Acoustic Pressure Amplitude Research Articles

Localized Oxidative Catalytic Reactions Triggered by Cavitation Bubbles Confinement on Copper Oxide Microstructured Particles.

Efficient energy transfer management in catalytic processes is crucial for overcoming activation energy barriers while minimizing costs and CO2 emissions. We exploit here a concept of CuO particle design with multiple gas-stabilizing sites, engineered to function as cavitation nuclei and catalysts. This concept facilitates the selective and efficient acoustic energy transfer directly to the catalyst surface, avoiding the undesired dissipation of acoustic energy into the bulk solution while demonstrating superior cavitation properties at lower acoustic pressure amplitudes. Utilizing a chemical thermometric approach, we demonstrate that the local temperature on the surface of our CuO particles during cavitation bubble implosions can create an effective equivalent temperature of about 360 °C. This temperature effect facilitates the efficient catalysis of oxidative reactions using an organic pollutant probe molecule. Density functional theory (DFT) calculations were used to assess the decomposition of H2O2 and of pollutant probe molecule on CuO (111). Our work represents a significant advance in sonocatalytic systems, promising efficient energy use in catalytic reactions.

Localized Oxidative Catalytic Reactions Triggered by Cavitation Bubbles Confinement on Copper Oxide Microstructured Particles.

AbstractEfficient energy transfer management in catalytic processes is crucial for overcoming activation energy barriers while minimizing costs and CO2 emissions. We exploit here a concept of CuO particle design with multiple gas‐stabilizing sites, engineered to function as cavitation nuclei and catalysts. This concept facilitates the selective and efficient acoustic energy transfer directly to the catalyst surface, avoiding the undesired dissipation of acoustic energy into the bulk solution while demonstrating superior cavitation properties at lower acoustic pressure amplitudes. Utilizing a chemical thermometric approach, we demonstrate that the local temperature on the surface of our CuO particles during cavitation bubble implosions can create an effective equivalent temperature of about 360 °C. This temperature effect facilitates the efficient catalysis of oxidative reactions using an organic pollutant probe molecule. Density functional theory (DFT) calculations were used to assess the decomposition of H2O2 and of pollutant probe molecule on CuO (111). Our work represents a significant advance in sonocatalytic systems, promising efficient energy use in catalytic reactions.

Design and experimental evaluation of a non-contact ultrasonic motor using acoustic phase holography

Abstract Non-contact ultrasonic motors address certain limitations of conventional ultrasonic motors. However, they continue to have intricate designs and electronics. Acoustic holography has emerged as a technique for its flexibility and dynamicity in manipulating acoustic phase and amplitude patterns in the nearfield, offering a reduction in mentioned complexities. Therefore, this technique may find utility in the development of non-contact ultrasonic motors. This paper discusses a novel design for non-contact rotary ultrasonic motor using acoustic holography. Acoustic holographic technique modulates the acoustic phase to create a phase gradient, resulting in a rotary flow that drives the rotor in the interface of aqueous media and air. The motor’s performance is influenced by factors such as the acoustic pressure amplitude, the number of 0 to 2 π pitches, and the rotor’s geometry. An empirical study using the Response Surface Method (RSM) identified an optimal number of pitches for maximum rotational speed at a constant voltage. The motor torque was measured by calculating the drag forces applied to the rotor blades. It was found that the minimum output torque occurs when the stator phase pitches match the rotor blades. The ideal motor performance is achieved with eight rotor blades and six phase pitches. The motor’s top speed reached 40 rpm, and the output torque varied around 0.1 μN.m, depending on the phase pitches and rotor blades. In summary, the research highlights the potential of acoustic holography in designing a non-contact ultrasonic motor, with specific configurations yielding optimal speed and torque.

