Additional Processing Research Articles

Investigation on the blooming behavior of additives in nitrile butadiene rubber at elevated temperature

AbstractThe degradation of rubber performance in service environments is closely associated with the blooming behavior of additives in the rubber. This study investigates surface precipitates and changes in tensile properties of nitrile butadiene rubber (NBR) after storage at 85°C in air. The morphology, elemental composition, phase composition, and functional groups of the precipitates were analyzed by scanning electron microscopy, energy dispersion spectroscopy, X‐ray diffraction, and fourier transform infrared spectroscopy. Based on the morphology of internal rubber particles and precipitates and variations in the Zn/C mass ratio (ERZn), the reaction between zinc oxide and stearic acid in rubber under long‐term thermal environment was determined. Four stages of blooming for the mixture of zinc oxide and zinc stearate were inferred, and the impact of the blooming on the degradation of tensile properties of NBR was established. A dramatic decrease in the elongation at break (δk) of NBR was correlated with the blooming of zinc stearate and its correspondingly weakened plasticizing effect.Highlights The core‐shell structured mixture of ZnO and Zn(St)2 bloomed onto the surface of nitrile butadiene rubber. The ratio of mass percentages of Zn to C evaluated the blooming process of additives. The migration and blooming process of precipitates were divided into four stages. The decrease in elongation of the rubber was attributed to the blooming of Zn(St)2.

Cobalt‐Catalyzed Enantioselective Reductive α‐Chloro‐Carbonyl Addition of Ketimine to Construct the β‐Tertiary Amino Acid Analogues

Abstractβ‐Tertiary amino acid derivatives constitute one of the most frequently occurring units in natural products and bioactive molecules. However, the efficient asymmetric synthesis of this motif still remains a significant challenge. Herein, we disclose a cobalt‐catalyzed enantioselective reductive addition reaction of ketimine using α‐chloro carbonyl compound as a radical precursor, providing expedient access to a diverse array of enantioenriched β‐quaternary amino acid analogues. This protocol exhibits outstanding enantioselectivity and broad substrate scope with excellent functional group tolerance. Preliminary mechanism studies rule out the possibility of Reformatsky‐type addition and confirm the involvement of radical species in stereoselective addition process. The synthetic utility has been demonstrated through the rapid assembly of iterative amino acid units and oligopeptide, showcasing its versatile platform for late‐stage modification of drug candidates.

Cobalt-Catalyzed Enantioselective Reductive α-Chloro-Carbonyl Addition of Ketimine to Construct the β-Tertiary Amino Acid Analogues.

β-Tertiary amino acid derivatives constitute one of the most frequently occurring units in natural products and bioactive molecules. However, the efficient asymmetric synthesis of this motif still remains a significant challenge. Herein, we disclose a cobalt-catalyzed enantioselective reductive addition reaction of ketimine using α-chloro carbonyl compound as a radical precursor, providing expedient access to a diverse array of enantioenriched β-quaternary amino acid analogues. This protocol exhibits outstanding enantioselectivity and broad substrate scope with excellent functional group tolerance. Preliminary mechanism studies rule out the possibility of Reformatsky-type addition and confirm the involvement of radical species in stereoselective addition process. The synthetic utility has been demonstrated through the rapid assembly of iterative amino acid units and oligopeptide, showcasing its versatile platform for late-stage modification of drug candidates.

Design of vibration sensors based on fibre Bragg grating type composites for earthquake detection and early warning application

Composite materials can be rapidly moulded using additive manufacturing processes due to their excellent mechanical and physical properties. Combining fibre Bragg gratings with composites results in high-performance fibre grating vibration sensors that address the limitations of electrical sensors and traditional materials. This study focused on developing a fibre optic acceleration sensor that utilizes a parabolic column made of silica gel. The sensor underwent fabrication, packaging, and calibration using a dedicated test system. Parametric calibrations and vibration detection tests were conducted to evaluate the performance of the system. The experimental results indicate that the sensor exhibits an intrinsic frequency of 70 Hz, a flat response range of 5 to 40 Hz, a linearity coefficient greater than 0.99, effective control of transverse interference, and exceptional low-frequency response, which improves the detection of vibration signals. Therefore, the sensor’s low intrinsic frequency and exceptional low-frequency response make it well-suited for detecting vibrations at low to medium frequencies.

