Motivated by the need to further improve film cooling in terms of both cooling effectiveness and coolant coverage area, the mist/air film cooling scheme is investigated through experiments using fan-shaped holes over an extended downstream length in this study. Both an existing wind tunnel and test facility, used in previous work, have been retrofitted. The first modification was extending the length of the flat plate test section to cover longer distances downstream of the injection holes, up to X/D = 100, in order to investigate whether mist cooling can be harnessed farther downstream where single-phase film cooling is not effective. X represents the axial distance downstream of the cooling hole of diameter D. The second modification was to incorporate fan-shaped (diffusion) holes which are proven to have a higher film cooling efficiency, than cylindrical holes. The objective is to investigate whether mist can further enhance the film cooling performance of the already highly effective fan-shaped holes. A phase Doppler particle analyzer (PDPA) system is employed to measure the droplet size, velocity, and turbulence information. An infrared camera and thermocouples are both used for temperature measurements. Part I is focused on the heat transfer result on the wall. The results show that, at low blowing ratios when the film is attached to the surface, the enhancement of the mist film cooling effectiveness, compared to the air-only case, on the centerline of the hole ranges from 40% in the near hole region to over 170% at X/D = 100. Due to the diffusive nature of the fan-shaped hole, the laterally averaged enhancement is on par with that on the centerline. The significant enhancement over the extended downstream distance from X/D = 40–100 is attributed to the evaporation time needed to evaporate all of the droplets. Each droplet acts as a cooling sink and flies over a distance before it completely vaporizes. This “distributed cooling” characteristic allows the water droplets to extend the cooling effects farther downstream from the injection location. At higher blowing ratios, when the cooling film is lifted off from the surface, the cooling enhancement drops below 40%. Although the enhancement in the near hole region X/D < 40 is about 20% lower than that achieved by using the cylindrical holes, the magnitudes of the mist adiabatic film cooling effectiveness using fan-shaped holes are still much higher than those of the cylindrical holes. Part II of this study is focused on analyzing the two-phase droplet multiphase flow behavior to explain the fundamental physics involved in the mist film cooling.