Transmission characteristics of vortex light superposition in atmospheric turbulence disturbed by plane acoustic waves

Herein, we derive the expression for the atmospheric refractive index structure constant under the influence of planar acoustic wave perturbations under the influence of the acoustic field on the refractive index and energy of the atmosphere. Utilizing the low-frequency compensated power spectrum inversion technique, we simulate the refractive index power spectrum of atmospheric turbulence perturbed by a planar acoustic wave. Numerical analysis is conducted on the transmission characteristics of the vortex light superposition states in atmospheric turbulence perturbed by a plane acoustic wave under different acoustic wave transmission heights, acoustic pressure amplitudes, and frequencies. Results indicate that introducing an acoustic field induces fluctuations in the atmospheric refractive index structure constant, with a more pronounced impact on the refractive index than on energy. Compared with the sole consideration of the impact of the acoustic field on the atmospheric refractive index, incorporating its effect on atmospheric energy results in a decrease in the atmospheric refractive index structure constant. The impact of the acoustic field on atmospheric turbulence is directly proportional to both acoustic pressure amplitude and frequency. The influence of the acoustic field on the transmission properties of the vortex optical superposition state varies with different acoustic transmission distances. Consequently, the transmission characteristics of the vortex light superposition state can be actively modulated according to varying acoustic wave transmission distances. This study offers a theoretical basis for modulating the optical field transmission characteristics via acoustic fields.

Dependence of acoustophoretic aggregation on the impedance of microchannel's walls

Background and Objectives: Acoustofluidic manipulation of particles and biological cells has been widely applied in various biomedical and engineering applications, including effective separation of cancer cell, point-of-care diagnosis, and cell patterning for tissue engineering. It is often implemented within a polydimethylsiloxane (PDMS) microchannel, where standing surface acoustic waves (SSAW) are generated by sending two counter-propagating ultrasonic waves on a piezoelectric substrate.Methods: In this paper, we develop a full cross-sectional model of the acoustofluidic device using finite element method, simulating the wave excitation on the substrate and wave propagation in both the fluid and the microchannel wall. This model allows us to carry out extensive parametric analyses concerning the acoustic properties of the fluid and the microchannel wall, as well as the dimensions of the channel, to explore their influences on the acoustic field, fluid flow and microparticle aggregation.Results: Our findings demonstrate an order-of-magnitude enhancement in acoustic pressure amplitude and aggregation speed and a reduction in the particle threshold radius to submicron levels, which can be achieved through adjustments to the channel height and the difference in acoustic impedance between the channel wall and the fluid. The optimum channel heights are determined, which depend on the acoustic properties of the channel wall. The particle trajectories, movements along pressure nodal planes, and terminal positions are identified, with relative strength between the radiation force and the streaming force compared in different combinations of parameters.Conclusions: This work demonstrates that finetuning the dimensions and acoustic properties of the fluid and microchannel wall in acoustofluidic device can greatly enhance particle aggregation throughput and reduce constraints on particle size. Our findings offer valuable insights into device design and optimization.

Experimental study on acoustic and flame responses in an annular combustor under azimuthal force

This study investigates the flame dynamics of an annular combustor under various azimuthal acoustic forces. The experimental platform was applied to external azimuthal acoustic force through four loudspeakers installed on the wall outside the plenum. Experiments were conducted with an equivalence ratio of Ф = 0.71 and a combustion power of P = 9.5 kW. Therein, four loudspeakers were used to precisely control the acoustic pressure amplitude, spinning ratio, and spinning direction, which stimulated the first-order standing mode, spinning modes, and second-order standing mode acoustic mode of the plenum, respectively. Our analysis of flame dynamics and acoustic response characteristics was based on different azimuthal modes, combined with dynamic mode decomposition (DMD) of the flame image sequence and acoustic pressure signal. The results corroborate the consistency between the acoustic field quaternion analysis and the flame image sequence DMD results despite varied external forcing conditions. Specifically, the characteristics of the flame vary by the applied forces. Moreover, DMD results indicate that the flame structure of the eigenfrequency mode is asymmetrical in spinning modes and tilts in the direction of the pressure gradient.

