Abundances Of Complex Organic Molecules Research Articles

PRODIGE – envelope to disk with NOEMA

Context. Complex organic molecules (COMs) have been found toward low-mass protostars, but the origins of the COM emission are still unclear. It can be associated with, for example, hot corinos, outflows, and/or accretion shock and disk atmospheres. Aims. We aim to disentangle the origin of the COM emission toward the chemically rich protobinary system SVS13A using six O-bearing COMs. Methods. We conducted NOrthern Extended Millimeter Array observations toward SVS13A as part of the PROtostars & DIsks: Global Evolution (PRODIGE) program. Our previous DCN observations reveal a possible infalling streamer, which may affect the chemistry of the central protobinary by inducing accretion outbursts and/or shocked gas. We further analyzed six O-bearing COMs: CH3OH, aGg’- (CH2OH)2, C2H5OH, CH2(OH)CHO, CH3CHO, and CH3OCHO. Although the COM emission is not spatially resolved, we constrained the source sizes to ≲0.3–0.4 arcsec (90–120 au) by conducting uv-domain Gaussian fitting. Interestingly, the high-spectral-resolution data reveal complex line profiles with multiple peaks; although the line emission is likely dominated by the secondary, VLA4A, at VLSR = 7.36 km s−1, the numbers of peaks (~2–5), the velocities, and the linewidths of these six O-bearing COMs are different. The local thermodynamic equilibrium (LTE) fitting unveils differences in excitation temperatures and emitting areas among these COMs. We further conducted multiple-velocity-component LTE fitting to decompose the line emission into different kinematic components. As a result, the emission of these COMs is decomposed into up to six velocity components from the LTE modeling. The physical conditions (temperature, column density, and source size) of these components from each COM are obtained, and Markov chain Monte Carlo sampling was performed to test the fitting results. Results. We find a variety in excitation temperatures (100–500 K) and source sizes (D ~ 10–70 au) from these kinematic components from different COMs. The emission of each COM can trace several components, and different COMs most likely trace different regions. Conclusions. Given this complex structure, we suggest that the central region is inhomogeneous and unlikely to be heated by only protostellar radiation. We conclude that accretion shocks induced by the large-scale infalling streamer likely exist and contribute to the complexity of the COM emission. This underlines the importance of high-spectral-resolution data when analyzing COM emission in protostars and deriving relative COM abundances.

Chemistry of Complex Organic Molecules in the V883 Ori Disk Revealed by ALMA Band 3 Observations

Complex organic molecules (COMs) in protoplanetary disks are key to understanding the origin of volatiles in comets in our solar system, yet the chemistry of COMs in protoplanetary disks remains poorly understood. Here, we present Atacama Large Millimeter/submillimeter Array Band 3 observations of the disk around the young outbursting star V883 Ori, where the COMs sublimate from ices and are thus observable thanks to the warm condition of the disk. We have robustly identified ten oxygen-bearing COMs including 13C isotopologues in the disk-integrated spectra. The radial distributions of the COM emission, revealed by the detailed analyses of the line profiles, show the inner emission cavity, similar to the previous observations in Band 6 and Band 7. We found that the COMs abundance ratios with respect to methanol are significantly higher than those in the warm protostellar envelopes of IRAS 16293-2422 and similar to the ratios in the solar system comet 67P/Churyumov-Gerasimenko, suggesting the efficient (re)formation of COMs in protoplanetary disks. We also constrained the 12C/13C and D/H ratios of COMs in protoplanetary disks for the first time. The 12C/13C ratios of acetaldehyde, methyl formate, and dimethyl ether are consistently lower (∼20–30) than the canonical ratio in the interstellar medium (∼69), indicating the efficient 13C-fractionation of CO. The D/H ratios of methyl formate are slightly lower than the values in IRAS 16293-2422, possibly pointing to the destruction and reformation of COMs in disks. We also discuss the implications for nitrogen and sulfur chemistry in protoplanetary disks.

