316L Austenitic Stainless Steel Research Articles

Hydrogen-enhanced densified deformation twins in 304L austenitic stainless steel fabricated by selective laser melting

Twin boundaries are the preferred site for crack nucleation and propagation in a hydrogen-rich environment. The relationship among hydrogen, cellular structure, and deformation twins is significant in further enhancing the resistance to hydrogen embrittlement of austenitic stainless steels produced by SLM. It has been demonstrated that cellular structures with high dislocation densities play a positive role in increasing stress above a critical level for deformation twin formation. The cellular structure affects the distribution of hydrogen, with hydrogen presence at cellular boundaries reducing its accumulation at grain boundaries. Hydrogen increases the density of deformation twins and reduces the thickness of individual deformation twins. This phenomenon can be attributed to an increase in nucleation sites for the deformation twin, which is closely related to the decrease in stacking fault energy and the increase in dislocation density caused by hydrogen. Both cellular structure and deformation twins play a positive role in improving the hydrogen embrittlement resistance of austenitic stainless steels.

Microstructural Characteristics and Properties of Wire Arc Additive Manufactured 304L Austenitic Stainless Steel Cylindrical Components by Different Arc Welding Processes

Wire arc additive manufacturing (WAAM) is an advanced additive manufacturing (AM) technology that offers low cost and high deposition rates, making it suitable for building large metal parts for structural engineering applications. However, various welding procedures result in differing heat inputs and repetitive heating treatments throughout the deposition process, which can affect the microstructural and mechanical characteristics of the parts. In the current study, cylindrical parts made of 304L austenitic stainless steel (ASS) were manufactured using the WAAM technique, employing both gas metal arc welding (GMAW) and cold metal transfer (CMT) processes. This study explores the correlation between WAAM techniques and their effects on the bead geometry, microstructure and mechanical properties. The microstructure of the cylinders consisted of vertically growing austenite dendrites with residual ferrite (μ) within the austenite (γ) matrix. Compared to the bottom region (region ①), the top region (region ②) contained more residual ferrite. Although the microstructural characteristics from region ① to region ② are similar, they exhibit different ferrite morphologies. The rapid cooling rate in the CMT-AM process resulted in finer structures and a greater presence of ferrite phases in both regions compared to the GMAW-AM method. Cylinders produced by the CMT process displayed nearly uniform properties across both regions and demonstrated superior tensile properties, hardness, and impact toughness relative to those made using the GMAW technique. The WAAM 304L ASS cylinders also showed enhanced performance compared to stainless steel manufactured using traditional industrial forging standards, indicating that WAAM-processed 304L ASS cylinders are suitable for industrial applications.

Hydrogen-induced softening and embrittlement in 316L stainless steel fabricated using laser-powder bed fusion

To investigate the effects of hydrogen (H) on the mechanical properties of 316L austenitic stainless steel (316L) additively manufactured using laser-powder bed fusion (L-PBF), tensile, nanoindentation, and micropillar compression tests were performed on samples in both the as-built (AB) and H-charged (HC) conditions. Microstructural characterization revealed that the electrochemical H charging exerted marginal effects on grains, phases, and overall dislocation densities of L-PBF 316L. However, the dislocation networks inherent to L-PBF 316L appear to disentangle upon H charging and are distributed more homogeneously through the matrix. Mechanical test results showed that H charging results in a marginal reduction in hardness and strength, indicating H-induced softening, possibly due to the elastic shielding effects of H that weaken the interactions between dislocations. The elastic shielding effect and the enhanced slip planarity, facilitate the H accumulation along slip bands and twins, promote H-enhanced localized plasticity, resulting cracking when a critical H concentration is reached. This, in turn, aids in H embrittlement mechanism that results in a significant loss in ductility upon H charging. A detailed discussion of all these micromechanisms is presented.

