Acrylonitrile Polymers Research Articles

The effect of high-intensity gamma radiation on PETG and ASA polymer-based fused deposition modelled 3D printed parts

There is growing interest in the application of 3D printing for demanding environments subject to gamma radiation in areas such as the nuclear industry and space exploration. In this work, the effect of gamma radiation on fused deposition modelled 3D printed parts composed of polyethylene terephthalate glycol (PETG) and acrylic styrene acrylonitrile (ASA) polymers was studied. Dose levels of up to 2.25 MGy were applied to the printed components, doses equivalent to over 1 year operating near spent nuclear fuel cells. Infrared spectroscopy showed the evidence of cross-linking by the formation of peaks corresponding to –OH and C–H bonds. Tensile and hardness testing was used to assess changes in mechanical properties and showed a reduction in ultimate tensile stress and maximum strain in parts made from both polymers, but with PETG retaining greater strength and ductility than ASA, especially at intermediate gamma exposure. Young’s modulus and hardness showed either modest increases or a fairly flat response with exposure. Mechanical properties were heavily dependent on the build structure, with horizontal build samples pulled parallel to the filament direction being several times stronger than vertical build samples pulled normal to the layers. Non-irradiated samples pulled parallel to the filament direction were indicative of ductile failure, with rough surfaces, distinct infill and wall regions and evidence of thinning occurring after fracture, but irradiated fracture surfaces were flatter, smoother and without local thinning, suggesting gamma radiation-induced embrittlement in the material. For samples pulled perpendicular to the filament direction, all fractures occurred between layers, creating flat fracture surfaces with no evidence of necking and indicative of brittle failure regardless of whether the samples were irradiated.

Application of Polymer Materials and Additive Technologies in Electrical Equipment of the Agro-Industrial Complex

Additive polymer technologies are widely used in the agro-industrial complex. Modeling by the method of layer-by-layer deposition is in demand today. The most popular polymer materials for FDM (Fused Deposition Modeling) / FFF (Fused Filament Fabrication) printing are acrylonitrile butadiene styrene, polycarbonate, polymethylmethacrylate, polyamide PA-6 and polymer composites based on them. (Research purpose) The research purpose is in studying the prospects of using additive polymer technologies in agriculture, taking real cases as a basis. (Materials and methods). The article presents the analyze of open information sources. Author used methods of collecting, studying and comparative analysis of information, considered real cases carried out with the use of the material and technical base of the FNAC VIM. (Results and discussion) The domestic market of polymer materials and composites based on them for 3D printing using FDM/FFF technology is not as diverse as similar for traditional methods of processing plastics and composite materials (injection molding, extrusion, pressing and others). The reason for this is the lack of knowledge of 3D printing technologies, in particular, FDM/FFF technology, as a method of plastics processing. The main factor in the development of additive polymer technologies in the agro- industrial complex is the growing demand for the use of 3D printing. The article proves the effectiveness of the application with real cases made as a result of the close work of several research laboratories of FNAC VIM. (Conclusions) Additive manufacturing has great potential for further development, including within the agro-industrial complex. FDM/FFF technology and additive polymer technologies in general perfectly complement traditional production technologies.

Preparation and characterization of novel Yellow-Green fluorescent polymerizable dye and its copolymer with application of highly selective sensor for cations iron

PurposeIn this work, A new 4–(2-aminoethylene) amino-N-(2-hydroxyethyl)-1,8-naphthalimide with intense green fluorescent was synthesized. This low molecular weight compound was immobilized by forming a covalent-bond with an acrylonitrile polymer containing carboxylic acid groups. The new prepared dye and self-coloured polymer were characterized by analytical techniques.Design/methodology/approachThe synthesized compounds were characterized by TLC, DSC, FTIR, 1HNMR, 13CNMR, GPC, UV–visible and Fluorometery. The photophysical characteristics of the dye and polymer containing naphthalimide moiety in the side chain, were measured both in the absence and in the presence of Ag+, Cd+2, Co+2, Cr+3, Cu+2, Fe+3, Hg+2, Ni+2, Pb+2 and Zn+2 cations.FindingsThe results showed that the characterization of the synthesized dye and its polymer verified their structural correctness. It is shown that dye and polymer are photo-induced electron transfer (PET) fluorescent sensors which exhibit fluorescence quenching in the presence of metal ions. Among the various metal ions, both dye and polymer are more sensitive to Fe+3 cations.Originality/valueThis study is original. A 4–(2-aminoethylene) amino-N-(2-hydroxyethyl)-1,8-naphthalimide and its self-coloured polymer were synthesized for the first time, successfully.

