Absence Of Superconductivity Research Articles

Gate induced metallicity and absence of superconductivity in BSTO/LCO heterostructure

We fabricated Ba0.8Sr0.2TiO3 (BSTO)/La2CuO4 (LCO) heterostructure on SrTiO3 (STO) substrate and investigated its structure and physical properties. X-ray diffraction and reciprocal space mapping confirm the epitaxial growth of BSTO/LCO/STO heterostructure. X-ray photoelectron spectroscopy and UV–Visible spectroscopy measurements reveal a straddling band alignment of the BSTO/LCO heterojunction. Such band alignment facilitates the accumulation of both electrons and holes at the interface. Their movement depends on the direction of the internal field of the BSTO film. Electrical transport measurements have revealed a signature of insulator-to-metal transition (IMT) in response to applied gate voltages ±Vg. Hall measurements confirm the presence of electron and hole type charge carriers under ＋Vg and −Vg, respectively. We have proposed a screening mechanism linked to the polarization state of the BSTO film to explain the observed IMT.

Geometric Inhibition of Superflow in Single-Layer Graphene Suggests a Staggered-Flux Superconductivity in Bilayer and Trilayer Graphene.

In great contrast to the numerous discoveries of superconductivity in layer-stacked graphene systems, the absence of superconductivity in the simplest monolayer graphene remains quite puzzling. Here, through realistic computation of the electronic structure, we identify a systematic trend that superconductivity emerges only upon alteration of the low-energy electronic lattice from the underlying honeycomb atomic structure. We then demonstrate that this inhibition can result from geometric frustration of the bond lattice that disables the quantum phase coherence of the order parameter residing on it. In comparison, upon deviation from the honeycomb lattice, relief of geometric frustration allows robust superfluidity with nontrivial spatial structures. For the specific examples of bilayer and trilayer graphene under an external electric field, such a bond-centered order parameter would develop superfluidity with staggered flux that breaks the time-reversal symmetry. Our study also suggests the possible realization of the long-sought superconductivity in single-layer graphene via the application of unidirectional strain.

Thermodynamic properties and enhancement of diamagnetism in nitrogen doped lutetium hydride synthesized at high pressure

Nitrogen doped lutetium hydride has drawn global attention in the pursuit of room-temperature superconductivity near ambient pressure and temperature. However, variable synthesis techniques and uncertainty surrounding nitrogen concentration have contributed to extensive debate within the scientific community about this material and its properties. We used a solid-state approach to synthesize nitrogen doped lutetium hydride at high pressure and temperature (HPT) and analyzed the residual starting materials to determine its nitrogen content. High temperature oxide melt solution calorimetry determined the formation enthalpy of LuH1.96N0.02 (LHN) from LuH2 and LuN to be -28.4 ± 11.4 kJ/mol. Magnetic measurements indicated diamagnetism which increased with nitrogen content. Ambient pressure conductivity measurements observed metallic behavior from 5 to 350 K, and the constant and parabolic magnetoresistance changed with increasing temperature. High pressure conductivity measurements revealed that LHN does not exhibit superconductivity up to 26.6 GPa. We compressed LHN in a diamond anvil cell to 13.7 GPa and measured the Raman signal at each step, with no evidence of any phase transition. Despite the absence of superconductivity, a color change from blue to purple to red was observed with increasing pressure. Thus, our findings confirm the thermodynamic stability of LHN, do not support superconductivity, and provide insights into the origins of its diamagnetism.

Absence of superconductivity in I4/mmm-FeH5: experimental evidence.

The experimentally discovered FeH5 exhibits a structure built of atomic hydrogen that only has bonding between hydrogen and iron atoms [C. M. Pepin, G. Geneste, A. Dewaele, M. Mezouar and P. Loubeyre, Science, 2017, 357, 382]. However, its superconductivity has remained unsolved since its discovery. In this work, we have synthesized I4/mmm-FeH5 at 139 GPa combined with laser-heating conditions. The electrical resistance measurements at ultrahigh pressures indicate that no evidence of superconducting transition of FeH5 is observed in the temperature range of 1.5 K to 270 K. These results indicate that I4/mmm-FeH5 does not exhibit superconductivity within the experimental temperature range, and the introduction of iron atoms is not beneficial to the formation of the superconducting phase.