Developing statistical tools to analyze historical stress-controlled fatigue data in additively manufactured austenitic stainless steel

The development of robust fatigue property data sets for additively manufactured 316L austenitic stainless steels is hindered by the small sample sizes, inconsistent reporting of material properties and processing conditions, and differences in testing procedures for current sources of testing data. By applying standardization and categorization protocols to account for these shortcomings, historical data sets were aggregated into a single large data set and analyzed in greater detail, providing new levels of insight into the stress-controlled fatigue behavior of additively manufactured materials. Using this single aggregated data set, scatter was quantified using an eigenvalue analysis, and a multi-variable statistical model for predicting the mean fatigue life was developed. Interactions between variables and the sensitivity to different loading conditions were then identified, with the scatter in the data being attributed to differences in testing and post-processing condition such as surface condition and heat treatment, and the model was used to identify the role that each variable plays in determining fatigue life. An analysis of the fatigue responses across the aggregated data set using clustering algorithms allowed two distinct trends to be identified and attributed to the differing roles of microstructure and porosity on the resulting fatigue lives across different equivalent stress amplitude ranges.

Study on Corrosion Fatigue Behavior of 304L Austenite Stainless Steel in 325 °C High-Temperature Water Environment

The fatigue crack growth behavior of 304L austenitic stainless steel (SS) in a 325 °C high-temperature and high-pressure water environment were investigated by a corrosion fatigue test system, by electron back scatter diffraction (EBSD), and by a transmission electron microscope (TEM). The experimental results indicated that the crack growth rate (CGR) of 304L SS increases with increasing the stress intensity factor, stress level, and fatigue frequency (f). Compared to dissolved hydrogen (DH) in a high-temperature water environment, dissolved oxygen (DO) significantly enhances the CGR by about an order of magnitude higher. The crack tip of 304L SS after the corrosion fatigue test under higher stress levels is sharper, with more secondary cracks on the fracture surface, while the crack tip under lower stress levels is blunter with relatively fewer secondary cracks. The oxidation behavior at the crack tip was analyzed under different loading and water chemistry conditions, and a related effect on the crack tip and CGR was clarified.

Investigations on corrosion behavior of 316LN and 316L austenitic stainless steel under corrosion-deformation interactions

Investigations on corrosion behavior of 316LN and 316L austenitic stainless steel under corrosion-deformation interactions

Solidification behavior and texture of 316L austenitic stainless steel by laser wire directed energy deposition

The solidification behavior and crystallographic texture of 316L austenitic stainless steel builds fabricated via laser-wire directed energy deposition additive manufacturing (AM) were investigated. Shielding gas set-up and build type (single-track vs. multi-track) were varied, which led to changes in the solidification conditions and the final build compositions. Primary δ-ferrite solidification is predicted based on equilibrium thermodynamic predictions of the bulk feedstock composition. However, the increased solidification velocity of the AM process promotes a solidification mode transition from primary δ-ferrite to primary austenite. Skeletal δ-ferrite and lathy δ-ferrite associated with primary δ-ferrite solidification and interdendritic δ-ferrite associated with primary austenite solidification were observed among the laser-wire directed energy deposition walls. Skeletal and interdendritic δ-ferrite exhibited a (001)δ // (001)γ parallel relationship with austenite and a {001} solidification texture aligned with the build direction for both austenite and δ-ferrite. Lathy δ-ferrite exhibited a Kurdjumov-Sachs orientation relationship, (101)δ//(11¯1)γ, with austenite due to austenite nucleation in the solid-state. It is shown that the solidification behavior of AM 316L is accurately represented by as-built composition data and a dendrite growth model, which combined, encompasses the compositional and solidification condition impacts on the solidification pathway.

Tensile and micro-compression behaviour of AISI 316L austenitic stainless steel single crystals at 20 °C and 300 °C: Experiments, modelling and simulations