Analysis of various polymer parts in contact with biodiesel

<p>In this paper, several parts consisting of polymeric materials are studied, in order to determine if they are affected when they are kept in contact with biodiesel at constant temperature and pressure. The samples used are constituted by polymers of silicone (S), acrylonitrile (AN) and propylene hexafluor (Viton-V7). These materials have been selected for investigation because they form part of an industrial process in which they are used, and have been observed early wear characteristics thereof. They consist of seals and cords which are in contact with biodiesel. These materials were kept immersed in biodiesel at atmospheric pressure at a temperature of 40°C for time periods up to 120 days. Virgins tested ones are characterized by various techniques: OM, SEM, XRD, DTA-TGA, among others. Viton sample was the least affected by treatment, while the acrylonitrile sample is the one that has shown the greatest variations.</p>

Acrylic polymers for conditions of weakly acid conversion to resins, complex syntheses

The paper presents materials on the conversion of acrylic monomers to acrylic polymers. Similarly, polymers and copolymers obtained from acrylonitrile were prepared. On the basis of the results of quantum chemical calculations, the parameters of polymer and copolymer materials were established, which will make it possible to evaluate the possibilities of complexes of acrylonitrile polymers for the production of membranes.

Polymers of vinylphosphonic acid, acrylonitrile, and methyl acrylate and their nanofibers

AbstractIn this study, a small amount of vinylphosphonic acid was used to produce fire‐retardant copolymers and terpolymers from acrylonitrile and methyl acrylate. The structures of copolymer and terpolymers were elucidated by 1H‐NMR and phosphorous analysis. Thermal decomposition of vinylphosphonic acid‐containing copolymers and terpolymers started at lower temperatures than of poly(acrylonitrile‐co‐methyl acrylate). Methyl acrylate contributes to the thermal resistance of the terpolymers. Poly(acrylonitrile‐co‐methyl acrylate‐co‐vinylphosphonic acid) with a phosphorous content about 0.25% burned at a slower rate and emitted less smoke compared to poly(acrylonitrile‐co‐methyl acrylate). The burning tests showed that both copolymer and terpolymers containing vinylphosphonic acid behaved as a fire‐retardant polymer. The phosphonate and phosphonic acid groups in the copolymer and terpolymers accelerate the cyclization of nitrile groups and inhibit the fire in the gas phase. Nanofibers were successfully produced by the electrospinning method from the copolymers and terpolymers containing vinylphosphonic acid moiety.

TAP/GMA@CN metal-chelating membrane for enhanced and efficient capture of Cu(II)

A novel metal-chelating membrane (MCM) capable of efficient Cu(II) rejection was synthesized by grafting glycidyl methacrylate into acrylonitrile polymers and then performing amination using eco-friendly 2,4,6-triaminopyrimidine. The MCM exhibited a pure water flux of 283 L m−2 h−1, a bovine serum albumin rejection of 95%, and a flux recovery ratio of 85%. A filtration study showed that the effective treatment volume of MCM for Cu(II) removal was 55.4 L m−2, which was 6.2 times those of blend membranes. This increase can be ascribed mainly to the presence of amino and carboxylic groups. The treatment volume of Cu(II) was further increased by a factor of 2 in the presence of tartaric acid (TA) in water through both rejection of the Cu(II)-TA complex and the bridging interaction of adsorbed TA. The MCM could be recovered using a 0.1 M HNO3 solution and remained usable for treatment of simulated wastewater. Therefore, the MCM may be able to efficiently remove heavy metal ions from wastewater in the presence of organic acids.

