Addition Of Surfactant Sodium Dodecyl Sulfate Research Articles

Role of surfactants in the degradation and sustainable dyeing for reactive dyeing wastewater

To enhance the decolorization rate of thermally activated sodium persulfate in dye wastewater, C.I. Reactive Black 5 (RB5) was investigated in this study, which was evaluated by the decolorization of the dye solution. The effect of surfactant concentration (including anionic surfactant sodium dodecyl sulfate (SDS), nonionic surfactant Tween 80 (TW-80) and amphoteric surfactant (BS-12)), SPS concentration, and reaction temperature on the degradation of RB5 was studied. Furthermore, the relationship between free radicals and RB5 degradation was investigated. The results showed that the addition of SDS and TW-80 would inhibit the decolorization of RB5. Correspondingly, the effect would enlarge as the surfactant concentration increased. Nevertheless, the addition of BS-12 wouldn’t affect the final decolorization of RB5 dye solution, despite it could increase the decolorization rate in the initial stage. After 10 min of decolorization, compared to the dye liquor without BS-12, the decolorization could increase by 9.07 % and 0.69 %, respectively, after adding 0.5 and 1.0 CMC of BS-12. Besides, when reactive dyes were degraded by thermally activated sodium persulfate, the SO4-· and ·OH would work together, and SO4-· played a major role while ·OH played an auxiliary part. When the treated wastewater was used for dyeing, the addition of BS-12 could effectively regulate the dyeing rate. The fixation and K/S value were increased by 1.1 % and 0.20, respectively. Furthermore, the dyed fabrics also exhibited improved uniformity, with negligible differences in color fastness. The effects of adding SDS were similar to BS-12, while it decreased the exhaustion and fixation rate of RB5. In addition, non-ionic TW-80 was unfavorable to dyeing. This work provides a new way for efficient treatment of dyeing wastewater as well as reuse, opening an environmentally friendly treatment concept.

Experimental study on heat transfer performance enhancement of pulsating heat pipes induced by surfactants

Pulsating heat pipe (PHP) is considered as a promising technique to address the thermal dissipation issues in micro-electronic devices, but its heat transfer performance needs to be further enhanced urgently. In this study, the PHP comprehensive performance experimental system was established. Then, the influence of surfactant sodium dodecyl sulfate (SDS) aqueous solution on the heat transfer performance of PHP was experimentally investigated and the visualization of PHP with surfactant was also accomplished. Additionally, based on Marangoni effect and surface tension, a comprehensive analysis was conducted on the impact mechanism of surfactants on PHP. The experimental results indicated that the oscillatory disturbance of the liquid slug inside the PHP is enhanced by the addition of SDS, and the resulting pressure imbalance and temperature difference enhance the directional flow of the working fluid. Meanwhile, under the operating conditions of 30 W working thermal power and the solution concentration of 0.001 wt%, the thermal resistance of PHP was reduced by 30.7 % compared with that of deionized water (DI water). This indicated that the working fluid with low concentration SDS could increase the area of liquid film and reduce the thermal resistance, which is induced by the surface tension and Marangoni effect due to the uneven distribution of surfactants. However, the thermal resistance of PHP with the SDS concentration of 0.2 wt% is higher than that of DI. This means that high concentration of SDS would deteriorate the startup characteristics and the heat transfer performance of PHP. Therefore, high concentrations of surfactants should be avoided from practical application of PHP.

Structure of Cellulose Ether Affected by Ionic Surfactant and Solvent: A Small-Angle Neutron Scattering Investigation.

