Additional Heat Research Articles

Regulating the Scaling Relations in Ammonia Synthesis through a Light-driven Bendable Seesaw Effect on Tailored Iron Catalyst.

Advancing the energy-intensive Haber-Bosch process faces significant challenges due to the intrinsic constraints of scaling relations in heterogeneous catalysis. Herein, we reported an approach of bending the "seesaw effect" to regulate the scaling relations over a tailored α-Fe metallic material (α-Fe-110s), realizing highly efficient light-driven thermal catalytic ammonia synthesis rate of 1260 μmol gcatalyst-1 h-1 without additional heating. Specifically, the thermal catalytic activity of α-Fe-110s was significantly enhanced by the novel stepped {110} surface, exhibiting a 3.8-fold increase compared to the commercial fused-iron catalyst with promoters at 350 °C. The photo-induced hot electron transfer further accelerates the dinitrogen dissociation and hydrogenation simultaneously, effectively overcoming the limitation of scaling relation over identical sites. Consequently, the ammonia production rate of α-Fe-110s was further enhanced by 30 times at the same temperature with irradiation. This work designs an efficient and sustainable system for ammonia synthesis and provides a novelapproach for regulating the scaling relations in heterogeneous catalysis.

Regulating the Scaling Relations in Ammonia Synthesis through a Light‐driven Bendable Seesaw Effect on Tailored Iron Catalyst

Advancing the energy‐intensive Haber‐Bosch process faces significant challenges due to the intrinsic constraints of scaling relations in heterogeneous catalysis. Herein, we reported an approach of bending the “seesaw effect” to regulate the scaling relations over a tailored α‐Fe metallic material (α‐Fe‐110s), realizing highly efficient light‐driven thermal catalytic ammonia synthesis rate of 1260 μmol gcatalyst−1 h−1 without additional heating. Specifically, the thermal catalytic activity of α‐Fe‐110s was significantly enhanced by the novel stepped {110} surface, exhibiting a 3.8‐fold increase compared to the commercial fused‐iron catalyst with promoters at 350 °C. The photo‐induced hot electron transfer further accelerates the dinitrogen dissociation and hydrogenation simultaneously, effectively overcoming the limitation of scaling relation over identical sites. Consequently, the ammonia production rate of α‐Fe‐110s was further enhanced by 30 times at the same temperature with irradiation. This work designs an efficient and sustainable system for ammonia synthesis and provides a novel approach for regulating the scaling relations in heterogeneous catalysis.

Mechanistic insights into combined effects of continuous microwave heating and tremella powder addition on physiochemical properties of Nemipterus virgatus surimi gel

The physicochemical properties of Nemipterus virgatus surimi gel were investigated, with tremella powder (TP) at concentrations ranging from 0 to 0.5% (w/w) combined with continuous microwave heating (CMH) using water-bath heating (WBH) as control. Results showed that TP addition (0.1%–0.3%, w/w) could significantly enhance the water holding capacity and reduce whiteness and cooking loss, attributed to the changed lateral relaxation time of water distribution. Notably, at 0.3% TP and 80 °C, the gel strength significantly increased by 96.84%, and the hardness, chewiness, and adhesiveness improved, but the quality of surimi decreased above 0.3% TP. The gel network structure was influenced by protein secondary structure composition, especially for increasing β-sheet in Raman spectra, thus promoting the gel microstructure density and uniform protein distribution. These findings offer insights for enhancing surimi gel quality and broadening tremella application in product processing.

Micro-encapsulated phase change material suspensions for heat and mass transfer: A thermo-physical characterization