The mechanical behaviour of 316L stainless steel single crystal is characterised at room temperature and 300°C. Elasticity moduli at room temperature are obtained with resonant ultrasound spectroscopy. Their dependence on temperature is calibrated with molecular dynamics simulations. The plastic behaviour is characterised by tensile tests on millimetre-sized single crystal specimens and compression tests on micrometre-sized single crystal specimens. A constitutive model of crystal plasticity based on dislocation density hardening at finite strains is developed and implemented in an open-source material subroutine compatible with several finite element (FE) and fast Fourier transform (FFT) solvers. Tensile curves at room temperature and 300°C are used to calibrate the interaction coefficients for self and coplanar dislocation interactions. The dislocation mean free path for obstacle dislocations and the annihilation distance are also calibrated. The calibrated model predicts tensile curves in excellent agreement with experimental data. In addition, the predicted plastic strain fields are in good agreement with the experimental fields obtained by digital image correlation. Semi-quantitative agreement between simulation and experimental data is obtained for micro-compression tests without further calibration of the model. Finally, an extension to polycrystals with grain size effects is finally proposed. The predicted strain hardening behaviour is compared with experimental data on stainless steel polycrystals.

Evaluation of microstructure, corrosion resistance performance, and mechanical properties of 316L austenitic stainless steel FCAW welded joints: a comparative study

ABSTRACT This research aims to not only examine the effect of different mixtures of Ar and CO2 on microstructural features and corrosion behavior of double-pass FCAW of 316L SS but also compare these characteristics with gas tungsten arc welding (GTAW) and self-shielded FCAW. Different shielding gas mixtures, namely 100%Ar, 100%CO2, 82%Ar+18%CO2 were used to make the specimens. All specimens represent biphasic microstructures containing austenite (Ɣ) and delta-ferrite (δ-ferrite). Based on the potentiodynamic (PD) test results, the anti-corrosion protection performance of the welded region was enhanced when using GTAW compared to self-shielded FCAW. Additionally, the impedance value of the GTAW joint was higher than that of the FCAW-welded specimens. The ductility of welded joints was ranked as GTAW > CO2 +Ar shielded FCAW > self-shielded FCAW > CO2 shielded FCAW. The ranking of transverse tensile strength was as follows: CO2 shielded FCAW> self-shielded FCAW > CO2+ Ar shielded FCAW> GTAW.

Design of Heterogeneous Lamella Microstructure of 316L Austenitic Stainless Steel and Effect of Aging on Its Mechanical Behavior and Corrosion Properties

316L austenitic stainless steel (ASS) with a heterogeneous structure exhibits favorable mechanical properties at room temperature, promising excellent application potential. However, the thermal stability of 316L ASS with heterogeneous lamella structure (HLS) has not been adequately addressed yet. Herein, an HLS of 316L ASS is fabricated through 78% cold rolling followed by annealing at 750 °C for 13 min. The detailed investigation focuses on the influence of microstructure evolution on the mechanical properties and corrosion resistance of the alloy after aging at temperatures ranging from 350 to 550 °C for 100 h. The results show that a notable quantity of residual martensite persists even after annealing at high temperatures for a brief duration. The dislocation density of the test steel is reduced after long‐term aging treatment, and the residual martensite is further reversed into austenite during aging. In addition, the aging treatment also promotes further growth of nanocrystalline/ultrafine‐grained, which weakens the heterogeneous characteristics of HLS 316L ASS, resulting in a slight decrease in mechanical properties. However, the decrease in defect density and the enhancement of recrystallization degree are beneficial for eliminating most of the corrosion‐sensitive areas in the cold‐deformed structure, thereby improving the corrosion resistance.

Unraveling the effects of nano-grained microstructure on mechanical behavior, corrosion, and in vitro biocompatibility of 316L austenitic stainless steel