Complex Organic Molecules in a Very Young Hot Corino, HOPS 373SW

We present the spectra of complex organic molecules (COMs) detected in HOPS 373SW with the Atacama Large Millimeter/submillimeter Array (ALMA). HOPS 373SW, which is a component of a protostellar binary with a separation of 1500au, has been discovered as a variable protostar by the JCMT transient monitoring survey with a modest (∼30%) brightness increase at submillimeter wavelengths. Our ALMA target-of-opportunity observation at ∼345 GHz for HOPS 373SW revealed extremely young chemical characteristics with strong deuteration of methanol. The dust continuum opacity is very high toward the source center, obscuring line emission from within 0.″03. The other binary component, HOPS 373NE, was detected only in C17O in our observation, implying a cold and quiescent environment. We compare the COM abundances relative to CH3OH in HOPS 373SW with those of V883 Ori, which is an eruptive disk object, as well as other hot corinos, to demonstrate the chemical evolution from envelope to disk. High abundances of singly, doubly, and triply deuterated methanol (CH2DOH, CHD2OH, and CD3OH) and a low CH3CN abundance in HOPS 373SW compared to other hot corinos suggest a very early evolutionary stage of HOPS 373SW in the hot corino phase. Since the COMs detected in HOPS 373SW would have been sublimated very recently from grain surfaces, HOPS 373SW is a promising place to study the surface chemistry of COMs in the cold prestellar phase before sublimation.

Deep search for glycine conformers in Barnard 5

ABSTRACT One of the most fundamental hypotheses in astrochemistry and astrobiology states that crucial biotic molecules like glycine (NH2CH2COOH) found in meteorites and comets are inherited from early phases of star formation. Most observational searches for glycine in the interstellar medium have focused on warm high-mass molecular cloud sources. However, recent studies suggest that it might be appropriate to shift the observational focus to cold low-mass sources. We aim to detect glycine towards the so-called methanol hotspot in the Barnard 5 dark cloud. The hotspot is a cold source (Tgas ≈ 7.5 K) with yet high abundances of complex organic molecules (COMs) and water in the gas phase. We carried out deep pointed observations with the Onsala 20 m telescope, targeting several transitions of glycine conformers I and II (Gly-I and Gly-II) in the frequency range 70.2–77.9 GHz. No glycine lines are detected towards the targeted position, but we use a line stacking procedure to derive sensitive abundance upper limits w.r.t. H2 for Gly-I and Gly-II, i.e. ≤(2–5) × 10−10 and ≤(0.7–3) × 10−11, respectively. The obtained Gly-II upper limits are the most stringent for a cold source, while the Gly-I upper limits are mostly on the same order as previously measured limits. The measured abundances w.r.t. H2 of other COMs at the B5 methanol hotspot range from 2 × 10−10 (acetaldehyde) to 2 × 10−8 (methanol). Hence, based on a total glycine upper limit of (2–5) × 10−10, we cannot rule out that glycine is present but undetected.

