Accelerator Mass Spectrometry 14C Ages Research Articles

Relict and Modern Sediments on the Continental Shelf of the Northern South China Sea: A Reconsideration

AbstractUnderstanding the temporal‐spatial patterns of modern and relict sediments is of importance for assessing changes in the Quaternary environment and sea‐level. Sedimentological and geochemical data is presented, along with in situ shell‐based accelerator mass spectrometry 14C ages of 30 samples from the surface sediments on the northern shelf of the South China Sea (NSSCS). The authors’ data show that the NSSCS surface sediments exhibit considerable diversity in composition. Modern sediments are primarily constrained to the NW inner shelf, which is fed by fluvial sands sourced from Coastal South China river systems and dominated by the Pearl River Estuary delivery. The transport and discharge of the terrestrial sediments to the NSSCS is highly influenced by the Guangdong Longshore Current and its secondary cyclonic eddies. Relict sediments dominated by well‐sorted, medium‐ and coarse‐grained sands were identified in the NW Shenhu and NW Dongsha areas of the outer NSSCS. The sedimentology and geochemistry of the relict sediments imply that they were deposited in a dry and cold environment either during the low sea levels of the late Pleistocene (∼40 ka) or the early Holocene (∼10 ka). To the east, the Taiwan Shoal and vicinity are dominated by a sand mixture, at which the relict sediments were reworked by terrigenous supply and modern hydrodynamic environment due to the compound action of the Guangdong Longshore Current, seasonal cyclones, and Kuroshio Intrusion. The present isobaths of ∼−90 m in the NSSCS might be the reflective of the early Holocene coastal delta or the last glacial maximum shoreline.

Dating of a late Quaternary loess section from the northern slope of the Tianshan Mountains (Xinjiang, China) and its paleoenvironmental significance

Late Quaternary loess deposits from the Tianshan Mountains are potentially valuable archives for the study of environmental change. However, the reported chronologies of the loess deposits in this area are still controversial. Previous studies have shown that there remain discrepancies between the optically stimulated luminescence (OSL) ages and accelerator mass spectrometry (AMS) 14C ages of the loess deposits from the Yili Valley. To establish a robust chronological sequence of the Shichengzi section (SCZ17) from the northern slope of the Tianshan Mountains in Xinjiang, we adopted both AMS14C and quartz OSL dating methods and the dates-based chronology was further refined by correlating sedimentary proxies (loss-on-ignition and grain size) with the proxy information from other sequences. Comparison of the AMS 14C and quartz OSL ages suggests that the AMS 14C ages of bulk organic matter are generally younger than the quartz OSL ages, with the maximum age discrepancy reaching up to ~10 ka. Regional correlation of the Holocene lithology of the SCZ17 section with other Holocene lithologies from the Tianshan Mountains reveals that the Holocene paleosol formation occurred in the late Holocene. The analyzed proxy data (e.g., grain size, carbonate content) indicate a cold and dry climate from 21.6 to ~10 ka, and a persistent wetting trend during the past ~10 ka. This study provided interesting and new evidence of late Quaternary environmental changes in arid central Asia.

Diet and Radiocarbon Dating of Tollund Man: New Analyses of an Iron Age Bog Body from Denmark

ABSTRACTTollund Man is one of the most famous Iron Age bog bodies due to his well-preserved head. Since he was unearthed in 1950 in Bjældskovdal, Denmark, he has been subjected to several scientific investigations, but until now no attempts to reconstruct his general diet through isotope analyses have been conducted. Furthermore, previous radiocarbon (14C) analyses have only been able to date him broadly to the 3rd–4th century BC. In this study, stable isotope measurements (δ13C, δ15N) on bone collagen from Tollund Man’s femur and rib showed that the diet of Tollund Man was terrestrial-based and that the crops he ate probably were grown on manured fields. Accelerator mass spectrometry (AMS) 14C dates were obtained on both the <30kDa and >30kDa fractions of ultrafiltered collagen. Results showed that the ultrafiltration removed contamination from older substances from the burial environment. The femur was dated to 2330±23 BP, the rib to 2322±30 BP. These dates statistically agree with a previously published AMS 14C age on skin. By combining the new dates with the previous date of his skin it was possible to narrow down the age of Tollund Man to the period 405–380 cal BC (95.4% confidence interval).

