Activated Fly Ash Research Articles

Development of filler-free and ambient-cured fly ash based geopolymer brick utilizing low molar concentration of activating solution

In this study, an effort has been undertaken to develop geopolymer bricks (GPB) using fly ash and an activating solution without the addition of any filler material. The primary objective is to establish the optimum mix ratio with the lowest possible concentration of sodium hydroxide (NaOH) in activating solution when mixed with fly ash, resulting in the GPB having compressive strength exceeding 10 MPa and water absorption below 20 % (Class-10 bricks). To achieve this objective, different activating solutions consisting of NaOH, a combination of NaOH and sodium silicate (Na2SiO3), and a combination of NaOH, Na2SiO3, and additional water were used. The samples underwent ambient curing until the age of testing. The X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS) analyses examined the microstructural behavior of the GPB. Experimental results indicated that the compressive strength of 18 MPa and water absorption of 16.49 % was achieved when 2 M NaOH with Na2SiO3 and 5 % extra water were used to activate fly ash. Microstructural analysis revealed that the undissolved fly ash particles served as filler material, while the dissolved fly ash helped in the synthesis of cementitious material. The performance of these bricks was found to be equivalent to that of the traditionally available burnt clay bricks.

Mechanical, Thermal, and Morphological Analysis of Himalayan Agave Fiber /GO Coated Fly Ash Hybrid Polypropylene Composites.

Composites containing two different types of reinforcements offer a wide range of possibilities and synergistic properties. This study investigates the hybridization effect of chemically active fly ash (FA) (5 wt.%) on the composites made from alkali (1 wt.%) - APTES silane (2 wt.%) treated Himalayan agave fibers (HAF) (25 wt.%) and polypropylene (PP). Prior to FA activation, the planetary ball mill was used to suitably reduce the particle size of the FA with was confirmed by the dynamic light scattering approach. Secondary reinforcement FA was modified with APTES silane (1 wt.%), followed by treatment with graphene oxide (GO) (0.5, 0.75, and 1 wt.%). The highest tensile strength of 40.47 MPa and modulus of 1.49 GPa were observed for the hybrid composites fabricated from 0.75 and 1.0 wt.% GO treated fly ash. Interestingly, this trend differed for flexural properties, and the highest flexural strength of 53.52 MPa was demonstrated by 0.5 wt.% GO treated FA hybrid composite. Thermal characterization revealed that addition of fiber increased crystallinity but decreased thermal stability, whereas a good wettability of the fiber and FA in matrix was demonstrated through morphological characterization.

The Evaluation and Detection of the Chemical Bond Between Silane Coupling Agent and Silver Layer on Alkali Activated Fly Ash.

In this study, wettability was employed to evaluate the effect of alkali activation by NaOH on different fly ash (FA) particle sizes. The results indicated that the surface wettability of FA particles with 13.8 μm increased from 0.025 g2/s to 0.034 g2/s after activation by the NaOH solution, which is suitable for silane modification and electroless plating. X-ray photoelectron spectroscopy (XPS) was used to analyze whether three kinds of silane coupling agents coated on FA surfaces could detect the chemical bonds between silane coupling agents coated on the FA surface and silver layers by shortening the plating time. The XPS results demonstrated that N-Ag coordination bonds can be detected by reducing silver plating time to 2 min for Ag-plated FA modified by N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (KH792). However, there were no chemical bonds detected for Ag-plated FA modified by γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) and methyltrimethoxysilane (MTMS), even when the satellite peak of Ag disappeared after plating for 80 s. The SEM showed that Ag particles agglomerated on FA surfaces, and even a bare surface was found after modification by KH560 and MTMS, which further proved no chemical bonds between silver layers and the silane coupling agents.

Strength and Microstructural Characteristics of Activated Fly Ash–Cement Paste

Incorporating high volumes of fly ash (FA) in filling materials reduces costs and carbon emissions, but low early strength limits its use. This study investigates the effects of sodium sulfate decahydrate (Na2SO4·10H2O) and calcium hydroxide (Ca(OH)2) as activators at concentrations of 0.5%, 1.0%, 1.5%, and 2.0% on the mechanical properties and microstructure of tailings–cement–fly ash composites. Compressive strength testing, X-ray diffraction (XRD), and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) were used to evaluate performance at different curing stages. Results indicate that all activators enhance early strength, with 2.0% Ca(OH)2 yielding the greatest improvement. Microstructural analysis showed that activators boost quartz reactivity and create denser structures. Na2SO4 promotes ettringite and gypsum formation, while Ca(OH)2 increases alkalinity, enhancing gel formation from FA. These findings clarify how activators improve the performance of activated fly ash–cement paste (AFCP).

