Ac Stark Research Articles

Analysis of Imperfect Rephasing in Photon Echo-Based Quantum Memories

Over the last two decades, quantum memories have been intensively studied for potential applications of quantum repeaters in quantum networks. Various protocols have also been developed. To satisfy no noise echoes caused by spontaneous emission processes, a conventional two-pulse photon-echo scheme has been modified. The resulting methods include double-rephasing, ac Stark, dc Stark, controlled echo, and atomic frequency comb methods. In these methods, the main purpose of modification is to remove any chance of a population residual on the excited state during the rephasing process. Here, we investigate a typical Gaussian rephasing pulse-based double-rephasing photon-echo scheme. For a complete understanding of the coherence leakage by the Gaussian pulse itself, ensemble atoms are thoroughly investigated for all temporal components of the Gaussian pulse, whose maximum echo efficiency is 26% in amplitude, which is unacceptable for quantum memory applications.

Investigating ground-state fine-structure properties to explore suitability of boronlike S11+−K14+ and galliumlike Nb10+−Ru13+ ions as possible atomic clocks

We study various properties of the $2p\phantom{\rule{0.16em}{0ex}}^{2}P_{1/2}\ensuremath{-}2p\phantom{\rule{0.16em}{0ex}}^{2}P_{3/2}$ fine-structure splittings in the boronlike ${\mathrm{S}}^{11+}, {\mathrm{Cl}}^{12+}, {\mathrm{Ar}}^{13+}$, and ${\mathrm{K}}^{14+}$ ions and the $4p\phantom{\rule{0.16em}{0ex}}^{2}P_{1/2}\ensuremath{-}4p\phantom{\rule{0.16em}{0ex}}^{2}P_{3/2}$ fine-structure splittings in the galliumlike ${\mathrm{Nb}}^{10+}, {\mathrm{Mo}}^{11+}, {\mathrm{Tc}}^{12+}$, and ${\mathrm{Ru}}^{13+}$ ions to find out the feasibility of using these highly charged ions as suitable optical atomic clocks. The roles of the electron correlations due to the Dirac-Coulomb-Breit Hamiltonian and accounting for lower-order quantum electrodynamics effects are shown explicitly in the calculations of electron affinities, excitation energies, transition-matrix elements, lifetimes, hyperfine-structure constants, and electric quadrupole moments of the states involved with clock transitions using a relativistic couple-cluster method. We also estimate the most commonly appearing systematic effects in the atomic clock experiments due to the electric quadrupole, the second-order Zeeman, both the dc and ac Stark, and the black-body radiation shifts in the aforementioned fine-structure splittings to demonstrate typical orders of magnitude of fractional frequency shifts.

Coherent spin-photon coupling using a resonant exchange qubit.

Electron spins hold great promise for quantum computation because of their long coherence times. Long-distance coherent coupling of spins is a crucial step towards quantum information processing with spin qubits. One approach to realizing interactions between distant spin qubits is to use photons as carriers of quantum information. Here we demonstrate strong coupling between single microwave photons in a niobium titanium nitride high-impedance resonator and a three-electron spin qubit (also known as a resonant exchange qubit) in a gallium arsenide device consisting of three quantum dots. We observe the vacuum Rabi mode splitting of the resonance of the resonator, which is a signature of strong coupling; specifically, we observe a coherent coupling strength of about 31 megahertz and a qubit decoherence rate of about 20 megahertz. We can tune the decoherence electrostatically to obtain a minimal decoherence rate of around 10 megahertz for a coupling strength of around 23 megahertz. We directly measure the dependence of the qubit-photon coupling strength on the tunable electric dipole moment of the qubit using the 'AC Stark' effect. Our demonstration of strong qubit-photon coupling for a three-electron spin qubit is an important step towards coherent long-distance coupling of spin qubits.

Terahertz emission from asymmetric, doped quantum wells under resonant pumping

When the intersubband transitions of a doped quantum well are strongly driven by a coherent optical pump, the bare energy levels are split into dressed doublets, a phenomenon known as the ac Stark (or Autler-Townes) effect. In time domain this can be understood as Rabi oscillations of the confined electrons between two subbands. Here we show how, by employing asymmetric quantum wells, the selection rule preventing emission from an upper to a lower state of the same doublet can be lifted. The fluorescence spectrum of such strongly-driven system is then marked by an additional peak that would appear at the Rabi frequency, in the terahertz portion of the electromagnetic spectrum.

