Ac Magnetic Measurements Research Articles

Preparation of Soft Magnetic Composite Using Cold Sintering Technique

Soft magnetic composites are powder metal products under development as an alternative to 2D laminates in electric motor applications. The 3D design of SMCs offers greater energy efficiency but poses a challenge to maintain adequate strength properties required for application. Soft magnetic composites are fabricated through compaction and heat treatment of iron particles coated with insulated coating to form a dense compact. The soft magnetic properties of the compact are affected by the properties of the iron powder, density of compact as well as the efficacy of forming uniform thin insulating coating at the particle boundary. Additionally, the strength of the compact is also affected by the nature of the insulating boundary at the particle interfaces. We report a low temperature process that involves cold sintering phenomenon to densify and strengthen soft magnetic composites. Iron powders have been modified using a co-precipitation method that forms a hydrated copper/iron oxalate coating on individual iron particles. Warm compaction of the modified iron powders at 100°C resulted in a highly dense soft magnetic composite which demonstrated ~ 3x improvement in strength. The compacts can be further heat treated in air at higher temperatures to form high strength oxide coating iron based soft magnetic composites. Results of the AC and DC magnetic measurements of fabricated cold sintered toroid compacts made as a function of heat treatment temperature reveal that DC permeability increased with heat treatment temperature. Analysis of AC core loss data showed that hysteresis power losses dominated the performance at lower heat treatment temperatures (< 300°C) beyond which dynamic core losses significantly increased.

Investigation of Gamma-Induced Changes to Screening Currents and AC Losses in Mono- Versus Multi-filamentary REBCO Coated Conductors Using DC and AC Magnetometry

REBCO (rare-earth barium copper oxide) coated conductor tapes are a highly attractive option for magnet materials in future tokamak fusion power plants. However, the threat of intense neutron and gamma radiation, together with AC losses during magnet coil ramping, has raised concerns around magnet coil lifetimes. Irradiation-induced changes to flux creep rate has been identified as a key performance-limiting factor in REBCO tapes at low temperatures and high fields post-irradiation with gamma rays; spontaneous flux creep contributes to hysteretic AC loss in REBCO cables under applied AC fields. Knowing that multi-filamentary tapes are under consideration for tokamaks as an AC loss mitigation, magnetic measurements and gamma irradiation experiments are presented here on striated and mono-filamentary YBCO tapes to investigate the differences in post-irradiation screening currents and AC losses. Reduction in AC losses improved magnetisation critical current density (Jc) retention after 1 MGy in the multi- relative to the mono-filamentary samples. After the 5 MGy dose, striations then made the multi-filamentary tape more susceptible to Jc degradation because of the thinner individual filament width. Scanning transmission electron microscopy analysis on an analogous GdYBCO mono-filamentary tape did not indicate the introduction of nm-scale amorphisation to the active GdYBCO layer after gamma irradiation. A potential theoretical explanation for the underlying mechanism altering the flux-pinning landscape across the REBCO layer surface in gamma-irradiated tapes is discussed. This work concluded that gamma effects on screening current capability should be considered in future tokamak REBCO tape qualification studies.

Manganese (III) Compounds Derived from R-Salicylaldoxime and 9-Anthracenecarboxylate Ligands: A Study of Their Synthesis and Structural, Magnetic, and Luminescent Properties

