In the present work, thermodynamics of the new black hole solutions to the four-dimensional Einstein–Maxwell-dilaton gravity theory have been studied. The dilaton potential, as the solution to the scalar field equations, has been constructed out by a linear combination of three Liouville-type potentials. Three new classes of charged dilatonic black hole solutions, as the exact solutions to the coupled equations of gravitational, electromagnetic and scalar fields, have been introduced. The conserved charge and mass of the new black holes have been calculated by utilizing Gauss's electric law and Abbott–Deser mass proposal, respectively. Also, the temperature, entropy and the electric potential of these new classes of charged dilatonic black holes have been calculated, making use of the geometrical approaches. Through a Smarr-type mass formula, the intensive parameters of the black holes have been calculated and validity of the first law of black hole thermodynamics has been confirmed. A thermal stability or phase transition analysis has been performed, making use of the canonical ensemble method. The heat capacity of the new black holes has been calculated and the points of type one- and type two-phase transitions as well as the ranges at which the new charged dilatonic black holes are locally stable have been determined, precisely.
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