Despite the growing popularity of phase change materials (PCM) and suspensions of micro-encapsulated phase change materials (mPCM) in both industrial and scientific applications, their properties characterization remains partial and mainly limited to thermal properties. The characterization of such suspension is a crucial aspect for comprehending their behavior and optimizing their performance. This paper is dedicated to a wide characterization of two suspensions containing micro-encapsulated phase change material. In pursuit of a thorough understanding, we also extend our characterization efforts to the bulk PCM encapsulated within the particles.Our primary focus is on determining the materials thermal properties such as latent heat and specific heat capacity using differential scanning calorimetry. Different cooling and heating rates have been employed in our measurements. Regarding our experiments, the bulk phase change material is predominantly identified as octadecane. Results obtained from calorimetry are then compared between the bulk PCM and the mPCM suspensions. By comparing the magnitudes of latent heat obtained for suspensions with the bulk material, we can accurately determine the mass fraction of PCM within each suspension. Noteworthy, during the solidification process an additional latent heat peak is observed only for the encapsulated PCM.The density of the materials is also measured. The phase change of PCM included in the capsules can be observed in densimetry: within the studied temperature range (283.15–306.15 K), the most significant density variations occur during intervals associated with phase change transitions. In ranges where the PCM, included in the capsules, is in a single-phase state (solid/liquid), we provide linear laws that account for density variations with temperature.Finally, our characterization work focuses on the rheological properties of the materials. While the bulk PCM in liquid phase exhibits a Newtonian viscosity, mPCM suspensions present a non-Newtonian viscosity. Both shear-thinning and shear-thickening behaviors are observed depending on the suspension particle volume fraction ϕ of mPCM. This paper concludes with a full comparison of our characterization results with models and correlations proposed in the literature.

Adapting Conductivity and Mechanical Properties through Layer Thickness Variation in Copper Niobium Laminated Metallic Composites

Cu/Nb laminated metallic composites (LMCs) exhibit extraordinary mechanical strength while electrical conductivity is maintained at a high level. In this research, Cu‐based LMCs with varying volume fraction of niobium are produced via accumulative roll bonding (ARB) and additionally cold‐rolled and heat‐treated to identify the role of these heterogeneous phase boundaries on the overall sheet properties. Deformation structures in these layered materials are studied through scanning transmission electron microscopy investigations. The existence of an interface‐affected zone at the phase boundaries and mechanical intermixing is attributed to decreasing electrical and increasing mechanical properties, especially in very thin layered LMCs. Atom probe tomography measurements show that mechanical alloying occurs due to severe plastic deformation during ARB processing of the laminates. An additional subsequent heat treatment leads to chemical demixing at the interfaces of the phase boundaries.

Thermal performance and life cycle analysis of 3D printed concrete wall building

Automated construction process with extrusion-based 3D concrete printing (3DCP) is widely recognised due to its ability to construct complex freeform geometrical shapes. Furthermore, the automation process reduces labour and minimises material wastage, thus improving productivity. The structural performance of printed structures has been widely discussed; however, addressing the knowledge gap in energy performance and their environmental impact needs further investigation. Thus, this study investigated and compared the insulation characteristics, life cycle cost and environmental impact assessment of 3DCP structures with traditional reinforced concrete members. The evaluation of the insulation properties of 3D printable concrete allows the characterisation of operational costs and greenhouse gas emissions incurred from the additional heating and cooling systems. Furthermore, this study also suggested a method to enhance the thermal resistance of 3DCP with recycled fibre recovered from face mask waste. A comparison between face mask fibre-reinforced 3D-printed wall element and conventional reinforced concrete wall is also performed across the thermal, life cycle cost and environmental impact parameters. The results showed that the insulation properties of 3DCP walls were increased by 49.5% with the addition of face mask fibres compared to RC walls. This results in reduced energy consumption from additional heating and cooling systems along with a reduction in greenhouse gas emissions, thereby improving the energy performance of the building. Further, face mask fibre-reinforced printed walls showed a reduction in the life cycle cost, mainly in the operation stage, due to the low labour requirement and elimination of formwork. Moreover, a significant reduction in the depletion of resources and ozone depletion was observed for 3DCP face mask fibre-reinforced walls, along with the reduced impact on human health and ecosystem damage. Consequently, the incorporation of face mask fibres into the 3DCP process paves the way for its potential in constructing energy-efficient and environmentally sustainable buildings.