The reaction of Mn(II) salts in the air with different R-salicylaldehyde oximes and the sodium or cesium salts of 9-anthracenecarboxylato (9-AC) allows for the isolation of new six polynuclear compounds: [Mn3NaO(salox)3(9-AC)2(EtOH)3H2O]n·2EtOH (1), [Mn3NaO(3-Me-salox)3(9-AC)2(EtOH)3H2O]n·EtOH (2), [Mn6O2(salox)6(9-AC)2(EtOH)2(H2O)2]·3EtOH (3), [Mn3O(3-Me-salox)3(9-AC)(EtOH)3(H2O)]·1.8EtOH·3H2O (4), [Mn6O2(Me-salox)6(9-AC)2(EtOH)4(H2O)2]·0.5H2O (5), and [Mn6O2(Et-salox)6(9-AC)2(EtOH)4(H2O)2]·3EtOH (6). H2salox is a salicylaldehyde oxime, H2(3-Me-salox) is a 3-methyl-salicylaldehyde oxime, H2Me-salox is a 1-(2-hydroxyphenyl)ethan-1-one oxime and a H2-Et-salox is 1-(2-hydroxyphenyl)propan-1-one oxime. Structurally, compounds 1 and 2 consist of chains of trinuclear {MnIII3(μ3-O)(salox)3}+ units connected by Na+ ions. Compounds 3, 5, and 6 are hexanuclear units formed by two parallel trinuclear units {MnIII3(μ3-O)(salox)3}+ or {MnIII3(μ3-O)(Me-salox)3}+ planes related through an inversion center. Compound 4 consists of two isolated [Mn3O(3-Me-salox)3(9-AC)(EtOH)3(H2O)] trinuclear molecules in the unit cell showing crystallographic differences. Magnetic studies reveal a set of antiferromagnetic interactions in compounds 1 and 2 and a combination of antiferromagnetic and ferromagnetic interactions in compounds 3, 5, and 6. In all cases, the magneto-structural correlation between the intramolecular MnIII-N-O-MnIII torsion angle and the magnetic exchange within these units have been confirmed. For compounds 5 and 6, ac magnetic measurements reveal the slow relaxation of magnetization with moderate energy barriers of 19.9 cm−1 and 31.1 cm−1, respectively. Absorbance and fluorescence measurements in solution show the transitions of the 9-anthracenecarboxylate chromophore for all the compounds.

Crystal structure and cryomagnetic study of a mononuclear erbium(III) oxamate inclusion complex.

The synthesis, crystal structure and magnetic properties of an oxamate-containing erbium(III) complex, namely, tetrabutylammonium aqua[N-(2,4,6-trimethylphenyl)oxamato]erbium(III)-dimethyl sulfoxide-water (1/3/1.5), (C16H36N)[Er(C11H12NO3)4(H2O)]·3C2H6OS·1.5H2O or n-Bu4N[Er(Htmpa)4(H2O)]·3DMSO·1.5H2O (1), are reported. The crystal structure of 1 reveals the occurrence of an erbium(III) ion, which is surrounded by four N-phenyl-substituted oxamate ligands and one water molecule in a nine-coordinated environment, together with one tetrabutylammonium cation acting as a counter-ion, and one water and three dimethyl sulfoxide (DMSO) molecules of crystallization. Variable-temperature static (dc) and dynamic (ac) magnetic measurements were carried out for this mononuclear complex, revealing that it behaves as a field-induced single-ion magnet (SIM) below 5.0 K.

Fabrication of cold sintered soft magnetic composites using oxalate coated iron powders

The advancement of electric vehicles to replace gas-powered cars requires more efficient designs for electric motors. Three-dimensional flux motors, employing high-strength soft magnetic composites made from powdered metals, are considered a promising alternative to current state-of-the-art motors. In this study, we demonstrate that utilizing cold sintering of iron particles coated with hydrated oxalate leads to the creation of a soft magnetic composite with approximately 55 MPa of transverse rupture strength when compacted at 100 °C. Upon subsequent heat treatment up to 700 °C, the strength significantly rose to almost 219 MPa. During the heat treatment process, the oxalate undergoes transformation into iron/copper oxides. We systematically examined this chemical transformation using diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, transmission electron microscopy, and electron dispersive x-ray spectroscopy. Our findings from AC and DC magnetic measurements of the cold-sintered toroid, in relation to heat treatment temperature, demonstrate an increase in DC permeability with rising heat treatment temperatures. Additionally, our analysis of AC core loss data revealed that hysteresis power losses dominate the performance at lower heat treatment temperatures (<300 °C), beyond which dynamic core losses show significant escalation.