That means something to me: How linguistic and emotional experience affect the acquisition, representation, and processing of novel abstract concepts.

We used a novel linguistic training paradigm to investigate the experience-dependent acquisition, representation, and processing of novel emotional and neutral abstract concepts. Participants engaged in mental imagery (n = 32) or lexico-semantic rephrasing (n = 34) of linguistic material during five training sessions and successfully learned the novel abstract concepts. Feature production after training showed that specifically emotion features enriched the emotional concepts' representations. Unexpectedly, for participants engaging in vivid mental imagery during training a higher semantic richness of the acquired emotional concepts slowed down lexical decisions. Rephrasing, in turn, promoted a better learning and processing performance than imagery, probably due to stronger established lexical associations. Our results confirm the importance of emotional and linguistic experience and additional deep lexico-semantic processing for the acquisition, representation, and processing of abstract concepts. (PsycInfo Database Record (c) 2024 APA, all rights reserved).

A corpus-based study of word-formation creativity in Facebook Philippine English

<span lang="EN-US">This paper is a study of English as a second language (ESL) teachers’ and students’ newly coined Facebook (FB) lexical items and expressions. It presents sample FB Philippine English (PhilE) words found in ESL teachers’ and students’ FB posts and messages and the formation mechanisms evident in the lexical items. The lexical items are culled from the researchers-built 50,000-word corpus of FB and FB Messenger conversations posted and sent by the mentioned texts’ contributors from the last quarter of 2016 to 2022. The PhilE neologisms are identified from their surrounding English lexical items and analyzed based on a proposed framework for PhilE word-formation processes, and ESL Englishes well-motivated innovations and criteria in standardizing its usages. Data analysis reveals over a hundred PhilE lexical items that are coined through the analytical frameworks used with the present paper’s additional proposed processes for FB lexical formation, hypocoristic extension, and anagrammatic transposition or backward spelling. The lexical items, in general, are colloquial, marking the informality of the FB PhilE register, although written in English. In terms of lexicon, it is advanced that FB English in the country is a variety of Internet PhilE, which should be taught in Sociolinguistics and ESL classrooms.</span>

Gerber-Shiu theory for discrete risk processes in a regime switching environment

In this paper we develop the Gerber-Shiu theory for the classic and dual discrete risk processes in a Markovian (regime switching) environment. In particular, by expressing the Gerber-Shiu function in terms of potential measures of an upward (downward) skip-free discrete-time and discrete-space Markov Additive Process (MAP), we derive closed form expressions for the Gerber-Shiu function in terms of the so-called (discrete) Wv and Zv scale matrices, which were introduced in [27]. We show that the discrete scale matrices allow for a unified approach for identifying the Gerber-Shiu function as well as the value function of the associated constant dividend barrier problems.

“I Remember Feeling Pretty Darn Lucky”: Crafting Family Resilience in Response to a Medical Emergency

ABSTRACT Through a combination of autoethnographic reflections and oral history interviews with my parents, I explore the ways in which we enacted resilience throughout my father’s unexpected hospitalization, rehabilitation, and his subsequent years of recovery, both individually and communally. Using communication theory of resilience (CTR) as a framework, I identify the ways in which we engaged in the five processes outlined by the theory: crafting normalcy, emphasizing action while backgrounding negative feelings, affirming identity anchors, relying on communication networks, and employing alternative logics. I then propose three additional processes of enacting resilience that emerged from my family’s insights: enacting performative resilience, connecting to broader experience, and emphasizing perspective-taking. To conclude, I reflect on the value of these communicative processes and the combination of research practices I engaged in the paper, as well as the practical benefits of CTR and my additions to the theory.