Impact of woody biomass in the composition of coal-water suspensions on their transportation and combustion

Relevance. A promising fuel from an environmental point of view is coal-water suspensions. Multiple studies have shown that when they are burned, emissions of anthropogenic gases into the Earth's atmosphere are significantly reduced compared to emissions from coal burning. But the large-scale introduction of coal-water suspensions into the overall balance of energy production is difficult due to a significant delay in their ignition, which can reach several tens of seconds at relatively low oxidizer temperatures (Tg≤1073 K). One of the possible ways to solve this problem is the use of new technologies for preparation for combustion, for example, the use of additional microwave heating of fuel and the introduction of special additives into the composition of coal-water suspensions, which accelerate their ignition. The introduction of such additives into the fuel composition can lead to a significant change in the rheological characteristics. Aim. To determine the degree of impact of the concentration and type of wood additive in the composition of the coal-water suspension on the rheological characteristics of droplets of coal-water fuel, as well as the possibility of reducing the duration of thermal preparation of the latter when exposed to microwave heating. Object. Water-coal suspension based on long-flame thermal coal and on long-flame thermal coal with the addition of sawdust and pine needles (Bio-water-coal suspension). Methods. Experimental studies to determine the time characteristics of water-coal suspension ignition were carried out using a high-speed video camera FASTCAM. Fuel combustion was carried out in a flow-through combustion chamber equipped with magnetrons for additional microwave heating of the fuel. Dynamic viscosity was determined using a Brookfield RVDV-II + Pro viscometer. Results. It has been established that the addition of microwave heating can significantly (up to 15%) reduce the ignition delay of water-coal suspension and Bio-water-coal suspension at relatively low oxidizer temperatures (673 K). Experimental studies shown that the type of biomass affects the time characteristics of fuel ignition at ambient temperatures up to 753 K; with a further increase in the temperature of the oxidizer, the type of additive does not have a significant effect. It is shown that when studying the rheological characteristics of the water-coal suspension, the dynamic viscosity of Bio-water-coal suspension does not go beyond the characteristic value of 1200 Pa s at a shear rate of 100 rpm when no more than 2% of pine sawdust and no more than 6% of pine needles are introduced into the water-coal suspension.

Integrated Power and Thermal Management System for a Hybrid-Electric Aircraft: Integrated Modelling and Passive Cooling Analysis

Abstract Aircraft electrification introduces challenges in power and thermal management. In a hybrid-electric aircraft (HEA), the additional heat loads generated by the high-power electrical components in the propulsion system can negate the benefits of the HEA. Consequently, an integrated energy management system is required for the HEA to reject the additional heat loads while minimizing energy consumption. This paper presents the integrated modelling method for an integrated power and thermal management system (IPTMS) for HEA. With this method, a platform can be developed to assess the varying efficiencies of the components in the electrical propulsion system (EPS), and the performance of the thermal management system (TMS), such as passive cooling, during a flight mission. This makes it applicable to modular designs and optimizations of the IPTMS. A small/medium range (SMR) aircraft similar to ATR72 is studied. In this study, the EPS operates only during take-off and climb. Therefore, the platform assesses the heat and power loads of the IPTMS for a typical flight mission (take-off and climb) in this study. The performance of passive cooling is also analysed across this typical flight mission and under normal, hot-day, and cold-day conditions. It was found that passive cooling is sufficient under these three conditions, and the active temperature control is requried to ensure the components' temperatures are above the minimum temperatures. These findings imply the potential to minimize TMS weight and energy consumption, providing an insight for further research on IPTMS.

An Economic Performance Improving and Analysis for Offshore Wind Farm-Based Islanded Green Hydrogen System

When offshore wind farms are connected to a hydrogen plant with dedicated transmission lines, for example, high-voltage direct current, the fluctuation of wind speed will influence the efficiency of the alkaline electrolyzer and deteriorate the techno-economic performance. To overcome this issue, firstly, an additional heating process is adopted to achieve insulation for the alkaline solution when power generated by wind farms is below the alkaline electrolyzer minimum power threshold, while the alkaline electrolyzer overload feature is used to generate hydrogen when wind power is at its peak. Then, a simplified piecewise model-based alkaline electrolyzer techno-economic analysis model is proposed. The improved economic performance of the islanded green hydrogen system with the proposed operation strategy is verified based on the wind speed data set simulation generated by the Weibull distribution. Lastly, the sensitivity of the total return on investment to wind speed parameters was investigated, and an islanded green hydrogen system capacity allocation based on the proposed analysis model was conducted. The simulation result shows the total energy utilization increased from 62.0768% to 72.5419%, and the return on investment increased from 5.1303%/month to 5.9581%/month when the proposed control strategy is adopted.

