Zone drawn NEW‐TPI thermoplastic polyimide and its blends with Xydar liquid crystalline polymer

Abstract

AbstractIn this work we report the effects of single stage zone drawing on the properties of NEW‐TPI thermoplastic polyimide homopolymer, and its blends with Amoco's Xydar liquid crystalline polymer. Zone drawing was performed first on homopolymer NEW‐TPI films to determine the effect of load weight, heater speed, and drawing temperature on the attainable draw ratio. Degree of crystallinity and chain orientation increase as the draw ratio increases for NEW‐TPI. Blends of NEW‐TPI/Xydar compositions 90/10 and 70/30 were studied next. In blends, the Xydar component is not molecularly dispersed, and is initially preferentially oriented along the machine direction during the film processing stage. Xydar acts as a nucleation site and lowers the temperature for crystallization of the NEW‐TPI from the rubbery amorphous state. Zone drawing was performed either parallel or perpendicular to Xydar's initial preferred orientation direction. Blends with lower Xydar fraction could be zone‐drawn to higher ratios. Zone drawing perpendicular to Xydar's initial orientation direction also resulted in increased draw ratio. Dynamic mechanical properties of the zone drawn materials were studied. In homopolymer NEW‐TPI, dynamic modulus increased by a factor of two to 4.0 GPa in zone drawn films, largely as a result of the formation of oriented crystallites. In the blends, the modulus parallel to Xydar's initial orientation direction was greater than that in the transverse direction. Depending upon composition and test direction, zone drawing increased the dynamic moduli of the blends from 1.5 up to 2.7 times, in the temperature range from 150°C to 300°C.