Photo‐Induced Synthesis of Functionalized γ‐Lactams via Iron‐Catalyzed LMCT Cascade

AbstractA base‐and‐additive‐free photo‐induced radical‐mediated cascade cyclization reaction of 1,6‐enyne compounds was presented. In this study, C(sp3)−H hydrocarbons, including various alkanes and ethers, were activated via Fe‐catalyzed photo‐induced conditions, providing a bunch of γ‐lactam products via hydrogen atom transfer and radical addition processes. Control experiments indicated that the reaction proceeded through photo‐induced ligand‐to‐metal charge transfer (LMCT) process. Gram scale experiment was also completed by using continuous‐flow‐photocatalytic‐device.

Microstructure evolution and mechanical properties of new Co-free maraging steel produced by wire arc additive manufacturing

In this work, P-MIG is used as additive process, a new low-cost Co-free maraging steel wire is used as raw material to additive manufacturing block component, and the microstructure and mechanical properties of the component is investigated. The microstructure of the component is composed of martensite and austenite, and the closer to the bottom, the more serious the elemental segregation and the more austenite content. From the top to the bottom the high-angle grain boundaries increase and the grain size decrease, the difference of the heat dissipation condition and the thermal cycle are the reasons for this phenomenon. The texture of austenite is mainly Cube texture, and the texture of martensite is Rotated Cube texture and Goss texture. The tensile strength of XD, YD, ZD three directions is 1172 ± 15 MPa, 1021 ± 7 MPa, 1139 ± 16 MPa, respectively, impact toughness is 64.7 ± 1.6 J/cm2, 51.1 ± 5.6 J/cm2, 51.4 ± 3.1 J/cm2, respectively, TRIP effect occurs in the process of tensile, the main mode of fracture in tensile and impact is toughness fracture. The microhardness decreases gradually from bottom to top, which is due to the short-lived aging strengthening by thermal cycle, the change of grain size and GND density. The results of the work reveal the successful application of the new low-cost Co-free maraging steel wire in WAAM and provide an important reference for the adjustment of additive process, subsequent heat treatment and the adjustment of wire composition.

Enhancement of vertical phase separation in sequentially deposited organic photovoltaics through the independent processing of additives

Herein, the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at the electron donor-acceptor interface are investigated. The film morphology exhibits notable variations, significantly depending on the layer to which 1,8-diiodooctane (DIO) was applied. Grazing incidence wide-angle X-ray scattering analysis reveals distinctly separated donor/acceptor phases and vertical crystallinity details in SD films. Time-of-flight secondary ion mass spectrometry analysis is employed to obtain component distributions in diverse vertical phase structures of SD films depending on additive control. In addition, nanosecond transient absorption spectroscopy shows that DIO control significantly affects the dynamics of separated charges in SD films. In SD OPVs, DIO appears to act through distinct mechanisms with minimal restriction, depending on the applied layer. This study emphasizes the significance of morphological optimization in improving device performance and underscores the importance of independent additive control in the advancement of OPV technology.

Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal-Organic Frameworks.

Electrically conductive metal-organic frameworks (MOFs) are promising candidates for electrochemical capacitors (EC) for fast energy storage due to their high specific surface areas and potential for redox activity. To maximize energy density, traditional inorganic pseudocapacitors have utilized faradaic processes in addition to double-layer capacitance. Although conductive MOFs are usually comprised of redox active ligands which allow faradaic reactions upon electrochemical polarization, systematic studies providing deeper understanding of the charge storage processes and structure-function relationships have been scarce. Here, we investigate the charge storage mechanisms of a series of triazatruxene-based 2D layered conductive MOFs with variable alkyl functional groups, Ni3(HIR3-TAT)2 (TAT=triazatruxene; R=H, Et, n-Bu, n-Pent). Functionalization of the triazatruxene core allows for systematic variation of structural parameters while maintaining in-plane conjugation between ligands and metals. Specifically, R groups modulate interlayer spacing, which in turn shifts the charge storage mechanism from double-layer capacitance towards pseudocapacitance, leading to an increase in molar specific capacitance from Ni3(HIH3-TAT)2 to Ni3(HIBu3-TAT)2. Partial exfoliation of Ni3(HIBu3-TAT)2 renders redox active ligand moieties more accessible, and thus increases the dominance of faradaic processes. Our strategy of controlling charge storage mechanism through tuning the accessibility of redox-active sites may motivate further design and engineering of electrode materials for EC.