Investigating the microstructure of alkali activated fly ash, ground granulated blast furnace slag (GGBS), or their mixtures by depth sensing nanoindentation and structure dependence of their composition by Magic Angle Spinning (MAS) NMR

Investigating the microstructure of alkali activated fly ash, ground granulated blast furnace slag (GGBS), or their mixtures by depth sensing nanoindentation and structure dependence of their composition by Magic Angle Spinning (MAS) NMR

Behavior of zero cement reinforced concrete slabs under monotonic and impact loads: Experimental and numerical investigations

Currently, there is a shift toward the use of low-carbon construction materials to reduce global carbon dioxide emissions. Zero-cement concrete (ZCC) synthesized from alkaline activated fly ash (FA) is a promising alternative for Portland cement in the construction industry to reduce global CO2 emissions, increase the consumption of waste materials, and save energy. A substantial amount of research on the impact load behavior of ordinary reinforced concrete (RC) structural components has been conducted. However, investigations on the behavior of zero cement concrete (ZCC) slabs under impact loads have not been reported. In this work, twenty simply supported two-way flat reinforced fly ash ZCC slabs (including two normal concrete (NC) slabs as reference samples) were tested under monotonic and impact loads. The test samples were categorized into eight groups on the basis of various parameters. Twelve RC slabs (1 NC and 11 ZCCs) were prepared for repeated impact tests, and eight slabs (1 NC and 7 ZCCs) were prepared for monotonic loading tests. Various parameters were investigated herein, including slab thickness, bar spacing, molarity concentration of alkali activators, hammer height, and hammer mass. Nonlinear finite element models were also developed and validated by using ABAQUS software for additional parametric study purposes. The results revealed that the behavior of ZCC slabs is approximately similar to that of NC slabs. The results also revealed that an increase in the ZCC slab thickness, reinforcement ratio, hammer height, and hammer mass has a noticeable effect on the dynamic response of the slab. However, increasing the molarity concentration of alkali activators has clearly a slight influence on the impact loadtime history. When the slab thickness was increased or the bar spacing was reduced, the static and impact energy absorption capacities were increased by 1.5 and 2.0 times, respectively. For impact load tests, the damage degree, penetration, and cracking pattern at failure were approximately typical for all test samples at the first hit except when the hammer mass and impact height were changed. For the samples subjected to monotonic loading, a flexural response was observed for almost all the slab samples at the first loading stage, and cracking started from the midpoint of the slab and propagated toward the slab edges; ultimately, punching shear failure was observed.

Linear electronic relationship of surface functionalized fly ash and substituted phenols on bactericidal activity with the computational study

AbstractFly ash is a solid waste by‐product obtained from coal‐burning power plants. It is a silico‐aluminate material with an admixture of several metal oxides, which finds an application in geopolymers, zeolites, cement, catalysts, etc. The present article aims to assess the antibacterial activity of fly ash and substituted phenols against Escherichia coli and Staphylococcus in broth and agar cultures, respectively. High‐Temperature Activated Fly Ash (TAFA) shows significant bactericidal activity against gram positive (+) and negative (−) bacteria as compared to Mechanically Activated Fly Ash (MAFA) and Waste Polyethylene Coated Fly Ash (WPCFA), which attribute to the augmentation of mullite phase (lacking charge balancing cation) of fly ash at high temperature. These modified fly ash (TAFA, MAFA, and WPCFA) were characterized by Fourier Transform Infra Red (FT‐IR), Scanning Electron Microscope (SEM), and X‐Ray Diffraction (XRD) techniques. The substituted phenols further explored the significance of charge on the antibacterial properties. The para‐substituted phenols with groups having (+) mesomeric effect M > (−) I Inductive effect and ortho substituents with (+) I effect shows a linear electronic relationship with antibacterial properties with gram (+) bacteria, owing to charge augmentation at oxygen atom of phenoxide ion due to electronic effects. Further, the bactericidal efficacy was less significant on gram (−) bacteria. Small energy gap (Egap) values corroborated the chemical reactivity of phenols and substituted phenols. The antimicrobial potential of phenol/substituted phenols can be correlated with global descriptors. Molecular Electrostatic Potential (MEP) maps obtained through Density Functional Theory (DFT) indicate the nucleophilic centers in the molecular structure.