Optical dating of Holocene sediments from the Yangtze River (Changjiang) Delta, China

Establishing a reliable chronology is essential for understanding delta evolution, which is normally performed using radiocarbon (14C) dating and the recently emerging technique of optically stimulated luminescence (OSL). The application of the latter one to the Holocene Yangtze River (Changjiang) Delta deposit is still quite limited. In this study, two 60.9-m-long cores were collected from Taizhou (TZ) and Nantong (NT) within the paleo-incised valley of the Yangtze River, and a total of seven and nine OSL samples were collected from the TZ and NT cores, respectively. In addition, ten accelerator mass spectrometry (AMS) 14C ages of the TZ core were presented with eight AMS 14C ages that were previously obtained from the NT core. The single-aliquot regenerative-dose (SAR) protocol was applied to coarse silt-sized (45–63 μm) and fine sand-sized (90–125 μm) quartz. The results showed that the grains in the 45–63 μm size fractions appeared to be better bleached than those in the 90–125 μm size fractions, and the detection of insufficiently bleached sediments is required in order to obtain accurate age estimates. The ages adopted for the samples range from 3 ka to 9 ka for the TZ core, and from 1 ka to 14 ka for the NT core, which were in general internally coherent within the limits of experimental errors and with respect to their stratigraphic order. The AMS 14C age of the TZ core were significantly older than their OSL ages, while those from the NT core generally showed good agreement with their OSL ages. One should be cautious when using AMS 14C to date deltatic deposits. Based on the OSL ages, two periods of rapid accumulation rates can be found in both cores, which are linked to the rapid sea level rise in early Holocene and migration of delta front facies in late Holocene. These investigations indicate that OSL technique is an effective method with which to date Holocene deltaic deposits, especially in coarse sedimentary layers where organic carbon material is sparse.

Coupled European and Greenland last glacial dust activity driven by North Atlantic climate

Centennial-scale mineral dust peaks in last glacial Greenland ice cores match the timing of lowest Greenland temperatures, yet little is known of equivalent changes in dust-emitting regions, limiting our understanding of dust-climate interaction. Here, we present the most detailed and precise age model for European loess dust deposits to date, based on 125 accelerator mass spectrometry 14C ages from Dunaszekcső, Hungary. The record shows that variations in glacial dust deposition variability on centennial-millennial timescales in east central Europe and Greenland were synchronous within uncertainty. We suggest that precipitation and atmospheric circulation changes were likely the major influences on European glacial dust activity and propose that European dust emissions were modulated by dominant phases of the North Atlantic Oscillation, which had a major influence on vegetation and local climate of European dust source regions.

Geochronology and mineral composition of the pleistocene sediments in Xitaijinair Salt Lake region, Qaidam Basin: Preliminary results

Xitaijinair (XT) Salt Lake, located in the western Qaidam Basin, is significant for reconstructing the evolution of inland drying climate. However, the chronological and mineralogical records from this lake are rare. This study investigated the chronology (accelerator mass spectrometry (AMS) 14C ages and optically stimulated luminescence (OSL) ages) and mineral compositions of sediment in the 240-cm-deep XT Section of the Xitaijinair Salt Lake region. The conclusions are drawn as follows: (1) Nine AMS 14C ages, ranging between 33 and 40 cal ka BP, are obviously younger than the two OSL ages (57.9 and 69.1 ka). The 14C ages probably reflect contamination with modern carbon. (2) Both 14C and OSL ages indicate that the surface of Xitaijinair Salt Lake region has suffered erosion. (3) The sediments of XT Section are composed of silicates (quartz, muscovite, clinochlore and albite), carbonates (calcite, dolomite, and ankertie), halite and gypsum.