Resolving desorption of complex organic molecules in a hot core

Context. The presence of many interstellar complex organic molecules (COMs) in the gas phase in the vicinity of protostars has long been associated with their formation on icy dust grain surfaces before the onset of protostellar activity, and their subsequent thermal co-desorption with water, the main constituent of the grains’ ice mantles, as the protostar heats its environment to ~100 K. Aims. Using the high angular resolution provided by the Atacama Large Millimetre/submillimetre Array (ALMA), we want to resolve the COM emission in the hot molecular core Sagittarius B2 (N1) and thereby shed light on the desorption process of COMs in hot cores. Methods. We used data taken as part of the 3 mm spectral line survey Re-exploring Molecular Complexity with ALMA (ReMoCA) to investigate the morphology of COM emission in Sagittarius B2 (N1). We also used ALMA continuum data at 1 mm taken from the literature. Spectra of ten COMs (including one isotopologue) were modelled under the assumption of local thermodynamic equilibrium (LTE) and population diagrams were derived for these COMs for positions at various distances to the south and west from the continuum peak. Based on this analysis, we produced resolved COM rotation temperature and column density profiles. H2 column density profiles were derived from dust continuum emission and C18O 1–0 emission and used to derive COM abundance profiles as a function of distance and temperature. These profiles are compared to astrochemical models. Results. Based on the morphology, a rough separation into O- and N-bearing COMs can be done. The temperature profiles span a range of 80–300 K with power-law indices from −0.4 to −0.8, which is in agreement with expectations of protostellar heating of an envelope with optically thick dust. Column density and abundance profiles reflect a similar trend as seen in the morphology. While abundances of N-bearing COMs peak only at the highest temperatures, those of most O-bearing COMs peak at lower temperatures and remain constant or decrease towards higher temperatures. Many abundance profiles show a steep increase at ~100 K. To a great extent, the observed results agree with results of astrochemical models that, besides the co-desorption with water, predict that O-bearing COMs are mainly formed on dust-grain surfaces at low temperatures, while at least some N-bearing COMs and CH3CHO are substantially formed in the gas phase at higher temperatures. Conclusions. Our observational results, in comparison with model predictions, suggest that COMs that are exclusively or, to a great extent, formed on dust grains desorb thermally at ~100 K from the grain surface, likely alongside water. A dependence on the COM binding energy is not evident from our observations. Non-zero abundance values below ~100 K suggest that another desorption process of COMs is at work at these low temperatures: either non-thermal desorption or partial thermal desorption related to the lower binding energies experienced by COMs in the outer, water-poor ice layers. In either case, this is the first time that the transition between two regimes of COM desorption has been resolved in a hot core.

Ice Age: Chemodynamical Modeling of Cha-MMS1 to Predict New Solid-phase Species for Detection with JWST

Chemical models and experiments indicate that interstellar dust grains and their ice mantles play an important role in the production of complex organic molecules (COMs). To date, the most complex solid-phase molecule detected with certainty in the interstellar medium is methanol, but the James Webb Space Telescope (JWST) may be able to identify still larger organic species. In this study, we use a coupled chemodynamical model to predict new candidate species for JWST detection toward the young star-forming core Cha-MMS1, combining the gas–grain chemical kinetic code MAGICKAL with a 1D radiative hydrodynamics simulation using Athena++. With this model, the relative abundances of the main ice constituents with respect to water toward the core center match well with typical observational values, providing a firm basis to explore the ice chemistry. Six oxygen-bearing COMs (ethanol, dimethyl ether, acetaldehyde, methyl formate, methoxy methanol, and acetic acid), as well as formic acid, show abundances as high as, or exceeding, 0.01% with respect to water ice. Based on the modeled ice composition, the infrared spectrum is synthesized to diagnose the detectability of the new ice species. The contribution of COMs to IR absorption bands is minor compared to the main ice constituents, and the identification of COM ice toward the core center of Cha-MMS1 with the JWST NIRCAM/Wide Field Slitless Spectroscopy (2.4–5.0 μm) may be unlikely. However, MIRI observations (5–28 μm) toward COM-rich environments where solid-phase COM abundances exceed 1% with respect to the column density of water ice might reveal the distinctive ice features of COMs.