Investigating Taconis oscillations in a U-shaped tube with hydrogen and helium

Taconis oscillations are thermally induced spontaneous excitations of acoustic modes in tubes subjected to large temperature gradients. Cryogenic systems that experience these excitations suffer from increased heat leak and vibrations. This heat leak may also increase boil-off in long-term storage vessels for liquid hydrogen. In this study, U-shaped closed-end tubes with a cold mid-section are experimentally investigated to quantify the oscillation characteristics for hydrogen- and helium-filled systems at various mean pressures, including supercritical hydrogen states. Experimental measurements of the temperature distribution along the tube and acoustic pressure amplitudes and frequencies are taken in constant- and variable-diameter configurations near the onset of oscillations. Thirty different conditions are recorded with mean pressures ranging from 126 kPa to 1127 kPa for helium and 161 kPa to 1816 kPa for hydrogen. A low-amplitude thermoacoustic model is applied to predict the cold temperature and frequency corresponding to the onset of Taconis oscillations. The findings of this study indicate that Taconis oscillations in systems with hydrogen occur at smaller temperature differences than in more traditional helium systems by approximately 10 K. Hydrogen in the constant-diameter configuration excited when cryogenic temperatures reached 35–40 K, whereas helium excited when cryogenic temperatures reached 20–30 K. Special tubing networks, such as wider segments in the warm portion, can drastically elevate the excitation cold temperature resulting in onset temperatures between 50–60 K for both fluids. Taconis oscillations are also found to exist in conditions when liquid hydrogen starts forming in the cold zone of the system, as well as in supercritical states. The presented measurements are useful for designing cryogenic hydrogen storage systems to control these oscillations.

Numerical analysis of ultrasound-mediated microbubble interactions in vascular systems: Effects on shear stress and vessel mechanics

The present study concerns the numerical modeling of microbubble oscillation within an elastic microvessel, aiming to enhance the safety and efficacy of ultrasound-mediated drug delivery and diagnostic imaging. The success of such applications depends on a thorough understanding of microbubble–vessel interactions. Despite some progress, the critical impact of the stabilizing shell around gas core has remained underexplored. To address this, we developed a novel numerical approach that models the stabilizing shell. Additionally, there is novelty in modeling consequent vascular deformation in response to complicated spatiotemporal microbubble oscillations. The novel approach was implemented for shear stress evaluation as a critical factor in vascular permeability. Finally, our unique approach offered novel insights into microbubble–vessel interactions under diverse acoustic conditions. Results indicated substantial impact of shell properties and acoustic parameters on induced shear stress. With a fourfold increase in acoustic pressure amplitude, 15.6-fold and sixfold increases were observed in maximum shear stress at 1 and 3 MHz, respectively. Also, the peak shear stress could reach up to 15.6 kPa for a shell elasticity of 0.2 N/m at 2.5 MHz. Furthermore, decreasing microvessel/bubble size ratio from 3 to 1.5 increased maximum shear stress from 5.1 to 24.3 kPa. These findings are crucial for optimizing ultrasound parameters in clinical applications, potentially improving treatment outcomes while minimizing risk of vessel damage. However, while our model demonstrated high fidelity in reproducing experimental observations, it is limited by assumptions of vessel geometry and homogeneity of vessel properties. Future work can improve our findings through in vitro experimental measurements.

Defect detection and imaging using electromagnetic acoustic transducer with butterfly coil.