Sedimentology, structure and age estimate of five continental slope submarine landslides, eastern Australia

ABSTRACTSedimentological and accelerator mass spectrometry (AMS) 14C data provide estimates of the structure and age of five submarine landslides (∼0.4–3 km3) present on eastern Australia's continental slope between Noosa Heads and Yamba. Dating of the post-slide conformably deposited sediment indicates sediment accumulation rates between 0.017 m ka–1 and 0.2 m ka–1, which is consistent with previous estimates reported for this area. Boundary surfaces were identified in five continental slope cores at depths of 0.8 to 2.2 m below the present-day seafloor. Boundary surfaces present as a sharp colour-change across the surface, discernible but small increases in sediment stiffness, a slight increase in sediment bulk density of 0.1 g cm–3, and distinct gaps in AMS 14C ages of at least 25 ka. Boundary surfaces are interpreted to represent a slide plane detachment surface but are not necessarily the only ones or even the major ones. Sub-bottom profiler records indicate that: (1) the youngest identifiable sediment reflectors upslope from three submarine landslides terminate on and are truncated by slide rupture surfaces; (2) there is no obvious evidence for a post-slide sediment layer draped over, or burying, slide ruptures or exposed slide detachment surfaces; and (3) the boundary surfaces identified within the cores are unlikely to be near-surface slide surfaces within an overall larger en masse dislocation. These findings suggest that these submarine landslides are geologically recent (<25 ka), and that the boundary surfaces are either: (a) an erosional features that developed after the landslide, in which case the boundary surface age provides a minimum age for the landslide; or (b) detachment surfaces from which slabs of near-surface sediment were removed during landsliding, in which case the age of the sediment above the boundary surface indicates the approximate age of landsliding. While an earthquake-triggering mechanism is favoured for the initiation of submarine landslides on the eastern Australian margin, further evidence is required to confirm this interpretation.

Comparison between luminescence and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia

Dust depositions are critical archives for understanding interior aridification and westerly climatic changes in Central Asia. Accurate and reliable dating of loess is very important for interpreting and correlating environmental records. There remains a disparity between luminescence ages and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia. In this study, we establish a closely spaced quartz optically stimulated luminescence (OSL) chronology for the 20.5-m-thick Nilka loess section in the Ili Basin. Based on OSL ages, two intervals of higher mass accumulation rate occurred at 49–43 ka and 24–14 ka. We further compare these OSL ages with 23 accelerator mass spectrometry (AMS) 14C ages of bulk organic matter. The results indicate that the OSL and radiocarbon ages agree well for ages younger than ca. 25 14C cal ka BP. However, beyond 30 cal ka BP, there is no consistent increase in AMS 14C age with depth, while the OSL ages continue to increase. These differences confirm the observation that the AMS 14C ages obtained using conventional acid–base–acid (ABA) pretreatment are severely underestimated in other terrestrial deposits in Central Asia, which could be due to 2–4% modern carbon contamination. However, OSL dating is applicable for constructing an accurate chronology beyond 30 cal ka BP. We suggest caution when interpreting paleoenvironmental changes based on radiocarbon ages older than 25 cal ka BP.

Combining radiocarbon and single-grain optically stimulated luminescence methods to accurately date pre-ceramic irrigation canals, Tucson, Arizona

We present 12 accelerator mass spectrometry (AMS) 14C and five quartz single-grain optically stimulated luminescence (OSL) ages from three Early Agricultural period irrigation canals recently discovered in the floodplains of the Santa Cruz River and Rillito Creek in Tucson, Arizona. Significant discrepancies in the AMS 14C ages are associated with fluvial redeposition of charcoal, producing at times, age overestimates of ∼1000 years. Single-grain OSL ages on canal sediments and application of a minimum age model accurately date the final operation of the canals but have relatively large standard errors of several hundred years. Based on single-grain OSL, one canal dates 730–310 B.C. and the other two date 560–100 B.C. This corresponds with a period of predominant floodplain aggradation (∼500 B.C.–A.D. 1) conducive to water control and irrigation agriculture. Stratigraphic evidence of uncontrolled flooding and rapid sedimentation is present in all three canals and marks the abandonment of two canals. Determining the age of the earliest canals is important for understanding the origins of water management and the transition from foraging to intensive agriculture in the North American Southwest. Due to potential problems with reworked organic material for 14C dating and partial bleaching (resetting) of luminescence signals in fluvial settings, we recommend a combined AMS 14C and single-grain OSL approach for dating early canals.