Novel lanthanide complexes with quinoline-2-carboxylic acid: Structural variety and magnetism

By means of the reaction of lanthanide chlorides with quinaldic (quinoline-2-carboxylic, HQA) acid in an aqueous-ethanolic medium in the presence of pyridine, the following complexes were obtained: the known binuclear [Nd2(QA)6(H2O)6]·3H2O (1) one and the novel compounds built of binuclear dicationic and mononuclear anionic moieties [Ln2(QA)4(H2O)4]2+[Ln(QA)4(H2O)]ˉ2·2EtOH·6H2O (Ln = Gd (2), Dy (3), Er (4), Yb (5)), as well as the anionic mononuclear one, [Hpy2]+[Er(QA)4]ˉ·4H2O (6). The complexes 2–5 were characterized by dc and ac magnetic measurements. Complex 3 exhibits the properties of a single-molecule magnet (SMM) in a zero static field with remagnetization barrier (Δeff/kB) of 82 K, while the other complexes display the properties of field-induced SMMs with the Δeff/kB values of 24, 19, and 33 K for the complexes 2, 4, and 5, respectively.

Eight-coordinate mono- and dinuclear Dy(III) complexes containing a rigid equatorial plane and an anisobidentate carboxylate ligand in the axial position: synthesis, structure and magnetism.

A rigid pentadentate chelating ligand (H2L) has been utilized to synthesize a series of octacoordinate mononuclear complexes, [Dy(L)(Ph3PO)(OOCR)] (where R = C6H5 (1), C(CH3)3 (2), CF3 (3)) and a dinuclear complex, [Dy2(L)2(Ph3PO)2{(OOC)2C6H4}] (4) based on the highly anisotropic Dy(III) ion. All the complexes were structurally characterized by single-crystal X-ray diffraction studies. The complexes were formed by the coordination action of the dianionic pentadentate ligand [L]2-, one phosphine oxide, and carboxylate ligands. DC and AC magnetic measurements were performed on 1-4. Complexes 1-4 show SMM behaviour, under zero DC field for 1 and 4, and under 500 Oe and 1000 Oe DC fields for 2 and 3 respectively, with thermally activated, Raman, and Raman and quantum tunnelling dominant relaxation mechanisms for 1 and 2, 3 and 4, respectively.

Magneto-structural correlation in lanthanide luminescent [2.2]paracyclophane-based single-molecule magnets.

The association of lanthanide ions and paracyclophane derivatives has been very scarcely reported in the literature. In this study, elaboration of five coordination lanthanide complexes involving the 1,4(1,4)-dibenzenacyclohexaphane-12,43-diylbis(diphenylphosphine oxide) ligand (L) was achieved with the determination of single-crystal X-ray diffraction structures of four mononuclear complexes of formula [Ln(hfac)3(L)] (hfac- = 1,1,1,5,5,5-hexafluoroacetylacetonate) (Ln = Dy(III) (1-Dy) and Yb(III) (2-Yb)) and [Ln(tta)3(L)] (tta- = 2-tenoyl-trifluoroacetylacetonate) (Ln = Dy(III) (3-Dy) and Yb(III) (4-Yb)) and one dinuclear complex [Na(Dy2(hfac)6(L)2)](BArF) (BArF- = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) (5-Dy). The compounds were characterized using elemental analysis, IR spectroscopy, DC and AC magnetic measurements and photophysical investigations. L is an efficient organic chromophore for the sensitization of both visible Dy(III) (1-Dy) and near-infrared Yb(III) (2-Yb and 4-Yb) luminescence. The combination of excitation and emission spectra allowed the determination of the crystal field spitting of both the 2F7/2 ground state and 2F5/2 excited state for 2-Yb and 4-Yb. Moreover, 3-Dy and the two Yb(III) derivatives displayed field-induced single-molecule magnet (SMM) behaviour with slow magnetic relaxation occurring through the Raman process only for 2-Yb and 4-Yb, whereas a combination of Orbach and Raman processes was identified for 3-Dy.