Electromagnetic ultrasonic detection technology utilizes the electromagnetic coupling method to generate and receive ultrasonic waves without a couplant, which is suitable for rapid detection. However, the detection can be affected by the spatial distribution of the acoustic field and the polarization direction of the shear wave, which can result in suboptimal detection performance. The acoustic field directivity of the shear wave generated by the butterfly coil electromagnetic acoustic transducer was measured using the transmission method. The data indicate that the acoustic pressure amplitude of the shear wave is maximized along the axis of the acoustic field, thereby meeting the requirements of synthetic aperture focusing technique imaging. We used the reflection method to detect the through-hole defects and investigated the effect of shear wave polarization direction. By comparing the experimental data and imaging results, it can be concluded that higher echo amplitudes are obtained when the polarization direction of the shear wave is perpendicular to the axis of the through-hole defects. Based on the explosive reflection model, the frequency domain phase shift migration (PSM) method converts the time-domain signal to the frequency domain for processing and uses a phase-shift factor for layer-by-layer imaging. We used the PSM method to process the experimental data, which not only produced high-resolution images but also had a high computational speed.

Numerical Study on the Dynamics of a Charged Bubble in the Acoustic Field

In this paper, the dynamics of an acoustic bubble with a constant charge in compressible liquid are investigated numerically, which is based on the Gilmore-NASG model to estimate the radial oscillations. The cavitation effects are enhanced due to the presence of the charge on the bubble surface. The obtained results from the present model are compared with that calculated by the previous model within a wide range of parameters (e.g., charge, acoustic pressure amplitude, ultrasound frequency, and liquid temperature). The similar influences of these parameters on bubble collapse intensity can be observed from both models. Since the present model fully considers the compressibility of gas and liquid, it can be applied to a wider parameter range and leads to the larger predicted values. The research in this paper can provide important insights about the effects of charge on bubble dynamics and the acoustic cavitation applications (e.g., sonochemistry, water treatment, and food industry).

Computational fluid dynamics simulations of single-bubble evolution under synergy of ultrasound and an electrostatic field

In the study reported here, a two-phase flow model was developed for the evolution of a single bubble under ultrasonic irradiation coupled with an electrostatic force. We started with the following assumptions: (I) the liquid is incompressible, (II) the effect of gravity is negligible in the liquid, (III) the bubble is insulating, and no free charges are distributed on the liquid–gas interface, and (IV) the liquid contains only one bubble. Using computational fluid dynamics, we analyzed how the bubble shape evolves under various conditions, and the main findings are as follows: (1) With increasing electric field strength, the bubble reaches a larger maximum area and a smaller minimum area. Furthermore, during the positive phase of ultrasound, a higher electric field strength leads to faster compression and a more slender bubble. (2) As the initial bubble radius is increased from 3 to 5 μm, the cavitation becomes significantly stronger, but when the initial bubble radius reaches 10 μm, the cavitation intensity decreases instead because of greater compression resistance caused by there being more gas in the bubble. (3) Cavitation cannot be triggered under an excessively low acoustic pressure amplitude, and an excessively high acoustic pressure amplitude results in weaker cavitation; the appropriate acoustic pressure amplitude is considered to be 1.35 atm.

A new model for bubble cluster dynamics in a viscoelastic media

Bubble cluster dynamics in viscoelastic media is instructive for ultrasound diagnosis and therapy. In this paper, we propose a statistical model for bubble cluster dynamics in viscoelastic media considering the radius distribution of bubble nuclei. By investigating and comparing the response for a bubble in three conditions: single bubble; multi-bubble with the same radius; multi-bubble with different radius, the following rules are found: The promotion or suppression of the bubble cluster on the bubble vibration is not monotonous with the increase of the number of bubbles. The promotion or suppression of the bubble cluster on the bubble vibration varies alternately with the frequency. The effect of bubble cluster on bubble vibration is mostly suppressed when the driving acoustic pressure amplitude pa is high (5000 kPa). Usually, the bubble cluster promotes the vibration of the large bubbles (R0 = 10 μm) more, or suppresses it less.

