Zweikernige und dreikernige Carbonyleisenkomplexe mit 1.2-und 1.3-Dithiolatobrückenliganden / Dinuclear and Trinuclear Carbonyliron Complexes Containing 1,2-and 1,3-Dithiolato Bridging Ligands

Abstract

The reactions of 1,2- and 1,3-dithioles, HSRSH, with Fo3(CO)12 give the dinuclear compounds Fe2(CO)6(SRS) in good yields. With R = C2H4 or R = C3H6 the trinuclear compounds (CO)3Fe(SRS)Fe(CO)(SRS)Fe(CO)3 containing an open Fe3 chain are obtained.