The mechanoluminescent materials attract increasing attention of scientists due to their capability of visualizing the mechanical stresses and deformations experienced by them. The deformations of materials arising under the action of powerful laser pulses were studied. The composite mechanoluminescent materials based on the polymer and phosphor powder were used for visualization and registration of deformation evolution dynamics. The mechanoluminescent materials were deposited on the surface of the materials under study. It has been shown that the spatial distribution of glow intensity of the mechanoluminescent layer and the rate of its change make possible judging the value and rate of material deformation under laser pulses.