On the synthesis methodologies to prepare ‘Pb9Cu(PO4)6O’: phase, composition, magnetic analysis and absence of superconductivity

We present the results of our various attempts to prepare the purported room-temperature and ambient-pressure superconducting compound ‘Pb9Cu(PO4)6O’ (LK-99). We experimented with various starting materials and used several synthesis techniques, such as reactions in sealed silica tubes or sintering in air, to prepare the reported phase. Repetition of the exact synthesis procedure reported by Lee et al failed to reproduce the superconducting phase yielding only a multiphase sample. None of our prepared samples exhibit Meissner effect or levitation. Very importantly, only a small amount of copper was detected in the samples of the phase designated ‘LK-99’. Dark gray flakes were found in some samples that reacted to a permanent magnet at room temperature, reminiscing of ‘half-levitation.’ Magnetic measurement reveal that all samples are diamagnetic in the temperature range of 2–325 K. At 2 K, a weak soft ferromagnetic behavior is observed, the origin of which is unknown.

Absence of Superconductivity in LK-99 at Ambient Conditions.

The report of the synthesis of modified lead apatite (LK-99), with evidence of superconductivity at more than boiling water temperature, has steered the scientific community. There have been several failures to reproduce superconductivity in LK-99, despite partial successes. Here, we have continued our efforts to synthesize phase-pure LK-99 with improved precursors. The synthesis process being followed is the same as suggested by Sukbae Lee et al. The phase purity of each precursor is evidenced by powder X-ray diffraction (PXRD) and is well-fitted by Rietveld refinement. The PXRD confirms the synthesis of phase-pure polycrystalline LK-99 with a lead apatite structure. The sample is highly resistive, showing insulator-like behavior in resistivity measurement in the temperature range from 215 to 325 K, which confirms the absence of superconductivity in synthesized LK-99 at room temperature. The magnetization measurements of LK-99 on the SQUID magnetometer resemble the behavior of a resistive diamagnetic material at 280 K. Moreover, we have also performed first principle calculations to investigate the electronic band structure of LK-99 in the vicinity of the Fermi level. Our study verifies that the copper (Cu)-doped lead apatite (LK-99) exhibits band crossing at the Fermi level, indicating the generation of strong correlation in the presently studied system. Our experimental results do not approve the appearance of superconductivity in LK-99, i.e., Pb9CuP6O25.

Destabilization of the Charge Density Wave and the Absence of Superconductivity in ScV6Sn6 under High Pressures up to 11 GPa.

RV6Sn6 (R = Sc, Y, or rare earth) is a new family of kagome metals that have a similar vanadium structural motif as AV3Sb5 (A = K, Rb, Cs) compounds. Unlike AV3Sb5, ScV6Sn6 is the only compound among the series of RV6Sn6 that displays a charge density wave (CDW) order at ambient pressure, yet it shows no superconductivity (SC) at low temperatures. Here, we perform a high-pressure transport study on the ScV6Sn6 single crystal to track the evolutions of the CDW transition and to explore possible SC. In contrast to AV3Sb5 compounds, the CDW order of ScV6Sn6 can be suppressed completely by a pressure of about 2.4 GPa, but no SC is detected down to 40 mK at 2.35 GPa and 1.5 K up to 11 GPa. Moreover, we observed that the resistivity anomaly around the CDW transition undergoes an obvious change at ~2.04 GPa before it vanishes completely. The present work highlights a distinct relationship between CDW and SC in ScV6Sn6 in comparison with the well-studied AV3Sb5.

Stability of the smectic phase in arrays of parallel quantum wires

Using bosonization, we study a microscopic model of parallel quantum wires constructed from two dimensional Dirac fermions in the presence of periodic topological domain walls. The model accounts for the lateral spread of the wavefunctions $\ell$ in the transverse direction to the wires. The gapless modes confined to each domain wall are shown to form Luttinger liquids, which realize a well known smectic non-Fermi liquid fixed point when interwire Coulomb interactions are taken into account. Perturbative studies on phenomenological models have shown that the smectic fixed point is unstable towards a variety of phases such as superconductivity, stripe, smectic and Fermi liquid phases. Here, we show that the considered microscopic model leads to a phase diagram with only smectic metal and Fermi liquid phases. The smectic metal phase is stable in the ideal quantum wire limit $\ell\to0$. For finite $\ell$, we find a critical Coulomb coupling $\alpha_{c}$ separating the strong coupling smectic metal from a weak coupling Fermi liquid phase. We conjecture that the absence of superconductivity should be a generic feature of similar microscopic models. Finally, we discuss the physical realization of this model with moire heterostructures.