How the spin state tunes the slow magnetic relaxation field dependence in spin crossover cobalt(II) complexes.

A novel family of cobalt(II) compounds with tridentate pyridine-2,6-diiminephenyl type ligands featuring electron-withdrawing substituents of general formula [Co(n-XPhPDI)2](ClO4)2·S [n-XPhPDI = 2,6-bis(N-n-halophenylformimidoyl)pyridine with n = 4 (1-3) and 3 (4); X = I (1), Br (2 and 4) and Cl (3); S = MeCN (1 and 2) and EtOAc (3)] has been synthesised and characterised by single-crystal X-ray diffraction, electron paramagnetic resonance, and static (dc) and dynamic (ac) magnetic measurements combined with theoretical calculations. The structures of 1-4 consist of mononuclear bis(chelating) cobalt(II) complex cations, [CoII(n-XPhPDI)2]2+, perchlorate anions, and acetonitrile (1 and 2) or ethyl acetate (3) molecules of crystallisation. This unique series of mononuclear six-coordinate octahedral cobalt(II) complexes displays both thermally-induced low-spin (LS)/high-spin (HS) transition and field-induced slow magnetic relaxation in both LS and HS states. A complete LS ↔ HS transition occurs for 1 and 2, while it is incomplete for 4, one-third of the complexes being HS at low temperatures. In contrast, 3 remains HS in all the temperature range. 1 and 2 show dual spin relaxation dynamics under the presence of an applied dc magnetic field (Hdc), with the occurrence of faster- (FR) and slower-relaxing (SR) processes at lower (Hdc = 1.0 kOe) and higher fields (Hdc = 2.5 kOe), respectively. On the contrary, 3 and 4 exhibit only SR and FR relaxations, regardless of Hdc. Overall, the distinct field-dependence of the single-molecule magnet (SMM) behaviour along with this family of spin-crossover (SCO) cobalt(II)-n-XPhPDI complexes is dominated by Raman mechanisms and, occasionally, with additional temperature-independent Intra-Kramer [LS or HS (D > 0)] or Quantum Tunneling of Magnetisation mechanisms [HS (D < 0)] also contributing.

Probing Evolution of the Flux-Pinning Landscape in REBCO Coated Conductors Caused by Gamma Irradiation Using DC and AC Magnetometry: A Novel Approach to Tokamak Magnet Material Development

Optimisation of REBCO coated conductor tapes specifically for use in nuclear fusion will help improve the magnet component lifetimes in future tokamak reactor power plants. The focus of this work was exploration of a novel approach to irradiation studies on REBCO tapes, utilising multiple magnetic measurements to probe evolution of the REBCO flux-pinning landscape more deeply than reported in other studies, for the purpose of identifying primary limiting factors affecting performance. Gamma irradiation experiments were conducted, and pre-/post-irradiation results from DC and AC magnetic measurements using a Physical Property Measurement System (PPMS) are discussed. Magnetisation critical current density (Jc) decreased in all samples with increasing dose, except for the silver overlayer-only samples which did not contain artificial pinning centres (APCs), where Jc increased with dose. Removal of the copper stabiliser coupled with the presence of APCs allowed gamma irradiation to induce pinning force maximum peak shifts, from above 14 T before irradiation to below 9 T afterwards. Flux creep rate varied with the evolving pinning landscape, and the degree of Jc degradation directly correlated with creep rate fluctuations post-irradiation. Changes in critical temperature and diamagnetic saturation also corresponded with changes in Jc and flux creep rate. The major conclusion from this study was that minimisation of flux creep rate is the key to maintenance of performance under fusion-relevant operating conditions. Flux creep manifests as problematic AC losses in all high-temperature superconducting machines; therefore, future work will focus on reduction/prevention of the phenomenon to enhance longevity of performance in any application.