Large-scale landslides in Toyama Prefecture, central Japan, and their probable relationship with earthquakes

Large-scale landslides along the Kubusu and Besso rivers in Toyama Prefecture are developed in the Miocene Iwaine Formation, which is composed of andesitic lava, tuff, and tuff breccia. In the middle member of this formation, the tuff is easily altered to montmorillonite-bearing rock, and subsequently plays an important role in the development of landslides events, which tend to be large-scale events, as the massive lava of the upper member forms a cap rock over the tuff. The Kiritani and Koinami basins, which are flat intermontane basins located along the Kubusu and Besso rivers, respectively, are interpreted as landslide-dammed lakes, later filled with sediment. Accelerator mass spectrometry 14C ages show that the landslides forming each dam occurred simultaneously, at approximately 2500 BP. These ages were measured from wood fragments embedded in the landslide material of Kiritani, and from an in situ stump drowned during the impoundment of Koinami. If the trigger of these landslides was an earthquake, it is most likely to have been the penultimate event along the Atotsugawa fault zone.

A combined luminescence and radiocarbon dating study of the Ili loess, Central Asia

Similar to the loess in the Chinese Loess Plateau (CLP), the loess deposits in the Ili basin of Central Asia arid area play an important role in understanding the climate and environmental changes. However, in contrast to the intensively investigated loess deposits in the CLP, the Ili loess is still insufficiently known and poorly understood. The geochronology study of the Ili loess remains controversial. In order to examine the potential of optically stimulated luminescence (OSL) dating for the Ili loess, we carry out a combined luminescence and radiocarbon dating study on a 6.9 m loess section in the south margin of the Ili basin. Polymineral fine grains were investigated by post infrared (IR) OSL using a Multiple-Aliquot Regenerative-dose (MAR) protocol. Radiocarbon dating of organic carbon were carried in a 3 Megavolt (MV) multi-element Accelerator Mass Spectrometry (AMS). The results indicate that the OSL ages are in agreement with the observed stratigraphy in the field, which is well correlated with that of the CLP, but the AMS 14C ages are much younger than the OSL and assumed stratigraphical ages. Thus, the OSL dating technique may provide an absolute chronology in this loess section. Further methodological approaches and more samples analysis will lead to the improvement of this chronology for high-resolution paleoclimatic interpretation.

High-Resolution Age Model Based on AMS Radiocarbon Ages for Kettle Lake, North Dakota, USA

A high-resolution age model was developed for Kettle Lake, North Dakota, USA, from a series of 53 accelerator mass spectrometry (AMS) radiocarbon ages calibrated with Bayesian statistical methods, which provide a monotonically increasing series of calibrated ages with depth. Evident in the sediment are several slumps, debris flows, or landslides, which are confirmed by 14C dating. Removal of these facies produces a continuous sedimentary sequence for the past 13,000 yr with exception of one ≃260-yr hiatus associated with a 1.5-m-thick slump deposit. All ages except one are on terrestrial macrofossils and charcoal. A test age on aquatic organic detritus shows a hardwater effect of 600 yr at ≃2000 cal BP. Two ages from the same level on herbaceous charcoal and Chenopodium seeds are statistically the same, which further demonstrates the suitability of charcoal from grassland environments for AMS 14C age control. However, 2 specimens of wood charcoal are too old relative to bracketing ages and glacial geologic history. These ages confirm the sedimentary interpretation of redeposition and provide a caution about the longevity of wood charcoal in the environment and its suitability for age control in lacustrine sediments.