Abstract 3800: Next generation of spatial biology: High-throughput multiplexed Imaging Mass Cytometry™ with whole slide modes

Abstract Gaining spatial insights into the cellular composition of tumor tissue has tremendous potential to inform clinical and translational researchers about mechanisms behind spatial predictors of immunotherapy success, disease etiology and progression. Imaging Mass Cytometry™ (IMC™) is a high-plex spatial biology imaging technique that enables deep characterization of the diversity and complexity of the tumor microenvironment (TME). IMC supports detailed assessment of cell phenotype and function using 40-plus metal-tagged antibodies simultaneously on a single slide without issues associated with fluorescence-based spectral overlap, tissue autofluorescence or implementation of multiple washing and acquisition cycles. Currently, IMC enables user-defined regions of interest (ROI) in tissues to evaluate cellular and structural composition. To enhance the IMC user experience, we developed two new whole slide imaging (WSI) modes which enable streamlined workflows using ultrafast preview mode (PM) and high-throughput tissue mode (TM). PM samples the entire tissue at predefined spacing to rapidly capture a low-resolution image of all expressed markers in the antibody panel. PM generates an image in minutes to enable informed ROI placements while leaving the stained tissue intact for higher-resolution imaging. PM and TM are designed so acquisitions can easily occur on the same slide without additional processing steps. TM rapidly acquires images of the whole tissue at lower resolution (7 μm pixel size) at a quality that can be used for quantitative analysis of the tissue spatial biology. Specifically designed for high-throughput applications, TM in combination with a newly available 40-slide loader for the Hyperion XTi™ Imaging System permits automated and continuous imaging of more than 40 large tissue samples (400 mm2 per tissue) per week. We showcase the application of WSI modes using the newly developed Maxpar® Human Immuno-Oncology IMC Panel Kit. The 31-marker panel was combined with catalog antibodies to create a 40-plus-marker panel that expands the ability to conduct comprehensive high-plex tumor and immune cell profiling. Tumor tissue microarrays (TMA) and whole tumor tissue sections were stained with the expanded panel. Single-cell analysis of selected ROIs, on whole tumor sections and TMAs, guided by PM data successfully provided quantitative analyses of spatial biology at single-cell resolution. In parallel, TM on whole tumor sections followed by pixel-based analysis provided a spatially resolved quantitative assessment of specific tumor and immune components of the TME. This work demonstrates the expanded capabilities of IMC and establishes it as a reliable high-plex spatial biology imaging platform with high-throughput imaging capabilities ideally suited for translational and clinical applications. For Research Use Only. Not for use in diagnostic procedures. Citation Format: Qanber Raza, Thomas D. Pfister, Jyh Yun Chwee, Liang Lim, David Howell, Nikesh Parsotam, David King, Christina Loh. Next generation of spatial biology: High-throughput multiplexed Imaging Mass Cytometry™ with whole slide modes [abstract]. In: Proceedings of the American Association for Cancer Research Annual Meeting 2024; Part 1 (Regular Abstracts); 2024 Apr 5-10; San Diego, CA. Philadelphia (PA): AACR; Cancer Res 2024;84(6_Suppl):Abstract nr 3800.