Diffusion of Alloying Cobalt Oxide (II, III) into Electrical Steel.

This paper aims to reduce power loss in electrical steel by improving its surface resistivity. The proposed approach involves introducing additional alloying elements through diffusion once the steel sheet reaches the desired thickness. Various effective techniques have been suggested and tested to enhance the resistivity of the strip. The method entails creating a paste by combining powdered diffusing elements with specific solutions, which are then applied to the steel's surface. After firing the sample, a successful transfer of certain elements to the steel surface is achieved. The amount and distribution of these elements can be controlled by adjusting the paste composition, modifying the firing parameters, and employing subsequent annealing procedures. This study specifically investigates the effectiveness of incorporating cobalt oxide (II, III) into non-oriented silicon iron to mitigate power loss. The experimental samples consist of non-oriented electrical steels with a composition of 2.4 wt% Si-Fe and dimensions of 0.305 mm × 300 mm × 30 mm. Power loss and permeability measurements are conducted using a single strip tester (SST) within a magnetic field range of 0.5 T to 1.7 T. These measurements are performed using an AC magnetic properties measurement system under controlled sinusoidal conditions at various frequencies. The research explores the impact of cobalt oxide (II, III) addition, observing successful diffusion into the steel through the utilization of a paste based on sodium silicate solution. This treatment results in a significant reduction in power loss in the non-oriented material, with power loss reductions of 14% at 400 Hz and 23% at 1 kHz attributed to the elimination of a porous layer containing a high concentration of the diffusing element. The formation of porosity in the cobalt addition was found to be particularly sensitive to firing temperature near the melting point. The diffusion process was examined through scanning electron microscopy (SEM) in combination with energy-dispersive X-ray spectroscopy (EDS). The results demonstrate improved power losses in the coated samples compared with the uncoated ones. In conclusion, this study establishes that the properties of non-oriented electrical steels can be enhanced through a safer process compared with the methods employed by previous researchers.

Heating efficiency of Gd- and Co-doped γ-Fe2O3 nanoparticles measured by AC magnetometer for magnetic-mediated hyperthermia

Most research groups, including us, utilize calorimetric methods to determine the heat dissipation by magnetic nanoparticles (MNPs) under an alternating magnetic field (AMF). Herein, we report the heating efficiencies of γ-Fe2O3 and doped γ-Fe2O3 NPs using AC magnetometry, which allows us to directly calculate the AC hysteresis loop area from which the heating abilities can be deduced. First, all NPs were prepared and thoroughly characterized both structurally (XRD, Rietveld, and TEM) and magnetically (DC and AC magnetization measurements). Structural analysis indicated the phase purity (γ-Fe2O3) and crystallite sizes (∼10 nm) of the as-prepared γ-Fe2O3 NPs. Both DC and AC measurements indicated the superparamagnetic behavior for γ-Fe2O3 and Gd-doped γ-Fe2O3(Gd-5%) NPs, while Co-doped γ-Fe2O3(Co-5%) NPs exhibited ferrimagnetic nature. The heating abilities and specific absorption rate (SAR) values were then analyzed at frequency, f = 132 kHz and several AC field amplitudes (µ0HAC) ranging from 0 to 88 mT. From AC magnetometry calculations, the SAR values were found to be 20 W/g and 17 W/g for γ-Fe2O3 and γ-Fe2O3(Gd-5%) NPs, respectively, while that of γ-Fe2O3(Co-5%) NPs reached SAR of 120 W/g, almost 6 times higher. This high heating efficiency of γ-Fe2O3(Co-5%) sample is attributed to their higher effective anisotropy and saturation magnetization where the heat release is mainly dominated by Neel relaxation. Finally, a viability assay against metastatic breast cancer cells was conducted, indicating the biocompatibility and low toxicity of the as-synthesized γ-Fe2O3 and doped γ-Fe2O3 NPs. These results strongly suggest the promising utilization of γ-Fe2O3 NPs, particularly Co-doped, as a potential candidate for magnetic-mediated hyperthermia.