Performance comparison of a standing-wave thermoacoustic engine with different resonator shapes with air working gas

The resonator is one of the key components of thermoacoustic machines and the choice of its geometry is of course of crucial importance, as it determines the way the machine operates. The resonator must be designed so that the quality factor of the resonance is as high as possible and must satisfy the technological production constraints related to the high pressurization of the working fluid and the presence of temperature non-uniformities. The shape of the resonator can be modified to reduce certain loss phenomena, particularly on the walls, and to limit the formation of harmonics in the high-level acoustic field. In this work, an acoustic power losses analysis and a numerical study of a standing-wave TAE with air working gas, considering changes in resonator shape, are performed to investigate the effect of resonator geometry on the thermoacoustic energy conversion. The acoustic power dissipation in the resonator is analyzed based on the simplified thermoacoustic theory and the numerical study is conducted based on a 2D numerical model based on a CFD analysis. Results show that the shape of the resonator significantly affects the frequency, the temperature along the stack, and the acoustic pressure produced on the TAE. In addition, it is shown that the resonator composed of two different diameters showed its ability to produce a high acoustic pressure amplitude (20.5% than the iso-diameter resonator) and minimize the viscous and thermal losses.

Controlled mean dynamics of red blood cells by two orthogonal ultrasonic standing waves

A computational model is developed to study the time-averaged mean dynamics of red blood cells (RBCs) driven by the time-averaged mean stress generated by two phase-shifted orthogonal ultrasonic standing waves in a viscous fluid. The cell is modelled as an ellipsoidal viscoelastic membrane enclosing the viscous fluid cytoplasm, the motion of which is described by the inclination angle of the ellipsoidal cell shape and the phase angle of the potential membrane cycle. Based on the acoustic perturbation method, the acoustic field and acoustic streaming field are solved to obtain the time-averaged mean stress, and then the temporal evolution equations of the inclination and phase angles of the cell are determined considering the torque balance and energy conservation. At a small acoustic pressure amplitude, this model reproduces the experimentally observed features of cell motion in orthogonal standing waves: the transition from steady stationary orientation to unsteady tumbling with the increase of the phase difference between the two standing waves. By turning up the acoustic pressure amplitude above a critical value, it is further predicted that the previously observed motions can be accompanied by the membrane tank-treading rotation. Observations of these motions, combined with the present computational model, can help to evaluate the mechanical properties of RBC membranes in an automated and high-throughput manner by acoustic methods.

A model of coupled oscillation of bubble cluster in liquid cavity wrapped by viscoelastic medium

Considering the interactions between bubbles in a multi-bubble system in a liquid micro-cavity, a spherical bubble cluster in a liquid cavity is modeled in order to describe the dynamical effect of the viscoelastic medium outside the liquid cavity on the oscillation of bubbles, and the coupled equations of bubbles are obtained. Subsequently, the acoustic response characteristics of bubbles are investigated by analyzing the radial oscillation, the stability of the non-spherical shape of bubbles and the threshold of inertial cavitation. The results show that the confinement of the cavity and the bubble cluster facilitates the suppression of bubble oscillation, however, it might enhance the nonlinear properties of bubbles to a certain extent. From the acoustic response curve at 1 MHz, it is found that the main resonance peaks shift leftward with the increase of the bubble number, which means a minor resonant radius can be obtained. The nonlinear stability of bubbles in a confined environment is mainly determined by acoustic pressure amplitude and frequency, the initial bubble radius, and bubble number density, while the effect of the cavity radius is enhanced with the increase of the driving pressure. There is a minimum unstable driving acoustic pressure threshold, depending on the initial bubble radius, and the unstable regions are mainly located in a range of less than 4 μm. With the increase in bubble number density, the strip-type stable region scattered of the unstable region in the map is gradually transformed into a random patch-like distribution, which indicates that the bubble oscillation under high acoustic pressure is more sensitive to the parameters, and it is very susceptible to interference, produces unstable oscillation and then collapses. When the bubble equilibrium radius is in a range greater than 4 μm, the influences of frequency and bubble number density on the inertial thresholds are particularly significant.