Comparative evaluation of drying methods for struvite produced from electrocoagulated source-separated urine: Implications for quality, energy and cost-effectiveness

Struvite precipitation from source-separated urine is crucial for waste utilization and sustainability. However, after precipitation, the high moisture content of struvite necessitates an additional drying process that can be costly and inefficient. In the present study, the performance of different drying methods—open sun drying, air drying, conventional drying (20–100 °C), and microwave drying (180–720 W) on the quality of struvite obtained from source-separated urine through electrocoagulation using Mg–Mg electrodes were evaluated. It was found that higher temperatures and power in the convective oven and microwave resulted in higher diffusivity (10−9-10−7 m2s−1), leading to reduced drying times. Different models were employed to comprehend the drying mechanism, and the one with the highest correlation coefficient (R2 = 0.99) and the lowest statistical values was selected. The key findings indicated that higher power and temperature levels were more cost-effective. However, characterization of the dried struvite using X-ray diffraction and Fourier-transformed infrared spectroscopy, disintegration of struvite crystals at temperatures above 60 °C in the conventional oven and 180 W in the microwave oven was observed. Based on the results, we conclude that sun drying is a cost-effective and environmentally friendly alternative for drying struvite without compromising its quality.

Exploration and Practice of Nitrogen Addition Process for LF Refining Ladle Bottom Blowing Nitrogen Steel Liquid

Exploration and Practice of Nitrogen Addition Process for LF Refining Ladle Bottom Blowing Nitrogen Steel Liquid

Microstructure, hardness, and tribological performance of D2 tool steel fabricated by laser cladding using pulsed wave and substrate heating

D2 steel is a tool grade steel that presents hot cracking problems during the solidification process due to its alloying elements. On the other hand, additive manufacturing processes have great potential to manufacture, repair, and functionalize metal parts due to their low heat input, minimal distortion, and excellent metallurgical bonding. In this work, D2 metallic powder was deposited by the laser cladding process using pulsed wave, without and with preheating of the substrate. Through ANOVA statistical analysis using a complete factorial design 24, the optimal regions were determined to obtain D2 deposits with minimum dilution and depth, and maximum widths, heights and high hardness. Once the optimal parameters of the process were established, the coatings were deposited without and with preheating the substrate where, regardless of the condition, coatings without defects and good metallurgical adhesion were obtained. Coatings with preheating obtained higher cooling rates, where lower laser powers promoted higher rates; while in the coatings without preheating, lower duty functions promoted higher rates. The austenite, martensite and M7C3 eutectic carbides phases were obtained, with austenite being the main phase due to the C content in solid solution due to the cooling rates achieved. The coatings in as-built condition, reached hardness values between 606 and 711 HV (55–60 HRC), where the preheated coatings obtained the highest values. On the contrary, the coatings without preheating showed a better wear resistance (7.672 x10-6 mm3/Nm) due to the formation of tribo-layers due to the formation of oxides due to the higher amount of austenite.

The influence of deformation affected region on microstructure and mechanical property of 316L fabricated by hybrid additive-subtractive manufacturing

The hybrid of additive manufacturing and subtractive manufacturing is promising in producing high-quality and high-accuracy parts made of hard-to-machine metallic materials with complex geometries. However, few studies have been conducted to analyze the influence of responses from subtractive manufacturing, especially the plastic deformation region induced by mechanical cutting, on the following additive manufacturing processes. This paper comprehensively investigates the impact of finishing milling on the mechanical properties and quality of 316L fabricated by hybrid additive-subtractive manufacturing. The whole manufacturing process consisted of a two-stage micro selective laser melting μSLM process with three scanning speeds and one finishing milling process. Typical machining responses including phase, cutting force, surface roughness at different manufacturing stages were analyzed; the mechanisms of how the deformation-affected region induced in subtractive manufacturing process affects the microstructure, hardness, and mechanical properties after the second-stage additive manufacturing were explored. Fine grains were formed after the second-stage μSLM in the connected region, because of the lower G/R ratio and the higher G × R value, whereas the hardness in this region was lower than the bulk material consisting of coarse grains, caused by the thermal softening effect induced in mechanical cutting. The elongation rate was increased due to the existence of the grain-boundary-rich connected region.