Experimental study on CO2 sequestration performance of alkali activated fly ash and ground granulated blast furnace slag based foam concrete

In an effort to reduce the emission level of carbon dioxide (CO2) from metallurgical, thermal, cement burning and other enterprises, an innovative solution is proposed in this study, which aims to sequester CO2 with alkali activated fly ash (FA) and ground granulated blast furnace slag (GGBFS) based foam concrete. The fluidity of alkali activated foam concrete (AAFC) fresh paste, dry density and compressive strength after hardening, micro-pore structure, carbonation products and CO2 sequestration capacity were comprehensively explored. The experimental findings indicated that the fluidity of AAFC slurry was almost unaffected by the content of foaming agent hydrogen peroxide (H2O2). When the H2O2 content ranges between 1 % and 3 %, the dry density of uncarbonated AAFC ranges approximately 752.3–365.2 kg/m3, and the compressive strength of carbonated AAFC ranges about 1.01–0.21 MPa. Accelerated carbonation increased the dry density of uncarbonated AAFC samples. The porous structure of AAFC facilitated CO2 gas penetration into the matrix, leading to rapid carbonation. When the H2O2 content was 1 %, the compressive strength of fully carbonated AAFC was lower than that of non-carbonated AAFC; however, when the H2O2 content exceeded 1.5 %, the trend in compressive strength reversed. The carbonation kinetics of AAFC demonstrated a linear relationship with the square root of carbonation time, and the carbonation coefficient increases proportionally with H2O2 content. The porosity of AAFC increased from 61.05 % to 71.51 % as the H2O2 content increased from 1 % to 2.5 %. The main pore size distribution range of AAFC was 30–400 µm and 5–50 nm. Accelerated carbonation minimally impacted the total porosity of AAFC but transformed certain large pores into capillary pores. Accelerated carbonation would generate calcite, aragonite, vaterite and additional amorphous phases. The maximum carbon sequestration capacity of AAFC, as determined in this study, reached 26.41 kg/m3, indicating significant potential for CO2 sequestration.

Effect of ball milling activation on CO2 mineralization performance in fly ash and fire resistance capabilities of mineralized product

Coal-fired power generation has always been a major energy supply source globally. However, a large amount of CO2 is emitted with the combustion of coal resources, and fly ash, a by-product of coal combustion, is also accumulated in large quantities. The application of CO2 mineralization in fly ash can not only reduce CO2 emission but also effectively manage industrial waste, thereby promoting environmental sustainability. This paper used the mechanical ball milling method to activate fly ash and investigated the effects of ball milling time and speed on the CO2 sequestration in fly ash. At 30 min ball milling time and 400 r/min ball milling speed, the modified fly ash achieves a good CO2 sequestration capacity of 81.70 gCO2/kgFA. Compared with raw fly ash, the CO2 consumption of treated fly ash is higher at 75.41 mmol/mL. The specific surface area and pore volume of treated fly ash are larger at 1.57 m2/g and 4.33 cm3/kg respectively, which is beneficial for enhancing mass transfer capacity and the carbonation effect. As the ratio of mineralized product/coal increases from 0.5 to 4, the crossing-point temperature increases from 157.20 °C to 165.15 °C. Based on the experimental results, the paper discussed the mechanism of ball milling activation to enhance the carbonation effect of fly ash. This study provides theoretical references for the environmentally friendly utilization of fly ash.

Optimization and Evaluation of Alkali Activated Fly Ash for Lightweight Aggregate Production

