Acid Deposition In China Research Articles

Acidity of Soil and Water Decreases in Acid-Sensitive Forests of Tropical China.

Acid deposition in China has been declining since the 2000s. While this may help mitigate acidification in forest soils and water, little is known about the recovery of soils and water from previous severe acidification in tropical China. Here, we assessed the chemistry of mineral soils, water, and acid gases (SO2 and NOx) from three successional forest types in tropical China from 2000 to 2022. Our results showed that soil pH increased synchronously from 3.9 (2000-2015) to 4.2 (2016-2022) across all three forest types, with exchangeable acid initially decreasing and thereafter stabilizing. Surface and ground water pH also gradually increased throughout the monitoring period. Soil pH recovery was stronger in the primary than in the planted forest. However, soil pH recovery lagged behind the increase in rainfall pH by approximately a decade. The recovery of soil pH was likely related to the positive effects of the dissolution of Al/Fe-hydroxysulfate mineral and subsequent sulfur desorption on soil acid-neutralizing capacity, increased soil organic matter, and climate warming, but was likely moderated by increased exchangeable aluminum and potentially proton-producing hydroxysulfate mineral dissolution that caused the lagged soil pH recovery. Surface and ground water pH recovery was attributed to increased water acid-neutralizing capacity. Our study reports the potential for the recovery of acidified soil and water following decreased acid deposition and provides new insights into the functional recovery of acid-sensitive forests.

High environmental costs behind rapid economic development: Evidence from economic loss caused by atmospheric acid deposition

The rapid growth of energy-intensive and high-emission industries has propelled China's economy but has also led to massive levels of air pollutant emissions and ecological problems, such as acid deposition. Despite recent declines, atmospheric acid deposition in China is still severe. Long-term exposure to high levels of acid depositions has a substantial negative impact on the ecosystem. Evaluating these hazards and incorporating this issue into planning and decision-making processes is critical to achieving sustainable development goals in China. However, the long-term economic loss caused by atmospheric acid deposition and its temporal and spatial variation in China is unclear. Hence, the aim of this study was to assess the environmental cost of acid deposition in the agriculture, forestry, construction, and transportation industries from 1980 to 2019, using long-term monitoring, integrated data, and the dose–response method with localization parameters. The results showed that the estimated cumulative environmental cost of acid deposition was USD 230 billion, representing 0.27% of the gross domestic product (GDP) in China. This cost, was particularly high for building materials, followed by crops, forests, and roads. Temporally, the environmental cost and the ratio of environmental cost to GDP decreased from their peaks by 43% and 91%, respectively, because of emission controls targeting acidifying pollutants and promotion of clean energy. Spatially, the largest environmental cost occurred in developing provinces, indicating that more stringent emission reduction measures should be implemented in these regions. These findings highlight the huge environmental costs behind rapid development; however, the implementation of reasonable emission reduction measures can effectively reduce these environmental costs, providing a promising paradigm for other undeveloped and developing countries.

The contributions of socioeconomic and natural factors to the acid deposition over China

China has experienced severe acid rain pollution during the past decades due to excessive sulfur oxides (SO2) and nitrous oxides (NOx) emissions, which further caused lake acidification, biodiversity losses and climate change. Although the major sources of acid deposition have been clarified previously, the contributions of socioeconomic (natural) factors to the regional acid deposition remained unknown. Therefore, a series of valuable data including socioeconomic (natural) variables and measured pH value in the rainwater at the city level were collected to identify the key factors influencing the rainwater pH value at the national and the regional scale using the spatial econometric model/geographical detector technique and geographical weight regression (GWR) model, respectively. The results showed that the annual mean pH value in the rainwater in China was 6.54 ± 0.72. The rainwater pH in winter (6.01 ± 0.41) was significantly lower than those observed during summer (6.74 ± 0.64), spring (6.71 ± 0.71) and autumn (6.71 ± 0.69). The spatial econometric model indicated that socioeconomic indicators including per capita gross industrial production (GIP), ratio of built-up area to the urban land (RBU), foreign direct investment (FDI), SO2 emission, and meteorological factors of annual mean precipitation (AMP), and annual mean relative humidity (AMRH) were the main factors for the acid deposition. The geographical detector technique implied that the power of determinants were in the order of AMRH (10.00%) = AMP (10.00%) > SO2 emission (8.51%) > FDI (8.32%) > RBU (7.64%) > per capita GIP (7.00%). The GWR implied that GIP, FDI, and SO2 emission made relatively higher contribution to acid deposition in East China relative to other regions owning to the huge population and the higher energy consumption. The higher rainfall amount and RH in Southeast China significantly increased the pollutant deposition fluxes and promoted the heterogeneous transformations of precursors of acid rain, respectively. The findings herein shed light upon the socioeconomic forces for the acid deposition in China for the first time and provided the new information for government sectors to control the acid rain pollution in the future.

