Zr/HZSM-5 catalyst for NO reduction by C2H2 in lean-burn conditions

Abstract

Abstract Zr-based zeolite catalysts were investigated for the first time in selective catalytic reduction of NO by hydrocarbon (HC-SCR). Highly dispersed zirconium species, especially the amorphous ultrafine zirconium oxide in the catalyst, considerably enhanced the activity for selective catalytic reduction of NO by acetylene (C 2 H 2 -SCR), both by accelerating the NO oxidation to NO 2 and enlarging the NO 2 adsorption capacity of the catalyst under the reaction conditions. Thus a durable and active Zr/HZSM-5 catalyst giving 89% of NO conversion to N 2 at 350 °C in 1600 ppm NO, 800 ppm C 2 H 2 , and 9.95% O 2 in helium was obtained. For the C 2 H 2 -SCR of NO, it was suggested that acidic sites with strong acidity on the Zr-based HZSM-5 catalysts are indispensable to initiate the aimed reaction via the route of NO oxidation to NO 2 , which explains the higher activity for the reaction obtained over the Zr/HZSM-5 catalyst sample with lower SiO 2 /Al 2 O 3 ratio. The zirconium species could only functioned in the presence of protons in the C 2 H 2 -SCR of NO, so a synergistic effect between the zirconium species and protons of the Zr/HZSM-5 catalyst was proposed.