This study investigates the utilization of solid waste, specifically fly ash, and other materials to produce aggregates through geopolymerisation. The research aims to explore the properties of fly ash aggregates and assess their viability in concrete production. The objectives of the study encompass the preparation of aggregates using different proportions of fly ash and alkali activator such as sodium hydroxide and sodium silicate, alongside the casting of concrete cubes utilizing the artificial aggregate. The methodology employed involves the preparation of alkali activator, mix proportioning, and the subsequent processes of mixing, casting, crushing, and curing. Various ratios of fly ash to activator (2.5:1, 3:1, and 3.5:1) were investigated, with corresponding results obtained for properties such as abrasion value, impact value, bulk specific gravity, and water absorption. The findings reveal that the properties of the fly ash aggregates vary with different ratios, with notable differences observed in abrasion value, impact value, bulk specific gravity, and water absorption. For 2.5:1 abrasion value is 26.02%, impact value is 19.32%, bulk specific gravity 1.821 and water absorption 9.61%.For 3:1 abrasion value is 37.14%, impact value is 25.15%, bulk specific gravity 1.78 and water absorption 10.58%.For 3.5:1 abrasion value is 46.5%, imapct value is 32.87%, bulk specific gravity 1.648 and water absorption 12.83%. Casting cude using ratio 2.5:1, 28 day strength is 20.46 N/mm2.. This research project offers an eco-friendly solution for utilizing fly ash in the production of high-performance aggregates, contributing to sustainable construction practices. The implications of the findings include reduced environmental impact, enhanced resource efficiency, and the potential for resilient and environmentally conscious built environments. Further research and development in this area could lead to broader adoption of geopolymerized fly ash aggregates in the construction industry, paving the way for a more sustainable and Greener future.

Experimental study on the effect of hydrothermal activation on the physicochemical properties and mineralization efficiency of fly ash-supercritical CO2

To address the challenge of low mineralization efficiency of fly ash-supercritical carbon dioxide (CO2), a hydrothermal activation method was proposed to enhance fly ash-supercritical CO2 mineralization. The study systematically investigated the mechanism through which hydrothermal activation parameters influenced the efficiency of fly ash-supercritical CO2 mineralization through a series of experimental reactions. The effects of hydrothermal activation temperature and time on mineralization efficiency were investigated macroscopically. The results indicated that the mineralization efficiency increased by 202.93 % when hydrothermally activated at 220 °C for 30 min. Furthermore, when the activation time was ≤10 min, 220 °C exhibited a significant effect on the mineralization efficiency. For activation time ≥20 min, mineralization efficiency exhibited high stability with increasing temperature. Subsequently, under 220 °C conditions, mineralization efficiency reached 18.79 % for 5 min and 21.69 % for 30 min, representing only a 15.43 % increase despite a six-fold increase in time. Microscopic analysis of the pore structure of hydrothermally activated fly ash indicated that pore parameters (volume, specific surface area, and volume change rate) exceeded those of original fly ash for pore diameters ≥9 nm, and the opposite was observed for pore diameters <9 nm. Additionally, compared with the pristine fly ash, the pore size and volume fraction of the mineralized fly ash macropores increased, while mesopores decreased, and small pores exhibited a slight decrease in volume fraction and size. This indicated that pores ≥9 nm were primarily affected by hydration expansion, while pores <9 nm were primarily affected by mineralization precipitation. The hydrothermal activation mineralization reaction predominantly affected medium and large pores ≥9 nm, exhibiting less effect on smaller pores.

Synthesis of Geopolymers Incorporating Mechanically Activated Fly Ash Blended with Alkaline Earth Carbonates: A Comparative Analysis

Synthesis of Geopolymers Incorporating Mechanically Activated Fly Ash Blended with Alkaline Earth Carbonates: A Comparative Analysis

MANFAAT AKTIVASI FLY ASH BATU BARA DENGAN VARIASI KONSENTRASI NAOH SEBAGAI ADSORBEN

Water is one of the most important natural resources for human life. However, there are some problems that cause water to get polluted and not be used properly, one of which is the liquid waste of the hydrocarbon industry. Fly ash is a residue from coal combustion. Fly ash can be used as an adsorbent to reduce the content of hazardous fluid waste that could threaten human life. The study aims to find out the best NaOH concentration ratio between 1 M and 3 M added to activate fly ash against COD decrease, BOD, TSS, pH, and color change in Kutawaru Cilacap battery waste. The study passes through several stages, namely the first phase of activation of fly ash with NaOH at concentration ratios of 1M and 3M with a ratio of 1:5 for 3 hours. Then, in the adsorption process, the activated fly ash is mixed with battery liquid waste. The final phase is the testing of batik waste at the DLH Cilacap. The results obtained are at the concentration of 1M NaOH because it can reduce COD, BOD, and TSS up to 76%. With the result of COD of 3286 mg/L, BOD of 4921 mg/L, and TSS of 115 mg/L, whereas the results of concentration 3M, with COD of 3615 mg/L, COD 5397 mg/L, and TSS of 36 mg/L, PH for both these concentrations of 8 and the change in color of waste batik that remains black concentrated.

