Hazardous chemical accidents pose a severe threat to human and economic activities. To explore the causes and paths of hazardous chemical explosion accidents (HCEAs) in China, a qualitative and quantitative model was proposed in this study. Firstly, 129 accident cases were collected from the official website of the Ministry of Emergency Management of the People's Republic of China, and the accident factors were screened based on association rule (AR). Then, the fault tree (FT) structure of HCEA was developed by the AR, and the qualitative model was transformed into a quantitative Bayesian network (BN) model. Finally, the accident path, the importance size of the basic events, and the sensitivity of the direct cause of the accident were uncovered based on the BN model. The results show that improper temperature control due to operating procedures is the most likely route to accidents. Among the basic events, process management and operating procedures issues ranked the first in importance, with the most significant impact on HCEA. The sensitivity of improper temperature control far exceeds other direct causes and is most likely to induce accidents directly. According to the study results, some feasible measures are put forward to improve the safety management of hazardous chemical production.
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