Polysaccharides and their derivatives are commonly used in pharmaceutical and agricultural formulations as rheology modifiers. Their performance is related to their conformation in solution, which in turn is affected by other ingredients present in the formulation. This study focuses on modulating the conformation of relatively rigid cellulose chains in aqueous solutions. In particular, we have investigated the nonionic cellulose derivative ethyl(hydroxyethyl)cellulose (EHEC) in water in the presence of the ionic surfactant sodium dodecyl sulfate (SDS) and/or ethanol acting as modulating agents. We have used small angle neutron scattering (SANS) with contrast variation to determine the EHEC chain conformation in the presence of (but not masked by) ethanol and SDS. In dilute and semidilute aqueous solutions, EHEC exhibits worm-like chain conformation due to the rigid cellulose backbone. Addition of ethanol does not impact the polymer conformation to a great extent. Addition of SDS alters the EHEC chain conformation, resulting in polyelectrolyte-like scattering behavior due to repulsive interactions between bound charged micelles which show similar structure as the free SDS micelles in solution (in the absence of polymers). Ethanol affects the polymer + surfactant system primarily by acting on the surfactant (bound on polymer) which, in turn, affects the polymer conformation. At higher ethanol concentrations (20 wt %), EHEC regains the worm-like chain conformation because of the detachment of the bound SDS micelles. To the best of our knowledge, this is the only study providing details on chain conformation of the rigid polymer EHEC in dilute or semidilute aqueous solutions in the presence of surfactant and alcohol and one of very few papers utilizing SANS for the characterization of polymer + surfactant + water + alcohol interactions. Such fundamental understanding of interactions and structure in multicomponent mixtures supports the design of industrial formulations.

Optimizing surfactant templating of yttria-stabilized zirconia aerogels for high-temperature applications: Effect of anionic and nonionic surfactant

Aerogels, mesoporous materials with extreme material properties including high specific surface area, low density, and low thermal conductivity, can be useful for applications including catalysis, sorption media, and drug delivery. The low thermal conductivity and high surface area of aerogels makes them advantageous as thermal management systems, specifically for aerospace or aeronautics applications. However, the pore collapse and subsequent surface area decrease of aerogels following exposure to high temperatures must be mitigated to allow aerogels to be effectively used in thermal management applications. This work investigates the anionic surfactant sodium dodecyl sulfate (SDS) and the nonionic surfactant Pluronic® P-123 as surfactant templates in yttria-stabilized zirconia (YSZ) aerogels. By utilizing surfactant templates, known to influence pore structure, it is anticipated that sintering and densification of the aerogels following high-temperature exposure will be mitigated. It was determined that the addition of SDS and P-123 increased the surface area and pore volume of as-dried aerogels and suppressed crystallite growth at high temperatures. However, the impact of surfactant templates on the surface area and pore volume of heat-treated aerogels was negligible, potentially due to low concentrations of surfactant and the removal of the surfactant following high-temperature exposure.

Effects of surfactant on Bacillus mucilaginosus adsorption characteristics during vanadium bioleaching process

Bioleaching is a sustainable and economical technology for extracting valuable elements from low-grade ores or refractory resources. Adsorption of bacteria on mineral surface is the usual basic condition for the deep interaction between bacteria and minerals, thereby improving the bioleaching efficiency of target elements. The addition of surfactants in bioleaching process is an efficient and promising method for improving the bacteria adsorption on mineral surface. Therefore, effects of surfactant SDS (Sodium Dodecyl Sulfate) on bacterial adsorption characteristics were investigated during the bioleaching process from vanadium-bearing shale by Bacillus mucilaginosus (B.M). The optimal vanadium bioleaching conditions were 0.5 g/L of SDS, 2 g/L of yeast dip powder, and 7.0 of the initial pH. The B.M adsorption equilibrium on the surface of the vanadium-bearing shale with and without addition of surfactant SDS fitted a Freundlich equation, and the addition of surfactant SDS could significantly enhance the B.M absorption on the vanadium-bearing shale. The Pseudo-first-order adsorption kinetics was more suitable to be selected for the demonstration of the B.M adsorption on the surface of the vanadium-bearing shale with and without addition of surfactant SDS, and the addition of surfactant SDS could accelerate the B.M adsorption rate on the surface of the vanadium-bearing shale.