Synthesis and properties of La1 – x Sr x NiO3 and La1–x Sr x NiO2

Superconductivity has been realized in films of La1−x Sr x NiO2. Here we report synthesis and characterization of polycrystalline samples of La1−x Sr x NiO3 and La1−x Sr x NiO2 (0 ≤ x ≤ 0.2). Magnetization and resistivity measurements reveal that La1−x Sr x NiO3 are paramagnetic metal and La1−x Sr x NiO2 exhibit an insulating behavior. Superconductivity is not detected in bulk samples of La1−x Sr x NiO2. The absence of superconductivity in bulk La1−x Sr x NiO2 may be due to the generation of hydroxide during reduction, a small amount of nickel impurity, or incomplete reduction of apical oxygen. The effect of interface in films of La1−x Sr x NiO2 may also play a role for superconductivity.

Infinite-Layer Nickelate Superconductors: A Current Experimental Perspective of the Crystal and Electronic Structures

After the reward of more than 2 decades of pursuit on the high-Tc cuprate analog with the hope to obtain a better understanding of the mechanism of high-Tc superconductivity, the discovery of superconductivity in the infinite-layer nickelate brings more mystery to the picture than expected. Tops in the list of questions are perhaps 1) absence of superconductivity in the bulk nickelate and limited thickness of the infinite-layer phase in thin film, 2) absence of superconductivity in the La-nickelate despite it being the earliest studied rare-earth nickelate, and the role of 4 f orbital in the recipe of superconductivity, 3) absence of Meissner effect and suspect of the origin of superconductivity from the interface, 4) whether nickelate hosts similar pairing symmetry to the single-band high-Tc cuprates or multiband iron-based superconductor. In this perspective article, we will discuss the following aspects: 1) stabilization of the infinite-layer phase on the SrTiO3(001) substrate and the thickness dependency of observables; 2) rare-earth dependence of the superconducting dome and phase diagram of the (La/Pr/Nd)- infinite-layer nickelate thin film; 3) experimental aspects of the measurement of Meissner effect; 4) theoretical framework and experimental study of the pairing symmetry of infinite-layer nickelate superconductor.

The absence of superconductivity in the next-to-leading order Ginzburg–Landau functional for Bardeen–Cooper–Schrieffer superconductor

Shortly after the Gor’kov microscopic derivation of the Ginzburg–Landau (GL) model via a small order parameter expansion in Bardeen–Cooper–Schrieffer theory of superconductivity, the derivation was carried to next-to-leading order in that parameter and its spatial derivatives. The aim was to obtain a generalized GL free energy that approximates the microscopic model better. Since 1960s, multiple works have claimed or implicitly assumed that this extended GL model corresponds to the free energy and has solutions in the form of local minima describing superconductivity, such as vortex solutions. In contrast to this, we prove that this extended GL functional does not represent free energy since it does not have any solutions in the form of minima. Accordingly, it cannot be used to describe superconducting states.

Entanglement entropy in multi-leg Kitaev ladders with interface defects

The entanglement of different parts of a quantum system is expected to be proportional to the common interface area. Therefore alterations across the interface will lead to changes on the behavior of entanglement entropy. In this work, the effects of bond defects at the boundaries of Kitaev ladders are considered. We find a logarithmic scaling for the ground state entanglement entropy between the two pieces. The prefactor of the logarithm (effective central charge (ECC)) varies continuously with the defect strength. The energy dispersion is also obtained and sharp features in the von Neumann entanglement entropy are observed when bands cross. Phase diagrams for homogeneous Kitaev Hamiltonians with nonzero superconducting paring potential are presented. They show that for chains/legs that are connected to one another through inter-leg hopping, when certain parameters are fine-tuned, the phase transition lines correspond to either single or double gapless modes dispersion. Moreover, even when the defect is turned on, the ECC for ladders with two gapless modes is exactly twice the one for ladders with a single gapless mode. On the other hand, in the absence of superconductivity, we can tune the parameters to obtain homogeneous systems whose number of gapless modes is up to the number of legs of the ladder. Additionally, in this situation, the presence of the bond defect makes the ECC becomes smaller than the number of gapless modes times the ECC of Hamiltonians with one gapless mode. Furthermore, the relationship between the cases with and without superconductivity is presented.

