Abstract
On the Mechanism of the Photoreduction of Water with Ruthenium‐trisbipyrazil as SensitizerOxidative and reductive primary steps can be differentiated in using Ru(bipy) and Ru(bipz), respectively, as sensitizers in a photochemically induced, Pt‐catalyzed sacrificial water reduction. Experimental evidence for the reductive primary step and kinetic data are given for the electron transfer to methylviologen as relay compound.
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