Abstract
By pressure fluorination in monel autoklaves samples of LiCuCoF6 (rutile type structure), LiMgCoF6, LiNiCoF6 and LiZnCoF6 (trirutile type structure), LiCdCoF6, LiCaCoF6, LiCaNiF6 and LiSrNiF6 (LiCaAlF6-type [2] structure), LiSrCoF6 (LiSrFeF6-type structure [3]) and LiBaCoF6 (LiBaCrF6-type structure [4]) were synthesised for the first time. The Madelung Part of Lattice Energie, MAPLE, is studied and discussed. By magnetic measurements we obtained new information on the structure of fluorotrirutile.
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