Conventional methods for assessing bond performance are hindered by challenges in measuring strain and a lack of sufficient sensitivity to internal structural damage. This paper examines the bond behavior between steel and ultra-high-performance concrete (UHPC) based on acoustic emission (AE). The tests included a total of 2 concrete-filled steel tube (CFST) specimens and 4 concrete-encased CFST specimens. The bonding test was analyzed using AE parameters in combination with the damage process, damage morphology, and loading curve of the test specimens. Furthermore, damage correspondence was explored for the AE parameter indexes and the bond damage indexes of the conventional method. The findings reveal that the AE peak frequencies associated with the bond failure between steel tube and concrete span 30–100 kHz, 110–130 kHz, and 220–260 kHz. The AE event rate, cumulative absolute energy, Ib-curve, and percentage of tensile cracks can be used as judgmental and early warning features for interface damage. The damage process at the interface and the concrete crack development can be characterized by the severity index HI and the severity value Sr. The measurement curves obtained from various AE sensor positions exhibit remarkable similarity. A correlation can be discerned between the severity index (Sr) of the AE and the bond damage degree (Dt) ascertained through conventional methods, effectively mirroring the structural damage progression.
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