The effect of sodium dodecyl sulfate and dodecyltrimethylammonium chloride on the kinetics of CO2 hydrate formation in the presence of tetra-n-butyl ammonium bromide for carbon capture applications

Tetra-n-butyl ammonium bromide (TBAB) is a commonly used promoter to moderate CO2 hydrate phase equilibrium. However, it decreases CO2 gas uptake. In this work, the effects of anionic surfactant sodium dodecyl sulfate (SDS) and cationic surfactant dodecyltrimethylammonium chloride (DTAC) on the kinetics of CO2–TBAB hydrate formation are investigated. Experiments in a batch reactor at the same initial pressure of CO2/N2 gas mixtures are conducted in systems of 10-wt% TBAB and varied SDS concentrations of 0–1500 ppm and DTAC concentrations of 0–0.6 wt%. Induction time, normalized gas uptake, split fraction and separation factor are the metrics to study in this paper. The results show that the hydrate formation is most accelerated with the addition of SDS, and the best CO2 separation performance is achieved in the presence of DTAC. 10-wt%TBAB with 0.1-wt% DTAC is found to be the optimum recipe, and it leads to the same amount of CO2 uptake at 283.15 K as that in a pure water system at 276.45 K under the same initial pressure. CO2 uptake is also found to increase with a higher subcooling. Furthermore, the intensive uptake period of different systems is determined for practical applications of hydrate-based carbon capture.

How Detergents Dissolve Polymeric Micelles: Kinetic Pathways of Hybrid Micelle Formation in SDS and Block Copolymer Mixtures.

Mixtures of amphiphilic polymers and surfactants are used in a wide range of applications, e.g., pharmaceuticals, detergents, cosmetics, and drug delivery systems. Still, many questions remain on how the structure and, in particular, the kinetics of block copolymer micelles are affected in the presence of surfactants and what controls the solubilization kinetics. In this work, we have studied the stability and solubilization kinetics of block copolymer micelles upon the addition of the surfactant sodium dodecyl sulfate (SDS) using small-angle X-ray/neutron scattering. The ability of the surfactant to dissolve polymer micelles or form mixed micelles has been investigated using two types of amphiphilic polymers, poly(ethylene-alt-propylene)–poly(ethylene oxide) (PEP1-PEO20) and n-alkyl-functionalized PEO (C28-PEO5). The exchange kinetics of C28-PEO5 micelles are in the order of hours, while PEP1-PEO20 micelles are known to be frozen on a practical timescale. In this work, we show that the addition of SDS to PEP1-PEO20 provides virtually no solubilization, even after an extended period of time. However, upon adding SDS to C28-PEO5 micelles, we observe micellar dissolution and formation of mixed micelles occurring on the timescale of hours. Using a coexistence model of mixed and neat micelles, the SAXS data were analyzed to provide detailed structural parameters over time. First, we observe a fast fragmentation/fission step followed by a slow reorganization process. The latter process is essentially independent of concentration at low volume fraction but is greatly accelerated at larger concentrations. This might indicate a crossover from a predominance of molecular exchange to fusion/fission processes.

Fully Automated Water Sampling-Surfactant-Enhanced Membrane Bag Liquid-Phase Microextraction-Ultrahigh Performance Liquid Chromatography-Mass Spectrometry.

