Acrylic-based Material Research Articles

The use of polyetheretherketone material as an occlusal splint

Occlusal splint is a treatment alternative that gives positive results in reducing the symptoms of temporomandibular diseases. This treatment involves placing an appliance made of various materials specifically for the cutting and chewing surfaces of the teeth. The most popular materials used in the construction of occlusal splints are soft and hard acrylic-based materials such as polymethylmethacrylate, ethylene vinyl acetate, polycarbonate, polyethylene terephthalate and polyetheretherketone. PEEK is a high performance, semi-crystalline, thermoplastic and thermally stable polymer belonging to the polyaryletherketone family. PEEK, which has very good dimensional stability against intraoral temperature changes, is not affected by the intraoral chemical environment. Since PEEK material is chemically stable, has high biocompatibility and abrasion resistance, its use as an occlusal splint material has become widespread today. The aim of this review is to provide information about occlusal splints produced using PEEK material and digital procedures, which are becoming increasingly popular in dentistry, and to contribute to the literature.

Stability analysis of multi-trigger nano tube sandwich structures considering thermal and magnetic effects

This research investigates the stability analysis of multi-trigger nanotube-based sandwich structures that carry fluid subjected to external stimulus. Acrylic-based material and magnetorheological elastomers (MRE) are considered multi-trigger cores in which the external stimulus alters the mechanical properties of the core and, subsequently, the sandwich structures. The system is subjected to an external magnetic field while the ambient temperature varies. The results demonstrate that incorporating a multi-trigger viscoelastic core can accelerate the divergence instability of the non-conservative system while delaying its flutter. Additionally, the impact of the external magnetic field, as a control parameter, for the frequency and stability region of the MRE is more significant than that of the Acrylic-based material. Furthermore, employing Acrylic-based material with a higher shear modulus in a constant magnetic field leads to a more stable system. Moreover, the effect of the external magnetic force on stability is affected smoothly by the ambient temperature. Finally, the influence of temperature on stability is nearly the same for both MRE and Acrylic-based material, with a more pronounced effect observed in systems with larger length-to-diameter ratios.

Effect Of Montmorillonite Incorporation on Shear Bond Strength And Surface Hardness Of Acrylic Base Soft Lining Material (In Vitro Study)

Abstract Objective: One problem with the soft lining material is that it detaches from the acrylic base of dentures after a particular time period. So, the aim of this work was to evaluate how adding Montmorillonite nano clay would affect the soft lining material's shear bond strength and surface hardness. Materials and Methods: The heat-cured acrylic denture material for the control group, polymer reinforced with (0.25%,0.5% by wt.) of montmorillonite nanoparticles for experimental groups was used in this study. For the shear bond strength test 60 blocks of acrylic-based material were constructed, each pair connected with soft lining material, the other 30 specimens for the surface hardness tests were carried out. to be tested with a shore A durometer. The data were statistically examined using the One-Way ANOVA test and Bonferroni multiple comparisons test. Result: 0.5% by weight MMTNPS should significantly increase in both shear bonding strength and surface hardness . Conclusion: MMTNPs were remarkably successful in improving the the strength of the shear connection between acrylic and soft liners.

Induced damage during STEM-EELS analyses on acrylic-based materials for Stereolithography

(Scanning) transmission electron microscopy, (S)TEM, offers a powerful characterization tool based on electron-matter interactions, highly valuable in materials science. However, the possible electron beam induced damage during (S)TEM measurements hinders the analysis of soft materials, such as acrylic resins. Importantly, acrylic resins offer an appealing playground for the development of novel composites with customized properties and convenient processing capabilities for 3D-printing technologies, including Stereolithography (SLA). There are several factors preventing the optimal performance of TEM measurements applied to acrylic resins, among which we focus on the quality of the analyzed specimen (i.e., compromise between thickness and robustness, to achieve electron transparency while keeping the material integrity), particularly challenging when working with soft materials; the electrostatic charging/discharging effects, resulting in sample drift and related noise/artefacts; and the radiolysis and knock-on electron-induced damage, which directly degrade the material under study. We explore and compare different methodologies to obtain resin specimens suitable for (S)TEM analysis, employed for the subsequent study of the electron–beam damage induced during STEM-EELS measurements. Furthermore, we propose likely underlying mechanisms explaining the acrylic resin degradation based on the different EELS monitored signals. On one hand, we assess the evolution of the carbon and oxygen content, as well as the material thinning as a function of the accumulated electron dose. On the other hand, we extract meaningful information from the spectral shape of carbon and oxygen K-edges upon increasing electron doses, unraveling likely degradation pathways. The earned understanding on the electron-beam induced damage and the determination of critical doses provide a useful framework for the implementation of (S)TEM techniques as useful tools to help in the smart engineering of acrylic-based composites for SLA.

