57Fe Mossbauer effect measurements have been performed on single crystals of57Fe doped GdBa2Cu3O7-δ at various c-axis orientations and temperatures. The analysis of the data yields information on the sign and direction of Vzz, the direction of Bhf with respect to Vzz and the anisotropy of the f-factor for the individual observed three quadrupole doublets. From these data we conclude that the quadrupole doublet with ΔEQ ≃1.9 mm/s is due to Fe on a regular Cu(1)-site (4-fold oxygen coordination) with distorted local symmetry (Vzz isnot parallel to the c-axis), while the other quadrupole doublets have higher oxygen coordinations (higher Lamb-Mossbauer-factor).