A new concept of thermodynamic Riphean-Phanerozoic evolution of upper geospheres: atmosphere, earth’s crust, hydrosphere and biosphere is presented. This evolution from Riphean to Phanerozoic is determined by the consistent cooling of the earth’s surface. For the hydrosphere (starting from 2.0 billion years), this is manifested in the appearance and increase in the Riphean and Phanerozoic of the mass of liquid water (mainly in the seas and oceans), which gradually decreases its acidity and increases its oxidizing properties. The primary atmosphere in the Early Proterozoic about 2 billion years ago mainly consisted of gaseous water and chlorine, with water gas pressure at about 230 bar and the chlorine pressure at about 5 bar at a temperature of 375 °С. At this, an acidic hydrosphere (pH = 0.15) was formed, with a pressure of about 1 bar of free oxygen in the atmosphere. In the acidic ocean in Riphean to Vendian, with little sedimentation, almost all components were removed from the rocks of the ocean floor, except for silica, with the formation, for example, of Ovruch quartzites. Since Vendian (from 620 million years ago, and especially in the Phanerozoic), the land area and the height of the continents rapidly increased, which are eroded by the seas with the deposition of thick sediments, including carbonates. At the same time, more and more volcanics are accumulating, which is associated with active plate tectonics. The modern composition of the Earth’s atmosphere was formed due to chemical reactions of oxidation in the hydrosphere and atmosphere and volcanism, followed by a change in pH, Eh, and temperature (below 60 °С) in the hydrosphere and atmosphere and the appearence of life. This led to a decrease in carbon dioxide in the hydrosphere and atmosphere, especially due to plants, as well as to stabilization of the oxygen content in the atmosphere at 0.2 bar and to the predominance in it of nitrogen, which has substantial stability in the atmosphere Views of some geologists that Archean banded ferruginous quartzites have originated as sedimentary rocks are contradicted by significant temperatures in the surface layers of the Earth in the Archean (about 600-700 °С), when active processes of regional metamorphism and gas formation took place.
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