A Comparative Analysis of a Microstructure and Properties for Monel K500 Hot-Rolled to a Round Bar and Wire Deposited on a Round Surface

Metal manufacturing processes based on deformation (forging, rolling) result in a fine grain structure with a complex dislocation substructure, which positively influence mechanical properties. Casting and additive manufacturing (powder- or wire-based) usually produce a coarse grain structure with a poorly developed dislocation substructure, which negatively affect mechanical properties. Heat treatment may alter phase balance and stimulate precipitation strengthening; however, precipitation kinetics depends on the dislocation substructure. In this paper, a comparative study of the microstructure and strength is presented for Monel K500 alloy containing 63 Ni, 30 Cu, 2.0 Mn, and 2.0 Fe (wt.%), and microalloyed with Al, Ti, and C hot-rolled to a round bar and deposited on a round surface using wire additive manufacturing (WAAM) technology. An increased dislocation density and number density of fine precipitates resulted in 8–25% higher hardness and 1.8–2.6 times higher compression yield stress in the hot-rolled alloy compared to these in the WAAM-produced alloy. However, due to a high work hardening rate, only 3–10% cold deformation was necessary to increase the strength of the WAAM alloy to this of the hot-rolled one. Age hardening heat treatment, through the intensification of the precipitation strengthening mechanism, reduced the value of cold deformation strain required to equalise the properties. Based on the obtained results, a new technology consisting of additive manufacturing, heat treatment, and cold deformation can be proposed. It can produce WAAM components with strength and hardness improved to the level of hot-rolled components, which is a significant development of additive manufacturing.

In-situ alloying of maraging steel with enhanced mechanical properties and corrosion resistance by laser directed energy deposition

Maraging steels are known for their exceptional strength derived from the martensite matrix and nano-precipitate strengthening. However, the trade-off to the high strength is often a loss of ductility and minimal strain hardening. Introducing metastable austenite to the matrix to activate transformation-induced plasticity (TRIP) is an effective approach to achieve high strength and ductility synergy. Existing methods to introduce TRIP into additively manufactured maraging steels are limited by the compositions of pre-alloyed powder or additional heat treatment steps. In-situ alloying via the laser directed energy deposition (L-DED) process allows flexibility in tailoring the alloying composition to achieve an austenite–martensite microstructure. Herein, we develop a TRIP–maraging steel by in-situ alloying of M789 with 316L (4–8 wt%) during the L-DED process. The addition of 316L facilitates austenite reversion in solution-treated maraging steel. As a result, the TRIP–maraging steel exhibits a 76 % increase in uniform elongation at the expense of a minimal sacrifice of strength. Furthermore, the corrosion resistance of the TRIP–maraging steel is enhanced. This work showcases a pathway to developing superior alloys by in-situ alloying via additive manufacturing.

On fire risk reduction when operating individual households

The article aims to elaborate a technical means for reducing fire occurrence in internal electrical networks of individual households. General scientific methods of numerical analysis, electric circuit theory, and prediction theory were used. It was determined that the operating mode of the electric network under study is characterized by a significant unbalanced power consumption due to the asymmetry and non-sinusoidality of phase currents caused by the occurrence of additional symmetrical components of forward, reverse, and zero sequences. Additional heat losses increase significantly and lead to overheating of the neutral conductor, thus intensifying fire risks. On the basis of measurements and the authors’ software, a simulation modeling of integration of the developed balancing device into the investigated network was carried out. The conducted analysis found that the developed device can reduce additional heat losses and fire risks by over 90%. Using statistical methods of forecasting, regression analysis in particular, a preventive long-term assessment of the level of additional power losses was conducted. Autoregressive equations for predicting the parameter of additional power losses at a certain probability level were derived. MATLAB graphic editor technologies and Excel software were used to visualize changes in the studied indicators. The results can be used by construction companies when designing the internal electrical network of individual households, as well as for researchers developing approaches to reducing additional losses of electrical energy.