Nanograins are often beneficial in achieving better cytocompatibility for metallic implants. In this work, we have achieved grains from the micro to nano range in 316L austenitic stainless steel by a combination of cryo-rolling (50%, 70%, and 90% thickness reduction) followed by annealing (750–1000 °C for 2–20 min). The combined effect of grain refinement along with texture on its mechanical, corrosion, and in vitro cellular behavior was thoroughly investigated. Microstructural observations revealed nanograins formation (grain size = 144 nm) only for the 90CRA sample, whereas grain refinement in the micron range was observed for 0-70CRA samples. Electron backscatter diffraction (EBSD) studies showed fully austenitic structures for all the annealed samples while low Kernel Average Misorientation (KAM) values indicated strain-free microstructures. Orientation distribution function (ODF) maps showed the presence of strong γ-fiber (<111>||ND) and weak α-fiber (<110>||ND) in the 90CRA sample. The grain refinement led to an increase in the yield strength and ultimate tensile strength from 470.6 ± 16.21 MPa and 858.35 ± 31.82 MPa (0CRA) to 1662.06 ± 58.44 MPa and 2112.3 ± 51.62 MPa (90CRA), respectively. The potentiodynamic polarization study revealed that the corrosion rate of the 90CRA sample was about eight times less than that of the 0CRA sample. This was further corroborated by Mott-Schottky analysis, which showed a lowering of both acceptor and donor densities with the reduction in grain size. The evolution of a strong <111> texture during cryo-rolling contributed towards enhanced corrosion resistance of nano-grained 316L. Furthermore, grain refinement improved wettability, which in turn led to better cell proliferation and differentiation. At all culture days, MC3T3-E1 cell proliferation and differentiation were considerably higher for nano-grained 316L micron-sized counterparts. Thus, grain refinement to the nano range is an effective technique for the property enhancement of biomedical implants.

Processing-microstructure relationships in ferrous alloys via mixed powder laser powder bed fusion

Three different approaches to control the phase formation in powder bed fusion - laser beam (PBF-LB) printing using a powder mixture of duplex stainless steel (DSS) 2507 and austenitic stainless steel 316L were examined: (i) in situ solid state reheating, (ii) utilization of an island scan strategy, and (iii) switching process parameters between layers of a build. Analytical modeling was used to determine the time-temperature profiles during each of these processes, and was combined with thermodynamic simulations through Thermo-Calc to predict and explain the phase formation measured experimentally. It was found that the reheating from additional layers was critical to the nucleation of austenite, even with the increased Ni content in powder mixtures. This was evident in the island scan strategy prints where the corners of the islands showed significantly less austenite (∼45%) as compared to the centers of the islands (∼96%), as well as in the multi-layer samples where alternating laser power for fixed chemical composition of powder mixture resulted in varying content from ∼75% (lower power) to ∼90% (higher power). Additionally, in situ reheating using a lower power laser was capable of minimally increasing the austenite content layer-by-layer, by raising the temperature of the layer above the nucleation temperature of austenite. These results showcase the capability of PBF-LB to manipulate phase structure in ways not possible through traditional manufacturing techniques, as well as the ability of Thermo-Calc to accurately predict the trends observed that can be applied to other alloy systems.

Evaluation of the Corrosion Resistance of Watch Links from 316L and 904L Austenitic Stainless Steels Obtained by the Metal Injection Molding (MIM) Technique Intended to Be in Contact with Human Skin

Watchmaking manufacturers obtain their bracelet links from machining drawn metal profiles. But, today, there is another process that represents an alternative to manufacture them: metal injection molding using metal powders (MIM technology). This process is less expensive than the machining of drawn metal profiles. The aim of this study was to evaluate the corrosion behavior and the nickel cation release of two stainless steel alloys: 316L MIM and 904L MIM. The general corrosion behavior was evaluated by the rotating electrode technique; the galvanic corrosion measurements were conducted with a 316L AISI bulk coupling partner. The pitting corrosion behavior was evaluated in FeCl3 0.5 M media (according to ASTM G48-11). For comparison, a complementary study was conducted on 316L and 904L bulk alloys. The Ni cation release tests were conducted on 316L and 904L MIM and bulk samples according to EN 1811. Different electrochemical parameters were measured and calculated (open circuit potential, polarization resistance, corrosion current and Tafel slopes, coulometric analysis). Generally, if MIM steels are compared with conventional steels, their corrosion resistance behavior is inferior. In the couplings studied, the galvanic currents generated are very important. The shape of the curves also reveals the presence of localized corrosion phenomena. According to tests in ferric chloride, MIM steels were noted to have inferior behavior compared to conventional steels. MIM type 904L steels are comparable in behavior to conventional type 316L steels. The quantities of nickel released according to EN 1811 were very significant (2 mg cm−2 week−1 up to 24 mg cm−2 week−1) and did not meet the requirements of the European directive (0.5 µg cm−2 week−1). In conclusion, conventional steels studied under the same experimental conditions revealed a better behavior compared to MIM steels independently of the phenomenological parameters chosen.