Development of atmospheric acid deposition in China from the 1990s to the 2010s

Atmospheric acid deposition is a global environmental issue. China has been experiencing serious acid deposition, which is anticipated to become more severe with the country's economic development and increasing consumption of fossil fuels in recent decades. We explored the spatiotemporal variations of acid deposition (wet acid deposition) and its influencing factors by collecting nationwide data on pH and concentrations of sulfate (SO42−) and nitrate (NO3−) in precipitation between 1980 and 2014 in China. Our results showed that average precipitation pH values were 4.59 and 4.70 in the 1990s and 2010s, respectively, suggesting that precipitation acid deposition in China has not seriously worsened. Average SO42− deposition declined from 40.54 to 34.87 kg S ha−1 yr−1 but average NO3− deposition increased from 4.44 to 7.73 kg N ha−1 yr−1. Specifically, the area of severe precipitation acid deposition in southern China has shrunk to some extent as a result of controlling the pollutant emissions; but the area of moderate precipitation acid deposition has expanded in northern China, associated with rapid industrial and transportation development. Furthermore, we found significant positive correlations between precipitation acid deposition, energy consumption, and rainfall. Our findings provide a relatively comprehensive evaluation of the spatiotemporal dynamics of precipitation acid deposition in China over past three decades, and confirm the idea that strategies implemented to save energy and control pollutant emissions in China have been effective in alleviating precipitation acid deposition. These findings might be used to demonstrate how developing countries could achieve economic development and environmental protection through the implementation of advanced technologies to reduce pollutant emissions.

Estimates of Economic Loss of Materials Caused by Acid Deposition in China

China is facing severe acid deposition. Acid deposition can cause economic loss, corrosion, and damage to materials, and the reduction of material life span. In this study, the administrative areas (including municipalities, prefecture-level cities, regions, autonomous prefectures, and leagues—hereinafter referred to the cities) at and above the prefecture level were selected as research areas. Monitoring results of acid precipitation and ambient air sulfur dioxide (SO2) from the China National Environmental Monitoring Network were used, research findings available domestically and abroad were summarized, and a set of material exposure inventory per capita was established, based on urban and rural areas in Eastern, Central, and Western China regions. Losses of construction materials caused by acid deposition in the cities were assessed by using the said materials’ acid rain exposure response functions available. The results showed that, material loss caused by acid deposition in China was 32.165 billion yuan (RMB, similarly hereinafter) in 2013, accounting for 0.057% of GDP (Gross Domestic Product) and 3.4% of the total investment for environmental pollution governance this year.

Is surface water acidification a serious regional issue in China?

Acidic deposition used to cause severe surface water acidification in Europe and the North America, but no damage of surface water acidification was reported under continuous heavy acid deposition in China. We present the first detailed study on regional surface water acidification in southern and northeastern China based on a survey of 255 forested headwater streams, which were investigated during 2010-2015 to explore the status and mechanism of surface water acidification. South China has a subtropical climate with high acid deposition, whereas northeast China is located in a cold temperature zone with relatively low acid deposition. High pH and acid neutralizing capacity (ANC) were observed for almost all of the streams, indicating that surface water acidification may not be a serious regional issue in China both at present and in the future. In northeast China, where soil types are similar in low weathering rate to those in Northern Europe and North America, the ANC of surface waters was lower than that in South China, indicating a higher acid-sensitivity of the surface water. In comparison, the high pH and ANC of streams in southwest China resulted from high soil weathering and atmospheric calcium (Ca) deposition, despite elevated atmospheric acid inputs due to the high sulfur (S) and nitrogen (N) deposition. Comparison of stream nitrate (NO3-) and sulfate (SO42-) concentrations with modeled N and S deposition showed significant N and possible S sinks in the catchments in south China, probably due to denitrification of NO3- in groundwater discharge zone and SO42- adsorption by acid soils respectively, which may also buffer the acidifying effect of S and N depositions. It seems that considerable NO3- leaching to stream waters does not occur in China unless N deposition is higher than 1.8keq·ha-1·yr-1 (2.50g N·m-2·yr-1) (or greater values in certain regions).

