This paper reports a flexible mechanical sensor developed by combining an opal photonic crystal and a flexible medium through UV curing technology. Under the action of external force, the deformation of the flexible medium causes the change of the photonic crystal lattice constant, which leads to the displacement of the reflection peaks, thus realizing the detection of the deformation of the film. The flexible medium is mixed by photoinitiators and polymer monomers, and its mechanical properties are directly related to the mass fraction of photoinitiators and polymer monomers. The results show that the film can reach a maximum strain of about 180% when the mass fraction of photoinitiator is 3% and the volume ratio of the polymer functional monomers is 8:2. In addition, for the responsiveness test of the sensor under tensile, the results show that at 0%, 26%, and 78% of tensile strain, its structural color is blue-shifted sequentially, and its spectral peaks are 668 nm, 535 nm, and 488 nm, respectively. Finally, the sensor is applied to the detection of acoustic waves in air, and it is found that its spectral response peaks can be obtained for acoustic waves of different frequencies (250–650 Hz), and a spectral peak at 500 Hz. This flexible photon sensor has the potential to match the acoustic resistance of water. It will greatly expand the response research of ocean exploration in the low frequency range.
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