Experimental Investigation into the Dry Reciprocating Wear Behavior of Additively Manufactured Austenitic Stainless Steel (316L) Alloys

Experimental Investigation into the Dry Reciprocating Wear Behavior of Additively Manufactured Austenitic Stainless Steel (316L) Alloys

The Formability and Mechanical Properties of 316L Stainless Steel Fabricated by Pulsed Arc Swing Additive Manufacturing

An austenitic stainless steel 316L deposition specimen is fabricated by cold metal transfer‐based swing arc additive manufacturing (CMT‐SAAM), and its formation, microstructure, and tensile properties are investigated. The results showed that the 316L deposited samples exhibited a multi‐layer structure with a small aspect ratio, and the surface forming accuracy is improved with the increase in the swing amplitude. The remelted zone near the interface is dominated by long grains perpendicular to the fusion line, whereas the deposited zone is dominated by columnar dendrites and shows an &lt;100&gt; orientation. Along the building and transverse direction of the swing deposits, the microhardness distribution is uniform. Compared with rollings and forgings, 316L deposited by using the CMT‐SAAM method has both a higher strength and toughness. The average ultimate tensile strength is 573 MPa, and the elongation at break is 52.6%. The high strength and toughness of 316L specimens are attributed to the fine microstructure, high‐density dislocations, and low‐angle grain boundaries (LAGBs) generated during the CMT‐SAAM process.

Temperature dependence of tensile mechanical properties and work hardening behavior in direct laser deposited austenitic stainless steel 316L

Austenitic stainless steel 316 L is widely used in various industries due to its good mechanical properties at elevated temperatures (up to 600 °C), excellent corrosion resistance, and relatively low cost. However, there is lack on investigations of high-temperature properties of direct laser deposited (DLD) 316 L alloy. In the present investigation, tensile tests were performed at temperatures ranging from 20 to 1000 °C to study the effect of temperature on mechanical properties and work hardening behaviour. It was found that DLD-processed 316 L alloy has minor anisotropy of mechanical properties and work hardening behaviour at elevated temperatures higher than 200 °C. A gradual decrease in yield stress accompanied by a slight altering of ductility in the temperature range between 200 °C and 700 °C is caused by the dynamic strain ageing effect. At higher temperatures, a rapid decrease in mechanical properties is observed. Strength properties of the DLD alloy are lower in comparison with selective laser melted alloy but higher than those of wrought alloy up to 900 °C. Stress-strain curves of the material has shown stage-by-stage work hardening behaviour, depending on the test temperature. Dilatometric tests revealed a linear increase in the coefficient of thermal expansion (CTE) during heating up to 670 °C for the longitudinal sample and up to 770 °C for the transverse one. Then a non-linear growth of the CTE was observed due to diffusion-controlled transformation of the delta-ferrite to austenite.

Scratch Response of Hollow Cathode Radiofrequency Plasma-Nitrided and Sintered 316L Austenitic Stainless Steel

Low-temperature plasma nitriding is a thermochemical surface treatment that promotes surface hardening and wear resistance enhancement without compromising the corrosion resistance of sintered austenitic stainless steels. Hollow cathode radiofrequency (RF) plasma nitriding was conducted to evaluate the influence of the working pressure and nitriding time on the microstructure and thickness of the nitrided layers. A group of samples of sintered 316L austenitic stainless steel were plasma-nitrided at 400 °C for 4 h, varying the working pressure from 160 to 25 Pa, and the other group was treated at the same temperature, varying the nitriding time (2 h and 4 h) while keeping the pressure at 25 Pa. A higher pressure resulted in a thinner, non-homogeneous nitrided layer with an edge effect. Regardless of the nitriding duration, the lowest pressure (25 Pa) promoted the formation of a homogenously nitrided layer composed of nitrogen-expanded austenite that was free of iron or chromium nitride and harder and more scratching-wear-resistant than the soft steel substrate.