Importance of source structure on complex organics emission

Context. The protostellar stage is known to be the richest star formation phase in emission from gaseous complex organic molecules. However, some protostellar systems show little or no millimetre (mm) line emission of such species. This can be interpreted as a low abundance of complex organic molecules. Alternatively, complex species could be present in the system, but are not seen in the gas. Aims. The goal is to investigate the second hypothesis for methanol as the most abundant complex organic molecule in protostellar systems. This work aims to determine how effective dust optical depth is in hiding methanol in the gas, and whether methanol can mainly reside in the ice due to the presence of a disk that lowers the temperatures. Hence, we attempt to answer the question whether the presence of a disk and optically thick dust reduce methanol emission even if methanol and other complex species are abundant in the ices and gas. Methods. Using the radiative transfer code RADMC-3D, we calculated methanol emission lines from an envelope-only model and from an envelope-plus-disk model. We compared the results with each other and with the observations. Methanol gas and ice abundances were parametrised inside and outside of the snow surfaces based on values from observations. Both models included either dust grains with low mm opacity or high mm opacity, and their physical parameters such as envelope mass and disk radius were varied. Results. Methanol emission from the envelope-only model is always stronger than from the envelope-plus-disk model by at least a factor ∼2 as long as the disk radius is larger than ∼30 au (for L = 8 L⊙). In most cases, this is due to lower temperatures (disk shadowing), which causes the smaller amount of warm (≳70 K) methanol inside the snow surface of the envelope-plus-disk model. The intensities drop by more than an order of magnitude for models including high mm opacity dust grains and disk radii of at least ∼50 au (for L = 8 L⊙) due to continuum over-subtraction. Conclusions. The line intensities from the envelope-only models match the observations moderately well when methanol emission is strong, but they overproduce the observations of protostars with lower methanol emission even with large dust optical depth effects. The envelope-plus-disk models can explain the bulk of the observations. However, they can only reproduce the observations of sources with high luminosities and very low methanol emission when the dust optical depth is significant in the envelope and continuum over-subtraction becomes effective in the disk (high mm opacity dust grains are used). Therefore, both the effects of disk and dust optical depth should be considered to explain the observations. In conclusion, it is important to take physical structure into account in future chemical studies of low-mass protostars: absence of gas-phase methanol emission does not imply absence of methanol molecules in either gas or ice.

Icy molecule desorption in interstellar grain collisions

ABSTRACT Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical model, we investigate if mechanical removal of ice fragments in oblique collisions between grains in two size bins (0.01 and 0.1 µm) can substantially affect COM abundances. Two grain collision velocities were considered – 10 and 50 m s−1, corresponding to realistic grain relative speeds arising from ambipolar diffusion and turbulence, respectively. From the smaller grains, the collisions are assumed to remove a spherical cap with height equal to 1/3 and 1 ice mantle thickness, respectively. We find that the turbulence-induced desorption can elevate the gas-phase abundances of COMs by several orders of magnitude, reproducing observed COM abundances within an order of magnitude. Importantly, the high gaseous COM abundances are attained for long time-scales of up to 1 Myr and for a rather low methanol ice abundance, common for starless cores. The simple model, considering only two grain size bins and several assumptions, demonstrates a concept that must be tested with a more sophisticated approach.

ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N 105 Star-forming Region

The Large Magellanic Cloud (LMC) is the nearest laboratory for detailed studies on the formation and survival of complex organic molecules (COMs), including biologically important ones, in low-metallicity environments—typical of earlier cosmological epochs. We report the results of 1.2 mm continuum and molecular line observations of three fields in the star-forming region N 105 with the Atacama Large Millimeter/submillimeter Array. N 105 lies at the western edge of the LMC bar with ongoing star formation traced by H2O, OH, and CH3OH masers, ultracompact H ii regions, and young stellar objects. Based on the spectral line modeling, we estimated rotational temperatures, column densities, and fractional molecular abundances for 12 1.2 mm continuum sources. We identified sources with a range of chemical makeups, including two bona fide hot cores and four hot core candidates. The CH3OH emission is widespread and associated with all the continuum sources. COMs CH3CN and CH3OCH3 are detected toward two hot cores in N 105 together with smaller molecules typically found in Galactic hot cores (e.g., SO2, SO, and HNCO) with the molecular abundances roughly scaling with metallicity. We report a tentative detection of the astrobiologically relevant formamide molecule (NH2CHO) toward one of the hot cores; if confirmed, this would be the first detection of NH2CHO in an extragalactic subsolar metallicity environment. We suggest that metallicity inhomogeneities resulting from the tidal interactions between the LMC and the Small Magellanic Cloud might have led to the observed large variations in COM abundances in LMC hot cores.

