ZnO nanorods decorated with Ag nanoflowers as a recyclable SERS substrate for rapid detection of pesticide residue in multiple-scenes

Abstract

Pesticide residues threaten the ecological environment and human health. Therefore, developing high performance SERS substrate to achieve highly sensitive detection of pesticide residues is meaningful. In this study, based on the strategy of combining “hot spots” engineering and material hybridization, we construct a novel hybrid SERS substrate by depositing Ag nanoflowers (NFs) on ZnO nanorods (NRs). Benefiting from the synergistic effect of electromagnetic enhancement and charge transfer effect, the Ag NFs@ZnO NRs substrate exhibits a low detection limit (10−13 M) for crystal violet molecules. This SERS substrate has good uniformity with a relative standard deviation of 7.463 %. Besides, owning to the photocatalytic property of ZnO NRs, the hybrid substrate can degrade probe molecules after SERS detection and realize recyclability. As a demonstration, we employed our SERS substrate for the trace detection of pesticide residues on apple surface and in river water. This study provides a new idea for improving the SERS performance of hybrid substrates.