Thermal effect of VIPV modules in refrigerated trucks

The integration of Photovoltaic (PV) modules within the outer structure of commercial transporters offers a great potential as an additional source of energy that can be utilized, for example, directly by the drive train of the vehicle, or by accessory equipment. However, to understand the benefits of such a system, the effect and relevance of some thermodynamic variables introduced by the Vehicle Integrated Photovoltaic (VIPV) system must be assessed. Particularly, the share of the solar irradiance that cannot be converted into electricity by the solar cell and is instead transformed into heat must be considered for certain applications such as the transportation of goods that require a controlled temperature. A one-dimensional thermal simulation model based on a Resistance-Capacitance methodology was created and validated experimentally. The model was used to predict the thermal behavior of the box-body of a truck for a representative year in three cities in Europe (Stockholm, Freiburg, and Seville), with a known Bill of Materials (BOM), and a set of given assumptions and constraints. It was found that, under the simulated conditions laid in this study, the additional heat generated by the PV modules that manages to go through the insulation material and reach the refrigerated cargo area, may raise the temperature of the contained air by an average of 0.36 °C, 0.5 °C, and 0.67 °C, respectively for the observed cities, and as much as 3.12 °C, 2.98 °C and 2.61 °C. When forced convection caused by the movement of the truck was applied into the model (with a constant wind speed of 50 km/h), the temperature of the solar cell dropped significantly, which, for the case of Freiburg, meant an increase in the contained air temperature of a maximum of 0.6 °C. A refrigeration system was subsequently considered for a target air temperature of 2 °C and −18 °C, and it was found that for the simulated scenarios, the harvested solar energy could easily offset the additional energetic demand caused by the PV system, and, in most cases, completely balance out the total annual demand of the chiller.

Performance analysis and configuration method optimization of AA-CAES-based air storage tanks

To improve the performance of the compressed air energy storage (CAES) system, flow and heat transfer in different air storage tank (AST) configurations are investigated using numerical simulations after the numerical model has been experimentally validated. System performance for different AST placement methods is analyzed through numerical simulations integrated with the thermodynamic model of advanced adiabatic compressed air energy storage (AA-CAES). An in-depth study examines the impact of key system parameters on system performance with different AST configurations. Based on these analyses, the AA-CAES system with a constant volume of AST is optimized. The results indicate that horizontal placement of the AST improves heat transfer capability within the same working pressure range but results in slightly lower energy storage efficiency, achieving 64.61% compared to 65.50% for vertical placement. However, horizontal placement offers higher energy storage density, achieving 3.54 kW h/m3 under specific conditions, compared to 3.14 kW h/m3 for vertical placement. As the energy storage flow rate increases, exceeding the critical flow rate significantly improves heat transfer in vertically placed ASTs, thus narrowing the energy storage density gap between configurations. Increased turbine efficiency, additional external heat sources, and further utilization of compression heat provide more significant performance improvements for the AA-CAES with the AST placed horizontally compared to vertically. Compared to the AA-CAES with vertically placed ASTs, the configuration of the ASTs is optimized to enhance the electrical output of the AA-CAES by 76.4 MW h and reduce the input by 78.9 MW h at a storage flow rate of 0.5 kg/s.

Dual-phase polycrystalline crystal plasticity model revealing the relationship between microstructural characteristics and mechanical properties in additively manufactured maraging steel

