Abstract

On the Oligomerization of Cyclic Alkenes in the Presence of Zirconium‐containing Catalytic SystemsIn connection with investigations on olefin metathesis we studied the reaction of cyclic olefins C5C8 and C12 in the presence of zirconium‐containing catalytic systems in the homogeneous liquid phase.The influence of different zirconium compounds on the reaction run off and on the distribution of the reaction products was examined in the presence and the absence of Lewis acids.The reaction products could be separated and identified by a combination of distillation, chromatographical, chemical and spectrometrical methods. The results show that under the conditions mentioned a metathetic polymerization and a normal olefin oligomerization take place simultaneously.

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