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Modelling the degradation of acidic and alkaline printing paper

Abstract There has always been an interest in the professional communities of libraries, archives and conservation science to find ways of estimating the rate of degradation of paper under archival conservation conditions. Previously we reported a number of considerations for developing a kinetic degradation model based on Whatman no.1 paper. In the present research, this model was extended to 10 different papers and validated. Various physical and chemical properties of acidic, neutral, and alkaline papers were measured, such as the degree of polymerization (DP), tensile strength, equilibrium moisture content (EMC), and pH, as well as alkaline reserve when applicable. The activation energy (Ea) based on DP of cellulose and zero-span tensile strength were determined. Ea and pH had the most significant influence on the simulated decay of paper. Papers with a high Ea (> 120 kJ mol-1), alkaline such as those containing at least 2% CaCO3, and acidic –but good printing quality papers made of bleached chemical pulp– were found the most durable in ambient conditions. Papers with a lower Ea (< 110 kJ mol-1) such as lignocellulosic papers containing significant amount of mechanical pulp were much less stable over time. Whatman filter papers, used as models of pure cellulosic papers, were found to have low Ea despite the good quality cotton fibers. A generic isoperm equation based on Ea was developed to predict the changes in the state of papers under various climatic conditions, and was applicable independently of the pH of the paper. The model developed allows a better quantification of the deterioration rate of printing papers such as those that are currently, and will be in the future, found in our archival collections.

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Looking Forward

The essays in this book reveal the remarkable pace of change in heritage conservationHeritage conservation theory and practice since World War II and especially in the last two decades. Each chapter focuses on a specific topic relevant to current practice, difficult topics with no easy solutions: Historic Urban LandscapesHistoric urban landscapes, intangible heritageIntangible heritage, view protection, cultural landscapesCultural landscapes, sustainabilitySustainability, heritage communicationHeritage communication, wind turbines, the cultural value of nature, climate changeClimate change, reconstructionReconstruction and tourism. In the early 1990s, three important developments in the implementation of the World HeritageWorld Heritage Convention introduced a global dialogue that prepared the ground for this change. The framework for cultural landscapesCultural landscapes paved the way for sites with associated intangible values, the Nara DocumentNara Document on authenticity built the foundation for a new vision of conservationConservation doctrine, and the Global Strategy for a balanced, representative and credible World HeritageWorld Heritage List enlarged the scope beyond historical, aesthetic and scientific values to take into account new perspectives. These three achievements are indicators of a paradigm shift in conservation theoryConservation theory and practice that subsequently unfolded in the twenty-first century. By this time, heritage conservationHeritage conservation practitioners were aware that they were operating in silos, and that heritage doctrine and practice needed to change. The most urgent issues that emerged concerned the construction of values, the implications of applying a cultural landscapesCultural landscapes approach to site management and the expanded reach of heritage.

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