Strength characteristics of self-compacting concrete with alkali-activated fly ash

The primary goal of this study is to examine the impact of sodium hydroxide (NaOH)/alkali-activated fly ash on the fresh properties and mechanical properties of self-compacting concrete (SCC). The fresh properties, known as the workability of SCC characteristics, were determined using the U-box, V-funnel, J-ring, and L-box tests. The M30 grade SCC containing superplasticizer of 0.86 wt. % of cement is replaced with 10%, 15%, 20%, 25%, 30%, and 40% of alkali-activated fly ash. On days 7, 14, and 28 after curing, the compressive strength and the splitting tensile strength of the SCC were examined. The study was further extended to evaluate the behavior of reinforced concrete beams containing fly ash and ground granulated blast furnace slag, whose size was 1200 × 100 × 150 mm3, under flexure loading. Based on the test results, it was found that the increase in the replacement of cement with alkali-activated fly ash increased the workability in the SCC. With the addition of superplasticizers, the SCC gained much more workability than conventional concrete containing no superplasticizer. The mechanical properties of 10% and 15% activated fly ash in Portland cement provided the maximum strength for the SCC at different ages of curing. The maximum first crack load and maximum ultimate flexure loading of the reinforced concrete beam containing 10% activated fly ash by weight of cement were greater than those of the control concrete beam. The microstructural scanning electron microscope observations confirmed that the alkali-activated fly ash increased the strength properties of the self-compacting concrete.

Synthesis and Surface Strengthening Modification of Silica Aerogel from Fly Ash.

This study focuses on using activated fly ash to preparate silica aerogel by the acid solution-alkali leaching method and ambient pressure drying. Additionally, to improve the performance of silica aerogel, C6H16O3Si (KH-570) and CH3Si(CH3O)3 (MTMS) modifiers were used. Finally, this paper investigated the factors affecting the desilication rate of fly ash and analyzed the structure and performance of silica aerogel. The experimental results show that: (1) The factors affecting the desilication rate are ranked as follows: hydrochloric acid concentration > solid-liquid ratio > reaction temperature > reaction time. (2) KH-570 showed the best performance, and when the volume ratio of the silica solution to it was 10:1, the density of silica aerogel reached a minimum of 183 mg/cm3. (3) The optimal process conditions are a hydrochloric acid concentration of 20 wt%, a solid-liquid ratio of 1:4, a reaction time of two hours, and a reaction temperature of 100 °C. (4) The optimal performance parameters of silica aerogel were the thermal conductivity, specific surface area, pore volume, average pore size, and contact angle values, with 0.0421 W·(m·K)-1, 487.9 m2·g-1, 1.107 cm3·g-1, 9.075 nm, and 123°, respectively. This study not only achieves the high-value utilization of fly ash, but also facilitates the effective recovery and utilization of industrial waste.

Effect of Precursor Blending Ratio and Rotation Speed of Mechanically Activated Fly Ash on Properties of Geopolymer Foam Concrete

This research used fly ash and slag to create geopolymer foam concrete. They were activated with an alkali, resulting in a chemical reaction that produced a gel that strengthened the concrete’s structural integrity. The experimental approach involved varying the fly ash content in the precursors at incremental percentages (10%, 30%, 50%, 70% and 90%) and subjecting the fly ash to mechanical activation through a planetary ball mill at distinct rotational speeds (380, 400, 420 and 440 rpm). The investigation discerned that the fly ash content and particle structure exert a discernible influence on macroscopic properties, including flowability, air generation height, compressive strength, dry density and microstructural characteristics such as pore distribution and hydration product arrangement in the geopolymer foam concrete. Employing analytical techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM), it was deduced that diminishing the fly ash content correlates with an enhancement in compressive strength. Furthermore, the specific strength of the geopolymer foam concrete reached a peak of 0.041 when the activated fly ash in the planetary ball mill rotated at 420 rpm, manifesting a lightweight and high-strength outcome.