Analysis of Changes in the Tensile Bond Strenght of Soft Relining Material with Acrylic Denture Material.

Abrasions and pressure ulcers on the oral mucosa are most often caused by excessive pressure or incorrect fitting of the denture. The use of soft relining materials can eliminate pain sensations and improve patient comfort. The main functional feature of soft elastomeric materials is the ability to discharge loads from the tissues of the mucosa. (1) Background: The aim of the work was a comparative laboratory study of ten materials used for the soft lining of acrylic dentures. (2) Methods: There were materials based on acrylates (Vertex Soft, Villacryl Soft, Flexacryl Soft) and silicones (Sofreliner Tough Medium, Sofreliner Tough Medium, Ufi Gel SC, GC Reline Soft, Elite Soft Relining, Molloplast). Laboratory tests include the analysis of the tensile bond strength between the relining material and the acrylic plate of the prosthesis. The tests were conducted taking into account 90-day term aging in the distilled water environment based on the methodology presented in the European Standard ISO 10139-2. (3) Results: After three months of observation, the highest strength of the joint was characterized by Flexacryl Soft acrylic, for which the average value was 2.5 MPa. The lowest average value of 0.89 MPa was recorded for the GC Reline Soft silicone material. Over time, an increase in the value of the strength of the combination of acrylic materials and a decrease in these values in the case of silicone materials was observed. (4) Conclusion: Each of the tested silicone materials showed all three types of damage, from adhesive to mixed to cohesive. All acrylic-based materials showed an adhesive type of failure. Time did not affect the type of destruction.

The Origins of Acrylates and Adhesive Technologies in Dentistry.

To examine the origins of acrylates and adhesive dentistry up to 1955. A search of MEDLINE database and a manual literature search were conducted to find relevant articles. Acrylic acid was discovered in 1843, methacrylic acid in 1865. In 1880, light polymerization of acrylate compounds using glass prisms was introduced. In 1928, polymethyl methacrylate (PMMA) was industrially produced from methyl methacrylate (MMA). In 1930, PMMA moldings that could be adapted under heat and pressure were introduced into dentistry. The process was improved in 1936 by mixing pulverized PMMA and liquid MMA. In 1940, the intraoral polymerization of dental resins using UV light or catalysts was discovered. In the same year, the combined procedure (dual-curing) and addition of inorganic fillers to improve the material properties (precursors of composites) were proposed. Effects on the oxygen inhibition layer and intraoral bonding between several resin portions were also described. In 1942, direct restorations with self-curing resins (combined with a precursory version of cavity sealing) were described. These new resins were marketed in the late 1940s. Intraoral repair of restorations and cementation of crowns and bridges with resins were also described in 1942. In 1949, a glycerophosphoric acid-based sealer was marketed. In the same year, it was discovered that etching of the enamel (with nitric acid) caused an adhesion to thin layers of acrylic-based materials. In 1955, phosphoric acid etching of enamel was shown to improve adhesion. In the first half of the 20th century, important but little or unknown discoveries took place. These discoveries can improve our understanding of how adhesive dentistry evolved.