A fully automated integrated analytical platform that included continuous water sampling, sample preparation (extraction), and analysis for the determination of nine glucocorticoids was developed. A peristaltic pump was employed to deliver the water sample automatically. The subsequent sample preparation and analytical processes were also fully automated with the use of a commercial autosampler unit coupled to an ultrahigh performance liquid chromatography-tandem mass spectrometric system. The sample preparation step involved membrane bag liquid-phase microextraction in which a synergistic mixture of n-octanol enhanced with surfactant sodium dodecyl sulfate (SDS) (0.10% in n-octanol) was applied as the extractant phase. Addition of SDS helped to improve the extraction, increasing enrichment factors (EFs) by severalfold compared with the use of n-octanol only as extractant solvent. Various parameters to improve extraction efficiency were evaluated. They included percentage of surfactant used, sample pH, agitation rate, extraction duration, salting out effect, extraction temperature, and flow rate for sample introduction. Under the most favorable conditions, enrichment factors of between 32 and 189 were attained with relative standard deviations of <8%. The limits of detection for the glucocorticoids were between 0.03 and 0.17 ng/mL, whereas the limits of quantitation were between 0.09 and 0.52 ng/mL, indicating the good sensitivity of the method. The method was successfully applied to determine glucocorticoids in industrial canal water. This work also provided some insights on the potential of on-site sampling and real-time monitoring of contaminants in environmental waters.

Characterization of the performance of venturi-based aeration devices for use in wastewater treatment in low-resource settings

Low-cost aerators relying on the venturi principle to entrain air into flowing water have the notable advantage of contributing both to water mixing and oxygen transfer, making them attractive for wastewater treatment in low-resource settings. This study aimed to characterize the performance of such aerators by describing the impact of different design characteristics, including water flow rate, the number of nozzles used, and the nozzle depth. The study also explored the effect on aeration performance of temperature, total dissolved solids (TDS) concentration, and addition of the archetypal surfactant sodium dodecyl sulphate (SDS). Tests were conducted in a 200 L reactor with 2, 3 or 4 nozzles, at depths of 20, 40 or 60 cm, while circulating water through the aeration device at a rate of 400, 600 or 800 L/h. The configuration that yielded the highest mass transfer coefficient (KLa20 of 20.8 h-1) had both the highest flow rate (800 L/h) and the smallest number of nozzles (2). Nozzle depth had no detectable effect on performance. The configuration with the highest standard aeration efficiency (SAE) had a low flow rate (400 L/h) and 4 nozzles. The effect of TDS concentration was not detected in the concentration range typical of domestic wastewater (300–1 250 mg/L). The effect of temperature on KLa followed a first-order exponential curve, as reported in the literature (θ = 1.02). Addition of SDS was found to increase the KLa20 of the tested aerator design by up to 60% of its value in tap water, in contrast to results from literature. The performance data obtained herein was compared to other types of aerators. Though venturi nozzles were found to be less efficient than other available technologies, it is proposed that using plunging rather than immersed venturi nozzles could increase performance to an attractive level for low-resource applications.

Influence of Sodium Dodecyl Sulfate on the Microstructure and Electrochromic Performance of an Electrodeposited Nickel Oxide Film

Nickel oxide (NiO) films were deposited on indium tin oxide (ITO) coated glass substrates using a potentiostatic electrodeposition method from Ni(NO3)2 aqueous solution containing the surfactant sodium dodecyl sulfate (SDS). The microstructure, morphology, and electrochromic performance of the NiO films were investigated. Our results showed that the addition of SDS inhibited the growth of NiO crystals, tailored the morphology of the films, and favoured their electrochromic performance. The NiO films deposited in the presence of 6mM SDS exhibited excellent electrochromic performance in OH− containing electrolytes (0.1M KOH), with a high optical contrast of over 77% at 550nm, short switching time (5.62s for bleaching and 7.34s for coloration), and enhanced cycling durability.

Aggregation behavior of self-assembled nanoparticles made from carboxymethyl-hexanoyl chitosan and sodium dodecyl sulphate surfactant in water

Biopolymers can be used to produce nano-objects in solution and they are generally of low cost and biocompatible. However, they commonly have low kinetic stability and form aggregates with a broad particle size distribution, characteristics that hinder their use in drug delivery systems. Herein, we report the thermodynamics and mechanisms underlying the formation of nanostructures through the self-assembly of carboxymethyl-hexanoyl chitosan (ONCHC) and the effect of the presence of the surfactant sodium dodecyl sulfate (SDS). The pre- and post-aggregation regimes were monitored using several techniques and indicated that self-assembly is thermodynamically favorable. The presence of SDS decreased the hydrodynamic radius and surface charge of the SDS-ONCHC nanoaggregates and increased the kinetic stability in aqueous solution over a period of 150 days. The SDS-ONCHC interaction is driven mainly by a hydrophobic effect and the addition of SDS increases the number and strength of the hydrophobic domains, where the integral enthalpy change for the aggregate formation is −2.11 kJ mol−1.