Dynamics of acoustically-induced droplet instability

The advancement of the theory of droplet stability in the acoustic field is of significant value in improving ultrasonic atomization and ultrasonic levitation technology. In this work, in order to reveal the detailed mechanism of acoustic droplet instability and give the instability criterion for easy application, the dynamics of droplet instability in standing wave acoustic field (19.8 kHz) is studied by combining practical experiment, theoretical derivation and numerical calculation. The acoustic instability of the droplet occurring near the wave nodes is mainly manifested in two typical modes: disk instability and edge-sharpening instability. The appearance of these two instability modes depends on the relative magnitude of the standing wave field strength. Specifically, with the gradual enhancement of the intensity of the standing wave field, the instability mode of the droplet will gradually change from disc instability to edge-sharpened instability.The droplets show obvious self-accelerating expansion in the equatorial plane in the instability process. The positive feedback between the droplet aspect ratio and the negative pressure of acoustic radiation at the equator of the droplet is the reason for the above self-accelerating behavior. The theoretical results obtained through deduction indicate that the amplitude of the negative acoustic radiation pressure at the droplet equator is proportional to the square of the droplet aspect ratio. The surface tension of the droplet is the main factor hindering its deformation, while the acoustic radiation suction at the equator is the main factor driving the deformation of the droplet. Based on this, the force equilibrium equation of the droplet interface is established, and the dimensionless criterion of acoustic droplet instability, i.e. the acoustic Weber number <i>We</i><sub>a</sub>, is derived. When <i>We</i><sub>a</sub>≤1, the droplet interface stays in equilibrium, and when <i>We</i><sub>a</sub> >1, the equatorial acoustic suction is larger than the surface tension, and the droplet instability occurs, and the average error between the experimental results and the theoretical results is only 9%.

Structural stability analysis of spherical bubble clusters in acoustic cavitation fields

The upwelling growth and evolution of spherical bubble clusters appearing at one-quarter wavelength from the water surface in ultrasonic cavitation fields at frequencies of 28 kHz and 40 kHz are studied by high-speed photography. Due to the interactions among bubbles, the stable bubble aggregation occurs throughout the rise of the bubble cluster, whose vertical pressure difference leads to a more significant spreading in the upper part of the cluster in the standing-wave field. At 28 kHz, the rising speed is about 0.6 m/s, controlled by the primary acoustic field. After a violent collapse of the bubble clusters, the aggregating structure begins to hover near the water surface. The size and stability of the structure are affected by the frequency and pressure of the primary acoustic field. If two clusters are close to each other, the clusters deviate from the spherical shape, even trailing off, and eventually merge into a single bubble cluster. By considering the influence of water-air boundary, based on the mirror principle, a spherical bubble cluster model is developed to explore the structure stability of the clusters, and the modified dynamics equations are obtained. The effects of driving acoustic pressure amplitude, bubble number density, water depth, and bubble equilibrium radius on the optimal stable radius of the spherical bubble cluster are numerically analyzed by using the equivalent potentials at 28 kHz and 40 kHz. The results show that the optimal stabilizing radius of spherical bubble cluster is in a range of 1–2 mm, and it tends to decrease slightly with the increase of the driving acoustic pressure and bubble number density. It is worth noting that the nonlinearity is enhanced by increasing acoustic pressure, which may promote the stability of the cluster structure. The smaller the unstable equilibrium radius, the easier it is to grow, and the stable size at 40 kHz is slightly smaller than that at 28 kHz. Generally, spherical clusters first appear in a high-pressure region and then move to a low-pressure region. If the acoustic pressure drops below a certain critical value, bubble clusters disappear. The theoretical analysis is in good agreement with the experimental observation. The analysis of the growth and structural stability of spherical bubble cluster is helpful in understanding the behavioral modulation of bubbles.