Surface modification of corneal prosthesis with nano-hydroxyapatite to enhance in vivo biointegration

The majority of clinical corneal prostheses (KPros) adopt a core-skirt configuration. This configuration is favored owing to the optic core (generally a cylindrical, acrylic-based material, such as PMMA), that not only provides a clear window for the patients’ vision, but also confers resistance to biodegradability. The surrounding skirt (typically a biological material, such as corneal tissue) allows for host tissue integration. However, due to poor biointegration between the dissimilar core and skirt materials, it results in a weak adhesion at the interface, giving rise to clinical complications, such as bacterial infections in the tissue-PMMA interface and device extrusion. Here, we physically immobilized nano-hydroxyapatite (nHAp) on a PMMA cylinder via a dip-coating technique, to create a bioactive surface that improved biointegration in vivo. We established that the nHAp coating was safe and stable in the rabbit cornea over five weeks. More importantly, we found that apoptotic, wound healing and inflammatory responses to nHAp-coated PMMA were substantially milder than to non-coated PMMA. More mature collagen, similar to the non-operated cornea, was maintained in the corneal stroma adjacent to the nHAp-coated implant edge. However, around the non-coated cylinder, an abundant new and loose connective tissue formed, similar to bone tissue response to bioinert scaffolds. As a result of superior biointegration, tissue adhesion with nHAp-coated PMMA cylinders was also significantly enhanced compared to non-coated cylinders. This study set a precedent for the future application of the nHAp coating on clinical KPros. Statement of significanceCurrently, all clinical corneal prostheses utilize as-manufactured, non-surface modified PMMA optic cylinder. The bioinert cylinder, however, has poor biointegration and adhesion with the surrounding biological tissue, which can give rise to postoperative complications, such as microbial invasion in the tissue-PMMA loose interface and PMMA optic cylinder extrusion. In the current study, we showed that surface modification of the PMMA cylinder with bioactive nano-hydroxyapatite (nHAp) significantly enhanced its biointegration with corneal stromal tissue in vivo. The superior biointegration of the nHAp-coated PMMA was signified by a more attenuated corneal wound healing, inflammatory and fibrotic response, and better tissue apposition, as well as a significantly improved corneal stromal tissue adhesion when compared to the non-coated PMMA.

The effect of recycled coarse aggregate (RCA) with surface treatment on concrete mechanical properties

This paper discusses the recycling system for concrete needed due to environmental and resource preservation issues. Construction and demolition waste is one problem faced in the construction site. One feasible solution to overcome this problem is by utilizing construction and demolition waste as a recycled coarse aggregate (RCA). This study aims to observe concrete mechanical properties using RCA with surface treatment. Acrylic-based material is used to treat the surface of recycled coarse aggregate (RCA) by spraying it from two sides. It is found that the recycled aggregate with surface treatment may reduce water absorption from 7.96% to 2.96%. In addition, the concrete using RCA with surface treatment may improve the compressive strength, modulus of elasticity and split tensile strength.

Halogenation of β-estradiol by a rationally designed mesoporous biocatalyst based on chloroperoxidase

AbstractChloroperoxidase from Caldariomyces fumago was immobilized in Eupergit® C, a commercial mesoporous acrylic-based material. Due to low stability of the enzyme under neutral and basic pH, the usual covalent immobilization procedures cannot be applied to this enzyme. Several strategies were followed in order to achieve a stable interaction between the protein and the support. The support was efficiently functionalized with different reactive groups such as aromatic and aliphatic amines, glutaraldehyde, diazonium ions, and maleimide moieties; solvent-exposed amino acid residues in chloroperoxidase were identified or created through chemical modification, so that they were reactive under conditions where the enzyme is stable. Enzyme load and retained activity were monitored, obtaining biocatalysts with specific activity ranging from 200 to 25,000 U/g. The highest load and activity was obtained from the immobilization of a chemically-modified CPO preparation bearing a solvent-exposed free thiol group. This biocatalyst efficiently catalyzed the transformation of β-estradiol, an endocrine disruptor.