Wet acid deposition in Chinese natural and agricultural ecosystems: Evidence from national‐scale monitoring

AbstractAcid deposition in precipitation has received widespread attention. However, it is necessary to monitor the acid deposition in Chinese agricultural and natural ecosystems because data derived from traditional urban/suburban observations might overestimate it to some extent. In this study, we continuously measured the acid deposition through precipitation (pH, sulfate (SO42−), and nitrate (NO3−)) in 43 field stations from 2009 to 2014 to explore the spatial patterns and the main influencing factors of acid deposition in Chinese agricultural and natural ecosystems. The results showed that the average precipitation pH at the 43 stations varied between 4.10 and 8.25 (average: 6.2) with nearly 20% of the observation sites being subjected to acid precipitation (pH < 5.6). The average deposition of SO42− and NO3− was 115.99 and 32.93 kg ha−1 yr−1, respectively. An apparent regional difference of acid deposition in Chinese agricultural and natural ecosystems was observed, which was most serious in south and central China and less serious in northwest China, Inner Mongolia, and Qinghai‐Tibet. The level of economic development and amount of precipitation could explain most of the spatial variations of pH, SO42−, and NO3− depositions. It is anticipated that acid deposition might increase further, although the current level of acid deposition in these Chinese agricultural and natural ecosystems was found to be less serious than projected from urban/suburban data. The control of energy consumption should be strengthened in future to prevent an increase of acid deposition in China.

Assessment of air quality benefits from the national pollution control policy of thermal power plants in China: A numerical simulation

In 2010, an emission inventory of air pollutants in China was created using the Chinese Bulletin of the Environment, the INTEX-B program, the First National Pollution Source Census, the National Generator Set Manual, and domestic and international research studies. Two emission scenarios, the standard failed emission scenario (S1) and the standard successful emission scenario (S2), were constructed based upon the Instructions for the Preparation of Emission Standards for Air Pollutants from Thermal Power Plants (second draft). The Fifth-Generation NCAR/Penn State Mesoscale Model (MM5) and the U.S. EPA Models-3 Community Multiscale Air Quality (CMAQ) model were applied to China to study the air quality benefits from Emission Standards for Air Pollutants from Thermal Power Plants GB13223-2011. The performance of MM5 and CMAQ was evaluated with meteorological data from Global Surface Data from the National Climatic Data Center (NCDC) and the daily Air Pollution Index (API) reported by Chinese local governments. The results showed that the implementation of the new standards could reduce the concentration of air pollutants and acid deposition in China by varying degrees. The new standards could reduce NO2 pollution in China. By 2020, for the scenario S2, the area with an NO2 concentration higher than the second-level emission standard, and the average NO2 concentration in 31 selected provinces would be reduced by 55.2% and 24.3%, respectively. The new standards could further reduce the concentration of declining SO2 in China. By 2020, for S2, the area with an SO2 concentration higher than the second-level emission standard and the average SO2 concentration in the 31 selected provinces would be reduced by 40.0% and 31.6%, respectively. The new standards could also reduce PM2.5 pollution in China. By 2020, for S2, the area with a PM2.5 concentration higher than the second-level emission standard and the average concentration of PM2.5 in the 31 selected provinces would be reduced by 17.2% and 14.7%, respectively. The new standard could reduce nitrogen deposition pollution in China. By 2020, for S2, the area with a nitrogen deposition concentration >2.0 tons·km−2 and the total nitrogen deposition in China would be reduced by 28.6% and 16.8%, respectively. The new standards could reduce sulfur deposition pollution in China. By 2020, for S2, the area with a sulfur deposition >1.5 tons·km−2 and the total sulfur deposition in China would be reduced by 55.3% and 21.0%, respectively.