To elucidate the relationship between microstructural characteristics and mechanical properties in additively manufactured (AM) maraging steel, this study introduces a computational approach that addresses two fundamental challenges. Firstly, it addresses the creation of representative volume elements (RVEs) that mimic the observed microstructural complexities, such as meltpool boundaries, prior austenite grains, packets and blocks of lath martensite. This is accomplished through the application of Potts Monte-Carlo methods and grain segmentation techniques in accordance with the Kurdjumov-Sachs orientation relationship. Secondly, this study develops a comprehensive crystal plasticity (CP) model encompassing both bcc and fcc plasticity. Inspired by atomistic and discrete dislocation dynamics studies, the proposed CP model incorporates characteristics intrinsic to bcc plasticity, including non-Schmid effects, dislocation and precipitate strengthening, and Hall-Petch type strengthening of elongated martensitic blocks. Utilizing the created RVEs and the proposed CP framework, finite element simulations are conducted based on an update-Lagrangian formulation. The purpose of this study is to investigate the deformation behavior, texture evolution, tension-compression asymmetry, and evolution in dislocation density in RVEs representative of as-built and heat-treated samples of maraging steel. This computational approach and its findings deepen our understanding of the intricate interplay between microstructural characteristics and mechanical properties in maraging steel and also provide valuable guidelines for refining its additive manufacturing and heat treatment processes.

Simulation of a scintillator-based fast ion loss detector for steady-state operation in Wendelstein 7-X (invited).

A quantitative theoretical framework has been created to model neutral beam injection and fast ion losses in the Wendelstein 7-X (W7-X) stellarator, including a novel method to develop synthetic diagnostics for fast ion loss detectors (FILDs) of many types, such as scintillating and Faraday Cup FILDs. This is the first time that this has been done in stellarator geometry with this level of fidelity, providing a way for fast ion losses to be predicted more precisely in future stellarator experiments and in W7-X. Simulations of the signal seen by a Faraday Cup FILD have been completed for multiple W7-X plasmas and show close agreement with the measured signals. This method is now applied to an actively water-cooled, scintillator-based FILD, which is currently in development to measure the fast ion loss distribution in W7-X in greater detail. The design makes use of a double slit to measure energy-and-pitch-angle-resolved losses of both co-going and counter-going fast ions. The diagnostic, which can be inserted to different radial positions, has been designed to withstand steady-state heat fluxes of up to 120 kW/m2 along with additional transient heat loads of 100 kW/m2 lasting for up to 20s at a time. Simulations of W7-X standard magnetic configuration show up to 8 × 1013 (s-1 cm-2) ion fluxes onto the sensor from each neutral beam source and no signal from the counter-going slit. These simulations will help inform experimental proposals for future W7-X campaigns after installation of this diagnostic.

The effect of adding layers of date stones on the profitability of brackish water solar desalination process

Lately, there has been a pronounced and alarming up tick in the global demand for fresh water, resulting in a limited availability of this precious resource. Solar desalination emerges as a promising solution, particularly for supplying the sparsely populated desert regions in the southern regions of Algeria, where plentiful solar energy and subterranean brackish water resources are present.The current paper seeks to optimize the performance of traditional solar stills and elevate the quality of distilled water by incorporating layers of blackened date stones as an additional heat storage medium. Date stones, typically discarded post-date consumption, undergo a process of washing and blackening before being introduced in two forms (stone and powder). They are then uniformly distributed across the horizontal surface of solar still’s absorber.Three solar stills of identical design featuring glass sides were designed, manufactured, and subjected to testing to compare their productivity with that of a control unit. Experimental trials conducted at Ouargla University reveal significant enhancements the inclusion of a single layer of date stones (approximately 2.210 kg/ (m2 of absorber area)) leads to a remarkable 45.66 % increase in yield. Conversely, an equivalent amount (≈ 504 g) of date stones in powder form results in a 29.42 % improvement in yield. Notably, the distillate quality is substantially enhanced in both cases contrasted with the conventional setup.