Investigation on thermal properties of Styrene Acrylonitrile (SAN) matrix with Polytetrafluroethylene (PTFE) particle reinforced composites

Temperature utilization of composites materials depends on its thermal conductivity and co-efficient of thermal expansion. Polymers are exceptionally combustible because of their structure and they can’t fulfill a few applications. Thermal treatment of soften polymer because of the preparing setup by injection molding fabrication process able to control polymer structure (fitting) and in this manner deciding its thermal conduct. The fundamental point of this work is to contemplate the impact of Polytetrafluroethylene polymer (PTFE) as particle with Styrene Acrylonitrile polymer (SAN) as matrix to examine its thermal properties. Samples of 100% SAN and 10% PTFE by weight, 20% PTFE by weight blended specimens with SAN are prepared successfully by Injection molding process. Heat capacity, Thermal expansion, Thermal conductivity and Thermal degradation are the thermal properties examined. From the observations it was found that PTFE particles blended samples exhibits maximum thermal conductivity and good dimensional stability.

Compressive strength after blast of sandwich composite materials

Composite sandwich materials have yet to be widely adopted in the construction of naval vessels despite their excellent strength-to-weight ratio and low radar return. One barrier to their wider use is our limited understanding of their performance when subjected to air blast. This paper focuses on this problem and specifically the strength remaining after damage caused during an explosion. Carbon-fibre-reinforced polymer (CFRP) composite skins on a styrene–acrylonitrile (SAN) polymer closed-cell foam core are the primary composite system evaluated. Glass-fibre-reinforced polymer (GFRP) composite skins were also included for comparison in a comparable sandwich configuration. Full-scale blast experiments were conducted, where 1.6×1.3 m sized panels were subjected to blast of a Hopkinson–Cranz scaled distance of 3.02 m kg−1/3, 100 kg TNT equivalent at a stand-off distance of 14 m. This explosive blast represents a surface blast threat, where the shockwave propagates in air towards the naval vessel. Hopkinson was the first to investigate the characteristics of this explosive air-blast pulse (Hopkinson 1948 Proc. R. Soc. Lond. A 89, 411–413 (doi:10.1098/rspa.1914.0008)). Further analysis is provided on the performance of the CFRP sandwich panel relative to the GFRP sandwich panel when subjected to blast loading through use of high-speed speckle strain mapping. After the blast events, the residual compressive load-bearing capacity is investigated experimentally, using appropriate loading conditions that an in-service vessel may have to sustain. Residual strength testing is well established for post-impact ballistic assessment, but there has been less research performed on the residual strength of sandwich composites after blast.

Super Absorbent Polymer (SAP) and Irrigation Water Conservation

Human activities require more and more resources- among them water is certainly the most precious. Modern agriculture consumes almost two thirds of the water pumped in United States. For this reason, more and more people are seeking ways to conserve it. In the quest for improving water conservation in soils during irrigation, the United States Department of Agriculture (USDA) conducted studies on various materials in the early 1960s. As a result, a resin based on the grafting of acrylonitrile polymer onto the backbone of starch molecules (starch-grafting) was developed, which was known as ?Super Slurper?. At the time, the USDA gave the basic technology to several USA companies for further development. As the Japanese companies were excluded from participating, they started independent research using starch, carboxy methyl cellulose (CMC), acrylic acid, polyvinyl alcohol (PVA) and isobutylene maleic anhydride (IMA). The hydrolyzed product of the hydrolysis of this starch-acrylonitrile co-polymer gave water absorption greater than 400 times its weight and did not release water as fiber-based absorbents do. Could super absorbent polymer (SAP) be the future of irrigation water conservation?

New procedure for preparation of highly stable and well separated carbon nanotubes in an aqueous modified polyacrylonitrile

AbstractCarbon nanotubes (CNTs) due to their nonreactive surface can not effectively disperse in polymeric matrix. Efficient exploitation of CNTs properties to improve material performance is generally related to the degree of dispersion, saturation by the matrix and interfacial adhesion. In order to obtain a suitable dispersion, the CNTs usually need treatment before they can be utilized. In this work, an easy procedure for preparation a stable dispersion of well separated and individual CNTs in an aqueous polymeric solution by using of Gum Arabic (GA) and modified polymer has been described. The applied polymer was a modified water soluble acrylonitrile polymer. The modification was carried out through functionalizing polyacrylonitrile by 2‐aminoethanol. Individual dispersion of the CNTs in the aqueous GA solution after two month can be observed. By incorporating the modified polyacrylonitrile to the solution, the stability of the individual CNTs dispersion several times was increased in such a way that after six month, the CNTs were still kept at their individual positions. According to the suggested mechanism of dispersion, hydrogen bonds between GA/CNTs and the modified polyacrylonitrile chains can be formed that increasing the dispersion ability. The effects of salts and temperature on dispersion ability of GA were also studied.