Optical and magnetoelectric coupling studies of ErCrO3

ErCrO3 samples were synthesized by solid state method. The structure, optical, magnetic, dielectric and low-temperature pyroelectric properties of the system were investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) revealed that the sample has an orthorhombic structure with the Pbnm space group, and an average particle size of 641 nm. Optical studies show that the optical band gaps are 2.1 eV and 3.2 eV for the sample. DC and AC magnetization indicate that ErCrO3 undergoes three magnetic phase transitions near TN (Cr3+), TSR, and TN(Er3+). Interestingly, another hump is observed in the range of 50–70 K during the AC magnetization measurements. Dielectric and pyroelectric measurements demonstrate significant anomalies in the dielectric permittivity and pyroelectricity around TN, TSR and the corresponding temperature of the hump. This suggests a close correlation between the dielectric and pyroelectric properties with the magnetic transition. Furthermore, the pyroelectric measurements at low temperatures prove that the magnetic field could regulate the electric polarization, a further proof of the strong magnetoelectric coupling effect in the system. These properties of ErCrO3 make it have significant applications in optoelectronic devices, storage devices, sensors, and so on.

A Chain of Vertex-Sharing {CoIII2CoII2}n Squares with Single-Ion Magnet Behavior

A new mixed-valence one-dimensional coordination polymer of formula {[CoII(MeOH)2][(μ-NC)2CoIII(dmphen)(CN)2]2}n·2nH2O (1) was obtained by reacting the Ph4P[CoII(dmphen)(CN)3] metalloligand (dmphen = 2,9-dimethyl-1,10-phenanthroline and Ph4P+ = tetraphenylphosphonium ion) with cobalt(II) acetate tetrahydrate. The structural analysis shows the formation of a neutral 4,2-ribbon-like chain of vertex-sharing cyanido-bridged {CoIII2CoII2} squares in which the metalloligand underwent an oxidation process and a reorganization to form {CoIII(dmphen)(CN)4}− linkers that coordinate to the [CoII(MeOH)2]2+ units through single cyanido ligands. Both cobalt(II) and Co(III) cations are six-coordinated in distorted octahedral environments. The shortest intrachain distance between the paramagnetic cobalt(II) ions is 7.36 Å, a value which is shorter than the shortest interchain one (10.36 Å). Variable-temperature (1.9–300 K) static (dc) magnetic measurements for 1 indicate the occurrence of magnetically isolated high-spin cobalt(II) ions with a D value of +67.0 cm−1. Dynamic alternating current (ac) magnetic measurements between 2.0–13 K reveal that 1 exhibits slow magnetic relaxation under non-zero applied dc fields, being thus a new example of field-induced SIM with easy-plane magnetic anisotropy. Theoretical calculations by CASSCF/NEVPT2 on 1 support the results from magnetometry. The relaxation of the magnetization occurs in the ground state under external dc fields through a two-phonon Raman process and one intra-Kramers mechanism.

Single-Ion Magnetism in a Three-Dimensional Thiocyanate-Bridged Dysprosium(III) Framework

New three-dimensional (3D) lanthanide framework compounds supported by bridging thiocyanate ligand and K+ cations, K4[Ln(NCS)4(H2O)4](NCS)3(H2O)2(1: Ln = Dy, 2: Ln = Tb, 3: Ln = Gd) have been synthesized. A single-crystal X-ray diffraction study showed that all three compounds were isostructural and crystallized in the I 2/a space group. The K+ ion form 2D layers with thiocyanates which are further linked by [Ln(NCS)4(H2O)4]- complexes and additional thiocyanate ions to generate an interesting 3D framework structure. Compound 1 shows slow magnetic relaxation behavior under a zero direct current (DC) field, indicating that 1 behaves as a single-ion magnet (SIM). As estimated from AC magnetic measurements, the effective energy barrier for spin reversal in 1 was Ueff = 42 cm–1. Slow relaxation of magnetization under a small external DC field was also detected for 2 and 3 at 1.8 K.