Detection of complex organic molecules in young starless core L1521E

ABSTRACT Determining the level of chemical complexity within dense starless and gravitationally bound pre-stellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We have searched for complex organic molecules (COMs) in the young starless core L1521E, and report the first clear detection of dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), and vinyl cyanide (CH2CHCN). Eight transitions of acetaldehyde (CH3CHO) were also detected, five of which (A states) were used to determine an excitation temperature to then calculate column densities for the other oxygen-bearing COMs. If source size was not taken into account (i.e. if filling fraction was assumed to be one), column density was underestimated, and thus we stress the need for higher resolution mapping data. We calculated L1521E COM abundances and compared them to other stages of low-mass star formation, also finding similarities to other starless/pre-stellar cores, suggesting related chemical evolution. The scenario that assumes formation of COMs in gas-phase reactions between precursors formed on grains and then ejected to the cold gas via reactive desorption was tested and was unable to reproduce observed COM abundances, with the exception of CH3CHO. These results suggest that COMs observed in cold gas are formed not by gas-phase reactions alone, but also through surface reactions on interstellar grains. Our observations present a new, unique challenge for existing theoretical astrochemical models.

The Connection between Warm Carbon-chain Chemistry and Interstellar Irradiation of Star-forming Cores

Abstract Some observations of warm carbon-chain chemistry (WCCC) cores indicate that they are often located near the edges of molecular clouds. This finding may suggest that WCCC is promoted in star-forming cores exposed to radiation from the interstellar medium. We aim to investigate the chemistry of carbon chains in such a core. A chemical simulation of a gas parcel in a low-mass star-forming core with a full level of irradiation by interstellar photons and cosmic rays was compared to a simulation of a core receiving only 1/10 of such irradiation. In the full irradiation model, the abundances of carbon chains were found to be higher by a factor of a few to a few hundred, compared to the model with low irradiation. Higher carbon-chain abundances in the prestellar stage and, presumably, in the extended circumstellar envelope arise because of irradiation of gas and dust by interstellar photons and cosmic rays. A full standard rate of cosmic-ray-induced ionization is essential for a high carbon-chain abundance peak to occur in the circumstellar envelope, which is heated by the protostar (the “true” WCCC phenomenon). The full irradiation model has lower abundances of complex organic molecules than the low-irradiation model. We conclude that WCCC can be caused by exposure of a star-forming core to interstellar radiation, or even just to cosmic rays. The Appendix describes an updated accurate approach for calculating the rate of cosmic-ray-induced desorption.

The Perseus ALMA Chemistry Survey (PEACHES). I. The Complex Organic Molecules in Perseus Embedded Protostars

Abstract To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecules (COMs). These protostars seem to possess a different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of the 50 embedded protostars surveyed, 58% of them have emission from COMs. 56%, 32%, and 40% of the protostars have CH3OH, CH3OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H2 column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH3OH has a tight correlation with CH3CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH3OH and CH3CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, which hints at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH3OCHO and CH3OCH3) relative to that of smaller COMs (CH3OH and CH3CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes.

Formation of Complex Organic Molecules in Cold Interstellar Environments through Nondiffusive Grain-surface and Ice-mantle Chemistry