Soil Vulnerability and Sensitivity to Acid Deposition in China

Sensitivity, in this context, refers to `the degree to which a system will respond to acid deposition', while vulnerability is `the extent to which acid deposition may damage or harm system'.Thus, sensitivity stresses the risk of an increase in the rateof change of the soil chemistry (the acidification rate), and vulnerability stresses the risk of damage to an organism or system (the acidification state). With regard to acid depositioneffects, both vulnerable and sensitive ecosystems are of concern;however, they are usually not well distinguished. The identification of ecosystems vulnerable (at risk for damage) or sensitive (high degree of response) to acid deposition is very important if policy makers are to derive cost-effective pollutioncontrol strategies. In this paper, the relative vulnerability andsensitivity of soils in China are assessed on the basis of soil base saturation and cation exchange capacity. Vulnerable and sensitive soils, as well as the risks associated with acid deposition, are identified. The characteristics of these two types of soils and their responses to acid deposition are discussed. Finally, results obtained by using different approaches are compared. The results show that the most vulnerable areas are located mainly in Guangdong, Guangxi, Guizhou, and Sichuan provinces andin the southern part of Yunnan province. On the other hand, themost sensitive areas are located mainly in Zhejiang, Jiangxi, Hunan, and Fujian provinces and in the northern part of Yunnanprovince. Combining the distribution of vulnerability and sensitivity with the sulfur deposition shows that the areas around Chongqing City and central Guizhou province are at highrisk for damage by acid deposition; central Zhejiang province andthe boundary region between Hunan and Jiangxi provinces would be at high risk for a high rate of acidification if acid depositionwere to increase.

The Importance of Calcium Deposition in Assessing Impacts of Acid Deposition in China

The extensive use of coal as an energy carrier in China has led to high deposition of sulfur in a large part of the country. In the southern part of China large areas receive acid deposition, while in the northern part of the country the acidity of the emissions is neutralized by alkaline dust from the desert areas. In this paper we demonstrate the importance of knowing the sources and deposition patterns of base cations when assessing the effects of changes in sulfur emissions. Regional-scale data of both sulfur and calcium deposition from modeling and monitoring are combined in order to demonstrate how the acidity of deposition in China has changed historically and may change in the future. The importance of base cation deposition is also demonstrated using the dynamic acidification model MAGIC with input data from an intensive monitoring site outside Guiyang. It is not known what fraction of the deposited base cations is of natural origin and anthropogenic origin, respectively. The relative source strength varies greatly between regions. Future effects of emission changes are highly dependent on the relative reduction in sulfur and base cation emissions.

Critical loads of acid deposition on soil in China.

Critical loads of acid deposition havebeen mapped for Chinese soils using a modifiedsemi-quantitative method, which is based on theminerals controlling weathering and soil development,and corrected by introducing an Arrhenius relationshipto describe the effect of temperature and a weightedaveraging approach to evaluate the effect of soiltexture, land use and precipitation. As a consequenceof these modifications, the method has been quantifiedand can be more widely used. Results from this studyshow that the lowest critical loads of acid depositionin China, i.e., those areas most sensitive to aciddeposition, occur in the Podzolic soils in theNortheast, followed by Latosol, Dark brown forest soiland Black soil areas. The Ferralsol areas in SouthChina are intermediate, tolerating about 0.8–1.6 g m-2 yr-1 sulfur deposition. The highestcritical loads of acid deposition are mainly locatedin the Alpine soil areas on the Plateau of Tibet andareas of Xerosol and Podocal soil in Northwest China.The reason for lower critical loads in the Northeastrelative to South China can be attributed to thedifference of temperature, soil moisture and soiltexture. Comparison of critical loads with the sulfurdeposition in 1995 identifies almost one fourth of theland area in southeast China to be subject to risk of acidification.