Hydrazine intercalated iron sulfide (N2H4)1-xFe2+δS2: Synthesis and characterization

The discovery of superconductivity in anti-PbO-type FeS has attracted great interest in the intercalation compounds of FeS. However, it is much more difficult to synthesize intercalates of FeS than to synthesize intercalates of FeSe. Here, we report a novel intercalation compound of FeS with chemical composition of (N2H4)1-xFe2+δS2 (x ​~ ​0.25, δ ​~ ​0.1), which is synthesized via a combination of self-flux solid state method and hydrothermal route. The successful intercalation of hydrazine was confirmed by X-ray diffraction, thermogravimetric analyses and attenuated total internal reflection-Fourier transform infrared spectroscopy, while the maintenance of anti-PbO-type FeS layer in the structure was verified by transmission electron microscopy and Raman spectroscopy. Magnetic and resistivity measurements show that (N2H4)1-xFe2+δS2 is a ferromagnetic metal rather than a superconductor. The low-temperature ferromagnetism may be caused by the intercalated hydrazine molecules or interlayer iron ions and the absence of superconductivity should be closely related to the ferromagnetic ordering.

Electronic properties and interfacial coupling in Pb islands on single-crystalline graphene

Introducing metal thin films on two-dimensional (2D) material may present a system to possess exotic properties due to reduced dimensionality and interfacial effects. We deposit Pb islands on single-crystalline graphene on a Ge(110) substrate and studied the nano- and atomic-scale structures and low-energy electronic excitations with scanning tunneling microscopy/spectroscopy (STM/STS). Robust quantum well states (QWSs) are observed in Pb(111) islands and their oscillation with film thickness reveals the isolation of free electrons in Pb from the graphene substrate. The spectroscopic characteristics of QWSs are consistent with the band structure of a free-standing Pb(111) film. The weak interface coupling is further evidenced by the absence of superconductivity in graphene in close proximity to the superconducting Pb islands. Accordingly, the Pb(111) islands on graphene/Ge(110) are free-standing in nature, showing very weak electronic coupling to the substrate.

NaOH-Intercalated Iron Chalcogenides (Na1-xOH)Fe1-yX (X = Se, S): Ion-Exchange Synthesis and Physical Properties.

The discovery of the (Li1-xFexOH)FeSe superconductor has aroused significant interest in metal hydroxide-intercalated iron chalcogenides. However, all efforts made to intercalate NaOH between FeSe and FeS layers have failed so far. Here we report two NaOH-intercalated iron chalcogenides (Na1-xOH)Fe1-yX (X = Se, S) that were synthesized by a low-temperature hydrothermal ion-exchange method. Their crystal structures were solved through single-crystal X-ray diffraction and refined against powder X-ray and neutron diffraction data. Different from the (Li1-xFexOH)FeX superconductors that crystallize in a tetragonal space group P4/nmm with Z = 2, (Na1-xOH)Fe1-yX belong to an orthorhombic space group Cmma with Z = 4. The structural solution also reveals that there are vacancies in both Na and Fe sites and there are not iron ions in the (Na1-xOH) layer. This is probably why both Fe(II) and Fe(III) species exist in the title compounds, as detected by X-ray photoelectron spectroscopy. Based on magnetization and electrical resistivity measurements, the two compounds were found to be paramagnetic semiconductors. The absence of superconductivity should be closely related to the iron vacancies in the Fe1-yX layer. Theoretical calculations suggest that inducing superconductivity in (Na1-xOH)Fe1-ySe is promising due to the similarity of the electronic structures between stoichiometric (NaOH)FeSe and the (Li1-xFexOH)FeSe superconductor.

NMR Evidence of Antiferromagnetic Spin Fluctuations in Nd0.85Sr0.15NiO2 Supported by the National Natural Science Foundation of China (Grant Nos. 51872328, 11674392, 11774401, and A0402/11927809), the National Key R&D Program of China (Grant Nos. 2016YFA0300504 and 2016YFA0300401), China Postdoctoral Science Foundation (Grant No. 2020M680797), the Fundamental Research Funds for the Central Universities, and the Research Funds of Renmin University of China

Despite the recent discovery of superconductivity in Nd1–x Sr x NiO2 thin films, the absence of superconductivity and antiferromagnetism in their bulk materials remains a puzzle. Here we report the 1H NMR measurements on powdered Nd0.85Sr0.15NiO2 samples by taking advantage of the enriched proton concentration after hydrogen annealing. We find a large full width at half maximum of the spectrum, which keeps increasing with decreasing the temperature T and exhibits an upturn behavior at low temperatures. The spin-lattice relaxation rate is strongly enhanced when lowering the temperature, developing a broad peak at about 40 K, then decreases following a spin-wave-like behavior at lower temperatures. These results evidence a short-range glassy antiferromagnetic ordering of magnetic moments below 40 K and dominant antiferromagnetic fluctuations extending to much higher temperatures. Our findings reveal the strong electron correlations in bulk Nd0.85Sr0.15NiO2, and shed light on the mechanism of superconductivity observed in films of nickelates.