Reverse atom transfer radical polymerization of acrylonitrile under microwave irradiation

AbstractReverse atom transfer radical polymerization was first used to successfully synthesize polyacrylonitrile under microwave irradiation. FeCl3, coordinated by isophthalic acid, was used as the catalyst, and 2,2′‐azobisisoheptonitrilewas used as the initiator. N,N‐Dimethylformamide was used as the solvent to improve the solubility of the ligand. Under the same experimental conditions, the apparent rate constant under microwave irradiation was higher than that under conventional heating. The polymerization not only showed the best control of the molecular weight and its distribution but also provided a rather rapid reaction rate with the [acrylonitrile]/[2,2′‐azobisisoheptonitrile]/[FeCl3]/[isophthalic acid] ratio of 300 : 1 : 1 : 2. The polymers obtained were used as macroinitiators to initiate the chain extension and successfully synthesize acrylonitrile polymers with a molecular weight higher than 50,000 and a narrow polydispersity as low as 1.30. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008

Consistency and variations in optical characteristics of four-layer polymeric waveguides

In the present work, four-layer polymeric waveguides have been fabricated and characterized by interchanging the film layer. Using polyvinyl alcohol (PVA) and styrene acrylonitrile (SAN) polymer it has been shown that polymers do not loose their own property in multilayer structure and better efficiency can be achieved in the form of low propagation losses and mode filtration. Due to high contrast of PVA and SAN films, a broad spectrum of refractive index in four-layer structure has been achieved.

Determination of degradation rate of acrylonitrile polymers

AbstractLow‐temperature degradations of acrylonitrile homopolymers and acrylonitrile/acrylamide copolymers in air were investigated by IR and thermogravimetry. The degradation rates of acrylonitrile polymers were determined by measurement of normalized absorbance of CN band and effects of the degradation temperature, time, and comonomer on the rate of degradations were discussed. It was found that the polymers start to degrade as the temperature increased to 150°C. In the temperature range of 180–210°C, values of the rate of polymer degradation were maximal and the rate of degradation of acrylonitrile/acrylamide copolymers was higher compared with that of acrylonitrile homopolymers. At 150°C, acrylonitrile homopolymers had an induction period of about 0.5 h. The rate of degradation of acrylonitrile/acrylamide copolymers showed an obvious trend of increase along with acrylamide concentration, and changes of the rate became less prominent as the weight ratio of acrylamide/acrylonitrile went beyond 5/95. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1511–1514, 2006

Biocompatibility Study Based on Differential Sequestration Kinetics of CD14+CD16+ Blood Monocyte Subsets with Different Dialyzers

The immune defect in hemodialysis (HD) patients is associated with a monocyte dysfunction, including an increase in the production of proinflammatory cytokines. Blood membrane contact leads to an increase in cellular activation and sequestration into the capillary bed of the lung. The influence of the sequestration on the number of mature monocytes was studied by analyzing the fate of monocytes, particularly, the CD14+CD16+ subpopulation, during HD treatment.In thirty stable HD patients, the distinct cell populations were determined by differential blood counts and flow cytometry. Patients with diabetes or systemic vasculitis, those showing evidence of infectious complications or malignancy, or those taking immunosuppressive medications were excluded from the study. Cells from this study population were analyzed before the start, 30 min thereafter, and at the end of HD treatment, each time using a different dialyzer: hemophan, methylmethacrylate (PMMA), triacetate membrane, cuprophane/vitamin E, acrylonitrile, and sodium methallylsulfonate polymer (AN69).The CD14+CD16+ subset decreased at 30 min and remained suppressed for the course of dialysis. To examine whether currently used biocompatible membranes differ in their effect on the sequestration of monocyte subpopulations, temporal monocytic changes were comparatively analyzed during HD with a different dialyzer. The drop in the first 30 min until the end of HD treatment was significant (p<0.05), very uniform, and sharp in all patients, and was independent upon membrane type.The CD14+CD16+ monocyte subpopulation showed increased and longer margination from the blood circulation during HD. Given the fact that CD14+CD16+ monocytes represent a sensitive marker for inflammation or cellular activation, the depletion of these cells may offer an easily accessible parameter that is more sensitive than complement activation for biocompatibility studies on forthcoming, improved dialyzer membranes.