Association between the physical stability of flurbiprofen suspension and the interaction of HPMC/SDS

The anionic surfactant sodium dodecylsulfate (SDS) has improved the physical stability of flurbiprofen (FBP) suspension, which was suspended by 0.2% (w/v) hydroxypropylmethyl cellulose (HPMC, K4M). Therefore, the physical stability of FBP suspensions and the interaction of HPMC/SDS were studied, and a certain association between them was revealed. The anti-solvent precipitation method was used to prepare suspensions. The apparent drug concentration from different sites was evaluated to get the dispersion of drug actually. The process of flocculation and deflocculation with the addition of SDS was caught by analyzing the morphology of the suspended particles. The physical stability of the FBP suspensions was characterized mainly by measuring the re-dispersion time, the zeta potential and particle size. Meanwhile, conductivity measurements were carried out to obtain the characteristic concentrations of SDS in HPMC/SDS system. The viscosities, the abilities for improving the solubility and wettability of FBP in the separate and mixed HPMC/SDS solutions were also contrasted respectively. The suspensions prepared with HPMC/SDS possessed better physical stability. The suspensions were uniform when the concentration of SDS was between the critical adsorption concentration (CAC) and the polymer saturation point (PSP). After PSP, the uniformity became worse and worse until the SDS was enough to form a deflocculation state. Besides, the re-dispersion time of FBP suspensions was longest when the concentration of SDS around CAC and shorter by shorter after the critical micelle concentration (CMC). The article provided a new sight on the relation between the interaction of excipient matrix and pharmaceutical preparations.

Microstructure Refinement in W-Y2O3 Alloy Fabricated by Wet Chemical Method with Surfactant Addition and Subsequent Spark Plasma Sintering

With the aim of preparing high performance oxide-dispersion-strengthened tungsten based alloys by powder metallurgy, the W-Y2O3 composite nanopowder precursor was fabricated by an improved wet chemical method with anion surfactant sodium dodecyl sulfate (SDS) addition. It is found that the employment of SDS can dramatically decrease W grain size (about 40 nm) and improve the size uniformity. What’s more, SDS addition can also remarkably improve the uniform dispersion of Y2O3 particles during the synthesis process. For the alloy whose powder precursor was fabricated by traditional wet chemical method without SDS addition, only a few Y2O3 dispersoids with size of approximate 10–50 nm distribute unevenly within tungsten grains. Nevertheless, for the sintered alloy whose powder precursor was produced by improved wet chemical method, the Y2O3 dispersoids (about 2–10 nm in size) with near spherical shape are dispersed well within tungsten grains. Additionally, compared with the former, the alloy possesses smaller grain size (approximate 700 nm) and higher relative density (99.00%). And a Vickers microhardness value up to 600 Hv was also obtained for this alloy. Based on these results, the employment of SDS in traditional wet chemical method is a feasible way to fabricate high performance yttria-dispersion-strengthened tungsten based alloys.