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable molecules. However, some gas-phase O-bearing COMs, notably acetaldehyde(CH$_3$CHO), methyl formate(CH$_3$OCHO), and dimethyl ether(CH$_3$OCH$_3$), are now observed at very low temperatures, challenging the warm scenario. Here, we introduce a selection of new non-diffusive mechanisms into an astrochemical model, to account for the failure of the standard diffusive picture and to provide a more generalized scenario of COM formation on interstellar grains. New generic rate formulations are provided for cases where: (i) radicals are formed by reactions occurring close to another reactant, producing an immediate follow-on reaction; (ii) radicals are formed in an excited state, allowing them to overcome activation barriers to react with nearby stable molecules; (iii) radicals are formed through photo-dissociation close to a reaction partner, followed by immediate reaction. Each process occurs without the diffusion of large radicals. The new mechanisms significantly enhance cold COM abundances, successfully reproducing key observational results for prestellar core L1544. H-abstraction from grain-surface COMs, followed by recombination, plays a crucial role in amplifying chemical desorption into the gas phase. The UV-induced chemistry produces significant COM abundances in the bulk ices, which are retained on the grains and may persist to later stages. O$_2$ is also formed strongly in the mantle though photolysis, suggesting cometary O$_2$ could indeed be interstellar.

Chemical Variation among Protostellar Cores: Dependence on Prestellar Core Conditions

Abstract Hot corino chemistry and warm carbon chain chemistry (WCCC) are driven by gas–grain interactions in star-forming cores: radical–radical recombination reactions to form complex organic molecules (COMs) in the ice mantle, sublimation of CH4 and COMs, and their subsequent gas-phase reactions. These chemical features are expected to depend on the composition of the ice mantle, which is set in the prestellar phase. We calculated the gas–grain chemical reaction network considering a layered ice mantle structure in star-forming cores to investigate how the hot corino chemistry and WCCC depend on the physical condition of the static phase before the onset of gravitational collapse. We found that WCCC becomes more active if the temperature is lower, or the visual extinction is lower in the static phase, or the static phase is longer. The dependence of hot corino chemistry on the static-phase condition is more complex. While CH3OH is less abundant in the models with a warmer static phase, some COMs are formed efficiently in those warm models because there are various formation paths of COMs. If the visual extinction is lower, photolysis makes COMs less abundant in the static phase. Once the collapse starts and visual extinction increases, however, COMs can be formed efficiently. The duration of the static phase does not largely affect COM abundances. The chemical diversity between prototypical hot corinos and hybrid sources, in which both COMs and carbon chains are reasonably abundant, can be explained by the variation of prestellar conditions. Deficiency of gaseous COMs in prototypical WCCC sources is, however, hard to reproduce within our models.

Questioning the spatial origin of complex organic molecules in young protostars with the CALYPSO survey

Context. Complex organic molecules (COMs) have been detected in a few Class 0 protostars but their origin is not well understood. While the usual picture of a hot corino explains their presence as resulting from the heating of the inner envelope by the nascent protostar, shocks in the outflow, disk wind, the presence of a flared disk, or the interaction region between envelope and disk at the centrifugal barrier have also been claimed to enhance the abundance of COMs. Aims. Going beyond studies of individual objects, we want to investigate the origin of COMs in young protostars on a statistical basis. Methods. We use the CALYPSO survey performed with the Plateau de Bure Interferometer of the Institut de Radioastronomie Millimétrique to search for COMs at high angular resolution in a sample of 26 solar-type protostars, including 22 Class 0 and four Class I objects. We derive the column densities of the detected molecules under the local thermodynamic equilibrium approximation and search for correlations between their abundances and with various source properties. Results. Methanol is detected in 12 sources and tentatively in one source, which represents half of the sample. Eight sources (30%) have detections of at least three COMs. We find a strong chemical differentiation in multiple systems with five systems having one component with at least three COMs detected but the other component devoid of COM emission. All sources with a luminosity higher than 4 L⊙ have at least one detected COM whereas no COM emission is detected in sources with internal luminosity lower than 2 L⊙, likely because of a lack of sensitivity. Internal luminosity is found to be the source parameter impacting the COM chemical composition of the sources the most, while there is no obvious correlation between the detection of COM emission and that of a disk-like structure. A canonical hot-corino origin may explain the COM emission in four sources, an accretion-shock origin in two or possibly three sources, and an outflow origin in three sources. The CALYPSO sources with COM detections can be classified into three groups on the basis of the abundances of oxygen-bearing molecules, cyanides, and CHO-bearing molecules. These chemical groups correlate neither with the COM origin scenarios, nor with the evolutionary status of the sources if we take the ratio of envelope mass to internal luminosity as an evolutionary tracer. We find strong correlations between molecules that are a priori not related chemically (for instance methanol and methyl cyanide), implying that the existence of a correlation does not imply a chemical link. Conclusions. The CALYPSO survey has revealed a chemical differentiation in multiple systems that is markedly different from the case of the prototypical binary IRAS 16293-2422. This raises the question of whether all low-mass protostars go through a phase showing COM emission. A larger sample of young protostars and a more accurate determination of their internal luminosity will be necessary to make further progress. Searching for correlations between the COM emission and the jet/outflow properties of the sources may also be promising.