Anatomy and sedimentary model of a hooked spit (Sylt, southern North Sea)

A sedimentary model for hooked spit depositional systems based on ground-penetrating radar and sedimentological data is presented. The recurved main spit of Sylt Island (southern North Sea) is dominated by migrating sand dunes; the investigated hooked spit exhibits a system of foredune ridges, oriented perpendicular to the dunes of the recurved spit. The development of the hooked spit is related closely to the presence of an adjacent tidal inlet, where strong tidal currents and a steep bathymetry prevent a further northward progradation of the main spit and trigger a deflection from northerly-directed to easterly-directed net sediment transport. Ground-penetrating radar data and shallow sediment cores reveal the sedimentary architecture of the hooked spit in high resolution and allow the proposition of a genetic stratigraphic model. It is shown that the growth of the hooked spit is controlled by the interplay of alongshore migrating foreshore beach drifts under fair-weather conditions and strong erosional events, interpreted as the result of rare severe storms. These storms may excavate scarps in the backshore, which play an important role in the development of foredune ridges. Accelerator mass spectrometry 14C ages indicate an absolute age of at least 1300 years for the hooked spit, which possibly correlates with strengthened erosion of the main spit. In contrast to the main spit, where the sediment budget is negative nowadays, growth of the hooked spit beach accelerated significantly during the last decades. This effect can probably be attributed to enhanced beach-nourishments updrift along the main spit and makes the investigated hooked spit a natural laboratory to study the influence of increasing sediment supply into a system developing under the conditions of sea-level rise. The study shows that the same external forces lead to distinct progradational processes along one barrier-spit system.

Radiocarbon and Stable Carbon Isotope Ratio Data from a 4.7-Mlong Sediment Core of Lake Baikal (Southern Siberia, Russia)

A sediment core (VER99G12; core length, 4.66 m) was taken from the Buguldeika Saddle of Lake Baikal in 1999. Radiocarbon measurements of total organic carbon (TOC) and pollen concentrate fractions from the VER99G12 core were performed by a Tandetron accelerator mass spectrometry (AMS) system (Model-4130, HVEE) at Nagoya University. The AMS 14C ages showed that the VER99G12 core spans the past ∼30 cal ka BP (from the MIS 3 to present), and the average sedimentation rate of this core was calculated to be 13.6 cm/kyr based on the calibrated ages. This means that the time resolution of VER99G12 sediment samples in this study is better than ∼70–80 yr/cm. Stable carbon isotope ratios of TOC (δ13CTOC) in the VER99G12 core varied widely from about 26.6‰ to 31.3‰ during the last glacial/post-glacial transition period (about 17–12 cal ka BP). Therefore, a rapid change in the carbon sources in Lake Baikal occurred in the last glacial/post-glacial transition period is concluded.

14C Ages of 43 Consecutive Single-Year Tree Rings Between 2710 and 2655 cal BP Using Accelerator Mass Spectrometry

We have measured the radiocarbon ages of 43 consecutive single-year tree rings using accelerator mass spectrometry (AMS) with a statistical accuracy of ∼2.3%. AMS 14C ages of the 36 viable samples are between 2708 and 2666 cal BP, a period in which the Δ14C of the IntCal04 curve (Reimer et al. 2004) shows an enhancement. The 14C ages of the samples are scattered with a Gaussian distribution around the interpolated IntCal04 calibration curve. The time profile of the deviations of the 36 14C ages from the interpolated IntCal04 calibration curve indicates a linear trend and a characteristic variability rather than a random fluctuation around the curve. The trend indicates a higher gradient than that of the interpolated IntCal04 calibration curve. The profile implies a periodic variation of approximately 11 yr and an amplitude of roughly 18 14C yr.

Further rock magnetic and chronostratigraphic results on reversal excursions during the last 50 ka as derived from northern high latitudes and discrepancies in precise AMS14C dating