Effects of free-electron-laser field fluctuations on the frequency response of driven atomic resonances

We study the effects of field fluctuations on the total yields of Auger electrons, obtained in the excitation of neutral atoms to a core-excited state by means of short-wavelength free-electron-laser pulses. Beginning with a self-contained analysis of the statistical properties of fluctuating free-electron-laser pulses, we analyse separately and in detail the cases of single and double Auger resonances, focusing on fundamental phenomena such as power broadening and ac Stark (Autler-Townes) splitting. In certain cases, field fluctuations are shown to influence dramatically the frequency response of the resonances, whereas in other cases the signal obtained may convey information about the bandwidth of the radiation as well as the dipole moment between Auger states.

Dynamic Stark effect and forbidden-transition spectral line shapes

We report on an experimental and theoretical study of the dynamic (ac) Stark effect on a forbidden transition. A general framework for parameterizing and describing off-resonant ac-Stark shifts is presented. A model is developed to calculate spectral line shapes resulting from resonant excitation of atoms in an intense standing light-wave in the presence of off-resonant ac-Stark shifts. The model is used in the analysis and interpretation of a measurement of the ac-Stark shifts of the static-electric-field-induced \mbox{${\rm 6s^2}~ ^1{\rm S}_0~\to ~{\rm 5d6s}~ ^3{\rm D}_1\:$} transition at 408 nm in atomic Yb. The results are in agreement with estimates of the ac-Stark shift of the transition under the assumption that the shift is dominated by that of the ${\rm 6s^2 \:} ^1{\rm S}_0\:$ ground state. A detailed description of the experiment and analysis is presented. A bi-product of this work is an independent determination (from the saturation behavior of the 408-nm transition) of the Stark transition polarizability, which is found to be in agreement with our earlier measurement. This work is part of the ongoing effort aimed at a precision measurement of atomic parity-violation effects in Yb.

Rotational spectroscopy of the first excited state of the acetylenic C–H stretch of 3-fluoropropyne performed by infrared-Fourier transform microwave–microwave triple-resonance spectroscopy

The rotational spectra of 3-fluoropropyne in the ground and first excited acetylenic C–H stretch vibrational state have been measured. The pure rotational spectrum of the normal species and the 13C isotopomers were measured using FTMW-cwMW double-resonance spectroscopy based on the Autler–Townes (AC Stark) effect. The lineshape properties of this measurement make it possible to determine the transition strength, Δ J-selection rules, and the relative energy ordering of the quantum states. The frequency accuracy of this technique is tested against a previous pure rotational study of 3-fluoropropyne. The rotational spectrum of vibrationally excited state was obtained through IR-FTMW-cwMW methods. In this technique a single-longitudinal-mode pulsed infrared laser source vibrationally excites the acetylenic C–H stretch with J-selectivity. The rotational spectrum of the excited state is then obtained by FTMW and FTMW-cwMW double-resonance methods. The excited-state measurements have a signal-to-noise ratio comparable to the pure rotational spectrum. The residuals in the excited-state fit are larger than those obtained in the ground-state fit. This greater deviation from a standard asymmetric top spectrum is most likely due to weak perturbations to the acetylenic C–H spectrum.

High-Resolution Coherent Raman Spectra of Vibrationally Excited14N2and15N2

At an effective resolution of 0.001 cm−1, we measured coherent anti-Stokes Raman spectra of electrically discharged14N2and15N2in the electronic ground stateX1Σg+, specificallyQbranches of bands with Δv= 1 up tov′ = 8 for14N2andv′ = 7 for15N2, andOandSbranches of the fundamental band of15N2. Account is taken of small wavenumber shifts due to pressure, AC Stark, and |χ|2interference effects. Separate fits of theQ-branch data of each isotopic variant, combined with selected data from the literature, yield term coefficientsYklandUklor potential-energy coefficientscjthat reproduce wavenumbers of measured spectral lines generally within 0.004 cm−1. The value of the harmonic vibrational parameter ωeis 2358.5402(4) cm−1for14N2and 2278.7913(7) cm−1for15N2. Efforts to combine spectral data of both isotopic variants to distinguish adiabatic and nonadiabatic effects arising from incomplete separation of electronic and nuclear motion in N2were unsuccessful.