Synthesis of polyacrylonitrile via reverse atom transfer radical polymerization catalyzed by FeCl3/isophthalic acid

AbstractFeCl3 coordinated by isophthalic acid was first used as a catalyst in the azobisisobutyronitrile‐initiated reverse atom transfer radical polymerization of acrylonitrile. N,N‐Dimethylformamide was used as a solvent to improve the solubility of the ligand. An FeCl3‐to‐isophthalic acid ratio of 0.5 not only gave the best control of the molecular weight and its distribution but also provided rather a rapid reaction rate. The effects of different solvents on the polymerization of acrylonitrile were also investigated. The rate of the polymerization in N,N‐dimethylformamide was faster than that in propylene carbonate and toluene. The molecular weight of polyacrylonitrile agreed reasonably well with the theoretical molecular weight in N,N‐dimethylformamide. The rate of polymerization increased with increasing polymerization temperature, and the apparent activation energy was calculated to be 59.9 kJ mol−1. Reverse atom transfer radical polymerization was first used to successfully synthesize acrylonitrile polymers with a molecular weight higher than 80,000 and a narrow polydispersity as low as 1.22. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 219–225, 2006

Encyclopedia of polymer science and technology

VOLUME 1. Acetylenic Polymers, Substituted. Acrylamide Polymers. Acrylic (and Methacrylic) Acid Polymers. Acrylic Ester Polymers. Acrylonitrile and Acrylonitrile Polymers. Acrylonitrile-Butadiene-Styrene Polymers. Additives. Adhesion. Adhesive Compounds. Aging, Physical. Alkyd Resins. Am,ino Resins and Plastics. Antifoaming Agents. Atomic Force Microscopy. Biotechnology Applications. Bloack Copolymers. Bloack Copolymers, Ternary Triblock. Blow Molding. Chitin and Chitosan. Chromatography, Affinity. Chromatography, HPLC. Chromatography, Size Exclusion. Coating Methods, Survey. Coatings. VOLUME 2 Coextrusion. Colorants. Coloring Processes. Composites, Fabrication. Conformation and Configuration. Critical Phase Polymerizations. Cyclohexanedimethanol Polyesters. Dendronized Polymers. Dental Applications. Diacethylene and Triacethylene Polymers. Elasticity, Rubber-Like. Electronic Packaging. Electrooptical Applications. Engineering, Thermoplastics, Overview. Enzymatic Polymerization. Ethylene Polymers, Chlorosulfonated. Ethylene Polymers, HDPE. Ethylene Polymers, LDPE. Ehtylene Polymers, LLDPE. Ethylene-Acrylic Elastomers. Ethylene-Norbornene Copolymers. Extrusion. Films, Orientation. Fluorocarbon Elastomers. Fractography. Fracture. Glass Transition. Hardness. Hydrogels. Hyperbranched Polymers. VOLUME 3 Injection Molding. Inorganic Polymers. Laser Light Scattering. Light-Emiting Diodes. Lignin. Liquid Crystalline Polymers, Main-Chain. Liquid Crystalline Thermosets. Mass Spectrometry. Membrane Technology. Methacrylic Ester Polymers. Micromechanical Properties. Modeling of Polymer Processing and Properties. Nanocomposites, Polymer-Clay. Packaging, Flexible. Perfluorinated Polymers, Perfluorinated Ethylene-Propylene Copolymers. Perfluorinated Polymers Polytetrafluoroethylene. Perfluorinated Polymers Tetrafluoroethylene-Ethylene Copolymers. Perfluorinated Polymers, Tetrafluoroethylene-Perfluorinated Copolymers. Perfluorinated Polymers. Tetrafluoroethylene-Perfluorovinyl Ether Copolymers. Phosgene. Phosphorus-Containing Polymers and Oligomers. Piezoelectric Polymers. Plasticizers. Poly(3-Hydroxyalkanoates). Poly(Trimethylene Terephthalate). Polyamides, Atomatic. Polyamides, Fibers. Polyamides, Plastics. Polycyanoacrylates. Polyesters, Fibers. Polyketones. Polynucleotides. Polysulfides. VOLUME 4 Polysulfones. Polyurethanes. Pressure-Sensitive Adhesive. Reinforcement. Release Agents. Shape-Memory Polymers. Single-Site Catalysis. Stabilization. Styrene-Butadiene Rubber (SBR). Styrene Polymers. Sulfur-Containing Polymers. Surface Properties. Syndiotactic Polystyrene. Vinyl Fluoride Polymers (PVF). Vinylidene Chloride Polymers. Vinylidene Fluoride Polymers. Viscoelasticity. Weathering.