Novel role of thermomechanical grain boundary engineering in the microstructure evolution of austenitic stainless steel

The effect of special grain boundary development via the grain boundary engineering process (GBE) was explored in a bimodal microstructured 316L austenitic stainless steel with an average grain size of 1.92 μm. The GBE process was carried out by the rolling-annealing method via two routes of low and medium applied strain, followed by a short annealing period in a single-step and iterative manner. The grain boundary character distribution was obtained by Electron Backscatter Diffraction (EBSD) analysis, and the intergranular corrosion resistance and the tensile behavior of the samples were examined. Microstructural characterization showed that applying low strain repetitively increased the coincidence site lattice (CSL) and Σ3 boundaries percentage and created large twin-related domains (TRD). The reduced sensitization was attributed to a high proportion of CSLs and large-sized TRDs by applying a low-strain route. In the early stages of the low-strain route, the grain boundary character distribution showed a high number of primary twin nuclei in coarse grains and a continuous network of single twin nuclei in smaller grains, creating a high percentage of Σ3-grain boundaries. The low applied strain and the absence of the necessary driving force for the recrystallization and GBs migration led to the formation of twin nuclei, which would assist with the reduction of microstructure energy. A high percentage of Σ3 boundaries and an increase in the percentage of triple points consisting of low energy boundaries were found to be influential factors in increasing elongation.

Fabrication and characterization of zirconium oxide coating on tubular steel by metal organic decomposition

In fusion reactor blankets, multifunctional ceramic coatings fabricated on structural materials have been investigated for tritium permeation reduction, electrical insulation, and corrosion protection. However, it has been challenging to manufacture a homogeneous coating on the complicated components in the blanket breeder, such as ducts. In terms of sustainable development, it is crucial to establish a ceramic coating technique on the inner walls of fuel pipes in liquid blanket systems. In this study, we applied the metal organic decomposition method to fabricate zirconium oxide coatings on 316L austenitic stainless steel tubes and characterized their properties as liquid tritium breeding pipes. Homogeneous zirconium oxide coatings with a thickness of 395 ± 12 nm have formed on the inner walls of SS316L tubes. The compatibility of the coated tubes with liquid lithium-lead was examined under static and flowing conditions at 550–600 °C for prolonged exposure of up to 2000 h. Under static conditions, ZrO2 coatings demonstrated exceptional compatibility with the liquid Li-Pb as they protected structural material from corrosion. At a flow rate of 0.16 m/s, the coatings were partly delaminated due to different thermal expansion coefficients of the coating and substrate and acceleration under a dynamic system. The coating thickness increased up to 650 ± 26 nm after exposure for 2000 h, which indicated ZrO2 coatings reacted with Li-Pb to form corrosion products. Besides, ZrO2 coatings achieved the insulating requirements of magnetohydrodynamic insulators as their electrical resistivities were on the order of 104–106 Ω m at the temperature range of 250–550 °C.

Numerical fracture toughness evaluation of SS316L CT specimens using an Elastic Plastic Fracture Mechanics (EPFM) approach

In this study, fracture toughness was determined using an elastic-plastic fracture mechanics approach via numerical simulation. The material chosen for study is austenitic stainless steel 316L, which is extensively used in the nuclear industry for core internal structures. Three different SS316L conditions were considered for the analysis, including welded and post-weld heat-treated conditions aged at 300 °C for 10,000 hours (over-aged) and at 400 °C for 5,000 hours (peak-aged). A compact tension (CT) specimen of standard dimensions, which was taken from ASTM E1820–01, was used to perform the analysis. The J-integral value that is obtained for those three conditions was compared with the base material, which was taken from the open literature. It was found that theJ-integral values of SS 316L for welded conditions were lower than the base material. Also, J-integral values of SS 316L for the two post-weld heat-treated conditions were found to be greater than the weldments but less than the base material. It can also be noted that the values obtained for the SS316L weldments and the post-weld heat-treated sample aged at 335 °C for 10,000 hours were notably similar.