Zonal Isolation in Reservoir Containing CO2 and H2S

Abstract

Abstract Carbonate reservoirs are often characterized by high pressure and high content of H2S and CO2. For these reasons, drilling the reservoir is the most challenging activity of such fields and long-term zonal isolation across the reservoir section is one of the primary requirements. In the example well considered for this study, the production liner is set at a depth of approximately 4,500 meters and the mud density is 16.2 lb/gal (1.95 g/cc). After a production liner is cemented, the well undergoes several operations such as fluid displacement, casing/liner pressure tests, stimulations, production, and injection; these operations create load on the cement sheath. Carbonation of neat Portland cement systems in CO2 environments is well known in the industry. The carbonation is of significant concern if the CO2 can enter the cemented annulus. The surface area of the cement sheath that contacts CO2 should be minimized to help prevent carbonation. This can be achieved by reducing the permeability, preventing the formation of cracks and micro-annulus, and reducing the components in the cement sheath prone to attack from CO2. To assure long-term sealing properties of the cement sheath during the life of the well, a cement formulation has been developed to be mechanically durable and chemically resistant to aggressive environments. The cement system discussed in this paper was designed to withstand the stresses imposed by changes of pressure regime during the well life by improving elasticity and thus helping prevent damage to the cement sheath. In addition, the potential for carbonation was limited by reducing the components in the slurry formulation that could react with CO2. Mechanical properties and resistance to CO2 environments of the cement system were tested in the laboratory. The cement system was successfully evaluated in the yard test. Cement sheath analysis, slurry design and testing are discussed. The results presented in this work should help in the design and implementation of solutions to contain reservoir fluid and injected fluids, including in the presence of H2S and CO2.