Absence of Superconductivity in the Hubbard Dimer Model for κ-(BEDT-TTF)2X

In the most studied family of organic superconductors κ-(BEDT-TTF)2X, the BEDT-TTF molecules that make up the conducting planes are coupled as dimers. For some anions X, an antiferromagnetic insulator is found at low temperatures adjacent to superconductivity. With an average of one hole carrier per dimer, the BEDT-TTF band is effectively 12-filled. Numerous theories have suggested that fluctuations of the magnetic order can drive superconducting pairing in these models, even as direct calculations of superconducting pairing in monomer 12-filled band models find no superconductivity. Here, we present accurate zero-temperature Density Matrix Renormalization Group (DMRG) calculations of a dimerized lattice with one hole per dimer. While we do find an antiferromagnetic state in our results, we find no evidence for superconducting pairing. This further demonstrates that magnetic fluctuations in the effective 12-filled band approach do not drive superconductivity in these and related materials.

Electronic correlations and absence of superconductivity in the collapsed phase of LaFe2As2

The interplay between structural phase and electronic correlations has been an intriguing topic of research. An prominent example is the pressure-induced uncollapsed to collapsed tetragonal phase transition observed in CaFe$_2$As$_2$, which is accompanied with the emergence of superconductivity in the collapsed phase. Recently, a very similar structural phase transition was discovered in LaFe$_2$As$_2$, but in contrast to CaFe$_2$As$_2$, superconductivity was only observed in the uncollapsed phase, not the collapsed phase. Previous studies have attributed this puzzling observation to the differences in the two materials' band coherence, orbital occupation, and Fermi surface topology. Here, we present a comparative study of LaFe$_2$As$_2$ and CaFe$_2$As$_2$ using the DFT+DMFT method. Surprisingly, we find that although La appears to have a valence higher than Ca, the doped one electron actually primarily resides on the La site. This leads to almost the same total Fe-$3d$ occupancy and electronic correlation strength as well as similar Lifshiftz transition in the Fermi surface topology for the two materials. In addition, we show that the two materials in both structural phases belong to the category of Hund's metals. Our results indicate that the electronic structures of LaFe$_2$As$_2$ and CaFe$_2$As$_2$ are not too different, which further suggest that superconductivity might also be induced in the collapsed phase of LaFe$_2$As$_2$ under similar non-hydrostatic conditions as for CaFe$_2$As$_2$.

The Effects of Oxygen Vatcancies on Electrical and Magnetic Properties of LaOBiSSe

LaO1−xBiSSe polycrystalline samples were successfully synthesized by conventional solid-state reaction method. The effects of oxygen vacancies on the crystal structure, magnetic properties under atmospheric and high pressure, and electrical property of LaOBiSSe were investigated. Polycrystalline samples LaO1−xBiSSe with x = 0–0.1 were well indexed to the tetragonal CeOBiS2-type structure with the space group P4/nmm. With increasing oxygen vacancy content, the crystal lattice contracted significantly along the c-axis, the semiconductor behavior was suppressed, and the metal-semiconductor transition temperature decreased, which is a necessary prerequisite for superconductivity in BiCh2-based (Ch = S and Se) system. However, oxygen vacancy level introduced in this work is insufficient to further contract the crystal lattice and increase carrier density. Even though external pressure (~ 1 GPa) was applied, no superconducting transition corresponding to LaO1−xBiSSe appeared except for that of manometer Pb. The reasons for the absence of superconductivity in LaO1−xBiSSe system were discussed.

Backscattering off a driven Rashba impurity at the helical edge

The spin degree of freedom is crucial for both understanding and exploiting the particular properties of the edges of two-dimensional topological insulators. In the absence of superconductivity and magnetism, Rashba coupling is the most relevant single particle perturbation in this system. Since Rashba coupling does not break time reversal symmetry, its influence on transport properties is only visible if processes that do not conserve the single particle energy are included. Paradigmatic examples of such processes are electron-electron interactions and time dependent external drivings. We analyze the effects of a periodically driven Rashba impurity at the helical edge, in the presence of electron-electron interactions. Interactions are treated by means of bosonization and the backscattering current is computed perturbatively up to second order in the impurity strength. We show that the backscattering current is non-monotonic in the driving frequency. This property is a fingerprint of the Rashba impurity, being absent in the case of a magnetic impurity in the helical liquid. Moreover, the non-monotonic behaviour allows us to directly link the backscattering current to the Luttinger parameter $K$, encoding the strength of electron-electron interactions.