A total of five sediment cores from three sites, the Arctic Ocean, the Fram Strait and the Greenland Sea, yielded evidence for geomagnetic reversal excursions and associated strong lows in relative palaeointensity during oxygen isotope stages 2 and 3. A general similarity of the obtained relative palaeointensity curves to reference data can be observed. However, in the very detail, results from this high-resolution study differ from published records in a way that the prominent Laschamp excursion is clearly characterized by a significant field recovery when reaching the steepest negative inclinations, whereas only the N–R and R–N transitions are associated with the lowest values. Two subsequent excursions also reach nearly reversed inclinations but without any field recovery at that state. A total of 41 accelerator mass spectrometry (AMS) 14C ages appeared to allow a better age determination of these three directional excursions and related relative palaeointensity variations. However, although the three sites yielded more or less consistent chronological as well as palaeomagnetic results a comparison to another site, PS2644 in the Iceland Sea, revealed significant divergences in the ages of the geomagnetic field excursions of up to 4 ka even on basis of uncalibrated AMS 14C ages. This shift to older 14C ages cannot be explained by a time-transgressive character of the excursions, because the distance between the sites is small when compared with the size of and the distance to the geodynamo in the Earth's outer core. The most likely explanation is a difference of reservoir ages and/or mixing with old 14C-depleted CO2 from glacier ice expelled from Greenland at site PS2644.

Etruscan archaeometallurgy record in sediments from the Northern Tyrrhenian Sea

The island of Elba has been known since antiquity as the major source of metals, especially iron, for the Etruscan civilisation. Unfortunately, the archaeometallurgic record of the island has been destroyed during our century so the present knowledge of this history is very poor and only historical sources constrain the timing. We present in this article indirect evidence of this activity buried in the sea deep that will shed new light on the archaeometallurgic history of the Western Mediterranean. Magnetic properties of marine sediments collected in the Corsica Channel imply enrichment in ferrimagnetic minerals and trace metals related to anthropic impact. Accelerator mass spectrometry 14C ages suggest that the contamination started about 4000 years ago; we attribute it to emissions of fly-ash from the Etruscan smelting technologies for metal production. These results show that archaeometallurgic activity started on Elba Island in the II Millennium BC, much earlier than previously assumed.

14C Ages of a Varved Last Glacial Maximum Section Off Pakistan

In a core off Pakistan, we obtained 38 14C analyses by accelerator mass spectrometry (AMS) from a 4.4-m-thick, expanded, annually-laminated Last Glacial Maximum (LGM) section, bracketed by bioturbated intervals ascribed to the Heinrich-1 (H1) and Heinrich-2 (H2) equivalent events (52 14C analyses between 24–15 kyr BP). A floating varve age scale, anchored to the oxygen isotope record of the layer-counted GISP2 ice core at the H2/LGM boundary, results in an annually dated record for the LGM from 23,450–17,900 cal BP. The floating varve scale of the LGM provides us with a tentative calibration of local marine AMS 14C age dates to calendar years.

Late Holocene extinction of Finsch's duck (Chenonetta finschi), an endemic, possibly flightless, New Zealand duck

Finsch's duck (Chenonetta finschi), an extinct, possibly flightless New Zealand endemic, was widely distributed and apparently abundant immediately before human settlement of New Zealand, but its bones have rarely been identified in archaeological sites. Its extinction has been variously attributed to habitat changes, predation by the introduced Pacific rat (Rattus exulans), and human predation. Discriminating between possible causes of its extinction hinges on determining the relative timing of phases of the extinction process and the arrival of rats and humans. Methodological problems of determining the time of extinction of fossil species are reviewed. Bayesian statistical analysis of a series of accelerator mass spectrometry 14C ages on gelatin from Finsch's duck bones from non‐cultural deposits suggests that the species began to decline before widespread Polynesian settlement and that it was much reduced in range and numbers by the time extensive human predation and habitat alteration began. Possible causes of its extinction after Polynesian settlement are discussed.

Late Holocene extinction of the New Zealand owlet‐nightjar Aegotheles novaezealandiae

The New Zealand owlet‐nightjar (Aegotheles novaezealandiae) was a small (c. 150 g), almost flightless endemic bird that was widely distributed before human settlement. It was extinct before European settlement and has not so far been found definitely in a Polynesian cultural context. A series of accelerator mass spectrometry 14C ages on gelatin from owlet‐nightjar bones from non‐cultural deposits was analysed using Bayesian statistics. The results indicate that the owlet‐nightjar may have begun to decline before Polynesian settlement. Such a decline would be consistent with the effects of predation by a new predator—most probably the Pacific rat Rattus exulans.