Void formation and suppression in CFRP laminate using newly designed ultrasonic vibration assisted RTM technique

This study introduces an ultrasonic vibration assisted resin transfer molding (RTM) technique as an innovative approach to address the inherent challenges associated with traditional methods for producing CFRP laminates. It investigates the mechanism of void formation in CFRP composites under ultrasonic vibration using 3D X-ray microscopy. Numerical calculations and simulation analyses are also employed to validate the impact of ultrasonic vibration on mechanical properties of CFRP. The findings indicate that ultrasonic vibration results in CFRP laminates with more uniform thickness, leading to a substantial increase in fiber volume fraction up to ∼16 %. Concurrently, there are significant improvements in flexural strength (∼20 %) and fracture energy (∼90 %). Ultrasonic vibration also effectively reduces CFRP porosity by at least 25 %, resulting in a more consistent distribution of voids, primarily consisting of small circular voids. This porosity reduction is attributed to the cavitation effect and enhancing wettability, consequently improving the mechanical properties of CFRP. Moreover, simulations and numerical calculations demonstrate the significant occurrence of cavitation effect within the resin under specific process conditions. The intensity of cavitation is influenced by factors such as the initial bubble radius, acoustic pressure amplitude, and static pressure of the resin. The ultrasonic-assisted RTM process is proved as a promising method for producing CFRP laminates with superior properties.

Acoustic Characterization of Transmitted and Received Acoustic Properties of Air-Coupled Ultrasonic Transducers Based on Matching Layer of Organosilicon Hollow Glass Microsphere.

An air-coupled transducer was developed in this study, utilizing hollow glass microsphere-organosilicon composites as an acoustically matching layer, which demonstrated outstanding acoustic performance. Firstly, a comparison and analysis of the properties and advantages of different substrates was carried out to determine the potential application value of organosilicon substrates. Immediately after, the effect of hollow glass microspheres with different particle sizes and mass fractions on the acoustic properties of the matching layer was analyzed. It also evaluated the mechanical properties of the matching layer before and after optimization. The findings indicate that the optimized composite material attained a characteristic acoustic impedance of 1.04 MRayl and an acoustic attenuation of 0.43 dB/mm, displaying exceptional acoustic performance. After encapsulating the ultrasonic transducer using a 3D-printed shell, we analyzed and compared its emission and reception characteristics to the commercial transducer and found that its emission acoustic pressure amplitude and reception voltage amplitude were 34% and 26% higher, respectively. Finally, the transducer was installed onto a homemade ultrasonic flow meter for practical application verification, resulting in an accuracy rate of 97.4%.

Efficient sonochemical catalytic degradation of tetracycline using TiO2 fractured nanoshells

Overexposure to antibiotics originating in wastewater has profound environmental and health implications. Conventional treatment methods are not fully effective in removing certain antibiotics, such as the commonly used antibiotic, tetracycline, leading to its accumulation in water catchments. Alternative antibiotic removal strategies are garnering attention, including sonocatalytic oxidative processes. In this work, we investigated the degradation of tetracycline using a combination of TiO2 fractured nanoshells (TFNs) and an advanced sonochemical reactor design. The study encompassed an examination of multiple process parameters to understand their effects on the degradation of tetracycline. These included tetracycline adsorption on TFNs, reaction time, initial tetracycline concentration, solvent pH, acoustic pressure amplitude, number of acoustic cycles, catalyst dosage, TFNs' reusability, and the impact of adjuvants such as light and H2O2. Though TFNs adsorbed tetracycline, the addition of ultrasound was able to degrade tetracycline completely (with 100% degradation) within six minutes. Under the optimal operating conditions, the proposed sonocatalytic system consumed 80% less energy compared to the values reported in recently published sonocatalytic research. It also had the lowest CO2 footprint when compared to the other sono-/photo-based technologies. This study suggests that optimizing the reaction system and operating the reaction under low power and at a lower duty cycle are effective in achieving efficient cavitation for sonocatalytic reactions.