Biomaterials for ocular reconstruction

Synthetic materials have played a significant role in ophthalmic applications to improve vision for many years. This has been in four main areas in ophthalmology: ocular surface reconstruction, lens replacement, vitreous replacement and structural support and cell transplantation in the retina. Corneal replacement therapies have been developed using both synthetic acrylic-based materials and more recently naturally derived materials such as amniotic membrane. Intraocular lenses as a replacement for the natural lens post cataract surgery has been used for many years. Newer developments include the opportunity to use gels so that the lenses can accommodate but these need improving in terms of the cross-linking chemistry. Silicone oils have been used as long-term tamponade agents as vitreous replacements but recent developments in their properties has enhanced the clinical outcomes and further research into their use as drug delivery vehicles will be a major advancement. Regenerative medicine therapies to repopulate the retina to repair and replace specific cell layers require the optimisation of synthetic scaffolds and this is a major area for development. Recent developments in biomaterials have emphasised the importance of the physical, chemical and mechanical properties specific to a particular ophthalmic application. Materials science has a critical role in developing strategies to overcome vision loss.

Dynamic characterization of viscoelastic materials used in composite structures

The main focus of this paper is the experimental comparative analysis of the viscoelastic properties of acrylic- and silicon-based viscoelastic materials. These materials are widely used in the aeronautic industry for structural and/or damping applications. It is therefore required to determine their viscoelastic properties such as shear modulus and loss factor following their integration to aircraft composite structures. The influence of material thickness, bonding quality, curing and cocuring with composite material was evaluated using dynamic mechanical analysis machine in plan shear configuration. This comparative analysis in the 0–600 Hz frequency range provides useful information that should be taken into consideration when designing bonded joints for structural and/or damping applications. The small variation of the acrylic-based material loss factor over a wide range of frequencies suggests that this material is a good candidate for damping applications at room temperature in metallic structures where no curing is required. However, cocuring of acrylic-based material with composite laminae increases its shear modulus up to six times with respect to the uncured material whereas its loss factor is reduced by about 20%. On the other hand, the silicon-based material remains stable after thermal treatment (curing and cocuring) suggesting that it is well suited for in situ damping treatment involving laminate composite structure. However, at room temperature its shear modulus after cocuring is lowered by almost 25% due to poor bonding quality, which depends on the nature of the substrate.

Effect of sealer coating on mechanical and physical properties of permanent soft lining materials

To evaluate the long-term effects of sealer coating on tensile bond strength and surface roughness of soft liners. Failure of the bond between resilient liners and denture base significantly compromise the dentures' longevity. In addition, surface roughness contributes to bacterial adherence on prosthetic materials, increasing the risk of oral infections. Specimens were manufactured from four reliners [Mucopren Soft (MS), Dentuflex (DF); Soft Comfort Denso (SC) and Ufi Gel SC (USC)], distributed into 10 groups (n = 10), according to material and coating treatment. Tensile bond strength was performed after one year of ageing, while surface roughness was evaluated at 0, 1, 3, 6 and 12 ageing months. Bond strength data were submitted to two-way anova and Tukey-HSD tests, while roughness data were submitted to mixed model analysis for repeated measurements (p ≤ 0.05). MS and DF without sealer coating presented the highest tensile bond strength. After coating, DF and SC presented increased tensile bond strength. No surface roughness difference was observed in the non-coated groups over time, acrylic-based reliners presented higher roughness. Among coated groups, only SC presented increased surface roughness. Acrylic-based materials presented reduced roughness at three months. Surface coating was effective for acrylic reliners in maintaining their initial properties. However, sealer coating should be re-applied every 3 months.

Changes in stress relaxation property and softness of soft denture lining materials after cyclic loading