Magnetoelastic coupling and microstructure dynamics associated with spin-orbit coupling in the ferrimagnetic/ferroelastic ordered double perovskite Ba2FeReO6

Strain coupling and relaxation dynamics associated with the ferrimagnetic/ferroelastic phase transition at ${T}_{c}\ensuremath{\approx}310\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ in double perovskite ${\mathrm{Ba}}_{2}{\mathrm{FeReO}}_{6}$ with a high degree of Fe/Re order have been investigated with resonant ultrasound spectroscopy through the temperature interval $\ensuremath{\sim}5--600\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ and with applied magnetic field of up to $\ifmmode\pm\else\textpm\fi{}2\phantom{\rule{0.28em}{0ex}}\mathrm{T}$. Strain analysis using diffraction data from the literature is consistent with a Landau model of the transition as $Fm\overline{3}m{1}^{\ensuremath{'}}\ensuremath{\rightarrow}I4/m{m}^{\ensuremath{'}}{m}^{\ensuremath{'}}$, improperly ferroelastic, driven by a magnetic order parameter with symmetry ${\mathrm{\ensuremath{\Gamma}}}_{4}^{+}$. Ferroelastic shear strain of up to $\ensuremath{\sim}0.0015$ arises from spin/orbit coupling and is smaller than is typical of coupling with octahedral tilting. It provides the underlying cause of softening of the shear modulus observed over an interval of $\ensuremath{\sim}100\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ below ${T}_{\mathrm{c}}$, though with order/disorder rather than displacive character for the transition. Hysteretic effects suggest that precursor microstructures and mixed magnetic/ferroelastic domains below ${T}_{\mathrm{c}}$ depend on the thermal history of the sample and can evolve on a timescale of hours and days at room temperature. Elasticity data collected as a function of external magnetic field reveal that poled samples are slightly softer than those with multiple magnetic domains at 4 K. At 300 K there is a time-dependent viscous component of the response to the field that relates to the bulk modulus and, hence, to volume changes associated with magnetic ordering. A loss peak seen $\ensuremath{\sim}20--50\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ below ${T}_{\mathrm{c}}$ in AC magnetic measurements made at frequencies of $0.2--1\phantom{\rule{0.28em}{0ex}}\mathrm{kHz}$ yielded an activation energy $\ensuremath{\sim}0.4\phantom{\rule{0.28em}{0ex}}\mathrm{eV}$ and has been attributed to freezing of magnetic/ferroelastic domain walls. No equivalent loss peak was seen in the acoustic data measured at $\ensuremath{\sim}100--500\phantom{\rule{0.28em}{0ex}}\mathrm{kHz}$, however, implying that these domain walls are mobile in response to a dynamic magnetic field on a timescale of $\ensuremath{\sim}{10}^{\ensuremath{-}2}\text{--}{10}^{\ensuremath{-}3}\phantom{\rule{0.28em}{0ex}}\mathrm{s}$ but immobile in response to a dynamic stress field applied on a timescale of $\ensuremath{\sim}{10}^{\ensuremath{-}5}\text{--}{10}^{\ensuremath{-}6}\phantom{\rule{0.28em}{0ex}}\mathrm{s}$. Debye-like acoustic loss peaks at temperatures below $\ensuremath{\sim}100\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ yielded activation energies of $\ensuremath{\sim}0.02--0.1\phantom{\rule{0.28em}{0ex}}\mathrm{eV}$ and are discussed in terms of pinning/freezing of polarons. ${\mathrm{Ba}}_{2}{\mathrm{FeReO}}_{6}$ is a material with magnetoelastic and magnetoelectric heterogeneities that might be tuned by choice of thermal history and cation order.

