The reported {RuIII2LnIII2} complexes are well-defended with both experimental and computational studies, and serve as an excellent illustration of how to enhance the 4d–4f magnetic interaction and increase the anisotropic barrier of 4d–4f-based SMMs.

Ru species-decorated hierarchical Nb 2 O 5− x was successfully constructed, where Ru species promoted water dissociation to provide sufficient protons, thereby steering the reaction pathway toward CH 4 with high selectivity.

The synthesis route and assembly of positive and negative electrodes.

Stable trinuclear “double sandwich” complexes of mercury( ii ) porphyrins with linear Hg 3 cores have been stabilized successfully, revealing unusual structures and properties and displaying strong mercurophilic interactions.

NaOH-induced in situ crystallization of EMT nanocrystals within GO layers forms Si–O–C crosslinks and expands interlayer spacing, creating multilayer ion-storage channels that synergistically enhance Cs + /Sr 2+ adsorption.

Compositional-gradient ZnS/GeS 2 heterojunctions constructed by Kirkendall-driven interdiffusion enable strong interfacial coupling and fast ion/electron transport, achieving over 6000 stable cycles at 10 A g −1 as sodium-ion battery anodes.

Orientation of the substituents of the coordinated phosphinate group was experimentally determined for the first time and exchange between its coordinated/non-coordinated oxygen atoms (“phosphinate rotation”) was experimentally/computationally confirmed.

This review summarizes recent advances in catalyst design, reaction mechanisms, and paired-electrolysis systems of the electrocatalytic upcycling of polyethylene terephthalate, highlighting the potential for efficient plastic valorization.

Synergistic integration of [SO 3 NH 2 ] and [C(NH 2 ) 3 ] via small heteroatom substitution balances properties. α-C(NH 2 ) 3 SO 3 NH 2 ( P 2 1 / c : 190 nm, 0.068@546 nm) and β-C(NH 2 ) 3 SO 3 NH 2 ( Iba 2: 190 nm, 1.41 × KDP, 0.074@546 nm) were successfully synthesized.

S,V co-doping modulates the local microenvironment of Ni 2 P, significantly enhancing HER/OER kinetics to achieve efficient and corrosion-resistant overall water splitting.