ADVANCES IN ULTRAPRECISION DIAMOND TURNING: TECHNIQUES, APPLICATIONS, AND FUTURE TRENDS

Advances in ultraprecision diamond turning have revolutionized manufacturing processes across various industries, offering unparalleled precision and surface quality in the fabrication of optical components, microfluidic devices, and advanced mechanical parts. This review delves into the techniques, applications, and future trends in ultraprecision diamond turning, highlighting recent advancements and potential trajectories. Techniques in ultraprecision diamond turning have evolved significantly, driven by innovations in machine design, tooling materials, and control systems. Diamond turning machines equipped with ultra-stiff structures, high-speed spindles, and advanced feedback mechanisms enable sub-nanometer level accuracy and surface finishes down to Angstrom levels. Additionally, advancements in single-point diamond turning (SPDT), fast tool servo (FTS), and deterministic microgrinding (DMG) techniques further enhance the versatility and precision of the process. Applications of ultraprecision diamond turning span a wide range of industries, including aerospace, automotive, biomedical, and telecommunications. In optics manufacturing, diamond turning facilitates the production of aspheric lenses, freeform optics, and diffractive optical elements with unprecedented accuracy, contributing to the development of high-performance imaging systems and laser applications. Moreover, in the biomedical field, diamond-turned microfluidic devices enable precise control over fluid flow and particle manipulation, empowering advancements in drug delivery systems and lab-on-a-chip technologies. Future trends in ultraprecision diamond turning are poised to address challenges related to scalability, multi-material processing, and in-situ metrology. Integration of adaptive control algorithms and machine learning techniques promises enhanced process stability and predictive maintenance, optimizing productivity and reducing downtime. Furthermore, the development of hybrid manufacturing approaches, combining diamond turning with additive manufacturing or laser processing, offers novel avenues for fabricating complex, multi-functional components with improved efficiency and cost-effectiveness. The ongoing advancements in ultraprecision diamond turning techniques, coupled with diverse applications across industries, underscore its pivotal role in advancing manufacturing capabilities. Anticipated future trends hold promise for further expanding the scope and impact of this technology, driving innovation and pushing the boundaries of precision engineering.
 Keywords: Ultraprecision, Diamond, Turning, Technique, Review.

A CALPHAD-Informed Enthalpy Method for Multicomponent Alloy Systems with Phase Transitions

Solid–liquid phase transitions of metals and alloys play an important role in many technical processes. Therefore, corresponding numerical process simulations need adequate models. The enthalpy method is the current state-of-the-art approach for this task. However, this method has some limitations regarding multicomponent alloys as it does not consider the enthalpy of mixing, for example. In this work, we present a novel CALPHAD-informed version of the enthalpy method that removes these drawbacks. In addition, special attention is given to the handling of polymorphic as well as solid–liquid phase transitions. Efficient and robust algorithms for the conversion between enthalpy and temperature were developed. We demonstrate the capabilities of the presented method using two different implementations: a lattice Boltzmann and a finite difference solver. We proof the correct behaviour of the developed method by different validation scenarios. Finally, the model is applied to electron beam powder bed fusion—a modern additive manufacturing process for metals and alloys that allows for different powder mixtures to be alloyed in situ to produce complex engineering parts. We reveal that the enthalpy of mixing has a significant effect on the temperature and lifetime of the melt pool and thus on the part properties.

Simulation Study on Temperature and Stress Fields in Mg-Gd-Y-Zn-Zr Alloy during CMT Additive Manufacturing Process.

A new heat source combination, consisting of a uniform body heat source and a tilted double ellipsoidal heat source, has been developed for cold metal transfer (CMT) wire-arc additive manufacturing of Mg-Gd-Y-Zn-Zr alloy. Simulations were conducted to analyze the temperature field and stress distribution during the process. The optimal combination of feeding speed and welding speed was found to be 8 m/min and 8 mm/s, respectively, resulting in the lowest thermal accumulation and residual stress. Z-axis residual stress was identified as the main component of residual stress. Electron Backscatter Diffraction (EBSD) testing showed weak texture strength, and Kernel Average Misorientation (KAM) analysis revealed that the 1st layer had the highest residual stress, while the 11th layer had higher residual stress than the 6th layer. Microhardness in the 1st, 11th, and 6th layers varies due to residual stress impacts on dislocation density. Higher residual stress increases dislocation density, raising microhardness in components. The experimental results were highly consistent with the simulated results.