Self-Assembly Heterometallic Cu-Ln Complexes: Synthesis, Crystal Structures and Magnetic Characterization

Using N2O4 donor symmetric ligand H2L and dca co-ligand, two new isostructural dinuclear CuII–LnIII complexes [Cu(Cl)(L)Ln(NO3)(CH3OH)(H2O)(dca)] [Ln=Ho (1CuHo), Gd (2CuGd)] [H2L = 6,6′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methoxyphenol); dca=dicyanamide] were designed, synthesized and studied. In the two isostructural compounds, the geometric environment around the nine-coordinated Ln(III) ions is muffin, whereas the geometry of the penta-coordinated Cu(II) ions is square pyramid. The magnetic properties of both complexes were also studied. Direct current magnetic susceptibility measurements indicate ferromagnetic interactions between the Cu(II) ion and Gd(III) ion in complex 2CuGd. Alternating current (ac) magnetic measurements indicate that complex 1CuHo displays slow magnetic relaxation behaviour.

Spin-Dependent Dynamics of Photocarrier Generation in Electrically Detected Nitrogen-Vacancy-Based Quantum Sensing

Electrical detection of nitrogen-vacancy (N-V) centers in diamond is advantageous for developing and integrating quantum information processing devices and quantum sensors and has the potential to achieve a higher collection efficiency than that of optical techniques. However, the mechanism for the electrical detection of N-V spins is not fully understood. In this study, we observe positive contrast in photocurrent detected magnetic resonance (PDMR). Note that negative PDMR contrast is usually observed. To discuss the sign of the PDMR contrast, we numerically analyze the dynamics of photocarrier generation by N-V centers using a seven-level rate model. It is found that the sign of the PDMR contrast depends on the difference in the photocurrent generated from the excited states and the metastable state of N-V centers. Furthermore, we demonstrate ac magnetic field sensing using spin coherence with the PDMR technique. ac magnetic field measurement with the PDMR technique is still challenging because the noise from a fluctuating magnetic environment is greater than the measured signal. Here, we introduce noise suppression using a phase-cycling-based noise-canceling technique. We demonstrate electrically detected ac magnetic field sensing with a sensitivity of 29 nT ${\mathrm{Hz}}^{\ensuremath{-}1/2}$. Finally, we discuss sensitivity enhancement based on the proposed model.

CO2 Fixation by Dimeric Tb(III) Complexes: Synthesis, Structure, and Magnetism

Two dinuclear complexes, [Tb2(L1)2(piv)2(NO3)2]·H2O (1) and [Tb2(L2)2(CF3CO2)2(H2O)4].2NO3 (2), have been prepared and characterized by single-crystal X-ray diffraction, where each metal ion is doubly phenoxido-bridged by the two phenolato oxygen atoms of the tetradentate Schiff-base ligand. Previous magnetic studies of 1 show that it is not a single-molecule magnet (SMM), while AC magnetic measurements of 2 show that it relaxes quite fast with μSQUID measurements revealing the presence of an interaction operating between the Tb ions. Through DC, μSQUID, and CASSCF calculations, the strength of the interaction in 2 can be quantified, which is of dipolar origin. Both complexes showed efficient catalytic activity toward the carbon dioxide insertion reaction into epoxides for the formation of organic cyclic carbonates. Catalytic synthesis of organic cyclic carbonates smoothly occurred at 60 °C under1 bar carbon dioxide pressure and neat conditions. Exocyclic as well as endocyclic epoxides produced a respective cyclic carbonate product with moderate to high yield (43–100%). Moreover, a high turnover number (7300–10000) along with a high turnover frequency (537.5–5000 h–1) are found in this catalytic reaction.

Hexacoordinated Co(ii) complex exhibiting strong magnetic anisotropy and field-induced slow magnetization relaxation: synthesis, magnetic characterization, and quantum-chemical modelling

A hexacoordinated Co(ii) complex [CoL(NCS)2]·2DMSO (L is diacetyl bis-quinolyl hydrazone) with field-induced SIM properties, has been synthesised and characterized by IR, SCXRD, and AC and DC magnetic measurements.