Prevalence of Complex Organic Molecules in Starless and Prestellar Cores within the Taurus Molecular Cloud

Abstract The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally believed that COMs first form in ices, only to be irradiated by UV radiation from the surrounding interstellar radiation field as well as forming protostars, and subsequently photodesorbed into the gas phase. However, starless and prestellar cores do not have internal protostars to heat up and sublimate the ices. Alternative models using chemical energy have been developed to explain the desorption of COMs, yet in order to test these models, robust measurements of COM abundances are needed toward representative samples of cores. We have conducted a large sample survey of 31 starless and prestellar cores in the Taurus molecular cloud, detecting methanol (CH3OH) in 100% of the cores targeted and acetaldehyde (CH3CHO) in 70%. At least two transition lines of each molecule were measured, allowing us to place tight constraints on excitation temperature, column density, and abundance. Additional mapping of methanol revealed extended emission detected down to A V as low as ∼3 mag. We find that COMs are detectable in the gas phase and are being formed early, at least hundreds of thousands of years prior to star and planet formation. The precursor molecule, CH3OH, may be chemically linked to the more complex CH3CHO; however, higher spatial resolution maps are needed to further test chemical models.

Search for high-mass protostars with ALMA revealed up to kilo-parsec scales (SPARKS)

Context. Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity that is represented by COMs, in particular, is poorly constrained in the early evolution of hot cores. Aims. We put observational constraints on the physical location of COMs in a resolved high-mass protostellar envelope associated with the G328.2551−0.5321 clump. The protostar is single down to ~400 au scales and we resolved the envelope structure down to this scale. Methods. High angular resolution observations using the Atacama Large Millimeter Array allowed us to resolve the structure of the inner envelope and pin down the emission region of COMs. We use local thermodynamic equilibrium modelling of the available 7.5 GHz bandwidth around ~345 GHz to identify the COMs towards two accretion shocks and a selected position representing the bulk emission of the inner envelope. We quantitatively discuss the derived molecular column densities and abundances towards these positions, and use our line identification to qualitatively compare this to the emission of COMs seen towards the central position, corresponding to the protostar and its accretion disk. Results. We detect emission from 10 COMs, and identify a line of deuterated water (HDO). In addition to methanol (CH3OH), methyl formate (CH3OCHO) and formamide (HC(O)NH2) have the most extended emission. Together with HDO, these molecules are found to be associated with both the accretion shocks and the inner envelope, which has a moderate temperature of Tkin ~ 110 K. We find a significant difference in the distribution of COMs. O-bearing COMs, such as ethanol, acetone, and ethylene glycol are almost exclusively found and show a higher abundance towards the accretion shocks with Tkin ~ 180 K. Whereas N-bearing COMs with a CN group, such as vinyl and ethyl cyanide peak on the central position, thus the protostar and the accretion disk. The molecular composition is similar towards the two shock positions, while it is significantly different towards the inner envelope, suggesting an increase in abundance of O-bearing COMs towards the accretion shocks. Conclusions. We present the first observational evidence for a large column density of COMs seen towards accretion shocks at the centrifugal barrier at the inner envelope. The overall molecular emission shows increased molecular abundances of COMs towards the accretion shocks compared to the inner envelope. The bulk of the gas from the inner envelope is still at a moderate temperature of Tkin ~ 110 K, and we find that the radiatively heated inner region is very compact (<1000 au). Since the molecular composition is dominated by that of the accretion shocks and the radiatively heated hot inner region is very compact, we propose this source to be a precursor to a classical, radiatively heated hot core. By imaging the physical location of HDO, we find that it is consistent with an origin within the moderately heated inner envelope, suggesting that it originates from sublimation of ice from the grain surface and its destruction in the vicinity of the heating source has not been efficient yet.