Objectives Soft denture lining materials show varied and changeable stress relaxation property and softness under cyclic loading conditions. The purpose of this study was to determine the changes in the stress relaxation property and the softness of commercial soft lining materials after cyclic loading. Methods One plasticized acrylic-based material (Coe Soft: COS) and two silicone-based materials (Mucosoft: MUS; Sofreliner S: SFL) were investigated. For each material, 10 cylinder-shaped specimens were subjected to 29 days of cyclic loading, 1800 times per day; other 10 unloaded specimens were used as control groups. Stress relaxation ratio and softness were measured after 1, 4, 8, 15, 22 and 29 days of cyclic loading or storage. Results During 29 day period, the stress relaxation ratios of the cyclic loaded and unloaded COS, MUS and SFL specimens were 28.5–31.6% and 30.9–32.6%, 6.4–15.1% and 1.8–15.4%, 14.0–38.2% and 19.8–40.6%, respectively. The softness values of the cyclic loaded and unloaded COS, MUS and SFL specimens were 42.6–60.6% and 56.4–61.8%, 47.6–52.5% and 46.9–51.5%, 56.6–58.4% and 58.0–65.1%, respectively. Based on repeated-measures, 3-way ANOVA, the stress relaxation ratio was influenced by the loaded or stored period and the type of material ( p < 0.05), but not by the application of cyclic loading; the softness value was influenced by the loaded or stored period and the application of cyclic loading ( p < 0.05), but not by the type of material. Significance Soft lining materials showed the loaded or stored period and the material type dependent stress relaxation properties regardless of the application of cyclic loading. Softness value was influenced by the loaded or stored period and the application of cyclic loading.

The influence of denture cleansers on the release of organic compounds from soft lining materials

Biocompatibility constitutes the most fundamental requirement with respect to all dental materials to be applied within the oral cavity. In its environment, various toxic compounds may be released by dental materials which pose potential threats to the patient's health. Due to the fact that dentures remain in the oral cavity for a very long time, a detailed examination and verification of prosthetic materials with a view to their toxicity seems to be essential. By using very sensitive measurement techniques such as gas chromatography, one may determine which compounds are released by these materials. The aim of this paper was to determine the influence of various denture cleansers on the release of organic compounds from four soft dental materials used in prosthetics for lining dentures. These materials when placed in commonly used disinfectants (Corega Tabs, sodium hypochlorite, chlorhexidine, hydrogen peroxide), as well as in artificial saliva, produced 13 chemical compounds such as monomers (methyl methacrylate, ethyl methacrylate, dodecyl methacrylate), plasticizers (dibutyl phthalate, diethyl phthalate, tributyl acetylcitrate) and others (e.g. benzophenone). A comparison of chemical compounds released from acrylic-based materials and those released from silica-based materials demonstrated that acrylic-based materials are less resistant to disinfectants.

Use of the thick adherend shear test for shear stress-strain measurements of stiff and flexible adhesives

Five commercial structural adhesives were tested using the thick adherend shear test (TAST). These adhesives have mechanical properties ranging from those of high-strength, heat-cured epoxies to ductile, acrylic-based materials. Consideration was given to the adherend selection and dimensions to approach a uniform shear stress-strain in the bonded area, so that the test could be used with both stiff and flexible adhesives. Comparison of the TAST results was also made with those obtained using the butt torsion test. The TAST extensometry has been shown to be suitable for measuring the shear strain properties of the adhesives tested without modification. From the shear behavior of the five adhesives measured using the TAST method, and from the results presented in this paper, it can be seen that the TAST method is repeatable and reproducible for a wide range of adhesive types and adhesive properties. From these results, it is possible to generate comprehensive adhesive shear data. Also, the curves from the butt torsion test and the TAST were found to be consistent and give the same behavior of the adhesives tested.

USE OF THE THICK ADHEREND SHEAR TEST FOR SHEAR STRESS-STRAIN MEASUREMENTS OF STIFF AND FLEXIBLE ADHESIVES

Five commercial structural adhesives were tested using the thick adherend shear test (TAST). These adhesives have mechanical properties ranging from those of high-strength, heat-cured epoxies to ductile, acrylic-based materials. Consideration was given to the adherend selection and dimensions to approach a uniform shear stress-strain in the bonded area, so that the test could be used with both stiff and flexible adhesives. Comparison of the TAST results was also made with those obtained using the butt torsion test. The TAST extensometry has been shown to be suitable for measuring the shear strain properties of the adhesives tested without modification. From the shear behavior of the five adhesives measured using the TAST method, and from the results presented in this paper, it can be seen that the TAST method is repeatable and reproducible for a wide range of adhesive types and adhesive properties. From these results, it is possible to generate comprehensive adhesive shear data. Also, the curves from the butt torsion test and the TAST were found to be consistent and give the same behavior of the adhesives tested.