This work presents an investigation on phase equilibria in partially miscible systems comprised of water, esters, and alkanols. Experimental liquid–liquid equilibria (LLE) were determined for ternaries of water+H2u–1Cu–1CO2CvH2v+1+CwH2w+1(OH) (u = 3,4; v = 2,3; w = 1–4) at 298.15 K and for the four corresponding water+ester binaries, in the temperature interval T = [283–328] K. The results reveal a complex behavior of the ternary LLE. The ester barely dissolves in the aqueous phase, even in the presence of alkanol (xmax,esterII ≈ 0.15). However, the organic phase contains high quantities of water when the compositions approach the plait point (xmax,waterI ≈ 0.75). Data modeling was carried out with a multiparametric model, obtaining an acceptable correlation with a maximum deviation in the compositions of sx = 0.031 for the system water(1)+propyl butanoate(2)+propan-1-ol(3). Estimations with COSMO-RS and UNIFAC differed from experimental values in all cases, especially in the systems containing propan-1-ol, since both models predict a nonreal immiscibility at 298.15 K in the binary water+propan-1-ol. Therefore, the simulation of the extractive process using UNIFAC was not adequate.
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