Investigating the Efficiency of Explosion Chemistry as a Source of Complex Organic Molecules in TMC-1

Abstract Many species of complex organic molecules (COMs) have been observed in several astrophysical environments but it is not clear how they are produced, particularly in cold, quiescent regions. One process that has been proposed as a means to enhance the chemical complexity of the gas phase in such regions is the explosion of the ice mantles of dust grains. In this process, a build up of chemical energy in the ice is released, sublimating the ices and producing a short lived phase of high density, high temperature gas. The gas–grain chemical code UCLCHEM has been modified to treat these explosions in order to model the observed abundances of COMs toward the TMC-1 region. It is found that, based on our current understanding of the explosion mechanism and chemical pathways, the inclusion of explosions in chemical models is not warranted at this time. Explosions are not shown to improve the model’s match to the observed abundances of simple species in TMC-1. Further, neither the inclusion of surface diffusion chemistry, nor explosions, results in the production of COMs with observationally inferred abundances.

The ice composition in the disk around V883 Ori revealed by its stellar outburst

Complex organic molecules (COMs), which are the seeds of prebiotic material and precursors of amino acids and sugars, form in the icy mantles of circumstellar dust grains but cannot be detected remotely unless they are heated and released to the gas phase. Around solar-mass stars, water and COMs only sublimate in the inner few au of the disk, making them extremely difficult to spatially resolve and study. Sudden increases in the luminosity of the central star will quickly expand the sublimation front (so-called snow line) to larger radii, as seen previously in the FU Ori outburst of the young star V883 Ori. In this paper, we take advantage of the rapid increase in disk temperature of V883 Ori to detect and analyze five different COMs, methanol, acetone, acetonitrile, acetaldehyde, and methyl formate, in spatially-resolved submillimeter observations. The COMs abundances in V883 Ori is in reasonable agreement with cometary values. This result suggests that outbursting young stars can provide a special opportunity to study the ice composition of material directly related to planet formation.

Substituent effects on H3 + formation via H2 roaming mechanisms from organic molecules under strong-field photodissociation.

Roaming chemical reactions are often associated with neutral molecules. The recent findings of roaming processes in ionic species, in particular, ones that lead to the formation of H3 + under strong-field laser excitation, are of considerable interest. Given that such gas-phase reactions are initiated by double ionization and subsequently facilitated through deprotonation, we investigate the strong-field photodissociation of ethanethiol, also known as ethyl mercaptan, and compare it to results from ethanol. Contrary to expectations, the H3 + yield was found to be an order of magnitude lower for ethanethiol at certain laser field intensities, despite its lower ionization energy and higher acidity compared to ethanol. In-depth analysis of the femtosecond time-resolved experimental findings, supported by ab initio quantum mechanical calculations, provides key information regarding the roaming mechanisms related to H3 + formation. Results of this study on the dynamics of dissociative half-collisions involving H3 +, a vital cation which acts as a Brønsted-Lowry acid protonating interstellar organic compounds, may also provide valuable information regarding the formation mechanisms and observed natural abundances of complex organic molecules in interstellar media and planetary atmospheres.