Release mechanism of doxazosin from carrageenan matrix tablets: Effect of ionic strength and addition of sodium dodecyl sulphate

The polyelectrolyte matrix tablets loaded with an oppositely charged drug exhibit complex drug-release mechanisms. In this study, the release mechanism of a cationic drug doxazosin mesylate (DM) from matrix tablets based on an anionic polyelectrolyte λ-carrageenan (λ-CARR) is investigated. The drug release rates from λ-CARR matrices are correlated with binding results based on potentiometric measurements using the DM ion-sensitive membrane electrode and with molecular characteristics of the DM-λ-CARR-complex particles through hydrodynamic size measurements. Experiments are performed in solutions with different ionic strength and with the addition of an anionic surfactant sodium dodecyl sulphate (SDS). It is demonstrated that in addition to swelling and erosion of tablets, the release rates depend strongly on cooperative interactions between DM and λ-CARR. Addition of SDS at concentrations below its critical micelle concentration (CMC) slows down the DM release through hydrophobic binding of SDS to the DM-λ-CARR complex. On the contrary, at concentrations above the CMC SDS pulls DM from the complex by forming mixed micelles with it and thus accelerates the release. Results involving SDS show that the concentration of surfactants that are naturally present in gastrointestinal environment may have a great impact on the drug release process.

Measurements of the stabilisation of liquid film flow by the soluble surfactant sodium dodecyl sulfate (SDS)

Gravity-driven film flow of aqueous solutions of SDS is studied experimentally and the evolution of small-amplitude, regular inlet disturbances is investigated. With the addition of SDS, strong attenuation of non-linear growth is observed, with traveling waves remaining relatively small in height and near-sinusoidal over an impressive parametric range. The critical Reynolds number of the primary instability rises by an order of magnitude. Maximum stabilization is observed at small surfactant loadings (characterized by surface tension 60–65mN/m) and the critical Reynolds number gradually decreases with further addition of surfactant. Observations are interpreted by the competing effects of surface elasticity -which increases with the adsorbed SDS and intensifies Marangoni stresses- and surfactant mass transfer between bulk and interface -which also increases with the amount of SDS and mitigates interfacial gradients and Marangoni stresses.

Formation of a Rigid Hydrophobin Film and Disruption by an Anionic Surfactant at an Air/Water Interface.

Hydrophobins are amphiphilic proteins produced by fungi. Cerato-ulmin (CU) is a hydrophobin that has been associated with Dutch elm disease. Like other hydrophobins, CU stabilizes air bubbles and oil droplets through the formation of a persistent protein film at the interface. The behavior of hydrophobins at surfaces has raised interest in their potential applications, including use in surface coatings, food foams, and emulsions and as dispersants. The practical use of hydrophobins requires an improved understanding of the interfacial behavior of these proteins, alone and in the presence of added surfactants. In this study, the adsorption behavior of CU at air/water interfaces is characterized by measuring the surface tension and interfacial rheology as a function of adsorption time. CU is found to adsorb irreversibly at air/water interfaces. The magnitude of the dilatational modulus increases with adsorption time and surface pressure until CU eventually forms a rigid film. The persistence of this film is tested through the sequential addition of strong surfactant sodium dodecyl sulfate (SDS) to the bulk liquid adjacent to the interface. SDS is found to coadsorb to interfaces precoated with a CU film. At high concentrations, the addition of SDS significantly decreases the dilatational modulus, indicating disruption and displacement of CU by SDS. Sequential adsorption results in mixed layers with properties not observed in interfaces generated from complexes formed in the bulk. These results lend insight to the complex interfacial interactions between hydrophobins and surfactants.

Self- and co-assembly of amphiphilic gradient polyelectrolyte in aqueous solution: Interaction with oppositely charged ionic surfactant

Association behavior of the biocompatible amphiphilic cationic gradient polyelectrolyte poly[(2-methyl-2-oxazoline)-grad-(2-phenyl-2-oxazoline)-mod-(ethylene imine)] (HPPhMeOx) prepared by partial hydrolysis of the gradient copolymer poly[(2-methyl-2-oxazoline)-grad-(2-phenyl-2-oxazoline)] and the interaction of HPPhMeOx with the anionic surfactant sodium dodecyl sulfate (SDS) in aqueous solutions were investigated by scattering techniques (SANS, DLS) and by atomic force microscopy. SANS measurements revealed that large particles with the hydrodynamic radius of ca. 500nm observed in HPPhMeOx aqueous solutions by DLS are formed by a network of physically crosslinked compact hydrophobic domains with the mean radius of ca. 10nm. Upon addition of sodium dodecyl sulfate (SDS), the size of the domains increases at low amounts of the added SDS due to hydrophobic interaction of the single surfactant ions with the aggregates. Further addition of SDS leads to the formation of the co-assembled polyelectrolyte–surfactant complex manifested in SANS by the presence of the correlation peak from the densely packed SDS micelles as well as by partial disruption of the domains.

