (4) MMSPC could also offer certain environmental and economic benefits. Carbon emissions per ton of cement produced were reduced by 7.95%, and the total cost per ton of cement produced was reduced by more than 10%. This study provided a theoretical basis for the high-value disposal of MMS and the reduction of carbon emissions in the cement industry.

Mechanical Properties and Neural Network Prediction of Cement Fly Ash-Enhanced Roadbed Soil in Seasonal Frozen Zones Under Short-Term Curing

The freezing and thawing of roadbed soils in seasonal frozen zones can cause uneven settlement and other road problems, which puts road operation at risk. This paper focuses on the rapid construction of expressways and analyzes the effects of using fly ash and cement as modifiers on the physical properties and chemical composition of subgrade soil. The study found that cement admixtures can improve soil mechanical attributes and frost resistance, while also increasing the degree of fly ash hydration. And the freeze-thaw cycle process can enhance the mechanical characteristics of soils with higher cement admixture content. This is due to the development of hydrates in cement fly ash-enhanced soils during freeze?thaw cycles, resulting in a denser interior structure. The use of neural network prediction analysis showed that using ANN4-10-3 to forecast soil mechanical property parameters can produce superior results. Therefore, it is recommended to use cement fly ash-enhanced soil for roadbed construction in seasonal freezing areas, and neural network can be used to predict soil mechanical parameters.

The Mechanical Properties and Water-Reducing and Retarding Mechanism of a Xylonic Cement Admixture.

This study explores the mechanical properties, as well as the water-reducing and setting delay mechanism, of a novel xylonic acid-based water reducer applied to cementitious materials. Four xylonic acid water reducers were synthesized in this study: XACa (PX) from pure xylose, XACa (HS) from hemicellulose hydrolysate, XANa (PX) from pure xylose, and XANa (HS) from hemicellulose hydrolysate. These were generated through the whole-cell catalysis of Gluconobacter oxydans bacteria, using pure xylose and hemicellulose hydrolysate as substrates. The findings indicate that the xylonic acid-based water reducer can attain a water-reducing capability between 14% and 16% when the dosage (expressed as a mass fraction of cement) is roughly 0.2%. In initial and final setting tests, XACa (PX) demonstrated a pronounced retarding influence at admixture levels below 0.15%, reaching its apex at 0.10%. This delayed the initial setting time by 76% and the final setting time by 136% relative to the control group. However, a slight pro-setting effect was noted beyond a 0.2% dosage. In the compressive and flexural tests of concrete, under the same slump, the XA group improved its mechanical properties by 5% to 10% compared to the SodiuM lignosulfonate (SL) group. In the air content and chloride ion migration resistance tests, the XA group reduced the air content by 38% compared to the SL group, but also increased the data of rapid chloride migration (DRCM) by 16%. Characterization studies revealed that the carboxyl and hydroxyl groups in xylonic acid undergo chemisorption with the Si-O bonds on the surface of cement particles. These groups interact with the Si-O bonds on cement particles, contributing to water-reducing effects and delaying the setting process by impeding Ca2+ ion aggregation in the calcium-silicate-hydrate gel. Its significant water-reducing effect, adjustable setting time, and excellent mechanical and durability properties suggest its viability as an alternative to lignosulfonate series water-reducing agents.

Influence of calcium carbonate sludge on cement-stabilized subgrade quality as investigated by means of electrical resistivity measurements

Calcium carbonate [CaCO3] is a key raw material used in the clarification of sugarcane juice for syrup production. The CaCO3 sludge produced during the clarification process is waste that needs to be stored, creating a geoenvironmental problem. On the other hand, it has been found that cement-stabilized subgrade is a suitable alternative for improving the quality of a subgrade course. This study aimed to investigate the influence of calcium carbonate sludge on the quality of the subgrade. The subgrade was composed of a mixture of 10% to 30% CaCO3 sludge, 1% to 3% of original Portland cement (OPC), and 67% to 100% of unqualified crushed rocks by weight. The modified Proctor method was used to compact soil–cement admixture samples, which were then tested for mechanical properties and electrical resistivity. The Wenner electrode array was used to measure electrical resistivity and compare it to the unconfined compressive strength of 16 different types of soil–cement mixtures after 7 days. The results of experiments show that the basic properties of CaCO3 sludge, when mixed with OPC and packed down, can make the best soil–cement mixture. As a result of this study, electrical resistivity was found to be in good correlation with unconfined compressive strength, thus opening up a time-saving and cost-effective way to check the quality of a soil–cement mixture.

Effects of recycled micro-powders mixing methods on the properties of recycled concrete

Recycled micro-powders were introduced into recycled concrete by adhering them to the surface of recycled aggregate, and a systematic comparison was conducted with recycled concrete prepared with the recycled micro-powder admixture to examine the effects of the mixing modes of recycled micro-powders on the workability and mechanical properties of recycled concrete. In addition, the microhardness test, the hydration products, and the hydrated microstructure were used to investigate its mechanism. The results indicated that recycled micro-powders as a cement admixture decreased the fluidity and compressive strength of recycled concrete. However, the incorporation of recycled micro-powders attached to recycled aggregates improved the fluidity of recycled concrete and obtained a higher compressive strength; in particular, the 28d and 56d compressive strengths increased by 3.66 % and 7.28 %, respectively, compared to those of ordinary recycled concrete. When the incorporation amounts of recycled micro-powders into recycled concrete were identical, the recycled concrete exhibited a denser microstructure and higher microhardness in the interface transition zone when the recycled micro-powders were adhered to the recycled aggregate.

Toward clima-resilient ultra-high performance concrete (UHPC): A survey on high-strength mortars engineered with extra-low dosage graphene-based materials (GBMs)

Latest advances showed that ultra-high performance concrete (UHPC) holds the potential to meet the criteria of future civil infrastructures. Several nanofillers (NFs) proved to enhance the performance of UHPC in terms of economic and environmental sustainability and even assigning novel features. Presently, this promising approach is still in its early stage. In this perspective, mortars based on Portland cement CEM I 52.5 N were engineered with extra-low dosage (0.01% by weight of cement) graphene nanoplatelets (GNPs) or nanographite (nG). An acrylic superplasticizer for high-strength concrete was used as additive. Fresh properties of the cementitious admixtures were characterized by viscosity measurements, flow table and bleeding tests. Prismatic specimens were hardened in water at room temperature for 28 days. Microstructure was observed by Scanning Electron Microscopy, the pore structure and specific surface area (SSA) investigated by Mercury Intrusion Porosimetry (MIP) and nitrogen adsorption-desorption measurements, thermal behavior studied by thermogravimetry, and mechanical strength evaluated by compression and bending tests. Electrical resistivity was determined by Electrochemical Impedance Spectroscopy (EIS). Both 2D-NFs induced a slight lubricant effect that did not significantly affect neither workability nor bleeding. GNPs do not appreciably impact on the mechanical properties of the hardened nano-engineered materials, a decay of bending strength was observed only for nG-loaded samples. The positive impact of the extra-low dosage GNPs on the hardened mortars was clearly detected by MIP and EIS in terms of reduced porosity (−31%), improved bulk density (+5.7%), pore refining (median and average pore diameter −35% and −9%, respectively), increased resistivity (+97%) and lowered predicted intrinsic permeability (−52%). In the same experimental condition, nG-engineered mortars suffered from uneven dispersion that led to increased porosity and pore coarsening.