Structural investigations of acrylonitrile–vinyl acid copolymers by NMR spectroscopy

Abstract1H, 13C [1H]‐, and 2D HETCOR NMR spectroscopy have been employed to characterize polyacrylonitrile (PAN) homopolymer and copolymers of methacrylic acid (MAA) and itaconic acid (IA) prepared by solvent–water suspension polymerization technique in a mixture containing DMF (solvent) and water. The chemical composition of P(AN–MAA) copolymers was determined using 1H‐NMR and that of P(AN–IA) using quantitative 13C[1H]‐NMR spectra. P(AN–IA) copolymers show two separate signals due to two carboxylic groups in different magnetic environments of IA, whereas P(AN–MAA) shows only one in the region of δ 6.32–7.60 ppm in 1H‐NMR and δ 171.0–176.0 ppm in 13C[1H]‐NMR spectra. Evidence of acrylamide formation by the partial hydrolysis of AN groups is obtained by the small broad signal at δ 7.9 ppm in 1H‐NMR spectra. No carboxylic proton signal was observed in copolymers containing 12 mol % of comonomer, which indicates the formation of anhydride. The microstructure was obtained in terms of the A‐ and M‐centered triad sequences from 13C[1H]‐and 1H‐NMR spectra of the copolymers, which showed configurational and compositional sequences. For example, at higher comonomer content, the concentration of AAM and AAI sequencing increases. This is confirmed by 2D HETCOR NMR spectra also. The distribution of AN sequences is found to be random (n0 ∼ nm ≃ 2.0). The tacticity values are not affected by the comonomer content. The isotacticity remained almost same at 27% (mm, 26.5–29.3) in all acrylonitrile polymers irrespective of the nature of the comonomer and polymerization medium, that is, DMF/H2O ratio. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1211–1217, 2003

Effects of Technical Adsorbents and Cleaning Agents in a Cement Matrix – A Case Study

ABSTRACTThe effects of organic cleaning agents (totally three) and degradation products from solid technical adsorbents (two) on the sorption of Eu on cement and TiO2 were measured with variation of concentration (0.001–10 % of the water phase for the cleaning agents, alkaline degradation products corresponding to 0.03–8 mM DOC for the adsorbents) and reaction time (up to 420 d). The effects of the cleaning agents Industrikombi and Prefect Citron were minor. The degradation of the ion exchanger (metaacrylic polymer) had no significant effect on the Eu-sorption. The other adsorbent (filter aid, inert fibre; acrylonitrile polymer) was rapidly degrading at high pH, and the degradation products had a significant reducing effect on the sorption of Eu at added DOC-levels in the mM-range. This category of adsorbent materials should not be incorporated in a cement waste matrix or be stored in a cementitious environment together with radionuclides.

Broadband Electromagnetic Shields Using Polyaniline Composites

Electromagnetic interference behaviour of conducting polyaniline composites in the radio frequency range X, Ku, and Ka bands is presented. Methods for determining the conductivity and the shielding effectiveness are discussed. The conducting composites are made from CSA-doped polyaniline blended with the styrene acrylonitrile host polymer. The samples exhibit high conductivities, up to 104 S.m−1, and therefore are compatible with an electromagnetic shielding application. The percolation threshold is very low—below 1% of mass fraction of polyaniline in the blend—and the shielding effectiveness is up to 70 dB, depending on the sample.