Stabilizing and destabilizing protein surfactant-based foams in the presence of a chemical surfactant: Effect of adsorption kinetics

Stimuli-responsive protein surfactants promise alternative foaming materials that can be made from renewable sources. However, the cost of protein surfactants is still higher than their chemical counterparts. In order to reduce the required amount of protein surfactant for foaming, we investigated the foaming and adsorption properties of the protein surfactant, DAMP4, with addition of low concentrations of the chemical surfactant sodium dodecylsulfate (SDS). The results show that the small addition of SDS can enhance foaming functions of DAMP4 at a lowered protein concentration. Dynamic surface tension measurements suggest that there is a synergy between DAMP4 and SDS which enhances adsorption kinetics of DAMP4 at the initial stage of adsorption (first 60s), which in turn stabilizes protein foams. Further interfacial properties were revealed by X-ray reflectometry measurements, showing that there is a re-arrangement of adsorbed protein–surfactant layer over a long period of 1h. Importantly, the foaming switchability of DAMP4 by metal ions is not affected by the presence of SDS, and foams can be switched off by the addition of zinc ions at permissive pH. This work provides fundamental knowledge to guide formulation using a mixture of protein and chemical surfactants towards a high performance of foaming at a low cost.

Interaction of Moringa oleifera seed protein with a mineral surface and the influence of surfactants

The paper describes the adsorption of purified protein from seeds of Moringa oleifera to a sapphire interface and the effects of addition of the anionic surfactant sodium dodecylsulfate (SDS) and the cationic surfactant hexadecyltrimethylammonium bromide (CTAB). Neutron reflection was used to determine the structure and composition of interfacial layers adsorbed at the solid/solution interface. The maximum surface excess of protein was found to be about 5.3mgm−2. The protein does not desorb from the solid/liquid interface when rinsed with water. Addition of SDS increases the reflectivity indicating co-adsorption. It was observed that CTAB is able to remove the protein from the interface. The distinct differences to the behavior observed previously for the protein at the silica/water interface are identified. The adsorption of the protein to alumina in addition to other surfaces has shown why it is an effective flocculating agent for the range of impurities found in water supplies. The ability to tailor different surface layers in combination with various surfactants also offers the potential for adsorbed protein to be used in separation technologies.

Thermodynamic study of the interaction between 5,10,15,20-tetrakis-(N-methyl-4-pyridyl)porphyrin tetraiodine and sodium dodecyl sulfate

Abstract The interaction between 5,10,15,20- tetrakis -( N -methyl-4-pyridyl)porphyrin tetraiodine (TMePyPI 4 ) and the anionic surfactant sodium dodecyl sulfate (SDS) has been studied in aqueous solutions using electrical conductivity, UV–vis and fluorescence spectrophotometries. The electrical conductivity data suggests that the addition of SDS to TMePyPI 4 solutions is accompanied by strong interactions (mainly electrostatic) with the formation of aggregates. These aggregates have a stoichiometry somewhat lower than the simple charge neutralization, possible due to the formation of supramolecular structures. At SDS/TMePyPI 4 ratios higher than the stoichiometry ratio, those SDS-TMePyPI 4 redissolve and at higher SDS concentrations formation of micelles is observed. The effect of both porphyrin surfactant and temperature allows a detailed thermodynamic analysis of the SDS micellization process in this multicomponent system.