Novel process for facile preparation of mesoporous silica-based materials with controllable pore structure from coal fly ash

Extraction of silica from fly ash to produce mesoporous silica materials is one of the most important utilization approaches. Mesoporous silica could not be synthesized on a large-scale by conventional sol-gel method. In this paper, facile preparation of mesoporous silica with controllable pore structure from fly ash by the template-free process via two steps of mineral phase transformation and selective acid etching was proposed. The influence of crystalline structure and acid etching degree on structure of as-synthesized mesoporous silica materials was revealed, as well as mechanism of crystalline structure transformation and pore structure formation. The results show that mullite and quartz could be transformed into acid-soluble kaliophilite when fly ash reacted with K2CO3 at temperature of 800–1100 °C. The hexagonal kaliophilite would be transformed into orthorhombic KAlSiO4–O1 phase when the temperature is controlled at 1100 °C. Mesoporous silica with specific surface area of 475.93 m2/g and 642.57 m2/g could be synthesized from activated fly ash with kaliophilite and KAlSiO4–O1 phase crystalline structure. By controlling the degree of acid etching, mesoporous silica materials with different pore structures can be obtained. This paper provides a cost-effective and large-scale process for the preparation of mesoporous silica materials with controllable pore structure from solid waste fly ash.

Applicability of waste foundry sand stabilization by fly ash geopolymer under ambient curing conditions

Recently, utilizing industrial waste in the construction industry has gained significant attention to meet sustainability demands and mitigate the adverse environmental impacts caused by the construction industry. This study evaluates the engineering properties of waste foundry sand as a target material after stabilization with an environmentally friendly stabilizing agent (fly ash geopolymer), focusing on achieving adequate strength under ambient curing conditions as a feasible choice for road bases in geotechnical applications. While fly ash geopolymer application is typically linked with temperature curing, this research explores its application under ambient curing to enhance feasibility and reduce production costs. The fly ash geopolymer was synthesized by activating fly ash using a combination of sodium hydroxide and sodium silicate. The experimental program investigated the geopolymer-stabilized waste foundry sand at varying dosages of 7, 15, and 25 %, examining physical properties, non-destructive tests, mechanical properties, XRD phase analysis, and SEM observation. The results demonstrated that increasing fly ash dosage significantly enhanced the physical properties, mechanical properties, and microstructure of the geopolymer-stabilized waste foundry sand samples. Dry density improved from 1.75 to 2.02 g/cm3; longitudinal wave velocity increased from 897.3 to 2028.4 m/s, and unconfined compressive strength rose from 109 to 5261 kPa. Notably, only samples with 25% fly ash achieved the requisite strength to satisfy the road base limit (4100 kPa). These outcomes instill confidence in the potential use of waste foundry sand as a construction material and transition it from mere filling material to a valuable resource, furthermore encouraging the adoption of fly ash geopolymer as an environmentally friendly stabilizing agent in geotechnical applications.

Rapid and inexpensive method for bisphenol a detection in water samples based on alkaline activated fly ash modified carbon paste electrode

Rapid and inexpensive method for bisphenol a detection in water samples based on alkaline activated fly ash modified carbon paste electrode

Efek Molaritas Aktivator (NaOH) pada Beton Geopolymer dengan Bahan Pengikat Limbah Fly Ash PLTU Lontar

The average temperature of the earth's surface has increased by 0.74 ± 0.18°C over the past hundred years, caused by 65% carbon dioxide (CO2) emissions. Of the total CO2 emissions, around 6% come from the cement industry. Geopolymer concrete can be a solution to the problem because it does not use cement as a binder, but uses fly ash and activator materials. This activator material is to activate fly ash to become a binder. The aim of this study was to determine the effect of variations in the molarity of the NaOH activator on the workability, setting time, and compressive strength of geopolymer concrete. This study used fly ash from PLTU Lontar with a ratio of NaOH:NNa2SiO3 of 1:1.5, then the NaOH was varied with concentration levels of 5 Molar, 8 Molar, 11 Molar, and 14 Molar. From this research, it is known that the molarity level of the activator (NaOH) affects the workability (slump value), setting time, and compressive strength of concrete. The higher the molarity level of the activator (NaOH), the lower the workability of the concrete (the slump value decreases), the slower the setting time of the concrete, and the higher the compressive strength of the concrete. The most optimal variation is 14 Molar NaOH geopolymer with a slump value of 15 cm, initial setting time of 90 minutes, final setting time of 203 minutes, and compressive strength at 28 days of 54.60 MPa.