Abstract
Molecule Linkage by Sulfur Chlorides. V. The Addition Reaction of Dichlorosulfane with Allyl‐phenyl‐ethers. A Synthesis for 3‐Chloromethyl‐2,3‐dihydro‐benz‐1,4‐oxathiines via Intramolecular SulfenylationIntermediates in the reaction of dichlorosulfane (sulfur dichloride) with allylphenyl‐ethers are sulfenyl chlorides (1:1 adducts). The sulfenyl chlorides with anti‐Markovnikov‐structure cyclize at the activated aromatic nucleus via intramolecular sulfenylation to 3‐chloromethyl‐2,3‐dihydro‐benz‐1,4‐oxathiines.
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