Sustainable valorisation of sewage sludge via carbon dioxide-assisted pyrolysis

The escalating volume of sewage sludge (SS) generated poses challenges in disposal, given its potential harm to the environment and human health. This study explored sustainable solutions for SS management with a focus on energy recovery. Employing CO2-assisted pyrolysis, we converted SS into flammable gases (H2 and CO; syngas). Single-stage pyrolysis of SS in a CO2 conditions demonstrated that CO2 enhances flammable gas production (especially CO) through gas phase reactions (GPRs) with volatile matter (VM) at temperatures ≥520 °C. Specifically, the CO2 partially oxidized the VM released from SS and concurrently underwent reduction into CO. To enhance the syngas production at temperatures ≤520 °C, multi-stage pyrolysis setup with additional heat energy and a Ni/Al2O3 catalyst were utilized. These configurations significantly increased flammable gas production, particularly CO, at temperatures ≤520 °C. Indeed, the flammable gas yield in the catalytic pyrolysis of SS increased from 200.3 mmol under N2 conditions to 219.2 mmol under CO2 conditions, representing a 4.4-fold increase compared to single-stage pyrolysis under CO2 conditions (50.0 mmol). By integrating a water-gas-shift reaction, the flammable gases produced from CO2-assisted catalytic pyrolysis were expected to have the potential to generate revenue of US$4.04 billion. These findings highlight the effectiveness of employing CO2 in SS pyrolysis as a sustainable and effective approach for treating and valorising SS into valuable energy resources.

Simulation of the work of glass furnaces with the purpose of searching for reserves and increase their efficiency

The object of research is the operation of a glass furnace. The work involved modeling the operation of a glass furnace by changing the technical and economic indicators of its operation in order to optimize the technological processes of manufacturing glass products, increase the energy efficiency of the process, and reduce the ecological burden on the environment. Glass furnaces are complex heat engineering units that require a large amount of energy to operate. Therefore, increasing their effectiveness is the main task of our research. In the work, computer modeling of thermal processes in the furnace was carried out, heat balances were calculated and analyzed, and the performance of the furnace was analyzed after changing and improving the technological regimes of combustion processes, glass boiling and furnace construction. Studies have shown that in order to increase the technical and economic performance of glass furnaces, it is advisable to conduct additional thermal insulation of the furnace enclosures. The thermal insulation of the vault increases the efficiency of the furnace by 2–3 %, and the thermal insulation of the remaining areas of the furnace in total allows to increase the efficiency of the heating unit up to 3 %. Such measures improve the sanitary and technical working conditions of the staff in the machine-bath shop. Studies have shown that additional heating of the air used for burning fuel significantly increases the efficiency of the furnace. Thus, an increase in air temperature by 100 °C increases the efficiency of the furnace by approximately 2.5 %. However, such a measure is possible with a corresponding increase in the volume of regenerator nozzles. A significant increase in the efficiency of the furnace was achieved when additional electric heating was installed. This allows to reduce the total energy costs, and at the same time, the introduction of every 10 % of additional electric heating increases the efficiency of the furnace by up to 3 % and improves the quality of the glass mass. Such additional heating can be recommended in the amount of 20–30 % of the total heat consumption for the operation of the furnace. The analysis of the obtained results showed a fairly good convergence of the results, which indicates the acceptable adequacy of the models. The obtained process simulation results allow choosing the optimal design and operation parameters of the glass furnace. The results of the work can be used in practice for the design of efficient glass furnaces of various purposes and performance.

Improving Net Energy Efficiency of Dimethyl Ether Production Process by Methanol Dehydration

Dimethyl ether (DME) is a source of fuel that produces clean energy for the future. Methanol can be used as a raw material for the manufacture of DME as a natural gas that is treated for synthesis. This paper evaluates how to improve net energy efficiency in DME production and how to review the net energy efficiency calculations in DME production. Methods used for production of DME are methanol dehydration, thermodynamics examination, also improving the net energy efficiency of DME with the addition of the heat exchanger (E-100), the addition of a heater (E-104) before entering a column (T-102), and moved the mixer position before the heater (E-100). By modifying the addition of a heat exchanger (E-100), heater (E-104), and changing the position of the mixer in DME production, it has been proven that it can reduce energy requirements in the dimethyl ether synthesis process from methanol and increase net energy efficiency by up to 98.83%. The results of the case study indicate that the addition heat exchanger (E-100) able to reduce the heater load after the creation process and remove the cooler (E-101) that existed before creation, then the addition of the heater (E-104) serves to reduce the load of Qcond2 and Qreb2 on columns (T-102), also the position of the mixer for the methanol recycling flow is moved before the heater (E-100) is intended to remove the heaters (E-103). Copyright © 2024 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).